Software engineering is an engineering discipline that guides software developers to carry out software development,software maintenance,and software management.The traditional evaluation methods of software engineeri...Software engineering is an engineering discipline that guides software developers to carry out software development,software maintenance,and software management.The traditional evaluation methods of software engineering courses do not highlight the training goal of outcomebased education(OBE).This paper systematically studies the evaluation methods for practical courses in software engineering from three aspects:course evaluation guidelines,course evaluation methods and course evaluation effects;establishes a comprehensive,scientific,and objective system of course evaluation;effectively measures students’learning effect;promotes teachers to continuously improve the teaching process;and thus improves the teaching quality of software engineering courses.Besides the general approach,this paper also takes software project construction practice as an example to demonstrate the effect of the proposed approach.展开更多
With the rapid development of computer technology,network and information technology have been widely used in people’s daily lives,which has brought great convenience to labor and life.At the same time,people are inc...With the rapid development of computer technology,network and information technology have been widely used in people’s daily lives,which has brought great convenience to labor and life.At the same time,people are increasingly dependent on computer technology.In this case,the social demand for computer professionals is increasing.However,due to the rapid changes and continuous updates of computer technology,the training of talents in computer specialty in China is far from meeting the demand and quality requirements of the society for this kind of talents.Colleges and universities are the important departments that cultivate computer professionals and technicians for the society.When cultivating talents in computer specialty,colleges and universities must conform to the requirements of the development of the times,adjust teaching strategies in a timely manner according to the actual needs of the society,build a talent training system,build a practical training teaching system of computer specialty,innovate teaching modes and teaching contents,and improve students’professional skills through perfect practical teaching,so as to ensure that they can skillfully apply computer technology to solve practical problems in the learning process and further improve their employment competitiveness.Therefore,this paper analyzes the practical teaching system of computer specialty,puts forward corresponding solutions to the existing problems,constructs a multi-collaborative practical training system,and implements the system.The implementation results show that the system can better meet the needs of students at different levels,and the results are fairer.Students’recognition and sense of acquisition of courses have also been greatly improved.The accumulated experience and data also provide good support for our continuous improvement of the system in the future.展开更多
Software engineering is a highly practical major,and students need a lot of hands-on practice to transform the theoretical contents learned in class into the practical ability to solve practical problems,so practical ...Software engineering is a highly practical major,and students need a lot of hands-on practice to transform the theoretical contents learned in class into the practical ability to solve practical problems,so practical courses are an essential and important part in the process of training talents in software engineering.From the point of view of cultivating talents in software engineering,this paper expounds the important position of practical courses in software engineering in the process of cultivating talents,analyzes the problems in the existing practical courses,and puts forward the construction ideas and characteristics of practical courses in software engineering which strengthen the foundation,advance steadily,and face the output.Taking the practical course for software system development as an example,this paper introduces in detail the concrete implementation process,achievements,existing problems and countermeasures of the course.展开更多
