Studies on Composting Spent Coffee Grounds by <i>Aspergillus sp</i>and <i>Aspergillus sp</i>in Aerobic Static Batch Temperature Control

Spent Coffee Ground (SCG) is characterized by high organic content, in the form of insoluble polysaccharides bound and phenol compounds. Phenol compounds are toxic to nature and are a cause of environmental pollution. Composting method of this study is aerobic static batch composting with temperature control with adding activators of some fungi such as Aspergillus sp, and Penicillium sp. The purpose of the research is to fill the research gap from previous studies of spent coffee grounds compost, which requires a long time in composting, so that if it is used directly on the soil and plants, the positive effect also requires a long time. The result of composting for 28 days with this method is that mature compost has black crumb and normal pH, with characteristics of C/N ratio below 10: C1 (7.06), C2 (6.99). This value is far from the control with a C/N ratio of 8.33. Decompose rate of macromolecule are above 40% for lignin and 70% for cellulose. Implementation of compost in radish plants, resulting Germination Index above 80% which indicates that the compost is ripe: control (92.39%), C1 (183.88%), C2 (191.86%). The results of the analysis with FTIR also showed that the compost was mature and stable, and rich in minerals. So, it can be concluded that this composting method can speed up composting time and optimize the results of compost produced.

Study of Potassium Recovery from Biomass Ash Using Tartaric Acid and Syngenite Method

Biomass has the potential and benefits of being an alternative energy source to replace fossil fuels that exist today in Indonesia and other tropical countries. In addition, biomass has an abundant stock or supply. By assessing the feasibility of recovering potassium, it is hoped that more potassium resources and in future Indonesia will be dependent on imported fertilizers and increase the agricultural industry, which is the aims of this study. The best extraction result is using CH3COOH. Treatment of 1:10 solid-liquid ratio with the help of 1 mol/l CH3COOH was chosen as the best treatment because it is more economically efficient. Recovery of K with the help of tartaric acid and acetic acid resulted in a K recovery efficiency of around 94%. The optimal condition for the syngenite method is the addition of a magnesium dose of 5 mmol/l and at pH 11, the Ca: K ratio is 1:2.1 with 42% K. This can be a suggestion which method is more effective and efficient in recovery K.

Recovery of Biomass Incinerated as Struvite-K Precipitates Followed Aluminium Removal

Phosphorus (P) and potassium (K) are non-renewable materials and widely in many industries such as agricultural sectors. On the other hand, the demand of P and K as fertilizers increases which following global population. The nutrient source of P and K which get from biomass waste i.e. incinerated of activated sludge and coffee husk biochar, respectively. The present study was conducted recovery of P and K as struvite-K (KMgPO4·6H2O) precipitates. The results showed that aluminium was released simultaneously with P from incinerated activated sludge with precipitate of Al:P of 1:1, K:P of 0.5, and Mg:P of 3. However, aluminium was inhibited to form struvite-K. Then, we examined cation removal especially for removed Al by dissolved 0.5 M HNO3 and the solution was mixed with KH2PO4 and MgCl2·6H2O as source of K and Mg, respectively. The results showed aluminium (Al) was removed with precipitate K:P of 0.5, and Mg:P of 0.8. This study was confirmed that recovery of biomass incinerated was successful as struvite-K and can be used as fertilizers.

Effects of Co-Existing Ions on the Phosphorus Potassium Ratio of the Precipitate Formed in the Potassium Phosphate Crystallization Process

Livestock wastewater is mainly treated with activated sludge, but ions such as phosphorus, potassium, ammonium, nitrate and sulfate remain in the effluent. In this study, the effects of residual ions on phosphorus recovery using the magnesium potassium phosphate crystallization method were investigated when magnesium was added to increase the pH. If co-existing ions affect the products, the phosphorus to potassium molar ratio (K/P ratio) of the precipitate will deviate from being equimolar. Artificial wastewater test solutions containing 5.6 - 20.3 mM ammonium, 25.6 mM potassium, 6.5 mM phosphorus, 0 - 7.35 mM nitrate, and 0 - 3.06 mM sulfate were used. First, the optimum operating pH and amount of magnesium added to give a high phosphorus removal rate and recovery rate were determined. The experimental setup was a 10 L aerated and stirred reactor, and a 5 L settling tank. The K/P ratio in precipitate was approximately 1 using the optimum conditions. Continuous 2 h treatment allowed a white precipitate containing about 30 g of needle-like crystals to be obtained. Next, the effects of varying the ammonium, nitrate, and sulfate ion concentrations in the artificial effluent were investigated. Ammonium and sulfate ion concentrations of 8 mM or more and 3 mM or more, respectively, caused the K/P ratio to decrease to about 0.7 and 0.5, respectively. Varying the nitrate concentration did not affect the K/P ratio, even at a nitrate concentration of 7.35 mM.