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Linear paired electrolysis of furfural to furoic acid at both anode and cathode in a multiple redox mediated system
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作者 xinxin li linchuan Cong +4 位作者 Haibo lin Fangbing liu Xiangxue Fu Hai-Chao Xu Nan lin 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期104-113,共10页
Implementing a new energy-saving electrochemical synthesis system with high commercial value is a strategy of the sustainable development for upgrading the bulk chemicals preparation technology in the future.Here,we r... Implementing a new energy-saving electrochemical synthesis system with high commercial value is a strategy of the sustainable development for upgrading the bulk chemicals preparation technology in the future.Here,we report a multiple redox-mediated linear paired electrolysis system,combining the hydrogen peroxide mediated cathode process with the I2 mediated anode process,and realize the conversion of furfural to furoic acid in both side of the dividedflow cell simultaneously.By reasonably controlling the cathode potential,the undesired water splitting reaction and furfural reduction side reactions are avoided.Under the galvanostatic electrolysis,the two-mediated electrode processes have good compatibility,which reduce the energy consumption by about 22%while improving the electronic efficiency by about 125%.This system provides a green electrochemical synthesis route with commercial prospects. 展开更多
关键词 Multiple redox mediated system Linear paired electrolysis FURFURAL Furoic acid
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Timing and splitting of nitrogen fertilizer supply to increase crop yield and efficiency of nitrogen utilization in a wheat–peanut relay intercropping system in China 被引量:13
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作者 Zhaoxin liu Fang Gao +9 位作者 Yan liu Jianqun Yang Xiaoyu Zhen xinxin li Ying li Jihao Zhao Jinrong li Bichang Qian Dongqing Yang Xiangdong li 《The Crop Journal》 SCIE CAS CSCD 2019年第1期101-112,共12页
Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay interc... Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay intercropping systems are a mainstay of economic and food security in China. We performed a field experiment to investigate the effects of N fertilizer on N recovery efficiency, crop yield, and N loss rate in wheat–peanut relay intercropping systems in the Huang-Huai-Hai Plain, China during 2015–2017. The N was applied on the day before sowing, the jointing stage(G30) or the booting stage(G40) of winter wheat, and the anthesis stage(R1) of peanut in the following percentage splits: 50-50-0-0(N1), 35-35-0-30(N2), and 35-0-35-30(N3), using 300 kg N ha-1, with 0 kg N ha-1(N0) as control. ^(15)N-labeled(20.14 atom %) urea was used to trace the fate of N in microplots. The yields of wheat and peanut increased by 12.4% and 15.4% under the N2 and N3 treatments, relative to those under the N1 treatment. The ^(15)N recovery efficiencies( ^(15)NRE) were 64.9% and 58.1% for treatments N2 and N3, significantly greater than that for the N1 treatment(45.3%). The potential N loss rates for the treatments N2 and N3 were23.7% and 7.0%, significantly lower than that for treatment N1(30.1%). Withholding N supply until the booting stage(N3) did not reduce the wheat grain yield; however, it increased the N content derived from ^(15)N-labeled urea in peanuts, promoted the distribution of ^(15)N to pods, and ultimately increased pod yields in comparison with those obtained by topdressing N at jointing stage(N2). In comparison with N2, the N uptake and N recovery efficiency(NRE) of N3 was increased by 12.0% and 24.1%,respectively, while the apparent N loss decreased by 16.7%. In conclusion, applying N fertilizer with three splits and delaying topdressing fertilization until G40 of winter wheat increased total grain yields and NRE and reduced N loss. This practice could be an environment-friendly N management strategy for wheat–peanut relay intercropping systems in China. 展开更多
关键词 NITROGEN management Wheat–peanut RELAY intercropping system Crop yield NITROGEN recovery EFFICIENCY Apparent N loss
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Computer-aided ionic liquid design for alkane/cycloalkane extractive distillation process 被引量:8
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作者 Zhen Song xinxin li +5 位作者 He Chao Fan Mo Teng Zhou Hongye Cheng lifang Chen Zhiwen Qi 《Green Energy & Environment》 SCIE CSCD 2019年第2期154-165,共12页
