Patent-based technological developments and surfactants application of lithium-ion batteries fire-extinguishing agent

While newer,more efficient Lithium-ion batteries(LIBs)and extinguishing agents have been developed to reduce the occurrence of thermal runaway accidents,there is still a scarcity of research focused on the application of surfactants in different LIBs extinguishing agents,particularly in terms of patented technologies.The aim of this review paper is to provide an overview of the technological progress of LIBs and LIBs extinguishing agents in terms of patents in Korea,Japan,Europe,the United States,China,etc.The initial part of this review paper is sort out LIBs technology development in different regions.In addition,to compare LIBs extinguishing agent progress and challenges of liquid,solid,combination of multiple,and microencapsulated.The subsequent section of this review focuses on an in-depth analysis dedicated to the efficiency and challenges faced by the surfactants corresponding design principles of LIBs extinguishing agents,such as nonionic and anionic surfactants.A total of 451,760 LIBs-related patent and 20 LIBs-fire-extinguishing agent-related patent were included in the analyses.The extinguishing effect,cooling performance,and anti-recombustion on different agents have been highlighted.After a comprehensive comparison of these agents,this review suggests that temperature-sensitive hydrogel extinguishing agent is ideal for the effective control of LIBs fire.The progress and challenges of surfactants have been extensively examined,focusing on key factors such as surface activity,thermal stability,foaming properties,environmental friendliness,and electrical conductivity.Moreover,it is crucial to emphasize that the selection of a suitable surfactant must align with the extinguishing strategy of the extinguishing agent for optimal firefighting effectiveness.

A review of fire-extinguishing agent on suppressing lithium-ion batteries fire

Safety issue of lithium-ion batteries(LIBs)such as fires and explosions is a significant challenge for their large scale applications.Considering the continuously increased battery energy density and wider large-scale battery pack applications,the possibility of LIBs fire significantly increases.Because of the fast burning and the easy re-ignition characteristics of LIBs,achieving an efficient and prompt LIBs fire suppression is critical for minimizing the fire hazards.Different from conventional fire hazards,the LIBs fire shows complicated and comprehensive characteristics,and an effective and suitable fire-extinguishing agent particularly designed for LIBs is highly desirable.Considerable efforts have been devoted to this topic,to the best of our knowledge,a comprehensive review on this regard is still rare.Moreover,in practice,a guidance for the design and selections of a proper fire-extinguishing agent for LIBs is urgently needed.Herein,the special mechanisms and characteristics for LIBs fire and the corresponding design principles for LIBs fire-extinguishing agent were introduced.It is revealed that a fire-extinguishing agent developed for LIBs fire will most likely need a high heat capacity,high wetting,low viscosity and low electrical conductivity.After a comprehensive comparison of these agents in terms of these performances,water-based fire-extinguishing agents show best.Several typical fire-extinguishing agents such as gaseous agents,dry powders,water-based and aerosol fire-extinguishing agents were then introduced,and their fire extinguishment mechanisms were presented.Finally,their effectiveness in suppressing the fire were summarized.Water-based fire-extinguishing agents possess high cooling capacity and excellent anti-reflash performance for the fire.We believe this review could shed light on developing an efficient fire-extinguishing agent particularly designed for LIBs.

Mechanical Response of Honeycomb Structures Under Impact

A honeycomb structure with a negative Poisson’s ratio(NPR)was designed,fabricated,and analyzed for utilization in personal protective clothing(PPC).The mechanical properties were investigated using a quasi-static mechanical testing and the Hopkinson pressure bar experimental system,and results were compared with similar samples containing regular hexagonal and regular quadrilateral honeycomb structures.The experimental results showed that under quasi-static loadings,the concave honeycomb structure had the highest compressive modulus and yield strength,which produced the highest strain absorption energy,anti-deformation performance and energy absorption.When exposed to a dynamic load at a high strain rate,the concave honeycomb also exhibited the highest dynamic compression modulus,the best impact resistance and best energy absorption among the three structures.In summary,the concave honeycomb structure was more resistant to deformation and had higher impact resistance than the regular hexagonal and regular quadrilateral honeycombs,and exhibited better energy absorption,which makes it a good candidate for application as a personal safety protection material.

Investigations on Structured Polyamide for Laser Sintered Body Armor

Stab resistance body armor（SRBA）is essential in protecting people from knife injuries.The protective parts of traditional SRBA are made of multi-layered ultra-high molecular weight polyethylene（UHMWPE）,which causes heavy heat stress for people wearing it.The protective parts of SRBA manufactured using laser sintering（LS）3D printing technology provide high manufacturing flexibility and low weight.Two different structures,plain plate and pyramid-structured plate,were investigated.The pyramid structure showed much higher stab resistance property then the plain plate,because of the angle and thickness effects.This is the first effort applying the LS technology and polyamide（PA）material（PA3200）on SRBA.By applying the pyramid structure on the protective layer of the SRBA,the total weight could reduce 30%-40%.

Quantitative Method of the Structural Damage Identification of Gas Explosion Based on Case Study:The Shanxi “11. 23” Explosion Investigation

In order to present a retrospective analysis of exposition accidents using input data from investigation processes,data from a specific accident was examined,in which we analyzed possible involved gas species（ liquefied petroleum gas; nature gas） and computed their concentrations and distributions based on the interactions between the structures and the effects of the explosion. In this study,5 scenarios were created to analyze the impact effect. Moreover,a coupling algorithm was put into practice,with a practical outflow boundary and joint strength are applied. Finally,the damage effects of each scenario were simulated. Our experimental results showed significant differences in the 5 scenarios concerning the damage effects on the building structures. The results from scenario 3 agree with the accident characteristics,demonstrating the effectiveness of our proposed modeling method. Our proposed method reflects gas properties,species and the concentration and distribution,and the simulated results validates the root cause,process,and consequences of accidental explosions. Furthermore,this method describes the evolution process of explosions in different building structures. Significantly,our model demonstrates the quantatative explosion effect of factors like gas species,gas volumes,and distributions of gases on explosion results. In this study,a feasible,effective,and quantitative method for structure safety is defined,which is helpful to accelerate the development of safer site regulations.

Large-scale experimental investigation of the effects of gas explosions in underdrains

This study involved the construction and explosion of a large-scale(80-meter-long)underdrain and detailed investigations of the damaging impacts of a gas explosion to provide an experimental foundation for similarity modeling and infrastructural designs.The experiment vividly recreated the scene and explosion damage of the"11.22″explosion accident in Qingdao,China,thus allowing for evaluations of the movements and destruction of the cover plates.The damage mechanism was determined by analyzing the overpressure curves inside and outside the underground canal.It was determined that the cover plates were first lifted by the precursor wave,which induced a maximum overpressure of 0.06 MPa and resulted in explosion venting.The pressure entered the deflagration stage at the end of the explosion.The combustion wave overpressure reached 3.115 MPa close to the initiation point,and had a significant influence on the projectile energy of the cover plates there.Overall,64%of the cover plates were only affected by the precursor wave,while 36%of the cover plates were subjected to both the precursor wave and the combustion wave;these cover plates were severely damaged.The results of this study provide fundamental insights relevant to the prevention and control of underdrain gas explosions.

Controlling Town Industry Explosion Hazard in China

This article introduces industrial safety issues encountered in the towns of China,points out the importance of damage control of industrial explosions and disaster management,and puts forward suggestions on safety design and management intended to reduce the frequency and impact of industrial explosions in Chinese town areas.