The incorporation of the quasicrystalline phase into the metal matrix offers a wide range of potential applications in particle-reinforced metal-matrix composites.The analytic solution of the piezoelectric quasicrysta...The incorporation of the quasicrystalline phase into the metal matrix offers a wide range of potential applications in particle-reinforced metal-matrix composites.The analytic solution of the piezoelectric quasicrystal(QC)microsphere considering the thermoelectric effect and surface effect contained in the elastic matrix is presented in this study.The governing equations for the QC microsphere in the matrix subject to the external electric loading are derived based on the nonlocal elastic theory,electro-elastic interface theory,and eigenvalue method.A comparison between the existing results and the finite-element simulation validates the present approach.Numerical examples reveal the effects of temperature variation,nonlocal parameters,surface properties,elastic coefficients,and phason coefficients on the phonon,phason,and electric fields.The results indicate that the QC microsphere enhances the mechanical properties of the matrix.The results are useful for the design and understanding of the characterization of QCs in micro-structures.展开更多
In the Windows XP 64 bit operating system environment, several common PC were used to build a cluster system, establishing the distributed memory parallel (DMP) computing system. A finite element model of whole aircra...In the Windows XP 64 bit operating system environment, several common PC were used to build a cluster system, establishing the distributed memory parallel (DMP) computing system. A finite element model of whole aircraft with about 260 million degrees of freedom (DOF) was developed using three-node and four-node thin shell element and two-node beam element. With the large commercial finite element software MSC.MARC and employing two kinds of domain decomposition method (DDM) respectively, realized the parallel solving for the static strength analysis of the whole aircraft model, which offered a high cost-effective solution for solving large-scale and complex finite element models.展开更多
In widely studied organic-inorganic hybrid perovskites,the organic component tends to volatilize and decompose under high temperatures,oxygen,and humidity,which adversely affects the performance and longevity of the a...In widely studied organic-inorganic hybrid perovskites,the organic component tends to volatilize and decompose under high temperatures,oxygen,and humidity,which adversely affects the performance and longevity of the associated solar cells.In contrast,all-inorganic perovskites demonstrate superior stability under these conditions and offer photoelectric properties comparable to those of their hybrid counterparts.The potential of tandem solar cells(TSCs)made from all-inorganic perovskites is especially promising.This review is the first to address recent advancements in TSCs that use all-inorganic perovskites and crystalline silicon(c-Si),both domestically and internationally.This work provides a systematic and thorough analysis of the current challenges faced by these systems and proposes rational solutions.Additionally,we elucidate the regulatory mechanisms of all-inorganic perovskites and their TSCs when combined with c-Si,summarizing the corresponding patterns.Finally,we outline future research directions for all-inorganic perovskites and their TSCs with c-Si.This work offers valuable insights and references for the continued advancement of perovskitebased TSCs.展开更多
LaMnO3 catalysts with three-dimensionally ordered holes perovskite structure were prepared via closepacked SiO2 template synthesized by Stober-Frink method. SEM, XRD and BET were employed to characterize the microstru...LaMnO3 catalysts with three-dimensionally ordered holes perovskite structure were prepared via closepacked SiO2 template synthesized by Stober-Frink method. SEM, XRD and BET were employed to characterize the microstructure, phases and specific surface area. CV method was used to the oxygen electrode beha-vior of catalysts. Diameter of the holes was about 330 nm, corresponding to the size of SiO2 template. Full-cell discharge tests were performed on aluminum-air battery fabricated by porous LaMnO3.Results showed that the discharge performance of porous LaMnO3 were 1.54 V, 1.42 V and 1.24 V respectively when the discharge currents were set at 5 mA/cm^2,10 mA/cm^2 and 20 mA/cm^2, respectively, which were higher than that of LaMnO3 prepared by coprecipitation method(1.33 V, 1.09 V, 0.63 V, respectively).展开更多
Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires(SiNWs) and silicon ...Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires(SiNWs) and silicon inverted pyramid arrays(SiIPs) were introduced on surface of Gr-Si solar cell through silver and copper-catalyzed chemical etching, respectively. The effects of SiNWs and SiIPs on carrier lifetime, optical properties and efficiency of Gr-SiNWs and Gr-SiIPs solar cells were systematically analyzed. The results show that the inverted pyramid arrays have more excellent ability for balancing antireflectance loss and surface area enlargement. The power conversion efficiency(PCE) and carrier lifetime of Gr-SiIPs devices respectively increase by 62% and 34% by comparing with that of Gr-SiNWs solar cells. Finally, the Gr-SiIPs cell with PCE of 5.63% was successfully achieved through nitric acid doping. This work proposes a new strategy to introduce the inverted pyramid arrays for improving the performance of Gr-Si solar cells.展开更多
A theoretical model is established to investigate the effect of martensitic transformation particle on the dislocation emission from a crack tip in ceramic-matrix nanocomposites. Using the model of dislocation-based s...A theoretical model is established to investigate the effect of martensitic transformation particle on the dislocation emission from a crack tip in ceramic-matrix nanocomposites. Using the model of dislocation-based strain nucleus and the Green's function met hod, the expressions of complex potentials and stress fields are derived in closed form. The critical stress intensity factors for the first-lattice dislocation emission and the maximum number of emitted dislocations are well calculated. The effects of important parameters such as the size of transformation particle, the dislocation emission angle and the distance from the crack tip to the transformation particle on dislocation emission are discussed in detail. The results reveal that the transformation particle shows a significant shielding effect on the dislocation emission from the crack tip, and the shielding effect enhances with an increase in the size of transformation particle. On the other hand, the results also imply that the emission of edge dislocations is closely related with the dislocation emission angle, and there exists a probable angle |θ|≈ 74° making the dislocation emission easiest. Besides, the remarkable crack blunting induced by the dislocation emission is quite difficult for small grain size but easy for the growth of crack.展开更多
In recent years,a novel PEDOT:PSS/n-Si planar heterojunction solar cell has been extensively studied in the photovoltaic field.Different V_(2)O_(5)-IPA concentrations mixed in PEDOT:PSS samples as hole transport layer...In recent years,a novel PEDOT:PSS/n-Si planar heterojunction solar cell has been extensively studied in the photovoltaic field.Different V_(2)O_(5)-IPA concentrations mixed in PEDOT:PSS samples as hole transport layer were prepared by means of spin coating technique and mechanical mixing of organic and inorganic materials.V_(2)O_(5)was studied for its effects on the surface morphology,chemical composition,and optical transmittance of PEDOT:PSS films.The findings of the study show that the addition of V_(2)O_(5)particles changes the surface morphology of PEDOT:PSS films and promotes its superior ohmic contact with the Si interface.Furthermore,PEDOT:PSS incorporated with V_(2)O_(5)particles that have outstanding optical and semiconductor properties reduces the rate of carrier recombination at the device interface and blocks electron transport to the anode in the fabricated Si-based solar cells.When compared to conventional PEDOT:PSS/Si planar heterojunction solar cells,the fill factor,photoelectric conversion efficiency,open-circuit voltage,and short-circuit current density of the devices prepared in this study can be significantly improved,reaching up to 70.98%,15.17%,652 mV and 32.8 mA/cm^(2),respectively.This research provides a promising and effective method for improving the photoelectric conversion performance of PEDOT:PSS/Si heterojunction solar cells,which enables the application of V_(2)O_(5)in Si solar cells.展开更多
Electrostatic torsional micromirrors are widely applied in the fields·of micro-optical switches,optical attenuators,optical scanners,and optical displays.In previous lectures,most of the micromirrors were twisted...Electrostatic torsional micromirrors are widely applied in the fields·of micro-optical switches,optical attenuators,optical scanners,and optical displays.In previous lectures,most of the micromirrors were twisted along the urtiaxial or biaxial direction,which limited the range of light reflection.In this·paper,a quasicrystal torsional micromirror that can be deflected in any direction is designed and the dynamic model of the electrostatically driven micromirror is established.The static and dynamic phenomena and pull-in characteristics are analyzed through the numerical solution of the strain gradient theory.The results of three kinds of mirror deflection directions are compared and analyzed.The results show the significant differences in the torsion models with different deflection axis directions.When the deflection angle along the oblique axis reaches 45°,the instability voltage is the smallest.The pull-in instability voltage increases with the increment ofphonon-phason coupling elastic modulus and phason elastic modulus.The perrriittivity of quasicrystal,the strain gradient parameter,and the air damping influence the torsion of the micromirror dynaniic system.A larger pull-in instability voltage generates with the decrease of surface distributed forces.展开更多