A computer-aided ionic liquid design(CAILD) study is presented for the frequently encountered alkane/cycloalkane separations in petrochemical industry. Exhaustive experimental data are first collected to extend the UN... A computer-aided ionic liquid design(CAILD) study is presented for the frequently encountered alkane/cycloalkane separations in petrochemical industry. Exhaustive experimental data are first collected to extend the UNIFAC-IL model for this system, where the proximity effect in alkanes and cycloalkanes is considered specifically by defining distinct groups. The thermodynamic performances of a large number of ILs for 4 different alkane/cycloalkane systems are then compared to select a representative example of such separations. By applying n-heptane/methylcyclohexane extractive distillation as a case study, the CAILD task is cast as a mixed-integer nonlinear programming(MINLP) problem based on the obtained task-specific UNIFAC-IL model and two semi-empirical models for IL physical properties. The top 5 IL candidates determined by solving the MINLP problem are subsequently introduced into Aspen Plus for process simulation and economic analysis, which finally identify 1-hexadecyl-methylpiperidinium tricyanomethane([C_(16)MPip][C(CN)_3]) as the best entrainer for this separation. 展开更多
关键词 CAILD Alkane/cycloalkane extractive DISTILLATION UNIFAC-IL MINLP Process performance and economics
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Novel synthesis of SiO_x/C composite as high-capacity lithium-ion battery anode from silica-carbon binary xerogel 被引量:3
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作者 xinxin li Hebang Shi +2 位作者 liqiang Zhang Jingbo Chen Pengpeng Lü 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第2期579-583,共5页
Micro/nanostructured SiOx/C composite was firstly synthesized by carbothermal reduction of silica-carbon binary xerogel.The homogeneous dispersion feature of the two components in binary xerogel contributes to effecti... Micro/nanostructured SiOx/C composite was firstly synthesized by carbothermal reduction of silica-carbon binary xerogel.The homogeneous dispersion feature of the two components in binary xerogel contributes to effectively carbothermally reduce the O/Si atomic ratio,enhancing the electrochemical activity of the SiOx component.The micron-sized SiOx/C spheres are composed of many near-spherical nanoparticles.The synthesized SiOx/C exhibits a stable and high reversible capacity of 830 m A·h·g^-1 for 100 cycles,and excellent rate-capability.The homogeneous dispersion structure of phases,the micro/nanostructure and the high electrochemical activity of SiOx component combinedly contribute the excellent electrochemical performance. 展开更多
关键词 Sol-gel BINARY XEROGEL Carbothermal reduction Silicon oxide LITHIUM-ION battery ANODE
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Scission of C–O and C–C linkages in lignin over RuRe alloy catalyst 被引量:2
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作者 xinxin li Yangming Ding +6 位作者 Xiaoli Pan Yanan Xing Bo Zhang Xiaoyan liu Yuanlong Tan Hua Wang Changzhi li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第4期492-499,共8页
The performance of lignin depolymerization is basically determined by the interunit C–O and C–C bonds.Numerous C–O bond cleavage strategies have been developed, while the cleavage of C–C bond between the primary a... The performance of lignin depolymerization is basically determined by the interunit C–O and C–C bonds.Numerous C–O bond cleavage strategies have been developed, while the cleavage of C–C bond between the primary aromatic units remains a challenging task due to the high dissociation energy of C–C bond.Herein, a multifunctional Ru Re alloy catalyst was designed, which exhibited exceptional catalytic activity for the cleavage of both C–O and C–C linkages in a broad range of lignin model compounds(β-1, a-5, 5–5,β-O-4, 4-O-5) and two stubborn lignins(kraft lignin and alkaline lignin), affording 97.5% overall yield of monocyclic compounds from model compounds and up to 129% of the maximum theoretical yield of monocyclic products based on C–O bonds cleavage from realistic lignin. Scanning transmission electron microscopy(STEM) characterization showed that Ru Re(1:1) alloy particles with hexagonal close-packed structure were homogeneously dispersed on the support. Quasi-in situ X-ray photoelectron spectroscopy(XPS), and X-ray absorption spectroscopy(XAS) indicate that Ru species were predominantly metallic state, whereas Re species were partially oxidized;meanwhile, there was a strong interaction between Ru and Re, where the electron transfer from Re to Ru was occurred, resulting in great improvement on the capability of C–O and C–C bonds cleavage in lignin conversion. 展开更多
