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Ⅱ/Z型Bi_(2)MoO_(6)/Ag_(2)O/Bi_(2)O_(3)异质结可见光催化降解四环素
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作者 叶茂森 王耀 +3 位作者 许冰 王康康 张胜楠 冯建情 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2024年第3期321-329,I0005-I0008,共13页
构建异质结能够有效抑制光催化剂中光生电子和空穴的快速复合。本研究采用水热法、煅烧法以及溶剂热法合成了Ⅱ/Z型Bi_(2)MoO_(6)/Ag_(2)O/Bi_(2)O_(3)异质结光催化剂,利用不同研究手段分析材料的组成、形貌以及光电化学性能。结果发现... 构建异质结能够有效抑制光催化剂中光生电子和空穴的快速复合。本研究采用水热法、煅烧法以及溶剂热法合成了Ⅱ/Z型Bi_(2)MoO_(6)/Ag_(2)O/Bi_(2)O_(3)异质结光催化剂,利用不同研究手段分析材料的组成、形貌以及光电化学性能。结果发现,复合材料的最佳组成为25%ABOBM(Ag_(2)O/Bi_(2)O_(3)和Bi_(2)MoO_(6)的质量比为1:4)。在可见光照射下25%ABOBM对四环素(TC)的降解效率可达85.6%,明显高于Ag_(2)O/Bi_(2)O_(3)和Bi_(2)MoO_(6),而且三次循环实验后仍具有良好的稳定性。25%ABOBM光催化性能的提高可归因于Ag_(2)O、Bi_(2)O_(3)以及Bi_(2)MoO_(6)之间异质结的构建和特殊形貌的形成。自由基捕获实验和电子顺磁共振谱(EPR)结果表明,h+和·O2-在TC的降解过程中发挥着主要作用,而·OH和1O2发挥着次要作用。实验还探索了相关光催化机理,并利用液相色谱-质谱联用仪(LC-MS)对TC可能的降解路径进行了分析。本研究为双异质结光催化剂的制备及其在有机污染物降解应用方面提供了新的思路。 展开更多
关键词 Bi_(2)MoO_(6) Ag_(2)O Bi_(2)O_(3) 光催化降解 四环素 异质结
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Monitoring and Evaluation of Present Situation of Environmental Quality in the Sea Area near the Aojiang Estuary in Wenzou 被引量:1
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作者 ye maosen Yang Dan +4 位作者 Zhang Rongbao Xu Hengtao Zhang Haisheng Yao Dongping ye Xinrong 《Meteorological and Environmental Research》 CAS 2017年第3期57-61,66,共6页
Based on the monitoring results of environmental quality in the sea area near the Aojiang estuary in Wenzou during 2010-2012,the present situation of environmental quality in the sea area was analyzed and evaluated. T... Based on the monitoring results of environmental quality in the sea area near the Aojiang estuary in Wenzou during 2010-2012,the present situation of environmental quality in the sea area was analyzed and evaluated. The results show that p H,DO,CODMn,petroleum,and heavy metals( Cu,Pb,Zn,Cd,Hg,As and Cr) in the sea area near the Aojiang estuary did not exceed the second-class standard of Seawater Quality Standard( GB 3097-1997),but both inorganic nitrogen and reactive phosphate in the sea area exceeded the second-class standard seriously,and the water quality of the sea area was in an eutrophic state; domestic sewage and fertilizer loss were the main sources of nitrogen and phosphorus. The standard index of most evaluation factors of sediment quality except for Zn was smaller than 1,meeting the demands of sediment quality for environmental protection. 展开更多
关键词 Sea area NEAR the Aojiang ESTUARY in Wenzou PRESENT SITUATION of environmental QUALITY Monitoring Evaluation Water QUALITY Sediment QUALITY
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Detection of Persistent Organochlorine Pollutants in Eggs of Antarctic Seabirds Based on Gas Chromatography and Their Ecological Environment Significance 被引量:1