In the future smart cities,parking lots(PLs)can accommodate hundreds of electric vehicles(EVs)at the same time.This trend creates an opportunity for PLs to serve as a potential flexibility resource,considering growing...In the future smart cities,parking lots(PLs)can accommodate hundreds of electric vehicles(EVs)at the same time.This trend creates an opportunity for PLs to serve as a potential flexibility resource,considering growing penetration of EVs and integration of distributed energy resources DER(such as photovoltaic and energy storages).Given this background,this paper proposes a comprehensive evaluation framework to investigate the potential role of DER-integrated PLs(DPL)with the capability of vehicle-to-grid(V2G)in improving the reliability of the distribution network.For this aim,first,an overview for the distribution system with DPLs is provided.Then,a generic model for the available generation capacity(AGC)of DPLs with consideration of EV scheduling strategy is developed.On the above basis,an iterative-based algorithm leveraging sequential Monte Carlo simulation is presented to quantify the contribution of DPLs to the reliability of the system.In order to verify the effectiveness of the proposed method,a series of numerical studies are carried out.The simulation results show that the integration of DPLs with the V2G capability could help to improve the reliability performance of distribution grid to a great extent and reduce the adverse impact incurred by EV accommodation,if utilized properly.展开更多
In the process of cultivating software engineering professionals,the practical teaching of professional courses is an indispensable link.In order to enable students to understand,consolidate and master theoretical kno...In the process of cultivating software engineering professionals,the practical teaching of professional courses is an indispensable link.In order to enable students to understand,consolidate and master theoretical knowledge,improve the ability to solve problems by combining theory with practice,and achieve the goal of combining theoretical knowledge with practice.Adopting the planning of through-type training,complete the teaching work of three practical courses of software system design,software system construction,and software product construction.Through the implementation of the plan,the digitization of teaching resources,the virtualization of real enterprises,the intelligentization of teaching guidance,the visualization of teaching process,and the panorama of learning process are realized.By adopting the teaching methods of taskdriven online practice teaching,artificial intelligence-based teaching training support and teaching process,and result big data evaluation,the students’comprehensive practical ability can be improved finally,and the whole practice teaching reform can provide experience for the follow-up reform.展开更多
The electrochemical nitrate reduction reaction(NO_(3)RR)to ammonia under ambient conditions is a promising approach for addressing elevated nitrate levels in water bodies,but the progress of this reaction is impeded b...The electrochemical nitrate reduction reaction(NO_(3)RR)to ammonia under ambient conditions is a promising approach for addressing elevated nitrate levels in water bodies,but the progress of this reaction is impeded by the complex series of chemical reactions involving electron and proton transfer and competing hydrogen evolution reaction.Therefore,it becomes imperative to develop an electro-catalyst that exhibits exceptional efficiency and remarkable selectivity for ammonia synthesis while maintaining long-term stability.Herein the magnetic biochar(Fe-C)has been synthesized by a two-step mechanochemical route after a pyrolysis treatment(450,700,and 1000℃),which not only significantly decreases the particle size,but also exposes more oxygen-rich functional groups on the surface,promoting the adsorption of nitrate and water and accelerating electron transfer to convert it into ammonia.Results showed that the catalyst(Fe-C-700)has an impressive NH_(3)production rate of 3.5 mol·h^(−1)·gcat^(−1),high Faradaic efficiency of 88%,and current density of 0.37 A·cm^(−2)at 0.8 V vs.reversible hydrogen electrode(RHE).In-situ Fourier transform infrared spectroscopy(FTIR)is used to investigate the reaction intermediate and to monitor the reaction.The oxygen functionalities on the catalyst surface activate nitrate ions to form various intermediates(NO_(2),NO,NH_(2)OH,and NH_(2))and reduce the rate determining step energy barrier(*NO_(3)→*NO_(2)).This study presents a novel approach for the use of magnetic biochar as an electro-catalyst in NO_(3)RR and opens the road for solving environmental and energy challenges.展开更多