关键词 C–C bonds Ru Re alloy catalyst Lignin depolymerization
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Interventional effect of scorpion venom from Buthus martensii Karsch in Liaoning on somatic pain 被引量:1
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作者 xinxin li Fengzhi Cui 《Neural Regeneration Research》 SCIE CAS CSCD 2006年第2期166-168,共3页
BACKGROUND: Scorpion venom from Buthus martensii Karsch is a kind of protein toxin secreted by scorpion tail. According to records of Pen-ts 'ao Kan-mu, the dried scorpion's body and tail are used as medicine, whic... BACKGROUND: Scorpion venom from Buthus martensii Karsch is a kind of protein toxin secreted by scorpion tail. According to records of Pen-ts 'ao Kan-mu, the dried scorpion's body and tail are used as medicine, which mainly treating rheumatism numbness, pain and convulsion. Some researches consider that scorpion toxin is the main pharmacological active component of the dried scorpion, and it has 4 times stronger analgesic effect on somatic pain than morphine. OBJECTIVE: To observe the interventional effect of scorpion venom of Buthus martensii Karsch analgesic active peptide on somatic pain. DESIGN: A randomized and controlled trial SETTING: Department of Physiology, Shenyang Medical College MATERIALS: Totally 80 Wistar rats (provided by Animal Center of Shenyang Medical College), male and female in half, aged 3 to 4 months, weighed 250 to 350 g, were used in this trial. They were randomly divided into 4 groups: experimental group, control group, morphine group and naloxone group, with 20 in each group. Analgesia active peptide from buthus martensii karsch venom (provided by Biochemical Department of Shenyang Pharmaceutical University, 1 mL/dosage), morphine (produced by Shanghai First Pharmaceutical Manufacturing Plant), naloxone (opium acceptor inhibitor, American Sigma Corporation), AT- AC-350 data-processing machine (Nihon Kohden Corporation), X-Y recording instrument (Nihon Kohden Corporation). METHODS: The experiment was conducted in the Department of Physiology, Shenyang Medical College from July 2003 to July 2005. ① After all the animals were anesthetized, common peroneal nerve is dissected and ligated at middle part. Posterior nucleus group of thalamus (PO) and the tail nuclear were oriented according to G. Paxino rat brain three-dimensional orientation atlas, Glass micro electrode was inserted into PO as guiding electrode, connected with ATAC-350 data-processing machine and X-Y recording instrument, to record the unit evoked potential of PO, taking the evoked potential discharge of the common peroneal nerve of PO as the somatic pain index.② Single square-wave stimulation of intensity 17-19 volt, wave wide 0.2 ms, time delay 20 ms was exerted on common peroneal nerve. The time interval was 5 minutes. X-Y recording instrument was used to draw the graph. 0,002 mg scorpion venom analgesic active peptide was injected into the rats of the experimental group; 0.002 mg normal saline was injected into the rats of the control group through caudate nucleus; 0.002 mg morphine was injected into the rats of morphine group through caudate nucleus; 1.0 mg/kg naloxone was intraperitoneally into the rats of naloxone group, then 0.002 mg scorpion venom was injected into the rats of control group through caudate nucleus.Changes of evoked potential of PO of 3 groups were observed. ③After experiment, 1 μA direct current was given to the guiding electrode and micro electrode , and it lasted for 5 minutes. Pontamine sky blue was used to label the peak of electrode by electrophoresis. Brain tissue was soaked in formalin for 1 week then sliced into 1.0 to 1.5 mm sections. Electrode was orientated according to blue spots. Compared with G . Parino rat brain three-dimensional orientation atlas, we confirmed if the electrode orientation is consistent with PO orientation of G. Parino rat brain three-dimensional orientation atlas. MAIN OUTCOME MEASURES : Changes of the evoked potential of PO in each group RESULTS: Totally 80 Wistar rats were enrolled in this experiment. Four rats in the experimental group and two in the morphine group died of overdose of anesthesia, and finally 74 rats entered the stage of result analysis. The inhibitory action time of evoked potential of PO has no statistical difference in between experiment group and morphine group (P 〉 0.05). The whole inhibitory action time, timeof initiate recovery and time of complete recovery of PO of experiment group were longer than those in the morphine group [(45±0.7), (50±9.2), (65±8.1):(35±7.8). (40±8.9). (50±7.6) min .P 〈 0.05].The change of evoked potential of PO was not obviously in the control group and naloxone group (P 〉 0.05), and the above-mentioned 4 indexes were nearly 0. CONCLUSION: Scorpion venom possesses obviously inhibitory effect on somatic pain, and its inhibitory effect is stronger than that of the same dosage and concentration of morphine. Scorpion venom exerts analgesic effect on somatic pain through opium acceptor. 展开更多
