Fluid property identification of the Lower Cretaceous reservoirs with complex oil-water contacts in Deseo Basin,Chad

Recently,exploration breakthroughs have been made in the Lower Cretaceous sandstone reservoirs in the Doseo Basin,but the identification of reservoir fluid property is difficult due to variable reservoir lithology,complex oil-water contact within and faint responses of the oil zone,which causes the lower accuracy of reservoir fluid property identification with conventional mudlogging and wirelogging techniques.Applying the geochemical logging,fluorescent logging,mud logging and cutting logging technology,in combination with formation test data,this paper distinguishes the crude oil types,analyzes the logging response characteristics of oil zone after water washing,and establishes the interpretation charts and parameter standards for reservoir fluid properties.The crude oil can be divided into two types,namely viscous-heavy and thin-light,based on total hydrocarbon content and component concentration tested by mud logging,features of pyrolysis gas chromatogram and fluorescence spectroscopy.The general characteristics of oil layers experienced water washing include the decrease of total hydrocarbon content and component concentration from mud logging,the decrease of S1 and PS values from geochemical logging,the decrease of hydrocarbon abundance and absence of some light components in pyrolysis gas chromatogram,and the decrease of fluorescence area and intensity from fluorescence logging.According to crude oil types,the cross plots of S1 versus peak-baseline ratio,and the cross plots of rock wettability versus fluorescence area ratio are drawn and used to interpret reservoir fluid property.Meanwhile,the standards of reservoir fluid parameter are established combining with the parameters of PS and the parameters in above charts,and comprehensive multiparameter correlation in both vertical and horizontal ways is also performed to interpret reservoir fluid property.The application in the Doseo Basin achieved great success,improving interpretation ability of fluid property in the reservoir with complex oil-water contact,and also provided technical reference for the efficient exploration and development of similar reservoirs.

Estimation of Summer Rainfall over an Arid Area using AMSR-E Measurements:A Case Study in Xinjiang,China

Rainfall estimate in arid region using passive microwave remote sensing techniques has been a complex issue for some time.The main reason for this difficulty is that the high and variable emissivity of land surfaces greatly aggravates the complexity of the signatures from the rain cloud.The Xinjiang area,located in the northwest of China,holds all the typical characteristics of arid climate.A rainfall algorithm has been developed for this region by using the Advanced Microwave Scanning Radiometer for Earth Observing System(AMSR-E) measurements.The algorithm attempts to use all 12 chan-nels on the AMSR-E instrument and a two-step method calibrated over 11 days of hourly rain-gauge data.First,Stepwise Discriminant Analysis(SDA) used to optimally estimate rain pixels based on all 12 channels,although only three channels were found to be necessary.Next,a rain predicator scattering index was used to estimate rain rates.A linear relationship between the rain rates and the scattering index above the threshold of 3.0K was constructed with a simple approximately linear function.The estimated rain rates were compared with the rain-gauge data used to calibrate the method,and a good relationship was found with a root-mean-square error of 2.1mm/h.The numerical calculations and comparisons show that the algorithm works well in the Xinjiang area.

Dynamic downscaling of near-surface air temperature at the basin scale using WRF-a case study in the Heihe River Basin, China

The spatial resolution of general circulation models （GCMs） is too coarse to represent regional climate variations at the regional, basin, and local scales required for many environmental modeling and impact assessments. Weather research and forecasting model （WRF） is a nextgeneration, fully compressible, Euler non-hydrostatic mesoscale forecast model with a runtime hydrostatic option. This model is useful for downscaling weather and climate at the scales from one kilometer to thousands of kilometers, and is useful for deriving meteorological parameters required for hydrological simulation too. The objective of this paper is to validate WRF simulating 5 km/ 1 h air temperatures by daily observed data of China Meteorological Administration （CMA） stations, and by hourly in-situ data of the Watershed Allied Telemetry Experimental Research Project. The daily validation shows that the WRF simulation has good agreement with the observed data; the R2 between the WRF simulation and each station is more than 0.93; the absolute of meanbias error （MBE） for each station is less than 2℃; and the MBEs of Ejina, Mazongshan and Alxa stations are near zero, with R2 is more than 0.98, which can be taken as an unbiased estimation. The hourly validation shows that the WRF simulation can capture the basic trend of observed data, the MBE of each site is approximately 2℃, the R2 of each site is more than 0.80, with the highest at 0.95, and the computed and observed surface air temperature series show a significantly similar trend.

On Water： Free Catalysis Approach for the Synthesis of Nitrones from Hydroxamic Acids and Dimethy/ Diethyl Acetylenedicarboxylate

Benzohydroxamic acid reacts with dimethyl acetylenedicarboxylate in the presence of 10 mol% NaOAc to gen- erate （E）-N-（1,4-dimethoxy-l,4-dioxobutan-2-ylidene）-l-phenylcarboxamide oxide in good-to-excellent yield in water at room temperature for 2 h, which supplies a simple, efficient and environmentally friendly method to syn- thesize a wide range of nitrones. The benefits of this strategy not only conform to the requirment of green chemisty, but also possess atom economy.

Simulation of FY-2D infrared brightness temperature and sensitivity analysis to the errors of WRF simulated cloud variables

This study simulated FY-2 D satellite infrared brightness images based on the WRF and RTTOV models. The effects of prediction errors in WRF micro-and macroscale cloud variables on FY-2 D infrared brightness temperature accuracy were analyzed. The principle findings were as follows. In the T+0–48 h simulation time, the root mean square errors of the simulated brightness temperatures were within the range 10–27 K, i.e., better than the range of 20–40 K achieved previously. In the T+0–24 h simulation time, the correlation coefficients between the simulated and measured brightness temperatures for all four channels were >0.5. The simulation performance of water channel IR3 was stable and the best. The four types of cloud microphysical scheme considered all showed that the simulated values of brightness temperature in clouds were too high and that the distributions of cloud systems were incomplete, especially in typhoon areas. The performance of the THOM scheme was considered best, followed in descending order by the WSM6, WDM6, and LIN schemes. Compared with observed values, the maximum deviation appeared in the range 253–273 K for all schemes. On the microscale, the snow water mixing ratio of the THOM scheme was much bigger than that of the other schemes. Improving the production efficiency or increasing the availability of solid water in the cloud microphysical scheme would provide slight benefit for brightness temperature simulations. On the macroscale, the cloud amount obtained by the scheme used in this study was small. Improving the diagnostic scheme for cloud amount, especially high-level cloud, could improve the accuracy of brightness temperature simulations. These results could provide an intuitive reference for forecasters and constitute technical support for the creation of simulated brightness temperature images for the FY-4 satellite.