Residual alkali-evoked cross-linked polymer layer for anti-air-sensitivity LiNi_(0.89)Co_(0.06)Mn_(0.05)O_(2)cathode

High-energy density lithium-ion batteries(LIBs)with layered high-nickel oxide cathodes(LiNi_(x)Co_(y)Mn_(1-x-y)O_(2),x≥0.8)show great promise in consumer electronics and vehicular applications.However,LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)faces challenges related to capacity decay caused by residual alkalis owing to high sensitivity to air.To address this issue,we propose a hazardous substances upcycling method that fundamentally mitigates alkali content and concurrently induces the emergence of an anti-air-sensitive layer on the cathode surface.Through the neutralization of polyacrylic acid(PAA)with residual alkalis and then coupling it with 3-aminopropyl triethoxysilane(KH550),a stable and ion-conductive cross-linked polymer layer is in situ integrated into the LiNi_(0.89)Co_(0.06)Mn_(0.05)O_(2)(NCM)cathode.Our characterization and measurements demonstrate its effectiveness.The NCM material exhibits impressive cycling performance,retaining 88.4%of its capacity after 200 cycles at 5 C and achieving an extraordinary specific capacity of 170.0 mA h g^(-1) at 10 C.Importantly,this layer on the NCM efficiently suppresses unfavorable phase transitions,severe electrolyte degradation,and CO_(2)gas evolution,while maintaining commendable resistance to air exposure.This surface modification strategy shows widespread potential for creating air-stable LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)cathodes,thereby advancing high-performance LIBs.

Discharge Characteristics of Bubbles at Interface Between AIN Ceramic and FC-72 Liquid

In order to evaluate the insulation of two-phase immersion cooling in the HV power electronic package,the insulation degradation of the dielectric interface induced by bubbles is investigated.In this paper,a test strategy with 50 Hz unipolar DC and AC combined voltage for partial discharge(PD)at boiling interface of AlN ceramic is proposed.The insulation threshold of an AlN ceramic surface is acquired in several dielectric environments,such as air,FC-72 liquid(FC-72,a Fluorinert^(TM) from 3^(TM)),FC-72 vapor,and boiling state of FC72.This reveals the deterioration of boiling on the insulation of the surface immersed in the dielectric refrigerant.To investigate the mechanism of the PD feature at the boiling interface,the PD patterns of the unrestricted bubble and the accumulated bubble are acquired and contrastively analyzed.Combined with the feature of the back discharge and the bubble behavior,the charged vapor-ceramic interface is relatively stable due to the accumulated vapor layer.This stability of the charged vaporceramic interface is broken if the bubble is unrestricted.Besides,it is discovered that the vapor-liquid interface inside the bubble may be another charged interface,which can also trigger a back discharge.

Study on space charge accumulation characteristics of silicone elastomer under DC voltage

The electric field distortion caused by the accumulation of space charge in the insulating dielectric is easy to lead to accelerated ageing and even breakdown.In this paper,the space charge characteristics and the interfacial electric field change with time of silicone elastomer under different polarity DC voltages are studied.The results show that the homopolar charge injection is dominant in the silicone elastomer,and the electric field threshold is less than 4 kV/mm.The accumulation of homopolar charge weakens the interfacial electric field,resulting in the reduction of charge injection,and the interfacial electric field and spatial charge distribution gradually stabilise over time.In addition,the electric field at the interface does not decrease to the charge injection field threshold when it reaches stability.A time-varying electric field model of the metal-dielectric interface under a direct current field is derived and a calculation method for the time of charge accumulation to stabilise is proposed,based on the Schottky injection model and the relation between current density and volume charge density.The accuracy of the model is verified by comparing it with the experimental results of the stability time of silicone elastomer.This model is used to estimate the time when space charge accumulation reaches stability by means of the electric field threshold and the interface barrier,which can provide reference for the experimental measurement of space charge.

Measurement of surface charges on the dielectric film based on field mills under the HVDC corona wire

The ion flow field on the ground is one of the significant parameters used to evaluate the electromagnetic environment of high voltage direct current（HVDC） power lines.HVDC lines may cross the greenhouses due to the restricted transmission corridors.Under the condition of ion flow field,the dielectric films on the greenhouses will be charged,and the electric fields in the greenhouses may exceed the limit value.Field mills are widely used to measure the groundlevel direct current electric fields under the HVDC power lines.In this paper,the charge inversion method is applied to calculate the surface charges on the dielectric film according to the measured ground-level electric fields.The advantages of hiding the field mill probes in the ground are studied.The charge inversion algorithm is optimized in order to decrease the impact of measurement errors.Based on the experimental results,the surface charge distribution on a piece of quadrate dielectric film under a HVDC corona wire is studied.The enhanced effect of dielectric film on ground-level electric field is obviously weakened with the increase of film height.Compared with the total electric field strengths,the normal components of film-free electric fields at the corresponding film-placed positions have a higher effect on surface charge accumulation.