关键词 VENOM LIAONING SOMATIC NALOXONE ANALGESIC injected analgesia endogenous inhib anesthesia
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Absorption Enhancement of Silicon Solar Cell in a Positive-Intrinsic-Negative Junction 被引量:1
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作者 Gen Yue Zhen Deng +9 位作者 Sen Wang Ran Xu xinxin li Ziguang Ma Chunhua Du Lu Wang Yang Jiang Haiqiang Jia Wenxin Wang Hong Chen 《Chinese Physics Letters》 SCIE CAS CSCD 2019年第5期64-66,共3页
Absorption coefficient is a physical parameter to describe electromagnetic energy absorption of materials, which is closely related to solar cells and photodetectors. We grow a series of positive-intrinsic-negative(PI... Absorption coefficient is a physical parameter to describe electromagnetic energy absorption of materials, which is closely related to solar cells and photodetectors. We grow a series of positive-intrinsic-negative(PIN) structures on silicon wafer by a gas source molecule beam epitaxy system and the investigate the absorption coefficient through the photovoltaic processes in detail. It is found that the absorption coefficient is enhanced by one order and can be tuned greatly through the thickness of the intrinsic layer in the PIN structure, which is also demonstrated by the 730-nm-wavelength laser irradiation. These results cannot be explained by the traditional absorption theory.We speculate that there could be some uncovered mechanism in this system, which will inspire us to understand the absorption process further. 展开更多
关键词 SI In PIN
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H2 solubility and mass transfer in anthraquinone working solution: Experimental and modeling study 被引量:2
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作者 Zhigang Lei Yaru Guo +2 位作者 Yanyan Guo xinxin li Chengna Dai 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第2期143-148,共6页
This work was focused on the measurement of the solubility of hydrogen (H2) in anthraquinone working solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS mo... This work was focused on the measurement of the solubility of hydrogen (H2) in anthraquinone working solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS model study. The influence of various factors, i.e., including pressure, temperature and solvent volume ratio, on H2 solubility was investigated. According to the experimental results, H2 solubility in anthraquinone working solution increases with the increase of pressure. At low pressures, the temperature had little effect on H2 solubility while under high pressures H2 solubility increases with increasing temperature. Henry's constant In/-/has a good linear relationship with 1/T (lnH = -- 1319.1/T + 9.91 ). The effect of volume ratio of trioctyl phos- phate to trimethylbenzene on the solubility of hydrogen was studied and the results showed that increasing the amount of trimethylbenzene was conducive to the dissolution of hydrogen. In addition, there is a linear relationship between ln((Po - Pe) / (Pt - Pe)) and the time t. Gas-liquid mass transfer coefficient was obtained by calculating the slope of the line. 展开更多
关键词 HydrogenSolubilityAnthraquinone working solutionTrimethylbenzeneCOSMO-RS modelMass transfer
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电催化两电子水氧化制备过氧化氢的研究进展
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作者 林柳 孙泽民 +7 位作者 陈华添 赵莲 孙明月 杨逸涛 廖振升 吴鑫宇 李欣欣 唐城 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第4期11-25,共15页
过氧化氢(H_(2)O_(2))是一种环境友好的化学氧化剂,广泛应用于水处理、医疗消毒、化学合成等工业领域。电催化两电子水氧化反应(2e^(-)WOR)是一种可以在温和条件下直接从水中生产H_(2)O_(2)的方法。然而,受限于反应机理认识和催化材料... 过氧化氢(H_(2)O_(2))是一种环境友好的化学氧化剂,广泛应用于水处理、医疗消毒、化学合成等工业领域。电催化两电子水氧化反应(2e^(-)WOR)是一种可以在温和条件下直接从水中生产H_(2)O_(2)的方法。然而,受限于反应机理认识和催化材料设计的不足,2e^(-)WOR的催化选择性和活性仍然较低。本文综述了近年来通过2e^(-)WOR反应路径电合成H_(2)O_(2)的研究进展,首先介绍了2e^(-)WOR的催化机理和研究方法,强调了理论计算加速高选择性、高活性和高稳定性催化剂研究的作用,并讨论了电合成H_(2)O_(2)的不同定量方法和原位表征手段;然后详细总结了高性能2e^(-)WOR电催化剂的调控策略,包括缺陷、掺杂、晶面和界面工程,同时指出了反应器创新设计的重要性;最后展望了电合成H_(2)O_(2)的研究挑战和机遇。 展开更多
关键词 水氧化反应 过氧化氢 催化剂设计 电化学机理 理论研究
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Rational design of Ni-MoO_(3–x) catalyst towards efficient hydrodeoxygenation of lignin-derived bio-oil into naphthenes