The microstructure design of electrode material is a crucial point to optimize the supercapacitor’s electrochemical properties.In this work,a Bi-based nanocomposite with a three-layer structure(Bi–Bi_(2)O_(3)@carbon...The microstructure design of electrode material is a crucial point to optimize the supercapacitor’s electrochemical properties.In this work,a Bi-based nanocomposite with a three-layer structure(Bi–Bi_(2)O_(3)@carbon armour(CA)/carbon dots(CDs))is synthesized and investigated.This material inherits high capacitance and high activity from bismuth-based materials,the coated CA protects the structure from complete oxidization and improves surface hydrophilicity.Furthermore,CDs in CA can enhance the ion conduction efficiency between the catalyst,carbon membrane,electrolyte.As a consequence,the specific capacitance of the electrode reaches 973 F·g^(−1)under 1 A·g^(−1),the energy density achieves 32.5 Wh·kg^(−1)with a power density of 266.9 W·kg^(−1),with impressive electrochemical stability that Coulomb efficiency of the electrode remains about 100%after 5000 cycles.Furthermore,in-situ Fourier transformation infrared(FT-IR)analyzes the structure evolvement of the material during synthesis and finds that the annealing process of the material removes a great number of oxygen-containing groups of CA and CDs,generating oxygen vacancies,defects,thus active sites,which enhance the capacitance of the material.展开更多
Weather forecasting is crucial to both the demand and supply sides of electricity systems. Temperature has a great effect on the demand side. Moreover, solar and wind are very promising renewable energy sources and ar...Weather forecasting is crucial to both the demand and supply sides of electricity systems. Temperature has a great effect on the demand side. Moreover, solar and wind are very promising renewable energy sources and are, thus, important on the supply side. In this paper, a large vector autoregression(VAR) model is built to forecast three important weather variables for 61 cities around the United States. The three variables at all locations are modeled as response variables. Lag terms are used to capture the relationship between observations in adjacent periods and daily and annual seasonality are modeled to consider the correlation between the same periods in adjacent days and years. We estimate the VAR model with16 years of hourly historical data and use two additional years of data for out-of-sample validation. Forecasts of up to six-hours-ahead are generated with good forecasting performance based on mean absolute error, root mean square error, relative root mean square error, and skill scores. Our VAR model gives forecasts with skill scoresthat are more than double the skill scores of other forecasting models in the literature. Our model also provides forecasts that outperform persistence forecasts by between6% and 80% in terms of mean absolute error. Our results show that the proposed time series approach is appropriate for very short-term forecasting of hourly solar radiation,temperature, and wind speed.展开更多
Photocatalytic reduction of carbon dioxide into valuable chemicals is a sustainable and promising technology that alleviates the greenhouse effect and energy crisis.In this study,the Mn_(3)O_(4)/FeNbO_(4) type Ⅱ hete...Photocatalytic reduction of carbon dioxide into valuable chemicals is a sustainable and promising technology that alleviates the greenhouse effect and energy crisis.In this study,the Mn_(3)O_(4)/FeNbO_(4) type Ⅱ heterojunction photocatalyst with a core-satellite structure was synthesized by the facile soft chemical method.The formation of a nano-heterojunction is supposed to effectively improve light capture,charge transfer,and interfacial charge separation in the photochemical reaction.Meanwhile,the heterojunction has a good ability to capture and activate CO_(2).Our results show that the prepared Mn_(3)O_(4)/FeNbO_(4) photocatalyst exhibit obvious enhanced catalytic properties in the photocatalytic CO_(2) reduction reaction,where the CH_(4) yielding rate is 1.96 and 9.81 times those of FeNbO_(4) and Mn_(3)O_(4),respectively.The transient photovoltage test(TPV)shows that the low frequency electrons are crucial to the effective transfer of photogenerated electrons and holes in the Mn_(3)O_(4)/FeNbO_(4) nano heterojunctions.Analysis of in situ Fourier transform infrared spectroscopy(FTIR)verifies the effective CO_(2) adsorption on the Mn_(3)O_(4)/FeNbO_(4) surface and the high selectivity of CH_(4) products.These properties of the Mn_(3)O_(4)/FeNbO_(4) photocatalyst infer its broad prospects in the fields of carbon fixation and energy conservation.展开更多
Flexibility in plug-in electric vehicle(PEV) charging can reduce the ancillary cost effects of wind variability and uncertainty on electric power systems. In this paper, we study these benefits of PEV charging, demons...Flexibility in plug-in electric vehicle(PEV) charging can reduce the ancillary cost effects of wind variability and uncertainty on electric power systems. In this paper, we study these benefits of PEV charging, demonstrating that controlled PEV charging can reduce costs associated with wind uncertainty and variability. Interestingly, we show that the system does not require complete control of PEV-charging loads to mitigate the negative cost impacts of wind variability and uncertainty. Rather, PEV owners giving the system a two-hour window of flexibility in which to recharge their vehicles provides much of the benefits that giving full charging control does.展开更多
