Unconventional superconductivity,in particular,in noncentrosymmetric systems,has been a long-sought topic in condensed matter physics.Recently,Re-based superconductors have attracted great attention owing to the poten...Unconventional superconductivity,in particular,in noncentrosymmetric systems,has been a long-sought topic in condensed matter physics.Recently,Re-based superconductors have attracted great attention owing to the potential time-reversal symmetry breaking in their superconducting states.We report the superconducting properties of noncentrosymmetric compounds Ta_(x)Re_(1-x) with 0.1 ≤x≤0.25,and find that the superconducting transition temperature reaches a maximum of ~8 K at the optimal level x=0.15.Nevertheless,muon-spin rotation and relaxation measurements reveal no time-reversal symmetry breaking existing in its superconducting state,which is in sharp contrast to both centrosymmetric Re metal and many other noncentrosymmetric Re-based superconductors.展开更多
The measurements of magnetization,longitudinal and Hall resistivities are carried out on the intrinsic antiferromagnetic(AFM) topological insulator ElSn2 As2.It is confirmed that our ElSn2 As2 crystal is a heavily hol...The measurements of magnetization,longitudinal and Hall resistivities are carried out on the intrinsic antiferromagnetic(AFM) topological insulator ElSn2 As2.It is confirmed that our ElSn2 As2 crystal is a heavily hole doping A-type AFM metal with the Neel temperature TN=24 K,with a metamagnetic transition from an AFM to a ferromagnetic(FIM) phase occurring at a certain critical magnetic Held for the different Held orientations.Meanwhile,we also find that the carrier concentration does not change with the evolution of magnetic order,indicating that the weak interaction between the localized magnetic moments from Eu2+4f7 orbits and the electronic states near the Fermi level.Although the quantum anomalous Hall effect(AHE) is not observed in our crystals,it is found that a relatively large negative magnetoresistance (-13%) emerges in the AFM phase,and exhibits an exponential dependence upon magnetic Held,whose microscopic origin is waiting to be clarified in future research.展开更多
The Ge_(2)Sb_(2)Te_(5)alloy has served as the core material in phase-change memories with high switching speed and persistent storage capability at room temperature.However widely used,this composition is not suitable...The Ge_(2)Sb_(2)Te_(5)alloy has served as the core material in phase-change memories with high switching speed and persistent storage capability at room temperature.However widely used,this composition is not suitable for embedded memories—for example,for automotive applications,which require very high working temperatures above 300℃.Ge–Sb–Te alloys with higher Ge content,most prominently Ge2Sb1Te2(‘212’),have been studied as suitable alternatives,but their atomic structures and structure–property relationships have remained widely unexplored.Here,we report comprehensive first-principles simulations that give insight into those emerging materials,located on the compositional tie-line between Ge_(2)Sb_(1)Te_(2) and elemental Ge,allowing for a direct comparison with the established Ge_(2)Sb_(2)Te_(5)material.Electronic-structure computations and smooth overlap of atomic positions(SOAP)similarity analyses explain the role of excess Ge content in the amorphous phases.Together with energetic analyses,a compositional threshold is identified for the viability of a homogeneous amorphous phase(‘zero bit’),which is required for memory applications.Based on the acquired knowledge at the atomic scale,we provide a materials design strategy for high-performance embedded phase-change memories with balanced speed and stability,as well as potentially good cycling capability.展开更多
基金Supported by the National Key R&D Program of China(Grant No.2018YFA0704300)the National Natural Science Foundation of China(Grant Nos.U1732162,11974061,11704047,U1832147 and 11674054)the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB25000000)。
文摘Unconventional superconductivity,in particular,in noncentrosymmetric systems,has been a long-sought topic in condensed matter physics.Recently,Re-based superconductors have attracted great attention owing to the potential time-reversal symmetry breaking in their superconducting states.We report the superconducting properties of noncentrosymmetric compounds Ta_(x)Re_(1-x) with 0.1 ≤x≤0.25,and find that the superconducting transition temperature reaches a maximum of ~8 K at the optimal level x=0.15.Nevertheless,muon-spin rotation and relaxation measurements reveal no time-reversal symmetry breaking existing in its superconducting state,which is in sharp contrast to both centrosymmetric Re metal and many other noncentrosymmetric Re-based superconductors.
基金Supported by the National Key Research and Development Program of China under Grant No.2016YFA0300402the National Basic Research Program of China under Grant No.2015CB921004+2 种基金the National Natural Science Foundation of China under Grant Nos.11974095 and 11374261the Zhejiang Natural Science Foundation(No.LY16A040012)the Fundamental Research Funds for the Central Universities.
文摘The measurements of magnetization,longitudinal and Hall resistivities are carried out on the intrinsic antiferromagnetic(AFM) topological insulator ElSn2 As2.It is confirmed that our ElSn2 As2 crystal is a heavily hole doping A-type AFM metal with the Neel temperature TN=24 K,with a metamagnetic transition from an AFM to a ferromagnetic(FIM) phase occurring at a certain critical magnetic Held for the different Held orientations.Meanwhile,we also find that the carrier concentration does not change with the evolution of magnetic order,indicating that the weak interaction between the localized magnetic moments from Eu2+4f7 orbits and the electronic states near the Fermi level.Although the quantum anomalous Hall effect(AHE) is not observed in our crystals,it is found that a relatively large negative magnetoresistance (-13%) emerges in the AFM phase,and exhibits an exponential dependence upon magnetic Held,whose microscopic origin is waiting to be clarified in future research.
基金W.Z.thanks the support of National Natural Science Foundation of China(61774123)111 Project 2.0(BP2018008)R.M.acknowledges funding from Deutsche Forschungsgemeinschaft(DFG)within SFB 917(‘Nanoswitches’).V.L.D.acknowledges a Leverhulme Early Career Fellowship.The authors acknowledge the support by the HPC platform of Xi’an Jiaotong University,and the International Joint Laboratory for Micro/Nano Manufacturing and Measurement Technologies of Xi’an Jiaotong University.
文摘The Ge_(2)Sb_(2)Te_(5)alloy has served as the core material in phase-change memories with high switching speed and persistent storage capability at room temperature.However widely used,this composition is not suitable for embedded memories—for example,for automotive applications,which require very high working temperatures above 300℃.Ge–Sb–Te alloys with higher Ge content,most prominently Ge2Sb1Te2(‘212’),have been studied as suitable alternatives,but their atomic structures and structure–property relationships have remained widely unexplored.Here,we report comprehensive first-principles simulations that give insight into those emerging materials,located on the compositional tie-line between Ge_(2)Sb_(1)Te_(2) and elemental Ge,allowing for a direct comparison with the established Ge_(2)Sb_(2)Te_(5)material.Electronic-structure computations and smooth overlap of atomic positions(SOAP)similarity analyses explain the role of excess Ge content in the amorphous phases.Together with energetic analyses,a compositional threshold is identified for the viability of a homogeneous amorphous phase(‘zero bit’),which is required for memory applications.Based on the acquired knowledge at the atomic scale,we provide a materials design strategy for high-performance embedded phase-change memories with balanced speed and stability,as well as potentially good cycling capability.