Deep decalcification of factory-provided freezing acidolysis solution to achieveα-high-strength gypsum

The freezing acidolysis solution of the nitric acid-phosphate fertilizer process has a high calcium content,which makes it difficult to produce fine phosphate and high water-soluble phosphate fertilizer products.Here,based on the potential crystallization principle of calcium sulfate in NH_(4)NO_(3)-H_(3)PO_(4)-H_(2)O,the deep decalcification(i.e.calcium removal)technology to achieveα-high-strength gypsum originated from freezing acidolysis-solutions has been firstly proposed and investigated.Typically,calcium can be removed from the factory-provided freezing acidolysis-solution by neutralizing it with ammonia,followed by the addition of ammonium sulfate solution.As a result,the formation of calcium sulfate in the reaction system undergoes the nucleation and growth of CaSO_(4)·2H_(2)O(DH),as well as its dissolution and crystallization into short columnarα-CaSO_(4)·0.5H_(2)O(α-HH).Remarkably,with the molar ratio of SO_(4)^(2-)/Ca^(2+)at 1.8,the degree of neutralization(NH_(3)/HNO_(3) molar ratio)at 1.7,the reaction temperature of 94℃,and the reaction time of 300 min,the decalcification rate can reach 86.89%,of which the high-strengthα-CaSO_(4)·0.5H_(2)O(α-HH)will be obtained.Noteworthy,the deep decalcification product meets the standards for the production of fine phosphates and highly water-soluble phosphate fertilizers.Consequently,the 2 h flexural strength ofα-HH is 5.3 MPa and the dry compressive strength is 36.8 MPa,which is up to the standard of commercialα-HH.

Electromechanical Transient Modeling Analysis of Large-Scale New Energy Grid Connection

The synchronous virtual machine uses inverter power to imitate the performance of the conventional synchronous machine.It also has the same inertia,damping,frequency,voltage regulation,and other external performance as the generator.It is the key technology to realize new energy grid connections’stable and reliable operation.This project studies a dynamic simulation model of an extensive new energy power system based on the virtual synchronous motor.A new energy storage method is proposed.The mathematical energy storage model is established by combining the fixed rotor model of a synchronous virtual machine with the charge-discharge power,state of charge,operation efficiency,dead zone,and inverter constraint.The rapid conversion of energy storage devices absorbs the excess instantaneous kinetic energy caused by interference.The branch transient of the critical cut set in the system can be confined to a limited area.Thus,the virtual synchronizer’s kinetic and potential energy can be efficiently converted into an instantaneous state.The simulation of power system analysis software package(PSASP)verifies the correctness of the theory and algorithm in this paper.This paper provides a theoretical basis for improving the transient stability of new energy-connected power grids.

Emergency Energy Management of Microgrid in Industrial Park Basedon Robust Optimization

Reducing the impact of power outages and maintaining the power supply duration must be considered in implementing emergency energy dispatching in micro-networks.This paper studies a new emergency energy treatment method based on the robust optimal method and the industrial park micro-network with the optical energy storage system.After controlling the load input,a control strategy of adjusting and removing is proposed.Rolling optimal theory is applied to emergency energy scheduling based on a robust optimal mathematical model.A weighting factor is introduced into the optimal model to balance the importance of reducing and retaining the power supply.Uncertainty is designed to adjust the effect of uncertainty on the problem.The example shows that this method can flexibly set the weight coefficient and uncertainty value according to the actual situation so that the input of the control load can be optimized.

An analytical model for the prediction of cross-section profile and mean roll radius in alloy bar rolling

In a round-oval-round pass rolling sequence, the cross-section profile of an outgoing workpiece was predicted first after getting the maximum spread. The concept ＂critical point on the contact boundary＂ was proposed and the coordinates of the critical point were solved. The equivalent contact section area was represented and the mean roll radius was determined. The validity of this model was examined by alloy bar rolling experiment and rigid-plastic FEM simulation. Compared with the existing models, the mean roll radius obtained by this model is similar to experiment data.

Motion-based pH sensing using spindle-like micromotors

In this study, we report a spindle-like micromotor. This device, which is fabricated using a one-step electrospinning method, consists of biodegradable polycaprolactone and an anionic surfactant. Intriguingly, not only can the resulting micromotor move autonomously on the surface of water for a long period of time （-40 min） due to the Marangoni effect, but it also exhibits a pH sensing behavior due to variations in the surface tension caused by the release of surfactant under different pH conditions. More interestingly, we reveal that the motion-based pH sensing property is size-dependent, with smaller structures exhibiting a higher sensitivity. In addition, since polycaprolactone is a biode- gradable material, the micromotor described in this study can be easily degraded in solution. Hence, features such as one-step fabrication, motion readout, and biodegradability render this micromotor an attractive candidate for sensing algplications.