Ammonia plays a vital role in the development of modern agriculture and industry.Compared to the conventional Haber–Bosch ammonia synthesis in industry,electrocatalytic nitrogen reduction reaction(NRR)is considered a...Ammonia plays a vital role in the development of modern agriculture and industry.Compared to the conventional Haber–Bosch ammonia synthesis in industry,electrocatalytic nitrogen reduction reaction(NRR)is considered as a promising and environmental friendly strategy to synthesize ammonia.Here,inspired by biological nitrogenase,we designed iron doped tin oxide(Fe-doped SnO_(2))for nitrogen reduction.In this work,iron can optimize the interface electron transfer and improve the poor conductivity of the pure SnO_(2),meanwhile,the synergistic effect between iron and Sn ions improves the catalyst activity.In the electrocatalytic NRR test,Fe-doped SnO_(2) exhibits a NH_(3) yield of 28.45μg·h^(−1)·mgcat^(−1),which is 2.1 times that of pure SnO_(2),and Faradaic efficiency of 6.54%at−0.8 V vs.RHE in 0.1 M Na_(2)SO_(4).It also shows good stability during a 12-h long-term stability test.Density functional theory calculations show that doped Fe atoms in SnO_(2) enhance catalysis performance of some Sn sites by strengthening N–Sn interaction and lowering the energy barrier of the rate-limiting step of NRR.The transient photovoltage test reveals that electrons in the low-frequency region are the key to determining the electron transfer ability of Fe-doped SnO_(2).展开更多
The large-scale production of ammonia mainly depends on the Haber-Bosch process,which will lead to the problems of high energy consumption and carbon dioxide emission.Electrochemical nitrogen fixation is considered to...The large-scale production of ammonia mainly depends on the Haber-Bosch process,which will lead to the problems of high energy consumption and carbon dioxide emission.Electrochemical nitrogen fixation is considered to be an environmental friendly and sustainable process,but its efficiency largely depends on the activity and stability of the catalyst.Therefore,it is imperative to develop high-efficient electrocatalysts in the field of nitrogen reduction reaction(NRR).In this paper,we developed a BiVO_(4)/TiO_(2) nanotube(BiVO_(4)/TNT)heterojunction composite with rich oxygen vacancies as an electrocatalytic NRR catalyst.The heterojunction interface and oxygen vacancy of BiVO_(4)/TNT can be the active site of N2 dynamic activation and proton transition.The synergistic effect of TiO_(2) and BiVO_(4) shortens the proton transport path and reduces the over potential of chemical reaction.BiVO_(4)/TNT has high ammonia yield of 8.54µg·h^(−1)·cm^(−2) and high Faraday efficiency of 7.70%in−0.8 V vs.RHE in 0.1 M Na_(2)SO_(4) solution.展开更多
Lung cancer is one of the most prevalent and malignant cancers,among which lung adenocarcinoma(LUAD)accounts for the majority and remains a major cause of cancer-related mortality worldwide(Cui et al.,2019).Despite th...Lung cancer is one of the most prevalent and malignant cancers,among which lung adenocarcinoma(LUAD)accounts for the majority and remains a major cause of cancer-related mortality worldwide(Cui et al.,2019).Despite the growing intensity of research on the pathobiology and progression of lung cancer and the fact that many genes have been identified as potential drivers and targets for therapy(Luo et al.,2019;Zhang et al.,2019),the treatment and prognosis of lung cancer patients have hardly improved.Therefore,this study aimed to investigate the precise mechanism of lung cancer development and explore efficient diagnostic and therapeutic methods for clinical treatment.展开更多
文摘Software engineering is an engineering discipline that guides software developers to carry out software development,software maintenance,and software management.The traditional evaluation methods of software engineering courses do not highlight the training goal of outcomebased education(OBE).This paper systematically studies the evaluation methods for practical courses in software engineering from three aspects:course evaluation guidelines,course evaluation methods and course evaluation effects;establishes a comprehensive,scientific,and objective system of course evaluation;effectively measures students’learning effect;promotes teachers to continuously improve the teaching process;and thus improves the teaching quality of software engineering courses.Besides the general approach,this paper also takes software project construction practice as an example to demonstrate the effect of the proposed approach.