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作者 ye maosen Zhang Rongbao +4 位作者 Chen Lihong Lin Bo Zheng Fangqin Lu Bing ye Xinrong 《Meteorological and Environmental Research》 CAS 2016年第1期48-51,54,共5页
By using internal standard method based on gas chromatography-electron capture detector (GC-ECD), the contents of persistent or- ganochlorine pollutants polychorinated biphenyls (PCBs) and organochlorine pesticid... By using internal standard method based on gas chromatography-electron capture detector (GC-ECD), the contents of persistent or- ganochlorine pollutants polychorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in eggs of seabirds ( Catharacta Ionnbergi, Cathar- acta maccormicki, Pygoscelis papua and Macronectes giganteus) breeding on King George Island, Antarctica were detected, and their ecological environment significance was discussed. The results showed that the recovery of various compounds ranged from 68.6% to 90.8% ; relative stand- ard deviation (RSD) was 3.6%, and the lowest detection limits of PCBs and OCPs were 0.8 - 16 and 2 - 12 pg respectively, which could meet the demands for the residue analysis of trace persistent organochlorine pollutants in the eggs of Antarctic seabirds. The contents of PCBs, DDTs, HCB and HCHs in the eggs of Antarctic seabirds were 0.5 -515.5, 2.0 -304.4,0.5 -70.5, and 0.5 -2.0 ng/g respectively. In addition, the accumula- tion of PCBs and OCPs in the skuas was enhanced gradually through the food chain. The maximums of persistent organochlorine pollutants ap- peared in the eggs of C. Ionnbergi, followed by the eggs of C. maccomicki. The detection of OCPs and PCBs in the eggs of Antarctic seabirds was not interfered by other compounds containing chlorine, showing that the extraction, purification and detection method was suitable for the analysis of OCPs and PCBs in the eggs of Antarctic seabirds and has high sensitivity and reliability. 展开更多
关键词 Gas chromatography Eggs of Antarctic penguins and skuas Persistent organochlorine pollutants China
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基于粗糙集法的五指毛桃补骨脂素合成酶基因序列获取与分析 被引量:1
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作者 叶茂森 瞿静涛 +3 位作者 杨琳 郑豫 刘柄良 张君诚 《分子植物育种》 CAS 北大核心 2021年第22期7398-7407,共10页
多重比对补骨脂素合成酶(psoralen synthase,PS)基因信息,预测单序列能量最低状态,基于粗糙集法,建立PS保守结构域的氨基酸残基识别体系,获取五指毛桃(Ficus hirta Vahl)的转录本中该Unigene序列信息,并通过生物信息学验证。结果表明,... 多重比对补骨脂素合成酶(psoralen synthase,PS)基因信息,预测单序列能量最低状态,基于粗糙集法,建立PS保守结构域的氨基酸残基识别体系,获取五指毛桃(Ficus hirta Vahl)的转录本中该Unigene序列信息,并通过生物信息学验证。结果表明,通过五指毛桃RNA测序得到61287240条高质量读长(Clean reads),注释得到179974条Unigene序列。采用粗糙集法,预测40条PS基因有10个区域的氨基酸序列同源性高。通过转录本比对,获取五指毛桃1751 bp Unigene序列,开放阅读框1533 bp,编码510个氨基酸,属于细胞色素P450超家族的成员,相对分子质量为57.8 kD,等电点为6.48,亚细胞定位于内质网;二级结构α-螺旋、无规则卷曲和延伸连的比例分别为50.39%、33.73%、10.98%。虽然该序列编码的氨基酸与其他植物PS的相似性不高,但与大阿米芹、珊瑚菜等植物PS蛋白的三级结构极为相似,与同为桑科的川桑补骨脂素合成酶序列聚在一支。综上结果验证了基于粗糙集法,建立PS保守结构预测,获取PS的Unigene为五指毛桃PS基因,为基于植物转录组测序,获取目标基因,提供一种保守结构域的氨基酸序列获取方法。 展开更多
关键词 补骨脂素 五指毛桃 粗糙集法 保守结构域 转录组测序
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