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作者 Chao Wang Luxian Guo +7 位作者 Kui Wu xinxin li Yanping Huang Zhigang Shen Hongyun Yang Yunquan Yang Weiyan Wang Changzhi li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期122-130,共9页
Design of a robust catalyst with high activity but the low cost for the hydrodeoxygenation(HDO) of biooils is of great importance to bring the biorefinery concept into reality.In this study,density functional theory(D... Design of a robust catalyst with high activity but the low cost for the hydrodeoxygenation(HDO) of biooils is of great importance to bring the biorefinery concept into reality.In this study,density functional theory(DFT) calculation was adopted to analyze the optimal location of Ni on MoO_(3-x) containing oxygen vacancy,and the corresponding result demonstrated that metallic Ni cluster located at the neighborhood of oxygen vacancies would significantly evoke HDO activity.Enlightened by DFT results,NiMoO_(4) was first hydrothermally synthesized and then employed to fabricate Ni-MoO_(3-x) catalyst via a low-temperature reduction,where Ni escaped from NiMoO_(4) and was reduced to its metallic state.Such an evolution of Ni species also induced the formation of oxygen vacancies around metallic Ni cluster.In the HDO of p-cresol,Ni-MoO_(3-x) exhibited high activity with a complete conversion and a methylcyclohexane selectivity of 99.4% at 150℃.Moreover,the catalyst showed good versatility in catalyzing HDO of diverse lignin-derived oxygenates and lignin oil.2D HSQC NMR,gas chromatograph and elemental analysis of the lignin oil demonstrated the high deoxygenation efficiency and saturation of the benzene ring over Ni-MoO_(3-x).In the upgrading of crude lignin oil,the deoxygenation degree was up to 99%,and the overall carbon yield of the naphthenes was as high as 69.4%.Importantly,the structures and carbon numbers of the naphthene products are similar to jet fuel-range cycloalka nes,which are expected to have a high density that can be blended into jet fuel to raise the range(or payload) of airplanes.This work demonstrates the feasibility for improving the targeted catalytic reactivity by rational tailoring the catalyst structure under the guidance of theoretical analysis,and provides an energy-efficient route for the upgrading of lignin crude oil into valuable naphthenes. 展开更多
关键词 Ni-MoO_(3–x)catalyst HYDRODEOXYGENATION Lignin-derived bio-oil Metal-vacancy interface Naphthene Renewable energy
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Two dimensional MoS_(2) finding its way towards constructing high-performance alkaline recovery membranes
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作者 xinxin li Hongwei Shao +4 位作者 Shichao Zhang Yong li Jingjing Gu Qiang Huang Jin Ran 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第8期155-164,共10页
The available alkaline recovery membranes are currently dominated by polymeric materials,but they suffer from a permeation-selectivity trade-off and inferior chemical resistance.Robust two dimensional(2D) lamellar mem... The available alkaline recovery membranes are currently dominated by polymeric materials,but they suffer from a permeation-selectivity trade-off and inferior chemical resistance.Robust two dimensional(2D) lamellar membranes with sub-nanometer wide channels are promising candidates for discerning OH^(-)and other anions.Here,we report the development of alkaline recycling membranes through stacking MoS_(2) nanosheets.Benefiting from the ordered and narrow 2D channels,MoS_(2) membranes show excellent alkaline recovery performances.The OH^(-)dialysis coefficient (U_(OH)-) and separation factor (S)towards simulated OH^(-) and WO_(4)^(2-) across the 500 nm thick MoS_(2) laminates reach 6.9×10^(-3)m·h^(-1)and 34.3 respectively.Furthermore,the chemical environments of MoS_(2) laminates were modulated by intercalating ionic poly(sodium 4-styrene sulfonate)(PSS@MoS_(2)).The U_(OH)-and S values of PSS@MoS_(2) membrane further improve to 11.7×10^(-3)m·h^(-1)and 49.8 respectively.Besides,both MoS_(2) and PSS@MoS_(2) membranes exhibit promising stability. 展开更多
关键词 Alkaline recovery Diffusion dialysis Two dimensional membranes MoS_(2) Poly(sodium 4-styrene sulfonate)
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Natural product rhynchophylline prevents stress-induced hair graying by preserving melanocyte stem cells via theβ2 adrenergic pathway suppression
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作者 xinxin li Runlu Shi +7 位作者 lingchen Yan Weiwei Chu Ruishuang Sun Binkai Zheng Shuai Wang Hui Tan Xusheng Wang Ying Gao 《Natural Products and Bioprospecting》 CSCD 2023年第1期14-29,共16页
