[ Objective] The content of total antimony (Sb) in fresh fruit was investigated and its pollution was evaluated, to provide the basic data for diet exposure evaluation. [ Method] The content of total Sb in 194 sampl...[ Objective] The content of total antimony (Sb) in fresh fruit was investigated and its pollution was evaluated, to provide the basic data for diet exposure evaluation. [ Method] The content of total Sb in 194 samples was detected by hydride generation-atomic fluorescence spectrometry (HG-AFS), and the Sb pollution in several fruits was evaluated by the method of single factor pollution index. [ Result ] The mean of total Sb was 0. 005 6 mg/kg, and the median was 0.003 8 mg/kg. The minimum value was not detected while the maximum value was O. 21 mg/kg, and the confidence interval was ND-O. 019 mg/kg (PS-P95). The medi- ans of total Sb content in different fruits successively were dragon fruit (0.011 0 mg/kg) 〉 kiwi fruit (0.008 0 mg/kg) 〉 peach (0.006 0 mg/kg). According to the method of single factor pollution index, the index from all samples was less than 0.2, suggesting that the samples involved were under the normal background value. [ Conclusion ] The Sb was detected in all samples but under the background value, and it was concluded that there was no Sb pollution in fresh fruit in Hunan Province.展开更多
[Objective] The purpose of this paper is paper was to master the spatial and temporal distribution of total antimony content in fresh vegetables in Hu- nan Province. [ Method ] Fresh vegetable samples were collected i...[Objective] The purpose of this paper is paper was to master the spatial and temporal distribution of total antimony content in fresh vegetables in Hu- nan Province. [ Method ] Fresh vegetable samples were collected in 14 areas of Hunan Province and Xikuangshan Street. The content of antimony was detected by Hydride Generation-atomic fluorescence spectrometry. The spatial and temporal distribution of total antimony in fresh vegetables in different areas and seasons were compared. [Result] In 703 vegetable samples, the reference range (P5-195) of total antimony content was ND -0.25mg/kg, and the median was 0. 018 mg/kg; and the median of total antimony content in Xiangtan City and Xikuangshan Street were 0.046 and 0.041 mg/kg respectively, significantly higher than those in other areas. The differences among groups were statistically significant ( P 〈 0. 05 ). The reference range of total antimony content in spring samples was ND -0.24 mg/kg, and the median was 0. 023mg/kg; the reference range of total antimony in autumn samples was ND -0. 088mg/kg, and the median was 0.007 4 mg/kg. [ CondusionJ The reference range of total antimony content in Hunan Province is ND -0.25mg/kg, and the median is 0.018 mg/kg. The con- tent of total antimony content in Xiangtan City and Xikiangshan Street is higher. And the total antimony content in spring samples are higher than those in autumn samples.展开更多
目的掌握湖南不同地区居民总锑的膳食暴露水平及地理分布趋势。方法收集2014—2016年湖南省14地州市食品样品1 586份,样品取可食部分切碎、粉碎(匀浆)、混匀后称取试样0.5~1 g(精确至0.001 g)于微波消解罐内,加4 m L浓硝酸和2 m L 30%...目的掌握湖南不同地区居民总锑的膳食暴露水平及地理分布趋势。方法收集2014—2016年湖南省14地州市食品样品1 586份,样品取可食部分切碎、粉碎(匀浆)、混匀后称取试样0.5~1 g(精确至0.001 g)于微波消解罐内,加4 m L浓硝酸和2 m L 30%过氧化氢,放置30 min后,密闭旋紧内罐置于微波炉内,调节升温程序进行消解,其消解液采用AFS-230E型双道原子荧光光度计进行荧光强度测定,通过标准曲线法计算样品中总锑含量。将食品中锑含量×居民食物每日摄入量/标准人体重,计算得出各地区居民每人每日单位体重锑的平均膳食暴露量(居民食物摄入量数据源自《湖南省常住居民营养与健康状况现状分析》)。再取每个地区中心位置的经度和纬度值作为坐标值(x,y),使用Suffer 8.0软件把拟合的最优趋势方程得出的各地区居民锑的膳食暴露趋势数据和坐标数据,绘制趋势分析等值线图,分析其地理分布趋势特征。结果湖南各区域食品中总锑含量中位数由高到低分别为湘中(0.021 0 mg/kg)、湘北(0.009 2 mg/kg)、湘东(0.009 0 mg/kg)、湘南(0.007 8 mg/kg)和湘西(0.007 7 mg/kg)。湘东、湘南、湘中、湘西和湘北地区的居民锑膳食平均暴露量分别为1.19、0.90、0.75、0.55、0.40μg/(kg·BW)。结论湖南东部地区居民膳食锑的暴露量明显偏高,并且在湘东、湘中地区均有高峰值出现,其他区域都处于一个相对较低范围。展开更多
基金Supported by Scientific Research Project of Medicine and Health Care in Hunan Province(B2014-162)Scientific Research Project of Xiangtan Science and Technology Bureau(SF20141003)
文摘[ Objective] The content of total antimony (Sb) in fresh fruit was investigated and its pollution was evaluated, to provide the basic data for diet exposure evaluation. [ Method] The content of total Sb in 194 samples was detected by hydride generation-atomic fluorescence spectrometry (HG-AFS), and the Sb pollution in several fruits was evaluated by the method of single factor pollution index. [ Result ] The mean of total Sb was 0. 005 6 mg/kg, and the median was 0.003 8 mg/kg. The minimum value was not detected while the maximum value was O. 21 mg/kg, and the confidence interval was ND-O. 019 mg/kg (PS-P95). The medi- ans of total Sb content in different fruits successively were dragon fruit (0.011 0 mg/kg) 〉 kiwi fruit (0.008 0 mg/kg) 〉 peach (0.006 0 mg/kg). According to the method of single factor pollution index, the index from all samples was less than 0.2, suggesting that the samples involved were under the normal background value. [ Conclusion ] The Sb was detected in all samples but under the background value, and it was concluded that there was no Sb pollution in fresh fruit in Hunan Province.
基金Supported by Scientific Research Project of Medicine and Health Care in Hunan Province(B2014-162)Scientific Research Project of Xiangtan Science and Technology Bureau(SF20141003)
文摘[Objective] The purpose of this paper is paper was to master the spatial and temporal distribution of total antimony content in fresh vegetables in Hu- nan Province. [ Method ] Fresh vegetable samples were collected in 14 areas of Hunan Province and Xikuangshan Street. The content of antimony was detected by Hydride Generation-atomic fluorescence spectrometry. The spatial and temporal distribution of total antimony in fresh vegetables in different areas and seasons were compared. [Result] In 703 vegetable samples, the reference range (P5-195) of total antimony content was ND -0.25mg/kg, and the median was 0. 018 mg/kg; and the median of total antimony content in Xiangtan City and Xikuangshan Street were 0.046 and 0.041 mg/kg respectively, significantly higher than those in other areas. The differences among groups were statistically significant ( P 〈 0. 05 ). The reference range of total antimony content in spring samples was ND -0.24 mg/kg, and the median was 0. 023mg/kg; the reference range of total antimony in autumn samples was ND -0. 088mg/kg, and the median was 0.007 4 mg/kg. [ CondusionJ The reference range of total antimony content in Hunan Province is ND -0.25mg/kg, and the median is 0.018 mg/kg. The con- tent of total antimony content in Xiangtan City and Xikiangshan Street is higher. And the total antimony content in spring samples are higher than those in autumn samples.