Marine risers play a key role in the deep and ultra-deep water oil and gas production. The vortex-induced vibration （VIV） of marine risers constitutes an important problem in deep water oil exploration and productio...Marine risers play a key role in the deep and ultra-deep water oil and gas production. The vortex-induced vibration （VIV） of marine risers constitutes an important problem in deep water oil exploration and production. VIV will result in high rates of structural failure of marine riser due to fatigue damage accumulation and diminishes the riser fatigue life. In-service monitoring or full scale testing is essential to improve our understanding of V1V response and enhance our ability to predict fatigue damage. One ma- rine riser fatigue acoustic telemetry scheme is proposed and an engineering prototype machine has been developed to monitor deep and ultra-deep water risers＇ fatigue and failure that can diminish the riser fatigue life and lead to economic losses and eco-catastrophe. Many breakthroughs and innovation have been achieved in the process of developing an engineering prototype machine. Sea trials were done on the 6th generation deep-water drilling platform HYSY-981 in the South China Sea. The inclination monitoring results show that the marine riser fatigue acoustic telemetry scheme is feasible and reliable and the engineering prototype machine meets the design criterion and can match the requirements of deep and ultra-deep water riser fatigue monitoring. The rich experience and field data gained in the sea trial which provide much technical support for optimization in the engineering prototype machine in the future.展开更多
The surface ion-imprinting concept and chitosan incorporated sol-gel process were applied to the preparation of a new attapulgite-supported organic-inorganic hybrid polymer for selective separation of Sr(II) from aque...The surface ion-imprinting concept and chitosan incorporated sol-gel process were applied to the preparation of a new attapulgite-supported organic-inorganic hybrid polymer for selective separation of Sr(II) from aqueous solution. The prepared polymer was characterized with SEM, IR and XRD. The results showed that as a sorbent, it had good configuration and binding sites. Its adsorption behaviors for Sr(II) was investigated by FAAS and ICP-AES. The effects on adsorption capacities, including pH, quiescent time, and adsorbent amount were discussed, and the adsorption isothermal curve was obtained. Then the Kd a parameter estimating relative adsorbability, was conducted to study the selectivity towards Sr(II) of the prepared polymer. Under the optimum conditions, the ion-imprinted polymer offered a fast kinetics for the adsorption of Sr(II) and the maximum capacity was 12.9mg/g. The Kd and K parameters estimating relative adsorbability towards target ion, suggested that selective recognition of the ion-imprinted polymer towards Sr(II) was much higher than that of the non-imprinted polymer and attapulgite. Furthermore, the ion-imprinted polymer is of great regeneration capacity. The prepared functional polymer was shown to be promising for selective preseparation and enrichment of trace Sr(II) in environmental samples.展开更多
Acylation reaction of anthracene with oxalyl chloride in the presence of [Emim]Cl-AlCl3 ionic liquid has been investigated. Pure 1,2-aceanthryenedione, which is used as intermediate of functional aromatic polymer mate...Acylation reaction of anthracene with oxalyl chloride in the presence of [Emim]Cl-AlCl3 ionic liquid has been investigated. Pure 1,2-aceanthryenedione, which is used as intermediate of functional aromatic polymer material, was obtained by recrystalling the reaction mixture with aether and was determined by GC/MS, 1↑HNMR and FTIR analysis. The influences of various parameters, such as the contents of AlCl3 in [Emim]Cl-AlCl3, the amount of acylation agent, amount of [Emim]Cl-AlCl3, reaction temperature and reaction time were investigated. The optimum conditions were as follows： the molar fraction of AlCl3 in ionic liquid [x（AlCl3）] being 0.67, molar ratio of ionic liquid to anthracene being 2：1, molar ratio of oxalyl chloride to anthracene being 2：1, reaction temperature being 40℃ and reaction time being 6h. Under above conditions, the yield and selectivity of 1,2-aceanthrylenedione can reach 91.5% and 98.3% respectively. Further more, [Emim]Cl-AlCl3 ionic liquid, compared with metal halides such as AlCl3, was found to catalyze the reaction as a novel environmental friendly catalyst and solvent and can be reused.展开更多