Norepinephrine(NA),a stress hormone,can accelerate hair graying by binding toβ2 adrenergic receptors(β_(2)AR)on melanocyte stem cells(McSCs).From this,NA-β_(2)AR axis could be a potential target for preventing the ... Norepinephrine(NA),a stress hormone,can accelerate hair graying by binding toβ2 adrenergic receptors(β_(2)AR)on melanocyte stem cells(McSCs).From this,NA-β_(2)AR axis could be a potential target for preventing the stress effect.However,identifying selective blockers forβ_(2)AR has been a key challenge.Therefore,in this study,advanced computer-aided drug design(CADD)techniques were harnessed to screen natural molecules,leading to the discovery of rhynchophylline as a promising compound.Rhynchophylline exhibited strong and stable binding within the active site ofβ_(2)AR,as verified by molecular docking and dynamic simulation assays.When administered to cells,rhyncho-phylline effectively inhibited NA-β_(2)AR signaling.This intervention resulted in a significant reduction of hair graying in a stress-induced mouse model,from 28.5%to 8.2%.To gain a deeper understanding of the underlying mechanisms,transcriptome sequencing was employed,which revealed that NA might disrupt melanogenesis by affecting intracellular calcium balance and promoting cell apoptosis.Importantly,rhynchophylline acted as a potent inhibitor of these downstream pathways.In conclusion,the study demonstrated that rhynchophylline has the potential to mitigate the negative impact of NA on melanogenesis by targetingβ_(2)AR,thus offering a promising solution for preventing stress-induced hair graying. 展开更多
关键词 Natural product RHYNCHOPHYLLINE STRESS Hair graying β2 adrenergic signaling
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Bibliometric Analysis of Research Trends and Hot Spots of Leakage and Diffusion of Hazardous Gases
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作者 xinxin li Xingzhuo liU Guohui ZHANG 《Meteorological and Environmental Research》 CAS 2022年第6期44-48,共5页
Dangerous gases widely exist in modern production and people’s daily life.Once they are used or maintained improperly,they are very easy to leak,leading to major accidents seriously endangering people’s health and a... Dangerous gases widely exist in modern production and people’s daily life.Once they are used or maintained improperly,they are very easy to leak,leading to major accidents seriously endangering people’s health and asset safety,such as fire,explosion,burns,poisoning,asphyxia,etc.In this paper,the data collected from CNKI was taken as the research object,and the relevant research in the field of leakage and diffusion of hazardous gases was analyzed through visual analysis by using the VOSviewer software,so as to provide reference for subsequent scholars. 展开更多
关键词 Dangerous gas Leakage and diffusion BIBLIOMETRICS
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Research on the Memory Ethics and Thought Transformation Pattern and the Applications on Contemporary Literature
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作者 xinxin li 《International Journal of Technology Management》 2016年第4期34-36,共3页
In this paper, we conduct research on the memory ethics and thought transformation pattern and the applications on contemporary literature. Compared to scientifi c thinking, historical thinking, the thinking process c... In this paper, we conduct research on the memory ethics and thought transformation pattern and the applications on contemporary literature. Compared to scientifi c thinking, historical thinking, the thinking process characterized by direct image of literary creation of system integration, literary creation process is a fi ction. Literary psychology studies have shown that the transmission of literature as a kind of aesthetic experience, is far from perfect memories of feature, but memory, association, imagination, illusion, such as the result of the comprehensive sports psychological function, is in the creation subject specifi c emotions and as under the guidance of the appearance of the restructuring, merger. From the discussion above we can see that whether it is a literary language of authenticity, or false judgment characteristics of literary language, explain the fact that in literary text is not has direct realistic context, but a self-reference words, and it is a virtual space of the empirical. In this paper, we discuss the related theory with modifi cation that is innovative. 展开更多
关键词 CONTEMPORARY Literature MEMORY ETHICS THOUGHT TRANSFORMATION PATTERN Mode
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Quantum confinement of carriers in the type-I quantum wells structure