Space charge characteristics of silicone elastomer for device packaging under positive square wave voltage

With the rapid development of power electronic devices towards high voltage and power,the insulation challenges faced by devices have attracted widespread attention.Silicone elastomer is widely used in device packaging as one insulating material,and the study of its insulating properties is helpful to the reliable operation of devices.To this end we obtained the space charge characteristics of silicone elastomer under positive square wave voltage by using the pulse-electroacoustic(PEA)method.Firstly based on the existing research and IEC standards,the selection criteria of the resistance and capacitance parameters of a PEA system for space charge measurement under square wave voltage are given.Through this experimental system,the space charge distribution under the positive square wave voltage with different waveform parameters is obtained,and the influences of the waveform parameters on the space charge accumulation are analysed.The amounts of charges under the action of square wave voltage with different waveform parameters are calculated,and the influences of waveform parameters on the amounts of charges are analysed.In addition,the reasons for the difference in the accumulation of positive and negative charges are explained through Schottky injection model,the synthesis reaction and the infrared spectrum of the silicone elastomer.

Influence of Parasitic Parameters on Dynamic Threshold Voltage Hysteresis of Silicon Carbide MOSFETs

Threshold voltage (V_(TH)) hysteresis affects the dynamic characteristics of silicon carbide (SiC) MOSFETs, whichin turn affects reliability of a device. In this paper, a dynamichysteresis curve is proposed as an evaluation method of theinfluence of V_(TH) hysteresis on the switching characteristics ofSiC MOSFETs. This method can eliminate the impact of triggerlevel and obtain the dynamic V_(TH). Furthermore, the influence ofparasitic parameters on dynamic V_(TH) hysteresis is theoreticallyanalyzed. Double pulse tests under different parasitic parametersare performed on three SiC MOSFETs with different gatestructures to verify the analysis. Results show that gate resistance(R_(G)) and source inductance (L_(S)) have more significant effectson dynamic V_(TH) hysteresis compared with gate inductance anddrain inductance. V_(TH) hysteresis phenomenon weakens withincrease of R_(G) or L_(S), which is related to device structure.The results presented in this paper can provide guidance forthe design of circuit parasitic parameters of SiC MOSFETs toregulate V_(TH) hysteresis.

Surface engineering of nickel-rich single-crystal layered oxide cathode enables high-capacity and long cycle-life sulfide all-solid-state batteries

Sulfide all-solid-state lithium batteries(SASSLBs)with a single-crystal nickel-rich layered oxide cathode(LiNix-CoyMn_(1-x-y)O_(2),x≥0.8)are highly desirable for advanced power batteries owing to their excellent energy density and safety.Nevertheless,the cathode material's cracking issue and its severe interfacial problem with sulfide solid electrolytes have hindered the further development.This study proposes to employ surface modification engineering to produce B-NCM cathode materials coated with boride nanostructure stabilizer in situ by utilizing NCM encapsulated with residual lithium.This approach enhances the electrochemical performance of SASSLBs by effectively inhibiting electrochemical-mechanical degradation of the NCM cathode material on cycling and reducing deleterious side reactions with the solid sulfide electrolyte.The B-NCM/LPSCl/Gr SASSLBs demonstrate impressive cycling stability,retaining 84.19%of its capacity after 500 cycles at 0.2 C,which represents a 30.13%increase vs.NCM/LPSCl/Gr.It also exhibits a specific capacity of 170.4 mAh/g during its first discharge at 0.1 C.This work demonstrates an effective surface engineering strategy for enhancing capacity and cycle life,providing valuable insights into solving interfacial problems in SASSLBs.