基金supported in part by the National Science and Technology Major Project of China (2011ZX 05026-001-06)the National Natural Science Foundation of China (51249005 60972153)
文摘Marine risers play a key role in the deep and ultra-deep water oil and gas production. The vortex-induced vibration （VIV） of marine risers constitutes an important problem in deep water oil exploration and production. VIV will result in high rates of structural failure of marine riser due to fatigue damage accumulation and diminishes the riser fatigue life. In-service monitoring or full scale testing is essential to improve our understanding of V1V response and enhance our ability to predict fatigue damage. One ma- rine riser fatigue acoustic telemetry scheme is proposed and an engineering prototype machine has been developed to monitor deep and ultra-deep water risers＇ fatigue and failure that can diminish the riser fatigue life and lead to economic losses and eco-catastrophe. Many breakthroughs and innovation have been achieved in the process of developing an engineering prototype machine. Sea trials were done on the 6th generation deep-water drilling platform HYSY-981 in the South China Sea. The inclination monitoring results show that the marine riser fatigue acoustic telemetry scheme is feasible and reliable and the engineering prototype machine meets the design criterion and can match the requirements of deep and ultra-deep water riser fatigue monitoring. The rich experience and field data gained in the sea trial which provide much technical support for optimization in the engineering prototype machine in the future.
基金China National Science Foundation (No.20877036)Science and Technology Ministry of China (N0.05C26213100474)
文摘The surface ion-imprinting concept and chitosan incorporated sol-gel process were applied to the preparation of a new attapulgite-supported organic-inorganic hybrid polymer for selective separation of Sr(II) from aqueous solution. The prepared polymer was characterized with SEM, IR and XRD. The results showed that as a sorbent, it had good configuration and binding sites. Its adsorption behaviors for Sr(II) was investigated by FAAS and ICP-AES. The effects on adsorption capacities, including pH, quiescent time, and adsorbent amount were discussed, and the adsorption isothermal curve was obtained. Then the Kd a parameter estimating relative adsorbability, was conducted to study the selectivity towards Sr(II) of the prepared polymer. Under the optimum conditions, the ion-imprinted polymer offered a fast kinetics for the adsorption of Sr(II) and the maximum capacity was 12.9mg/g. The Kd and K parameters estimating relative adsorbability towards target ion, suggested that selective recognition of the ion-imprinted polymer towards Sr(II) was much higher than that of the non-imprinted polymer and attapulgite. Furthermore, the ion-imprinted polymer is of great regeneration capacity. The prepared functional polymer was shown to be promising for selective preseparation and enrichment of trace Sr(II) in environmental samples.
基金National Natural Science Foundation of China (No.20207003)
文摘Acylation reaction of anthracene with oxalyl chloride in the presence of [Emim]Cl-AlCl3 ionic liquid has been investigated. Pure 1,2-aceanthryenedione, which is used as intermediate of functional aromatic polymer material, was obtained by recrystalling the reaction mixture with aether and was determined by GC/MS, 1↑HNMR and FTIR analysis. The influences of various parameters, such as the contents of AlCl3 in [Emim]Cl-AlCl3, the amount of acylation agent, amount of [Emim]Cl-AlCl3, reaction temperature and reaction time were investigated. The optimum conditions were as follows： the molar fraction of AlCl3 in ionic liquid [x（AlCl3）] being 0.67, molar ratio of ionic liquid to anthracene being 2：1, molar ratio of oxalyl chloride to anthracene being 2：1, reaction temperature being 40℃ and reaction time being 6h. Under above conditions, the yield and selectivity of 1,2-aceanthrylenedione can reach 91.5% and 98.3% respectively. Further more, [Emim]Cl-AlCl3 ionic liquid, compared with metal halides such as AlCl3, was found to catalyze the reaction as a novel environmental friendly catalyst and solvent and can be reused.