Graphene/silicon(Gr/Si)Schottky barrier solar cells(SBSCs)are attractive for harvesting solar energy and have been gaining grounds for its low-cost solution-processing.The interfacial barrier between graphene and sili...Graphene/silicon(Gr/Si)Schottky barrier solar cells(SBSCs)are attractive for harvesting solar energy and have been gaining grounds for its low-cost solution-processing.The interfacial barrier between graphene and silicon facilitates the reducing excessive carrier recombination while accelerating the separation processes of photo-generated carriers at the interface,which empowers the performance of Gr/Si SBSCs.However,the difficulty to control the interface thickness prevents its application.Here,we introduce the graphene oxide quantum dots(GOQDs)as a unique interfacial modulation species with tunable thickness by controlling the GOQDs particle size.The power conversion efficiency(PCE)of 13.67%for Gr/Si-based SBSC with outstanding stability in the air is obtained with the optimal barrier thickness(26 nm)and particle size(4.15 nm)of GOQDs.The GOQDs in Gr/Si-based SBSCs provide the extra band bending which further enhances the PCE for its photovoltaic applications.展开更多
基金supported by the National Natural Science Foundation of China(Nos.U2067220 and 82000980)。
文摘The incorporation of the quasicrystalline phase into the metal matrix offers a wide range of potential applications in particle-reinforced metal-matrix composites.The analytic solution of the piezoelectric quasicrystal(QC)microsphere considering the thermoelectric effect and surface effect contained in the elastic matrix is presented in this study.The governing equations for the QC microsphere in the matrix subject to the external electric loading are derived based on the nonlocal elastic theory,electro-elastic interface theory,and eigenvalue method.A comparison between the existing results and the finite-element simulation validates the present approach.Numerical examples reveal the effects of temperature variation,nonlocal parameters,surface properties,elastic coefficients,and phason coefficients on the phonon,phason,and electric fields.The results indicate that the QC microsphere enhances the mechanical properties of the matrix.The results are useful for the design and understanding of the characterization of QCs in micro-structures.
文摘In the Windows XP 64 bit operating system environment, several common PC were used to build a cluster system, establishing the distributed memory parallel (DMP) computing system. A finite element model of whole aircraft with about 260 million degrees of freedom (DOF) was developed using three-node and four-node thin shell element and two-node beam element. With the large commercial finite element software MSC.MARC and employing two kinds of domain decomposition method (DDM) respectively, realized the parallel solving for the static strength analysis of the whole aircraft model, which offered a high cost-effective solution for solving large-scale and complex finite element models.
基金the National Natural Science Foundation of China(Grant Nos.52164050 and 51762043)Major Science and Technology Project of Yunnan Province(Grant No.202202AB080010).
文摘In widely studied organic-inorganic hybrid perovskites,the organic component tends to volatilize and decompose under high temperatures,oxygen,and humidity,which adversely affects the performance and longevity of the associated solar cells.In contrast,all-inorganic perovskites demonstrate superior stability under these conditions and offer photoelectric properties comparable to those of their hybrid counterparts.The potential of tandem solar cells(TSCs)made from all-inorganic perovskites is especially promising.This review is the first to address recent advancements in TSCs that use all-inorganic perovskites and crystalline silicon(c-Si),both domestically and internationally.This work provides a systematic and thorough analysis of the current challenges faced by these systems and proposes rational solutions.Additionally,we elucidate the regulatory mechanisms of all-inorganic perovskites and their TSCs when combined with c-Si,summarizing the corresponding patterns.Finally,we outline future research directions for all-inorganic perovskites and their TSCs with c-Si.This work offers valuable insights and references for the continued advancement of perovskitebased TSCs.
