Fracture network types revealed by well test curves for shale reservoirs in the Sichuan Basin,China

Pressure buildup testing can be used to analyze fracture network characteristics and conduct quantitative interpretation of relevant parameters for shale gas wells,thus providing bases for assessing the well productivity and formulating proper development strategies.This study establishes a new well test interpretation model for fractured horizontal wells based on seepage mechanisms of shale reservoirs and proposes a method for identifying fracturing patterns based on the characteristic slopes of pressure buildup curves and curve combination patterns.The pressure buildup curve patterns are identified to represent three types of shale reservoirs in the Sichuan Basin,namely the moderately deep shale reservoirs with high pressure,deep shale reservoirs with ultra-high pressure,and moderately deep shale reservoirs with normal pressure.Based on this,the relationship between the typical pressure buildup curve patterns and the fracture network types are put forward.Fracturing effects of three types of shale gas reservoir are compared and analyzed.The results show that typical flow patterns of shale reservoirs include bilinear flow in primary and secondary fractures,linear flow in secondary fractures,bilinear flow in secondary fractures and matrix,and linear flow in matrix.The fracture network characteristics can be determined using the characteristic slopes of pressure buildup curves and curve combinations.The linear flow in early secondary fractures is increasingly distinct with an increase in primary fracture conductivity.Moreover,the bilinear flow in secondary fractures and matrix and the subsequent linear flow in the matrix occur as the propping and density of secondary fractures increase.The increase in the burial depth,in-situ stress,and stress difference corresponds to a decrease in the propping of primary fractures that expand along different directions in the shale gas wells in the Sichuan Basin.Four pressure buildup curve patterns exist in the Sichuan Basin and its periphery.The pattern of pressure buildup curves of shale reservoirs in the Yongchuan area can be described as 1/2/→1/4,indicating limited stimulated reservoir volume,poorly propped secondary fractures,and the forming of primary fractures that extend only to certain directions.The pressure buildup curves of shale reservoirs in the main block of the Fuling area show a pattern of 1/4/→1/2 or 1/2,indicating greater stimulated reservoir volume,well propped secondary fractures,and the forming of complex fracture networks.The pattern of pressure buildup curves of shale reservoirs in the Pingqiao area is 1/2/→1/4→/1/2,indicating a fracturing effect somewhere between that of the Fuling and Yongchuan areas.For reservoirs with normal pressure,it is difficult to determine fracture network characteristics from pressure buildup curves due to insufficient formation energy and limited liquid drainage.

Horizontal Well Interference Performance and Water Injection Huff and Puff Effect on Well Groups with Complex Fracture Networks:A Numerical Study

Well interference has become a common phenomenon with the increasing scale of horizontal well fracturing.Recent studies on well interference in horizontal wells do not properly reflect the physical model of the postfracturing well groups and the realistic fracturing process of infill wells.Establishing the correspondence between well interference causative factors and manifestations is of great significance for infill well deployment and secondary oil recovery.In this work,we develop a numerical model that considers low velocity non-Darcy seepage inshale reservoirs to study the inter-well interferencephenomenon that occurs in theSantanghufield,andconstruct an explicit hydraulic fracture and complex natural fracture network model with an embedded discrete fracture model,focusing on the effect of fracture network morphology on well interactions.The model also considers a multi-segment wellbore model to accommodate the effect of inter-well crossflow on wellbore tubular flow.The changes in formation pressure and water saturation during fracturing are performed by controlling the injection pressure and water injection rate.The result shows that the shape of the fracture network generated by the infill well with the old well determines the subsequent fluid and oil-increasing performance of the disturbed well.The synergistic production or competitive relationship formed by fractures with different connectivity between the two wells determines the positive and negative effects of the interference.The paper also investigates the adaptation study of water injection huff and puff schemes for well groups with different connectivity,and demonstrated a potential yield increase of up to 10.85%under adaptation injection.This method of identifying well interference based on the production dynamics of affected wells and the subsequent corresponding water injection method provides valuable references for the selection of secondary oil recovery measures.

Fluorine-Doped High-Performance Li_(6)PS_(5)Cl Electrolyte by Lithium Fluoride Nanoparticles for All-Solid-State Lithium-Metal Batteries

All-solid-state lithium-metal batteries(ASSLMBs)are widely considered as the ultimately advanced lithium batteries owing to their improved energy density and enhanced safety features.Among various solid electrolytes,sulfide solid electrolyte(SSE)Li_(6)PS_(5)Cl has garnered significant attention.However,its application is limited by its poor cyclability and low critical current density(CCD).In this study,we introduce a novel approach to enhance the performance of Li_(6)PS_(5)Cl by doping it with fluorine,using lithium fluoride nanoparticles(LiFs)as the doping precursor.The F-doped electrolyte Li_(6)PS_(5)Cl-0.2LiF(nano)shows a doubled CCD,from 0.5 to 1.0 mA/cm^(2) without compromising the ionic conductivity;in fact,conductivity is enhanced from 2.82 to 3.30 mS/cm,contrary to the typical performance decline seen in conventionally doped Li_(6)PS_(5)Cl electrolytes.In symmetric Li|SSE|Li cells,the lifetime of Li_(6)PS_(5)Cl-0.2LiF(nano)is 4 times longer than that of Li_(6)PS_(5)Cl,achieving 1500 h vs.371 h under a charging/discharging current density of 0.2 mA/cm^(2).In Li|SSE|LiNbO_(3)@NCM721 full cells,which are tested under a cycling rate of 0.1 C at 30℃,the lifetime of Li_(6)PS_(5)Cl-0.2LiF(nano)is four times that of Li_(6)PS_(5)Cl,reaching 100 cycles vs.26 cycles.Therefore,the doping of nano-LiF off ers a promising approach to developing high-performance Li_(6)PS_(5)Cl for ASSLMBs.

A universal performance-enhancing method for Li-S batteries:the cathode material of Li_(2)S@Li_(2)S_(2)@Li_(2)S_(6) double-shell structure

Lithium sulfide(Li_(2)S)as a cathode material for lithium-sulfur(Li-S)batteries,one of the most promising advanced batteries in the future,has received tremendous attention in the past decades.However,developing the practical Li_(2)S cathode confronts challenges of low conductivity for Li-ions and electrons,high sensitivity to environmental moisture,big overpotential barrier to electrochemical activation,and poor cyclability due to the shuttle effect of intermediate species.This article herein reports a simple and effective strategy for making Li_(2)S@Li_(2)S_(2)@Li_(2)S_(6) double-shelled microparticles,which can significantly mitigate these problems.They are synthesized by dissolving Li2S together with S in dimethoxyethane,then drying off the solvent,and finally calcining the collected solid.Compared with pure Li_(2)S,such a double-shell material presents a 26.7% improvement in cycling capacity,0.5 V lower in activation overpotential,and prolonged tolerance in the ambient environment.The density functional theory calculation shows that the performance enhancement lies in the higher stability of Li2S6in contact with moisture and some autocatalytic effect of Li_(2)S_(2)@Li_(2)S_(6).Such a double-shell structure becomes a universal performanceenhancing approach when being combined with other means,such as cathodes composited with catalytic MoS_(2),separators modified with selenium-doped sulfurized-polyacrylonitrile/montmorillonite,electrolytes containing fluorenone additive,and Li anodes coated with a layer of Li_(3)N.The corresponding capacity retention shows up to 80%improvement compared with pure Li_(2)S.