文摘With the rapid development of computer technology,network and information technology have been widely used in people’s daily lives,which has brought great convenience to labor and life.At the same time,people are increasingly dependent on computer technology.In this case,the social demand for computer professionals is increasing.However,due to the rapid changes and continuous updates of computer technology,the training of talents in computer specialty in China is far from meeting the demand and quality requirements of the society for this kind of talents.Colleges and universities are the important departments that cultivate computer professionals and technicians for the society.When cultivating talents in computer specialty,colleges and universities must conform to the requirements of the development of the times,adjust teaching strategies in a timely manner according to the actual needs of the society,build a talent training system,build a practical training teaching system of computer specialty,innovate teaching modes and teaching contents,and improve students’professional skills through perfect practical teaching,so as to ensure that they can skillfully apply computer technology to solve practical problems in the learning process and further improve their employment competitiveness.Therefore,this paper analyzes the practical teaching system of computer specialty,puts forward corresponding solutions to the existing problems,constructs a multi-collaborative practical training system,and implements the system.The implementation results show that the system can better meet the needs of students at different levels,and the results are fairer.Students’recognition and sense of acquisition of courses have also been greatly improved.The accumulated experience and data also provide good support for our continuous improvement of the system in the future.
文摘Software engineering is a highly practical major,and students need a lot of hands-on practice to transform the theoretical contents learned in class into the practical ability to solve practical problems,so practical courses are an essential and important part in the process of training talents in software engineering.From the point of view of cultivating talents in software engineering,this paper expounds the important position of practical courses in software engineering in the process of cultivating talents,analyzes the problems in the existing practical courses,and puts forward the construction ideas and characteristics of practical courses in software engineering which strengthen the foundation,advance steadily,and face the output.Taking the practical course for software system development as an example,this paper introduces in detail the concrete implementation process,achievements,existing problems and countermeasures of the course.
基金financially supported by the National Social Science Fund of China(No.19ZDA081)Fundamental Research Funds for the Central Universities(No.2020MS067).
文摘In the future smart cities,parking lots(PLs)can accommodate hundreds of electric vehicles(EVs)at the same time.This trend creates an opportunity for PLs to serve as a potential flexibility resource,considering growing penetration of EVs and integration of distributed energy resources DER(such as photovoltaic and energy storages).Given this background,this paper proposes a comprehensive evaluation framework to investigate the potential role of DER-integrated PLs(DPL)with the capability of vehicle-to-grid(V2G)in improving the reliability of the distribution network.For this aim,first,an overview for the distribution system with DPLs is provided.Then,a generic model for the available generation capacity(AGC)of DPLs with consideration of EV scheduling strategy is developed.On the above basis,an iterative-based algorithm leveraging sequential Monte Carlo simulation is presented to quantify the contribution of DPLs to the reliability of the system.In order to verify the effectiveness of the proposed method,a series of numerical studies are carried out.The simulation results show that the integration of DPLs with the V2G capability could help to improve the reliability performance of distribution grid to a great extent and reduce the adverse impact incurred by EV accommodation,if utilized properly.
文摘In the process of cultivating software engineering professionals,the practical teaching of professional courses is an indispensable link.In order to enable students to understand,consolidate and master theoretical knowledge,improve the ability to solve problems by combining theory with practice,and achieve the goal of combining theoretical knowledge with practice.Adopting the planning of through-type training,complete the teaching work of three practical courses of software system design,software system construction,and software product construction.Through the implementation of the plan,the digitization of teaching resources,the virtualization of real enterprises,the intelligentization of teaching guidance,the visualization of teaching process,and the panorama of learning process are realized.By adopting the teaching methods of taskdriven online practice teaching,artificial intelligence-based teaching training support and teaching process,and result big data evaluation,the students’comprehensive practical ability can be improved finally,and the whole practice teaching reform can provide experience for the follow-up reform.