基金supported by the National Natural Science Foundation of China (Grant Nos. U1137601 and 51466005)the Science and Technology Program of Yunnan Province (Grant No.2014RD016)the Program for Innovative Research Team of Yunnan Province (Grant No. 2014HC013)
文摘LaMnO3 catalysts with three-dimensionally ordered holes perovskite structure were prepared via closepacked SiO2 template synthesized by Stober-Frink method. SEM, XRD and BET were employed to characterize the microstructure, phases and specific surface area. CV method was used to the oxygen electrode beha-vior of catalysts. Diameter of the holes was about 330 nm, corresponding to the size of SiO2 template. Full-cell discharge tests were performed on aluminum-air battery fabricated by porous LaMnO3.Results showed that the discharge performance of porous LaMnO3 were 1.54 V, 1.42 V and 1.24 V respectively when the discharge currents were set at 5 mA/cm^2,10 mA/cm^2 and 20 mA/cm^2, respectively, which were higher than that of LaMnO3 prepared by coprecipitation method(1.33 V, 1.09 V, 0.63 V, respectively).
基金support of this work from the NSFC (Nos. 51504117, 61764009 and 51762043)Yunnan Applied Basic Research Project (No. Y0120150138)Research Fund of Yunnan Province Collaborative Innovation Center (No. 2014XTZS009)
文摘Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires(SiNWs) and silicon inverted pyramid arrays(SiIPs) were introduced on surface of Gr-Si solar cell through silver and copper-catalyzed chemical etching, respectively. The effects of SiNWs and SiIPs on carrier lifetime, optical properties and efficiency of Gr-SiNWs and Gr-SiIPs solar cells were systematically analyzed. The results show that the inverted pyramid arrays have more excellent ability for balancing antireflectance loss and surface area enlargement. The power conversion efficiency(PCE) and carrier lifetime of Gr-SiIPs devices respectively increase by 62% and 34% by comparing with that of Gr-SiNWs solar cells. Finally, the Gr-SiIPs cell with PCE of 5.63% was successfully achieved through nitric acid doping. This work proposes a new strategy to introduce the inverted pyramid arrays for improving the performance of Gr-Si solar cells.
基金the support from the National Natural Science Foundation of China (11572191 and 51601112)the Specialized Research Fund for the Doctoral Program of Higher Education of China (20130073110057).
文摘A theoretical model is established to investigate the effect of martensitic transformation particle on the dislocation emission from a crack tip in ceramic-matrix nanocomposites. Using the model of dislocation-based strain nucleus and the Green's function met hod, the expressions of complex potentials and stress fields are derived in closed form. The critical stress intensity factors for the first-lattice dislocation emission and the maximum number of emitted dislocations are well calculated. The effects of important parameters such as the size of transformation particle, the dislocation emission angle and the distance from the crack tip to the transformation particle on dislocation emission are discussed in detail. The results reveal that the transformation particle shows a significant shielding effect on the dislocation emission from the crack tip, and the shielding effect enhances with an increase in the size of transformation particle. On the other hand, the results also imply that the emission of edge dislocations is closely related with the dislocation emission angle, and there exists a probable angle |θ|≈ 74° making the dislocation emission easiest. Besides, the remarkable crack blunting induced by the dislocation emission is quite difficult for small grain size but easy for the growth of crack.
基金supported by the National Natural Science Foundation of China(Grant No.52164050,51762043,61764009,51974143)National Key R&D Program of China(No.2018YFC1901801,No.2018YFC1901805)+1 种基金Major Science and Technology Project of Yunnan Province(202202AB080010,2019ZE00703)Yunnan University“Double First-class”Construction Joint Special Project-major project(202201BF070001-018).