Finite Element Method for Transient Electric Field by Using Indirect Laplace Transform with High Accuracy

This paper focuses on the finite element method in the complex frequency domain(CFD-FEM)for the transient electric field.First,the initial value and boundary value problem of the transient electric field under the electroquasistatic field in the complex frequency domain is given.In addition,the finite element equation and the constrained electric field equation on the boundary are derived.Secondly,the indirect algorithm of the numerical inverse Laplace transform is introduced.Based on it,the calculation procedures of the CFD-FEM are illustrated in detail.Thirdly,the step response,zero-state response under the positive periodic square waveform(PPSW)voltage,and the zero-input response by the CFD-FEM with direct algorithm and indirect algorithm are compared.Finally,the reason for the numerical oscillations of the zero-state response under the PPSW voltage is analyzed,and the method to reduce oscillations is proposed.The results show that the numerical accuracy of the indirect algorithm of the CFD-FEM is more than an order of magnitude higher than that of the direct algorithm when calculating the step response of the transient electric field.The proposed method can significantly reduce the numerical oscillations of the zero-state response under the PPSW voltage.The proposed method is helpful for the calculation of the transient electric field,especially in the case of frequency-dependent parameters.

Influence of AC Voltage on the Positive DC Corona Current Pulses in a Wire-cylinder Gap

In the development of hybrid HVDC and HVAC transmission lines,the study of radio interference is an important issue.Positive corona current pulses from high voltage transmission lines are the main source of radio interference.In this paper,the design of a wire-cylinder gap electrode system is presented to study the influence of AC voltage on the characteristics of positive corona current pulses.The study shows that the mode of the current pulses is different from that of either DC or AC corona discharge.Waveform parameters of the pulses,such as rise time,half wave time,duration time,repetition rates,average amplitude,and time intervals of secondary pulses are all statistically analyzed in this study.The empirical formulas for the repetition rates with different AC voltages are presented.A theoretical explanation based on an ion cloud model is given to reveal the mechanism behind the influence of AC voltage on positive corona discharge.The experimental results could provide some references for the prediction of radio interference from hybrid AC/DC transmission lines.

Trap Characteristics and Their Temperature-dependence of Silicone Gel for Encapsulation in IGBT Power Modules

Silicone gel is a prevailing material for encapsulation in insulated gate bipolar transistor(IGBT)power modules.The space charge transport behavior in silicone gel is significant to evaluate the electrical insulation characteristics.This paper focuses on the trap characteristics and electrical properties of the silicone gel,which were rarely studied before.The experiments are performed on the surface potential decay of silicone gel after the charge injection.Then,the energy distributions of electron or hole traps are determined by a double-trap energy level model,which can be fitted by the Gaussian distribution.In addition,the mobilities of positive and negative charges are determined,which are 1.38×10^(-12) m^(2)·V^(-1)·s^(-1) and 1.74×10^(12) m^(2)·V^(-1)·s^(-1),respectively.Furthermore,considering the heat as a byproduct resulting in thermal issues,the temperature-dependence of surface potential decay characteristics are also studied in this paper.When temperature rises,the decay rate of surface potential increases,especially when the temperature is higher than 80℃.Finally,the contrastive analysis illustrates that the trap characteristics of silicone gel are between the trap characteristics in liquid-state material and solid-state material,which supports the phenomenon that silicone gel is more resistive to the sharp edges in power modules.This work can provide a useful reference for the design of encapsulation in high-voltage IGBT power modules.

Transient electric field of the combined insulation structure under positive periodic square waveform voltage:Analytical analysis and application

The working voltage of the high-voltage high-power electronic devices is the positive periodic square waveform(PPSW)voltage,which is much different from the conventional AC or DC voltage.For the composite insulation structure of devices,it is important to analyse the transient electric field under the PPSW voltage.However,the existing investigations are often conducted under the electrostatic field due to the high frequency of the PPSW voltage.Thus,the transient characteristics of the electric field are missed.To obtain some qualitative conclusions,this paper focusses on the theoretical analysis of the transient characteristics of electric field for the composite insulation structure under the PPSW voltage.First,the formula of the electric field intensity and the interfacial charge density are derived analytically.Second,the influence of the cycle and the duty cycle on the transient characteristics are investigated.Third,the maximum of the electric field intensity and the interfacial charge density in the positive square waveform steady-state are discussed in detail.Besides,the engineering calculation methods for obtaining these maximum values are also suggested.Lastly,an actual model is employed to testify the validity of the analytical analysis.This work is significant for the numerical calculation of the transient electric field of composite insulation structure under the PPSW voltage in engineering.

Interface Finite Element Method with Lower Calculation Amount for Step Size-varying Electro-quasistatic Field Problem

A novel FEM called interface finite element method(I-FEM)is proposed for the step size-varying electro-quasistatic field(EQS)in this paper.First,the corresponding equation and interface conditions for I-FEM are given.Then,the numerical principle of I-FEM is conducted.In the proposed method,by the inverse matrix modification lemma,the calculation amount of I-FEM is decreased greatly.Furthermore,the corresponding example is given to verify the effectiveness and correctness of IFEM.At last,the error analysis and universal promotion of the proposed I-FEM are given.Compared with the normal FEM,I-FEM can greatly decrease the calculation amount while the numerical accuracy of I-FEM is even better than the normal FEM in some case.