基金the National Natural Science Foundation of China(Nos.52072152 and 51802126)the Jiangsu University Jinshan Professor Fund,the Jiangsu Specially-Appointed Professor Fund,Open Fund from Guangxi Key Laboratory of Electrochemical Energy Materials,Zhenjiang“Jinshan Talents”Project 2021,China PostDoctoral Science Foundation(No.2022M721372)+3 种基金“Doctor of Entrepreneurship and Innovation”in Jiangsu Province(No.JSSCBS20221197)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX22_3645)the National Natural Science Foundation of China(No.22208134)Jiangsu Agricultural Science and Technology Innovation Fund(No.CX(21)1010).
文摘The electrochemical nitrate reduction reaction(NO_(3)RR)to ammonia under ambient conditions is a promising approach for addressing elevated nitrate levels in water bodies,but the progress of this reaction is impeded by the complex series of chemical reactions involving electron and proton transfer and competing hydrogen evolution reaction.Therefore,it becomes imperative to develop an electro-catalyst that exhibits exceptional efficiency and remarkable selectivity for ammonia synthesis while maintaining long-term stability.Herein the magnetic biochar(Fe-C)has been synthesized by a two-step mechanochemical route after a pyrolysis treatment(450,700,and 1000℃),which not only significantly decreases the particle size,but also exposes more oxygen-rich functional groups on the surface,promoting the adsorption of nitrate and water and accelerating electron transfer to convert it into ammonia.Results showed that the catalyst(Fe-C-700)has an impressive NH_(3)production rate of 3.5 mol·h^(−1)·gcat^(−1),high Faradaic efficiency of 88%,and current density of 0.37 A·cm^(−2)at 0.8 V vs.reversible hydrogen electrode(RHE).In-situ Fourier transform infrared spectroscopy(FTIR)is used to investigate the reaction intermediate and to monitor the reaction.The oxygen functionalities on the catalyst surface activate nitrate ions to form various intermediates(NO_(2),NO,NH_(2)OH,and NH_(2))and reduce the rate determining step energy barrier(*NO_(3)→*NO_(2)).This study presents a novel approach for the use of magnetic biochar as an electro-catalyst in NO_(3)RR and opens the road for solving environmental and energy challenges.
基金supported by the National Key R&D Program of China (2022YFA1404400 and 2022YFA1404500)the National Natural Science Foundation of China (12074183, 11834008, 12104226, 12225408, and 12227809)+2 种基金the Fundamental Research Funds for the Central Universities (020414380181 and 020414380211)the support from the Funds for Zijin Scholars of Nanjing Universityhe support from the Spanish Ministry of Science and Innovation through a Consolidación Investigadora grant (CNS2022-135706)。
基金the National Natural Science Foundation of China(Nos.52072152 and 51802126)the Jiangsu University Jinshan Professor Fund and the Jiangsu Specially-Appointed Professor FundOpen Fund from Guangxi Key Laboratory of Electrochemical Energy Materials.
文摘The microstructure design of electrode material is a crucial point to optimize the supercapacitor’s electrochemical properties.In this work,a Bi-based nanocomposite with a three-layer structure(Bi–Bi_(2)O_(3)@carbon armour(CA)/carbon dots(CDs))is synthesized and investigated.This material inherits high capacitance and high activity from bismuth-based materials,the coated CA protects the structure from complete oxidization and improves surface hydrophilicity.Furthermore,CDs in CA can enhance the ion conduction efficiency between the catalyst,carbon membrane,electrolyte.As a consequence,the specific capacitance of the electrode reaches 973 F·g^(−1)under 1 A·g^(−1),the energy density achieves 32.5 Wh·kg^(−1)with a power density of 266.9 W·kg^(−1),with impressive electrochemical stability that Coulomb efficiency of the electrode remains about 100%after 5000 cycles.Furthermore,in-situ Fourier transformation infrared(FT-IR)analyzes the structure evolvement of the material during synthesis and finds that the annealing process of the material removes a great number of oxygen-containing groups of CA and CDs,generating oxygen vacancies,defects,thus active sites,which enhance the capacitance of the material.
