We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experime...We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experimental results show that the addition of BSi in the silicone rubber(SR)system significantly increases the tensile shear strength between BSi and epoxy resin(EP),reaching 309%of the original value.On this basis,the mechanism of BSi to enhance the adhesion effect was discussed.The electron deficient B in BSi attracted the electron rich N and O in EP to enhance the chemical interaction,combined with the interfacial migration behavior in the curing process,to improve the adhesion strength.This study provides the design and synthesis ideas of adhesive aids,and a reference for further exploring the interface mechanism of epoxy resin matrix composites.展开更多
To develop an efficient and bio-compatible way to improve the thermal and mechanical properties of addition type liquid silicone rubber（LSR）, a series of modified LSR samples were prepared by introducing octavinyl-p...To develop an efficient and bio-compatible way to improve the thermal and mechanical properties of addition type liquid silicone rubber（LSR）, a series of modified LSR samples were prepared by introducing octavinyl-polyhedral oligosilsesquioxanes（VPOSS） and high purity silicon sol singly or in combination before vulcanization. Significant correlation was found between the loading rate of VPOSS and thermal properties. However, mechanical properties were negatively correlated with VPOSS content within the range experimented, which may be ascribed to material defect caused by uneven distribution and aggregation. Furthermore, test results approved that the introducing of silicon sol indeed affected the stabilities of the polymer by restraining the material defect caused by the aggregation of POSS molecules and improving cross link density. For example, adding 10%-20% of silicon sol into VPOSS（1.0%） modified LSR will increase tear resistance by 43.9%-85.7%, elongation at break by 31.7%-57.3%, residue at 800 ℃ in N2 atmosphere by 32.0%-37.9%, residue at 650 ℃ in air atmosphere by 70.9%-91.6%, respectively. This work proves that, to incorporate VPOSS into LSR by hydrosilylation, and to use silicon sol as dispersant and reinforce filler can become an efficient way to improve the mechanical property, thermal stability and bio-compatibility of LSR in the future.展开更多
基金the Core Research Facilities of College of Chemistry and Molecular Sciences and Wuhan University Test Center and Open Fund of Hubei Key Laboratory of Aerospace Power Advanced Technologythe Open Fund of Hubei Key Laboratory of Aerospace Power Advanced Technologythe Special Fund for Industrial and informatization Industry Foundation Reconstruction and High Quality Development of Manufacturing Industry(No.TC220H068)。
文摘We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experimental results show that the addition of BSi in the silicone rubber(SR)system significantly increases the tensile shear strength between BSi and epoxy resin(EP),reaching 309%of the original value.On this basis,the mechanism of BSi to enhance the adhesion effect was discussed.The electron deficient B in BSi attracted the electron rich N and O in EP to enhance the chemical interaction,combined with the interfacial migration behavior in the curing process,to improve the adhesion strength.This study provides the design and synthesis ideas of adhesive aids,and a reference for further exploring the interface mechanism of epoxy resin matrix composites.
基金Funded by the National Natural Science Foundation of China(No.31170558)
文摘To develop an efficient and bio-compatible way to improve the thermal and mechanical properties of addition type liquid silicone rubber（LSR）, a series of modified LSR samples were prepared by introducing octavinyl-polyhedral oligosilsesquioxanes（VPOSS） and high purity silicon sol singly or in combination before vulcanization. Significant correlation was found between the loading rate of VPOSS and thermal properties. However, mechanical properties were negatively correlated with VPOSS content within the range experimented, which may be ascribed to material defect caused by uneven distribution and aggregation. Furthermore, test results approved that the introducing of silicon sol indeed affected the stabilities of the polymer by restraining the material defect caused by the aggregation of POSS molecules and improving cross link density. For example, adding 10%-20% of silicon sol into VPOSS（1.0%） modified LSR will increase tear resistance by 43.9%-85.7%, elongation at break by 31.7%-57.3%, residue at 800 ℃ in N2 atmosphere by 32.0%-37.9%, residue at 650 ℃ in air atmosphere by 70.9%-91.6%, respectively. This work proves that, to incorporate VPOSS into LSR by hydrosilylation, and to use silicon sol as dispersant and reinforce filler can become an efficient way to improve the mechanical property, thermal stability and bio-compatibility of LSR in the future.
