An electron donor-π-bridge-electron acceptor(D-π-A) optical functional organic compound comprising a triphenylamine moiety as the electron donor and pyridine moiety as the electron acceptor was synthesized. The stru...An electron donor-π-bridge-electron acceptor(D-π-A) optical functional organic compound comprising a triphenylamine moiety as the electron donor and pyridine moiety as the electron acceptor was synthesized. The structure of the compound was solved by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P21, with a = 9.753(5), b = 8.815(5), c = 25.554(5) ?, β = 96.315(5)°, V = 2184(2) ?~3, Z = 2, D_c = 1.136 g/m^3, F(000) = 792, Μr = 746.92, μ = 0.069 mm^(-1), the final R = 0.0658 and wR = 0.1730 for 6790 observed reflections with I > 2(I). Study of nonlinear optical properties shows that the compound exhibits excellent two-photon excited fluorescence with the two-photon absorption cross-section value of 116 GM. The structure-property relationship was researched in detail through X-ray crystallography and quantum chemical calculation. Result of living cell imaging experiment shows its potential in fluorescence microscopy bioimaging.展开更多
An identification-based approach for aircraft engine modeling using the nonlinear HammersteinWiener representation was proposed.Hammerstein-Wiener modeling for both limited flight envelope and extended flight envelope...An identification-based approach for aircraft engine modeling using the nonlinear HammersteinWiener representation was proposed.Hammerstein-Wiener modeling for both limited flight envelope and extended flight envelope was investigated.Simulation shows that the resulting model can be valid over 10%variation of rotational speed of the engine,compared with those linear models that are only valid over 3%—5%change of rotational speed.It is further demonstrated that the proposed method can be utilized over large envelope up to 20% variation of rotational speed of the engine.The fundamental idea is to use nonlinear models to extend the feasible/valid region rather than those linear models.This may consequently simplify the switching logic in the onboard digital control units.This is often overlooked in aircraft engine control community,but has been emphasized in the research.展开更多
基金supported by the Major Project of Natural Science Research in Universities of Anhui Province(KJ2018ZD037,KJ2018A0333)Key Project of Youth Talents in Universities of Anhui Province(gxyqZD2017067)+5 种基金National Natural Science Foundation of China(21401024)Natural Science Foundation of Anhui Province(1508085MB21)National Students Research Training Program(201810371028)Research Innovation Team of Fuyang Normal University(kytd201710)Horizontal Cooperation Project of Fuyang Municipal Government and Fuyang Normal University(XDHX2016011,XDHX2016004)Anhui University Research Innovation Platform Team Project(201549)
文摘An electron donor-π-bridge-electron acceptor(D-π-A) optical functional organic compound comprising a triphenylamine moiety as the electron donor and pyridine moiety as the electron acceptor was synthesized. The structure of the compound was solved by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P21, with a = 9.753(5), b = 8.815(5), c = 25.554(5) ?, β = 96.315(5)°, V = 2184(2) ?~3, Z = 2, D_c = 1.136 g/m^3, F(000) = 792, Μr = 746.92, μ = 0.069 mm^(-1), the final R = 0.0658 and wR = 0.1730 for 6790 observed reflections with I > 2(I). Study of nonlinear optical properties shows that the compound exhibits excellent two-photon excited fluorescence with the two-photon absorption cross-section value of 116 GM. The structure-property relationship was researched in detail through X-ray crystallography and quantum chemical calculation. Result of living cell imaging experiment shows its potential in fluorescence microscopy bioimaging.
文摘An identification-based approach for aircraft engine modeling using the nonlinear HammersteinWiener representation was proposed.Hammerstein-Wiener modeling for both limited flight envelope and extended flight envelope was investigated.Simulation shows that the resulting model can be valid over 10%variation of rotational speed of the engine,compared with those linear models that are only valid over 3%—5%change of rotational speed.It is further demonstrated that the proposed method can be utilized over large envelope up to 20% variation of rotational speed of the engine.The fundamental idea is to use nonlinear models to extend the feasible/valid region rather than those linear models.This may consequently simplify the switching logic in the onboard digital control units.This is often overlooked in aircraft engine control community,but has been emphasized in the research.
