FCC dry gas contains a large amount of ethylene. It is used by most of the refineries in China as fuel or simply burned in atmosphere. Few refineries make good use of the dry gas, so the precious ethylene resource in ...FCC dry gas contains a large amount of ethylene. It is used by most of the refineries in China as fuel or simply burned in atmosphere. Few refineries make good use of the dry gas, so the precious ethylene resource in the dry gas is wasted. In this article, the possibility of catalytic conversion of ethylene to C3, C4, and some high molecular weight hydrocarbons in a fixed bed micro-reactor using LTB-1 catalyst, with pure ethylene as feedstock was studied. Effects of reaction temperature, reaction pressure, and feedstock flow rate, on the conversion of ethylene and the distribution of products were investigated to determine the proper reaction parameters to be used in practice. Good results indicate that this study may provide a new way of using the ethylene resource in the FCC dry gas.展开更多
The flow dynamics in a novel fast-turbulent fluidized bed (FTFB) with middle-upper expanding structure and two different ring-feeder internals (mixed and vortex ring-feeder) were studied to achieve a reduction in ...The flow dynamics in a novel fast-turbulent fluidized bed (FTFB) with middle-upper expanding structure and two different ring-feeder internals (mixed and vortex ring-feeder) were studied to achieve a reduction in gasoline olefin production, Compared with a conventional circulating fluidized bed, the novel FTFB displayed unique characteristics and advantages. A higher solids holdup and more uniform solids holdup distribution existed in the diameter-expanding region, especially for the FTFB with vortex ring-feeder structure, A probability density distribution analysis indicated that the novel fluidized bed could reduce gas-solids segregation and enhance gas-solids interaction. A constant carbon dioxide tracer system was used to simulate the reactant gas distribution. The gas-solids contact efficiency was defined according to the solid dispersibility and the amount of gas covering the solid surface. Novel FTFB risers, especially those with vortex ring-feeders, have a much higher gas-solids contact efficiency than that of traditional risers.展开更多
文摘FCC dry gas contains a large amount of ethylene. It is used by most of the refineries in China as fuel or simply burned in atmosphere. Few refineries make good use of the dry gas, so the precious ethylene resource in the dry gas is wasted. In this article, the possibility of catalytic conversion of ethylene to C3, C4, and some high molecular weight hydrocarbons in a fixed bed micro-reactor using LTB-1 catalyst, with pure ethylene as feedstock was studied. Effects of reaction temperature, reaction pressure, and feedstock flow rate, on the conversion of ethylene and the distribution of products were investigated to determine the proper reaction parameters to be used in practice. Good results indicate that this study may provide a new way of using the ethylene resource in the FCC dry gas.
基金the financial support of the CNPC in the National Program on Key Basic Research Project(973 Program) of China(No.2012CB215000)
文摘The flow dynamics in a novel fast-turbulent fluidized bed (FTFB) with middle-upper expanding structure and two different ring-feeder internals (mixed and vortex ring-feeder) were studied to achieve a reduction in gasoline olefin production, Compared with a conventional circulating fluidized bed, the novel FTFB displayed unique characteristics and advantages. A higher solids holdup and more uniform solids holdup distribution existed in the diameter-expanding region, especially for the FTFB with vortex ring-feeder structure, A probability density distribution analysis indicated that the novel fluidized bed could reduce gas-solids segregation and enhance gas-solids interaction. A constant carbon dioxide tracer system was used to simulate the reactant gas distribution. The gas-solids contact efficiency was defined according to the solid dispersibility and the amount of gas covering the solid surface. Novel FTFB risers, especially those with vortex ring-feeders, have a much higher gas-solids contact efficiency than that of traditional risers.