基金supported by the National Science Foundation (No: 1029337)supported by an allocation of computing time from the Ohio Supercomputer Center
文摘Weather forecasting is crucial to both the demand and supply sides of electricity systems. Temperature has a great effect on the demand side. Moreover, solar and wind are very promising renewable energy sources and are, thus, important on the supply side. In this paper, a large vector autoregression(VAR) model is built to forecast three important weather variables for 61 cities around the United States. The three variables at all locations are modeled as response variables. Lag terms are used to capture the relationship between observations in adjacent periods and daily and annual seasonality are modeled to consider the correlation between the same periods in adjacent days and years. We estimate the VAR model with16 years of hourly historical data and use two additional years of data for out-of-sample validation. Forecasts of up to six-hours-ahead are generated with good forecasting performance based on mean absolute error, root mean square error, relative root mean square error, and skill scores. Our VAR model gives forecasts with skill scoresthat are more than double the skill scores of other forecasting models in the literature. Our model also provides forecasts that outperform persistence forecasts by between6% and 80% in terms of mean absolute error. Our results show that the proposed time series approach is appropriate for very short-term forecasting of hourly solar radiation,temperature, and wind speed.
基金supported by the National Natural Science Foundation of China(Nos.52072152 and 51802126)the Jiangsu University Jinshan Professor Fund,the Jiangsu SpeciallyAppointed Professor Fund(No.17TPJS-003)Open Fund from Guangxi Key Laboratory of Electrochemical Energy Materials.
文摘Photocatalytic reduction of carbon dioxide into valuable chemicals is a sustainable and promising technology that alleviates the greenhouse effect and energy crisis.In this study,the Mn_(3)O_(4)/FeNbO_(4) type Ⅱ heterojunction photocatalyst with a core-satellite structure was synthesized by the facile soft chemical method.The formation of a nano-heterojunction is supposed to effectively improve light capture,charge transfer,and interfacial charge separation in the photochemical reaction.Meanwhile,the heterojunction has a good ability to capture and activate CO_(2).Our results show that the prepared Mn_(3)O_(4)/FeNbO_(4) photocatalyst exhibit obvious enhanced catalytic properties in the photocatalytic CO_(2) reduction reaction,where the CH_(4) yielding rate is 1.96 and 9.81 times those of FeNbO_(4) and Mn_(3)O_(4),respectively.The transient photovoltage test(TPV)shows that the low frequency electrons are crucial to the effective transfer of photogenerated electrons and holes in the Mn_(3)O_(4)/FeNbO_(4) nano heterojunctions.Analysis of in situ Fourier transform infrared spectroscopy(FTIR)verifies the effective CO_(2) adsorption on the Mn_(3)O_(4)/FeNbO_(4) surface and the high selectivity of CH_(4) products.These properties of the Mn_(3)O_(4)/FeNbO_(4) photocatalyst infer its broad prospects in the fields of carbon fixation and energy conservation.
基金financially supported by the National Science Foundation(No.1548015)
文摘Flexibility in plug-in electric vehicle(PEV) charging can reduce the ancillary cost effects of wind variability and uncertainty on electric power systems. In this paper, we study these benefits of PEV charging, demonstrating that controlled PEV charging can reduce costs associated with wind uncertainty and variability. Interestingly, we show that the system does not require complete control of PEV-charging loads to mitigate the negative cost impacts of wind variability and uncertainty. Rather, PEV owners giving the system a two-hour window of flexibility in which to recharge their vehicles provides much of the benefits that giving full charging control does.
基金supported by the National Natural Science Foundation of China(Nos.51802126 and 52072152)the Jiangsu University Jinshan Professor Fund and the Jiangsu SpeciallyAppointed Professor Fund,Open Fund from Guangxi Key Laboratory of Electrochemical Energy Materials,and the Science and Technology Planning Social Development Project of Zhenjiang City(No.SH2019010).