An Improved Behavioral Model for High-voltage and High-power IGBT Chips

High-voltage and high-power IGBT chips have a noticeable carrier storage effect,which is related to the load current.However,the research on the carrier storage effect of existing IGBT behavior models is insufficient.In this paper,An improved behavioral model for high-voltage and high-power insulated gate bipolar transistor(IGBT)chips is proposed,which could be used under different load conditions.The problems for applying the traditional behavioral model to more load conditions are discussed.Carrier behavior,in the wide base region,is analyzed,and the analytical expression of the carrierstorage-effect equivalent capacitance and the initial value of the tail current are provided to establish an improved IGBT behavioral model.A corresponding parameter extraction method is proposed.In order to verify the improved behavioral model,an experimental platform is built for resistive load and inductive load,and the results show that the accuracy of the improved behavioral model is much better than that of the traditional model.In addition,the errors of the improved model are within 12.5%under different current and load types.Considering that the maximum error of other models,which could be applied in a variety of load conditions,is more than 25%,the accuracy of the model proposed in this paper is excellent.

Time-domain and Frequency-domain Analyses of PETT Oscillation in Press Pack IGBTs

Plasma extraction transit time(PETT)oscillation might appear in IGBT devices,which is harmful to the electromagnetic compatibility(EMC)of a renewable energy system.To eliminate this oscillation,its frequency-domain characteristics in wire-bonded IGBT devices have been extensively studied.However,the time-domain analysis of PETT oscillation,especially in Press Pack IGBT(PPI)devices,has not attracted enough attention yet.In this paper,PETT oscillations with multi-chips in PPI devices are systematically investigated by experiments.It is first reported there are multiple resonant oscillations at the tail period when multi-chips turn off.Oscillations overlap in the time domain waveforms,which lead PETT oscillation to be more serious in multi-chips.Then,PETT oscillation is divided into three different feedback states for the first time.For the IGBT chip in the PETT oscillation,its physical based model and behavior model are proposed,which further form the equivalent circuit as the two-port network.Moreover,it is indicated that only parallel resonances can lead to PETT oscillation,which is consistent with experiment results.

Interface Finite Volume Method with Low Calculating Amount for Step Size Varying Electro-Quasistatic Field Problem

In this paper,a novel numerical method called interface finite volume method(I-FVM)for calculation of step-varying Electro-quasistatic(EQS)field is proposed.First,the principle of I-FVM is derived.Then,with numerical example of double layers parallel plate structure under step voltage which has an analytical solution,effectiveness and correctness of the I-FVM are verified.It can be found the calculating time of I-FVM is only 30%of normal FVM without decreasing accuracy during the whole calculating process.Furthermore,an engineering example about the electric field of DBC(Direct Bonding Copper)structure in a high voltage IGBT device is given.It can be found that accuracy of the I-FVM is the same as normal FVM,while time cost of I-FVM is only 20.8%of normal FVM.At last,the I-FVM is extended to one dimension based on the two-direction tri-diagonal matrix algorithm(TDMA)method given in this paper which can save processing of LU decomposition compared to one-dimensional traditional TDMA.In conclusion,the novel method called I-FVM proposed in this paper can decrease calculating amount for a step size varying electro-quasistatic field calculation problem.It may be a good method for large-scale EQS field calculation.

Partial Discharge Measurement and Analysis in High Voltage IGBT Modules Under DC Voltage

Insulation performance of high voltage IGBT modules is one of the key attributes in power system applications.However,the existing standards of IGBT devices and research on the evaluation of insulation performance of high voltage IGBT modules are insufficient;for example,partial discharge resistance under DC voltage blocking condition is not considered.In this paper,a new test was proposed to allow the measurement of partial discharges in all the components of IGBT modules under DC voltage.The topology of the measuring circuit is arranged in the polarity discrimination way to exclude the interference,and the voltage and discharge current waveforms during the partial discharge process are measured by the wideband time domain measurement technique.According to the proposed test,the discharge phenomenon of the IGBT modules below the rating voltage were detected.A comprehensive waveform analysis on the voltage and discharge current was performed,and the influence of the applied voltage on the waveform parameters was obtained.The waveform parameters are influenced by the applied voltage and insulation structure,which enables the discrimination of the causes of the observed partial discharge in the IGBT module under DC voltage by the waveform analysis technique.Based on the waveform analysis technique,the types and causes of the observed partial discharges were discussed and inferred,and the correctness of the inference was further verified by observation.The proposed test and waveform analysis technique provide the possibility to evaluate and distinguish partial discharges in the high voltage IGBT module under DC voltage,which may be helpful to insulation performance evaluation and insulation defect diagnosis in high voltage IGBT module.

