Fluid identification and tight oil layer classification for the southwestern Mahu Sag,Junggar Basin using NMR logging-based spectrum decomposition

The intricate distribution of oil and water in tight rocks makes pinpointing oil layers challenging.While conventional identification methods offer potential solutions,their limited accuracy precludes them from being effective in their applications to unconventional reservoirs.This study employed nuclear magnetic resonance(NMR)spectrum decomposition to dissect the NMR T_(2)spectrum into multiple subspectra.Furthermore,it employed laboratory NMR experiments to ascertain the fluid properties of these sub-spectra,aiming to enhance identification accuracy.The findings indicate that fluids of distinct properties overlap in the T_(2)spectra,with bound water,movable water,bound oil,and movable oil appearing sequentially from the low-value zone to the high-value zone.Consequently,an oil layer classification scheme was proposed,which considers the physical properties of reservoirs,oil-bearing capacity,and the characteristics of both mobility and the oil-water two-phase flow.When applied to tight oil layer identification,the scheme's outcomes align closely with actual test results.A horizontal well,deployed based on these findings,has produced high-yield industrial oil flow,underscoring the precision and dependability of this new approach.

Kinetic mechanism of copper extraction from methylchlorosilane slurry residue using hydrogen peroxide as oxidant

Copper was extracted from methylchlorosilane slurry residue by a direct hydrogen peroxide leaching method.A number of experimental parameters were analyzed to determine the extraction efficiency of copper.The extraction efficiency of copper reached 98.5%under the optimal leaching conditions,such as the hydrogen peroxide concentration of 1.875 mol·L^(-1),the leaching temperature of 323 K,the liquid–solid ratio of 20 ml·g^(-1),and the stirring speed of 300 r·min^(-1).The leaching kinetics of the copper extraction process was then described by the shrinking core model.There were two stages.The first stage was controlled by chemical reactions,while the second stage was controlled by interface transfer and product layer diffusion.The activation energy and kinetic control equations were determined,as well as an explanation of the leaching mechanism of copper extraction based on kinetic analysis and materials characterization.Copper resources can be recovered from the methylchlorosilane slurry residue efficiently and inexpensively with the methods used in this study.

Genesis and microscopic characteristics of tight reservoirs in the Fengcheng Formation, at the southern margin of the Mahu Sag

The tight reservoirs of the Fengcheng Formation at the southern margin of the Mahu Sag have strong heterogeneity due to the diversity in their pore types, sizes, and structures. The microscopic characteristics of tight reservoirs and the mechanisms that generate them are of significance in identifying the distribution of high-quality reservoirs and in improving the prediction accuracy of sweet spots in tight oil reservoirs. In this paper, high-pressure mercury intrusion (HPMI) and nuclear magnetic resonance (NMR) experiments were carried out on samples from the tight reservoirs in the study area. These experimental results were combined with cluster analysis, fractal theory, and microscopic observations to qualitatively and quantitatively evaluate pore types, sizes, and structures. A classification scheme was established that divides the reservoir into four types, based on the microstructure characteristics of samples, and the genetic mechanisms that aided the development of reservoir microstructure were analyzed. The results show that the lower limit for the tight reservoir in the Fengcheng Formation is Φ of 3.5% and K of 0.03 mD. The pore throat size and distribution span gradually decrease from Type I, through Type II and Type III reservoirs to non-reservoirs, and the pore type also evolves from dominantly intergranular pores to intercrystalline pores. The structural trend shows a decrease in the ball-stick pore-throat system and an increase in the branch-like pore-throat system. The dual effects of sedimentation and diagenesis shape the microscopic characteristics of pores and throats. The sorting, roundness, and particle size of the original sediments determine the original physical properties of the reservoir. The diagenetic environment of ‘two alkalinity stages and one acidity stage’ influenced the evolution of pore type and size. Although the cementation of authigenic minerals in the early alkaline environment adversely affected reservoir properties, it also alleviated the damage of the later compaction to some extent. Dissolution in the mid-term acidic environment greatly improved the physical properties of this tight reservoir, making dissolution pores an important reservoir space. The late alkaline environment occurred after large-scale oil and gas accumulation. During this period, the cementation of authigenic minerals had a limited effect on the reservoir space occupied by crude oil. It had a more significant impact on the sand bodies not filled with oil, making them function as barriers.

Remote ischemic conditioning-induced hyperacute and acute responses of plasma proteome in healthy young male adults:a quantitative proteomic analysis

Background: Long-term remote ischemic conditioning (RIC) has been proven to be beneficial in multiple diseases, such as cerebral and cardiovascular diseases. However, the hyperacute and acute effects of a single RIC stimulus are still not clear. Quantitative proteomic analyses of plasma proteins following RIC application have been conducted in preclinical and clinical studies but exhibit high heterogeneity in results due to wide variations in experimental setups and sampling procedures. Hence, this study aimed to explore the immediate effects of RIC on plasma proteome in healthy young adults to exclude confounding factors of disease entity, such as medications and gender. Methods: Young healthy male participants were enrolled after a systematic physical examination and 6-month lifestyle observation. Individual RIC sessions included five cycles of alternative ischemia and reperfusion, each lasting for 5 min in bilateral forearms. Blood samples were collected at baseline, 5 min after RIC, and 2 h after RIC, and then samples were processed for proteomic analysis using liquid chromatography-tandem mass spectrometry method. Results: Proteins related to lipid metabolism (e.g., Apolipoprotein F), coagulation factors (hepatocyte growth factor activator preproprotein), members of complement cascades (mannan-binding lectin serine protease 1 isoform 2 precursor), and inflammatory responses (carboxypeptidase N catalytic chain precursor) were differentially altered at their serum levels following the RIC intervention. The most enriched pathways were protein glycosylation and complement/coagulation cascades. Conclusions: One-time RIC stimulus may induce instant cellular responses like anti-inflammation, coagulation, and fibrinolysis balancing, and lipid metabolism regulation which are protective in different perspectives. Protective effects of single RIC in hyperacute and acute phases may be exploited in clinical emergency settings due to apparently beneficial alterations in plasma proteome profile. Furthermore, the beneficial effects of long-term (repeated) RIC interventions in preventing chronic cardiovascular diseases among general populations can also be expected based on our study findings.