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作者 xinxin li Zhen Deng +4 位作者 Yang Jiang Chunhua Du Haiqiang Jia Wenxin Wang Hong Chen 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第9期553-558,共6页
Quantum confinement is recognized to be an inherent property in low-dimensional structures.Traditionally,it is believed that the carriers trapped within the well cannot escape due to the discrete energy levels.However... Quantum confinement is recognized to be an inherent property in low-dimensional structures.Traditionally,it is believed that the carriers trapped within the well cannot escape due to the discrete energy levels.However,our previous research has revealed efficient carrier escape in low-dimensional structures,contradicting this conventional understanding.In this study,we review the energy band structure of quantum wells along the growth direction considering it as a superposition of the bulk material dispersion and quantization energy dispersion resulting from the quantum confinement across the whole Brillouin zone.By accounting for all wave vectors,we obtain a certain distribution of carrier energy at each quantized energy level,giving rise to the energy subbands.These results enable carriers to escape from the well under the influence of an electric field.Additionally,we have compiled a comprehensive summary of various energy band scenarios in quantum well structures relevant to carrier transport.Such a new interpretation holds significant value in deepening our comprehension of low-dimensional energy bands,discovering new physical phenomena,and designing novel devices with superior performance. 展开更多
关键词 energy band quantum confinement type-I quantum wells low-dimensional structures
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Reanalysis of energy band structure in the type-II quantum wells
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作者 李欣欣 邓震 +4 位作者 江洋 杜春花 贾海强 王文新 陈弘 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期75-78,共4页
Band structure analysis holds significant importance for understanding the optoelectronic characteristics of semiconductor structures and exploring their potential applications in practice. For quantum well structures... Band structure analysis holds significant importance for understanding the optoelectronic characteristics of semiconductor structures and exploring their potential applications in practice. For quantum well structures, the energy of carriers in the well splits into discrete energy levels due to the confinement of barriers in the growth direction. However, the discrete energy levels obtained at a fixed wave vector cannot accurately reflect the actual energy band structure. In this work, the band structure of the type-II quantum wells is reanalyzed. When the wave vectors of the entire Brillouin region(corresponding to the growth direction) are taken into account, the quantized energy levels of the carriers in the well are replaced by subbands with certain energy distributions. This new understanding of the energy bands of low-dimensional structures not only helps us to have a deeper cognition of the structure, but also may overturn many viewpoints in traditional band theories and serve as supplementary to the band theory of low-dimensional systems. 展开更多
关键词 energy band structure type-II quantum wells low-dimensional semiconductors
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油田调驱用聚合物微球的研究进展 被引量:14
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作者 康万利 周博博 +4 位作者 杨红斌 李欣欣 张弘文 唐雪辰 高永博 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2020年第9期173-180,共8页
聚合物微球以其良好的吸水膨胀和黏弹性能广泛用于油田调驱增产,并取得了良好应用效果。通过文献调研及本团队近几年的研究成果,文中全面论述了油田调驱用聚合物微球的调驱作用机理及研制方法,并在此基础上介绍了双交联聚合物微球、荧... 聚合物微球以其良好的吸水膨胀和黏弹性能广泛用于油田调驱增产,并取得了良好应用效果。通过文献调研及本团队近几年的研究成果,文中全面论述了油田调驱用聚合物微球的调驱作用机理及研制方法,并在此基础上介绍了双交联聚合物微球、荧光聚合物微球和有机/无机复合聚合物微球3种新型的聚合物功能微球。最后,对聚合物微球调驱技术的未来发展趋势进行展望。随着聚合物微球调驱技术的发展,聚合物微球的功能性会不断展现,研制成本也必将进一步降低,其用于油田调驱的规模也会越来越大。 展开更多
关键词 聚合物微球 油田调驱 吸水膨胀 提高采收率
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植物响应环境变化的长距离信号传导
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作者 罗熹晨 刘慧 +3 位作者 刘学英 李欣欣 廖红 傅向东 《遗传》 CAS CSCD 北大核心 2022年第7期556-566,共11页
高等植物在应对复杂环境变化时,需要整合和协调不同器官与组织感知的信息,并通过一套精细且复杂的机制经维管系统向受体组织或器官传递,进而系统性协调植物整体的生长发育和环境响应。在维管系统中移动的信号物质称为长距离信号。近年... 高等植物在应对复杂环境变化时,需要整合和协调不同器官与组织感知的信息,并通过一套精细且复杂的机制经维管系统向受体组织或器官传递,进而系统性协调植物整体的生长发育和环境响应。在维管系统中移动的信号物质称为长距离信号。近年来研究发现,能够长距离移动的信号分子主要有小RNA、mRNA、小肽、激素、第二信使以及蛋白质等几类,这些信号分子能够将细胞外刺激从感知组织传递到靶器官,从而系统性地调控植物发育进程和环境响应。本文重点总结了植物体内长距离移动的RNA、小肽和蛋白质这3类长距离信号分子在调控植物器官发育、养分吸收以及环境响应等方面的研究进展,并对该领域在作物育种方面的应用潜力进行了探讨和展望,以期为作物遗传育种应用提供理论基础。 展开更多
关键词 长距离信号 长距离移动 维管 系统性调控
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Theoretical fundamentals of short pulse laser–metal interaction: A review 被引量:9