Time-domain Finite Element Method for Transient Electric Field and Transient Charge Density on Dielectric Interface

This paper is devoted to solving the transient electric field and transient charge density on the dielectric interface under the electroquasistatic(EQS)field conditions with high accuracy.The proposed method is suitable for both 2-D and 3-D applications.Firstly,the governing equations represented by scalar electric potential are discretized by the nodal finite element method(FEM)in space and the finite difference method in time.Secondly,the transient constrained electric field equation on the boundary(TCEFEB)is derived to calculate the normal component of the transient electric field intensities on the Dirichlet boundary and dielectric interface as well as the transient charge density on the dielectric interface.Finally,a 2-D numerical example is employed to demonstrate the validity of the proposed method.Furthermore,the comparisons of the numerical accuracy of the proposed method in this paper with the existing FEMs for electric field intensity and charge density on the dielectric interface are conducted.The results show that the numerical accuracy of the proposed method for calculating the normal component of transient electric field intensities on the Dirichlet boundary and dielectric interface as well as the transient charge density on the dielectric interface is close to that of nodal electric potential and an order of magnitude higher than those of existing FEMs.

Comparison Between the Audible Noises Generated from Single Corona Source Under DC and AC Corona Discharge

The corona-generated audible noise(AN)factor is an important consideration in the design and operation of ultrahigh voltage direct current(DC)and alternate current(AC)transmission lines.Due to the differences in discharge process and corona-generated space charges between the DC and AC corona discharge,the audible noise from DC and AC corona has different characteristics.This paper conducts a series of experiments by measuring the time-domain waveforms of the audible noise from a single corona source under DC and AC voltage.Sound pressure pulses are extracted from a correlation analysis,and then a detailed comparison of the basic characteristics of DC and AC corona-generated AN in time-domain and frequency spectrum is given.Results from this paper stand to contribute to an explanation of existing results in AN measurement and analysis from DC and AC transmission lines.

Characterization of Electric Field Distribution Within High Voltage Press-packed IGBT Submodules Under Conditions of Repetitive Turn-on and Turn-off

The high-voltage high-power press-packed IGBT(PPI)devices are the key component of the DC transmission apparatus.A PPI device is composed of several PPI submodules.In general,the PPI submodule works in a state of repetitive turn-on and turn-off,and the corresponding working voltage is the positive periodic square waveform(PPSW)voltage,which is much different from the conventional AC or DC voltage.In addition,insulation capability is one of the most critical challenges in the design and fabrication of PPI devices.To improve the insulation capability of the device,composite insulation structures with multiple dielectrics are usually employed.Under the PPSW voltage,it is essential to analyze the transient electric field to solve the insulation challenge of the PPI devices.However,the electric field of the PPI is often calculated under the electrostatic field or DC field.Moreover,the transient characteristics of the electric field are ignored.Therefore,this paper focuses on the analysis of the transient characteristics of the electric field of the PPI submodule under the PPSW voltage.The influences of the waveform parameters of the PPSW voltage on the transient characteristics are demonstrated in detail.This study is significant for the insulation analysis and design of the PPIs.

Influence of frequency on the surface discharge characteristics of PEEK under positive repetitive square voltage

In this study, the surface discharge current pulses of polyetheretherketone (PEEK) material under positive repetitive square voltage in a nitrogen atmosphere are measured. The influences of different voltage amplitudes and frequencies on the detail parameters of forward discharge and backward discharge current pulses are statistically analysed. The results show that as the square voltage amplitude increases, the current pulse amplitude, fall time and pulse width of both forward and backward discharge current increase, and the rise time does not change significantly. As the voltage frequency increases, current pulse amplitude, fall time and pulse width of both forward and backward discharge current decrease, and the rise time does not change significantly. Due to the independence of the discharge at different repetitive cycles, the specific discharge process in one cycle is analysed in detail to explain the influence mechanism of the voltage amplitude and frequency on the discharge current. By mean of the Richardson-Schottky and the Cavallini relaxation model, the relationship between discharge voltage ratio and surface charge, and the decay process of surface discharge are analysed. Furthermore, the influences of amplitude and frequency of the positive repetitive square voltage on the PEEK surface current pulses are explained qualitatively.