The development of efficient systems for the catalytic oxidation of 2-nitro-4-methylsulfonyltoluene(NMST)to 2-nitro-4-methylsulfonyl benzoic acid(NMSBA)with atmospheric air or molecular oxygen in alkaline medium prese...The development of efficient systems for the catalytic oxidation of 2-nitro-4-methylsulfonyltoluene(NMST)to 2-nitro-4-methylsulfonyl benzoic acid(NMSBA)with atmospheric air or molecular oxygen in alkaline medium presents a significant challenge for the chemical industry.Here,we report the synthesis of FeOOH/Fe_(3)O_(4)/metal-organic framework(MOF)polygonal mesopores microflower templated from a MIL-88B(Fe)at room temperature,which exposes polygonal mesopores with atomistic edge steps and lattice defects.The obtained FeOOH/Fe_(3)O_(4)/MOF catalyst was adsorbed onto glass beads and then introduced into the microchannel reactor.In the alkaline environment,oxygen was used as oxidant to catalyze the oxidation of NMST to NMSBA,showing impressive performance.This sustainable system utilizes oxygen as a clean oxidant in an inexpensive and environmentally friendly NaOH/methanol mixture.The position and type of substituent critically affect the products.Additionally,this sustainable protocol enabled gram-scale preparation of carboxylic acid and benzyl alcohol derivatives with high chemoselectivities.Finally,the reactions can be conducted in a pressure reactor,which can conserve oxygen and prevent solvent loss.Moreover,compared with the traditional batch reactor,the self-built microchannel reactor can accelerate the reaction rate,shorten the reaction time,and enhance the selectivity of catalytic oxidation reactions.This approach contributes to environmental protection and holds potential for industrial applications.展开更多
为研究干湿循环对深部砂岩的强度劣化机制和能量演化规律,对经历不同干湿循环次数的砂岩进行基本物理参数的测定、单轴压缩试验和扫描电子显微镜(scanning electron microscope,SEM)观测,探讨砂岩单轴抗压强度劣化及单轴压缩过程中能量...为研究干湿循环对深部砂岩的强度劣化机制和能量演化规律,对经历不同干湿循环次数的砂岩进行基本物理参数的测定、单轴压缩试验和扫描电子显微镜(scanning electron microscope,SEM)观测,探讨砂岩单轴抗压强度劣化及单轴压缩过程中能量演化规律。试验结果表明:随着干湿循环次数的增加,单轴抗压强度和弹性模量劣化效果明显,但平均劣化度逐渐减小,说明干湿循环对岩石的损伤劣化效果逐渐趋于稳定。干湿循环10次以后,砂岩在SEM下可以观测到明显的絮状物,单轴抗压强度降低明显,并呈现一定的延性特征。在单轴压缩试验中,随着干湿循环次数的增加,砂岩试件中储存的弹性能逐渐减少,耗散能呈波动性下降。展开更多
基金supported by the National Natural Science Foundation of China(22078251)Hubei Province Key Research and Development Program(2023DJC167)the research project of Hubei Provincial Department of Education(D20191504).
文摘The development of efficient systems for the catalytic oxidation of 2-nitro-4-methylsulfonyltoluene(NMST)to 2-nitro-4-methylsulfonyl benzoic acid(NMSBA)with atmospheric air or molecular oxygen in alkaline medium presents a significant challenge for the chemical industry.Here,we report the synthesis of FeOOH/Fe_(3)O_(4)/metal-organic framework(MOF)polygonal mesopores microflower templated from a MIL-88B(Fe)at room temperature,which exposes polygonal mesopores with atomistic edge steps and lattice defects.The obtained FeOOH/Fe_(3)O_(4)/MOF catalyst was adsorbed onto glass beads and then introduced into the microchannel reactor.In the alkaline environment,oxygen was used as oxidant to catalyze the oxidation of NMST to NMSBA,showing impressive performance.This sustainable system utilizes oxygen as a clean oxidant in an inexpensive and environmentally friendly NaOH/methanol mixture.The position and type of substituent critically affect the products.Additionally,this sustainable protocol enabled gram-scale preparation of carboxylic acid and benzyl alcohol derivatives with high chemoselectivities.Finally,the reactions can be conducted in a pressure reactor,which can conserve oxygen and prevent solvent loss.Moreover,compared with the traditional batch reactor,the self-built microchannel reactor can accelerate the reaction rate,shorten the reaction time,and enhance the selectivity of catalytic oxidation reactions.This approach contributes to environmental protection and holds potential for industrial applications.
文摘为研究干湿循环对深部砂岩的强度劣化机制和能量演化规律,对经历不同干湿循环次数的砂岩进行基本物理参数的测定、单轴压缩试验和扫描电子显微镜(scanning electron microscope,SEM)观测,探讨砂岩单轴抗压强度劣化及单轴压缩过程中能量演化规律。试验结果表明:随着干湿循环次数的增加,单轴抗压强度和弹性模量劣化效果明显,但平均劣化度逐渐减小,说明干湿循环对岩石的损伤劣化效果逐渐趋于稳定。干湿循环10次以后,砂岩在SEM下可以观测到明显的絮状物,单轴抗压强度降低明显,并呈现一定的延性特征。在单轴压缩试验中,随着干湿循环次数的增加,砂岩试件中储存的弹性能逐渐减少,耗散能呈波动性下降。