文摘In recent years,a novel PEDOT:PSS/n-Si planar heterojunction solar cell has been extensively studied in the photovoltaic field.Different V_(2)O_(5)-IPA concentrations mixed in PEDOT:PSS samples as hole transport layer were prepared by means of spin coating technique and mechanical mixing of organic and inorganic materials.V_(2)O_(5)was studied for its effects on the surface morphology,chemical composition,and optical transmittance of PEDOT:PSS films.The findings of the study show that the addition of V_(2)O_(5)particles changes the surface morphology of PEDOT:PSS films and promotes its superior ohmic contact with the Si interface.Furthermore,PEDOT:PSS incorporated with V_(2)O_(5)particles that have outstanding optical and semiconductor properties reduces the rate of carrier recombination at the device interface and blocks electron transport to the anode in the fabricated Si-based solar cells.When compared to conventional PEDOT:PSS/Si planar heterojunction solar cells,the fill factor,photoelectric conversion efficiency,open-circuit voltage,and short-circuit current density of the devices prepared in this study can be significantly improved,reaching up to 70.98%,15.17%,652 mV and 32.8 mA/cm^(2),respectively.This research provides a promising and effective method for improving the photoelectric conversion performance of PEDOT:PSS/Si heterojunction solar cells,which enables the application of V_(2)O_(5)in Si solar cells.
基金supported by the National Natural Science Foundation of China(Grant Nos.11572191,51701117,and 51779139).
文摘Electrostatic torsional micromirrors are widely applied in the fields·of micro-optical switches,optical attenuators,optical scanners,and optical displays.In previous lectures,most of the micromirrors were twisted along the urtiaxial or biaxial direction,which limited the range of light reflection.In this·paper,a quasicrystal torsional micromirror that can be deflected in any direction is designed and the dynamic model of the electrostatically driven micromirror is established.The static and dynamic phenomena and pull-in characteristics are analyzed through the numerical solution of the strain gradient theory.The results of three kinds of mirror deflection directions are compared and analyzed.The results show the significant differences in the torsion models with different deflection axis directions.When the deflection angle along the oblique axis reaches 45°,the instability voltage is the smallest.The pull-in instability voltage increases with the increment ofphonon-phason coupling elastic modulus and phason elastic modulus.The perrriittivity of quasicrystal,the strain gradient parameter,and the air damping influence the torsion of the micromirror dynaniic system.A larger pull-in instability voltage generates with the decrease of surface distributed forces.
基金the National Natural Science Foundation of China(Grant No.61764009,51762043,51974143)the National Key R&D Program of China(No.2018YFC1901801,No.2018YFC1901805)+2 种基金the Major Science and Technology Projects in Yunnan Province(No.2019ZE007)the Key Project of Yunnan Province Natural Science Fund(No.2018FA027)the Yunan Ten Thousand Talents Plan Young&Elite Talents Project,and the Program for Innovative Research Team in University of Ministry of Education of China(No.IRT_17R48).
文摘Graphene/silicon(Gr/Si)Schottky barrier solar cells(SBSCs)are attractive for harvesting solar energy and have been gaining grounds for its low-cost solution-processing.The interfacial barrier between graphene and silicon facilitates the reducing excessive carrier recombination while accelerating the separation processes of photo-generated carriers at the interface,which empowers the performance of Gr/Si SBSCs.However,the difficulty to control the interface thickness prevents its application.Here,we introduce the graphene oxide quantum dots(GOQDs)as a unique interfacial modulation species with tunable thickness by controlling the GOQDs particle size.The power conversion efficiency(PCE)of 13.67%for Gr/Si-based SBSC with outstanding stability in the air is obtained with the optimal barrier thickness(26 nm)and particle size(4.15 nm)of GOQDs.The GOQDs in Gr/Si-based SBSCs provide the extra band bending which further enhances the PCE for its photovoltaic applications.