文摘Ammonia plays a vital role in the development of modern agriculture and industry.Compared to the conventional Haber–Bosch ammonia synthesis in industry,electrocatalytic nitrogen reduction reaction(NRR)is considered as a promising and environmental friendly strategy to synthesize ammonia.Here,inspired by biological nitrogenase,we designed iron doped tin oxide(Fe-doped SnO_(2))for nitrogen reduction.In this work,iron can optimize the interface electron transfer and improve the poor conductivity of the pure SnO_(2),meanwhile,the synergistic effect between iron and Sn ions improves the catalyst activity.In the electrocatalytic NRR test,Fe-doped SnO_(2) exhibits a NH_(3) yield of 28.45μg·h^(−1)·mgcat^(−1),which is 2.1 times that of pure SnO_(2),and Faradaic efficiency of 6.54%at−0.8 V vs.RHE in 0.1 M Na_(2)SO_(4).It also shows good stability during a 12-h long-term stability test.Density functional theory calculations show that doped Fe atoms in SnO_(2) enhance catalysis performance of some Sn sites by strengthening N–Sn interaction and lowering the energy barrier of the rate-limiting step of NRR.The transient photovoltage test reveals that electrons in the low-frequency region are the key to determining the electron transfer ability of Fe-doped SnO_(2).
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.51802126 and 52072152)the Jiangsu University Jinshan Professor Fund and Jiangsu Specially-Appointed Professor Fund,Open Fund from Guangxi Key Laboratory of Electrochemical Energy Materials+1 种基金The authors also acknowledged the financial support by Guangdong Innovation Research Team for Higher Education(No.2017KCXTD030)High-level Talents Project of Dongguan University of Technology(No.KCYKYQD2017017).
文摘The large-scale production of ammonia mainly depends on the Haber-Bosch process,which will lead to the problems of high energy consumption and carbon dioxide emission.Electrochemical nitrogen fixation is considered to be an environmental friendly and sustainable process,but its efficiency largely depends on the activity and stability of the catalyst.Therefore,it is imperative to develop high-efficient electrocatalysts in the field of nitrogen reduction reaction(NRR).In this paper,we developed a BiVO_(4)/TiO_(2) nanotube(BiVO_(4)/TNT)heterojunction composite with rich oxygen vacancies as an electrocatalytic NRR catalyst.The heterojunction interface and oxygen vacancy of BiVO_(4)/TNT can be the active site of N2 dynamic activation and proton transition.The synergistic effect of TiO_(2) and BiVO_(4) shortens the proton transport path and reduces the over potential of chemical reaction.BiVO_(4)/TNT has high ammonia yield of 8.54µg·h^(−1)·cm^(−2) and high Faraday efficiency of 7.70%in−0.8 V vs.RHE in 0.1 M Na_(2)SO_(4) solution.
基金supported by the National Science and Technology Major Project of China(No.2018ZX10302205)the Major Project of Science and Technology in Henan Province(No.161100311400)+3 种基金the Natural Science Foundation of Henan Province(Nos.182300410361 and 222300420306)the Project of Basic Research Fund of Henan Institute of Medical and Pharmacological Sciences(No.2022BP0103)the Key Scientific and Technological Project of Henan Province(Nos.212102310124 and 222102310083)support of Henan Key Laboratory for Pharmacology of Liver Diseases where most of the experiments were performed。
文摘Lung cancer is one of the most prevalent and malignant cancers,among which lung adenocarcinoma(LUAD)accounts for the majority and remains a major cause of cancer-related mortality worldwide(Cui et al.,2019).Despite the growing intensity of research on the pathobiology and progression of lung cancer and the fact that many genes have been identified as potential drivers and targets for therapy(Luo et al.,2019;Zhang et al.,2019),the treatment and prognosis of lung cancer patients have hardly improved.Therefore,this study aimed to investigate the precise mechanism of lung cancer development and explore efficient diagnostic and therapeutic methods for clinical treatment.