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作者 xinxin li Yingchun Guan 《Nanotechnology and Precision Engineering》 EI CAS CSCD 2020年第3期105-125,共21页
Short and ultrashort pulse lasers offer excellent advantages in laser precision machining mainly because of their high pulse energy and low ablation threshold. The complex process of laser interaction with metals limi... Short and ultrashort pulse lasers offer excellent advantages in laser precision machining mainly because of their high pulse energy and low ablation threshold. The complex process of laser interaction with metals limits the indepth investigation into laser ablation. Numerical simulation is important in the study of fundamental mechanisms. This review explores the start-of-the-art methods for the theoretical simulation of the laser ablation of metals, including plasma formation and expansion. Laser-induced period surface structures are also studied. 展开更多
关键词 Laser-material interaction Nanosecond laser Femtosecond laser METALS Simulation
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Effect of scorpion venom analgesic active peptide extracted from Buthus martensii Karsch on evoked potential in the thalamic posterior nucleus group in rats 被引量:4
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作者 Qiuhong lin xinxin li 《Neural Regeneration Research》 SCIE CAS CSCD 2008年第4期453-455,共3页
BACKGROUND: Buthus martensii Karsch is a rare medicinal animal, and dried integral Buthus rnartensii Karsch is an important drug in traditional Chinese medicine. OBJECTIVE: To investigate the effects of scorpion ven... BACKGROUND: Buthus martensii Karsch is a rare medicinal animal, and dried integral Buthus rnartensii Karsch is an important drug in traditional Chinese medicine. OBJECTIVE: To investigate the effects of scorpion venom analgesic active peptide (SAP) extracted from Buthus martensii Karsch on evoked unit discharge of the common peroneal nerve in the posterior nucleus group of the thalamus using a stereotaxic electrophysiological extracellular microelectrode recording. DESIGN, TIME AND SETTING: One-way designed study, performed in the Physiological Laboratory of Shenyang Medical College on September 15, 2006. MATERIALS: Fifty 3-4 months old Wistar rats (25 males and 25 females) were used. SAP was provided by Shenyang Pharmaceutical University. Morphine solution was made by the First Drug Manufactory, Northeastern Drug Manufacture Group (batch number: H20013351). Naloxone solution was made by Hunan Pharmaceutical Co., Ltd. (batch number: H43021669). Type ATAC-350 medical data processing equipment was made by the Photoelectricity Company, Japan. METHODS: Fifty rats were randomly divided into the SAP group (n=20), saline group (n=10), morphine group (n=10), or naloxone group (n=10). In the SAP group, the common peroneal nerve was separated and stimulated with a single square wave (17-19 V intensity; 0.2 ms width; 20 ms retardation time). Subsequently, SAP (0.01%, 2 μL) was injected into the posterior nucleus group of the thalamus. Rats in the naloxone group were injected with naloxone (1.0 mg/kg i.v.) before SAP injection. Rats in the saline group and the morphine group were injected with saline (2 μL) or morphine (0.01%, 2μL), respectively, before SAP injection. Other procedures were the same as those in the SAP group. MAIN OUTCOME MEASURES: Evoked discharge in the posterior nucleus group of the thalamus and effects of SAP alone and SAP in combination with saline, morphine, or naloxone on discharges in the posterior nucleus group of the thalamus as measured by TQ-19 medical data processing equipment. RESULTS: SAP group: At 1-3 minutes after SAP injection, evoked discharges in the posterior nucleus group of the thalamus were inhibited, and the inhibitory time lasted for (45.0±0.7) minutes. Saline group: Evoked discharges in the posterior nucleus group of the thalamus did not change after saline injection. Morphine group: At 1-3 minutes after morphine injection, evoked discharges in the posterior nucleus group of the thalamus were inhibited, and the inhibitory time lasted for (35.0±7.8) minutes. Naloxone group: SAP had no effects on evoked potentials in the posterior nucleus group of the thalamus. CONCLUSION: The inhibitory effect of SAP on evoked potentials was superior to that of morphine at the same concentration (2 μL of 0.01% solution). Naloxone resupination demonstrated that the inhibitory effects of SAP on evoked discharges were influenced by the opioid receptor. 展开更多
关键词 Buthus martensii Karsch STEREOTAXIS microelectrode recording posterior nucleus group of thethalamus
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