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Covalently Bonded Ni Sites in Black Phosphorene with Electron Redistribution for Efficient Metal‑Lightweighted Water Electrolysis
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作者 Wenfang Zhai Ya Chen +5 位作者 Yaoda Liu Yuanyuan Ma Paranthaman Vijayakumar yuanbin qin Yongquan Qu Zhengfei Dai 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第6期233-245,共13页
The metal-lightweighted electrocatalysts for water splitting are highly desired for sustainable and economic hydrogen energy deployments,but challengeable.In this work,a low-content Ni-functionalized approach triggers... The metal-lightweighted electrocatalysts for water splitting are highly desired for sustainable and economic hydrogen energy deployments,but challengeable.In this work,a low-content Ni-functionalized approach triggers the high capability of black phosphorene(BP)with hydrogen and oxygen evolution reaction(HER/OER)bifunctionality.Through a facile in situ electro-exfoliation route,the ionized Ni sites are covalently functionalized in BP nanosheets with electron redistribution and controllable metal contents.It is found that the as-fabricated Ni-BP electrocatalysts can drive the water splitting with much enhanced HER and OER activities.In 1.0 M KOH electrolyte,the optimized 1.5 wt%Nifunctionalized BP nanosheets have readily achieved low overpotentials of 136 mV for HER and 230 mV for OER at 10 mA cm^(−2).Moreover,the covalently bonding between Ni and P has also strengthened the catalytic stability of the Ni-functionalized BP electrocatalyst,stably delivering the overall water splitting for 50 h at 20 mA cm^(−2).Theoretical calculations have revealed that Ni–P covalent binding can regulate the electronic structure and optimize the reaction energy barrier to improve the catalytic activity effectively.This work confirms that Ni-functionalized BP is a suitable candidate for electrocatalytic overall water splitting,and provides effective strategies for constructing metal-lightweighted economic electrocatalysts. 展开更多
关键词 Black phosphorus Water electrolysis ELECTROCATALYST Electron redistribution Covalent functionalization
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用于低功率神经形态晶体管的金属氧化物半导体纳米纤维中阳离子比例的合理调整 被引量:2
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作者 丛浩菲 常宇 +7 位作者 周睿夫 张文鑫 孙广欣 徐沛龙 秦元斌 Seeram Ramakrishna 刘旭海 王凤云 《Science China Materials》 SCIE EI CAS CSCD 2023年第8期3251-3260,共10页
宽带隙金属氧化物半导体(MOS)纳米纤维神经形态晶体管(NFNTs)可以潜在地用于构建低功耗的仿生人工电路.但文献中对于NFNTs所采用MOS的阳离子配比并没有给出详细的原因.在本研究中,我们首次系统地研究了用低成本静电纺丝技术结合纳米纤... 宽带隙金属氧化物半导体(MOS)纳米纤维神经形态晶体管(NFNTs)可以潜在地用于构建低功耗的仿生人工电路.但文献中对于NFNTs所采用MOS的阳离子配比并没有给出详细的原因.在本研究中,我们首次系统地研究了用低成本静电纺丝技术结合纳米纤维转移工艺制备的氧化铟锌(InZnO)基NFNTs的阳离子比例.基于双阳离子InZnO纳米纤维的电驱动NFNTs可以大大简化实验过程.在In_(x)Zn_(1−x)O的阳离子比(x=0.6,0.7,0.8,0.9)中,我们发现基于In_(0.7)Zn_(0.3)O的NFNTs表现出最低的兴奋性突触后电流,可以为低功耗操作和突触功能模拟提供电效益.MOS纳米纤维成分的合理调整可以为高性能低功耗NFNTs提供新的思路. 展开更多
关键词 纳米纤维 静电纺丝技术 金属氧化物半导体 突触功能 电驱动 晶体管 氧化铟锌 合理调整
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从导体到半导体:ITO纳米线直径调控制备低成本电子器件
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作者 陈广寿 丛浩菲 +6 位作者 常宇 张煜 周睿夫 王昱晓 秦元斌 刘旭海 王凤云 《Science China Materials》 SCIE EI CAS CSCD 2023年第11期4445-4452,共8页
金属氧化物半导体(MOSs)由于具有优异的光电学性能和稳定性,在场效应晶体管(FETs)中具有广泛的研究价值.然而,以相同的MOSs材料作为FETs的沟道和源漏电极仍存在较大挑战.本文采用静电纺丝工艺和纳米线转移技术,以一维氧化铟锡(ITO)为主... 金属氧化物半导体(MOSs)由于具有优异的光电学性能和稳定性,在场效应晶体管(FETs)中具有广泛的研究价值.然而,以相同的MOSs材料作为FETs的沟道和源漏电极仍存在较大挑战.本文采用静电纺丝工艺和纳米线转移技术,以一维氧化铟锡(ITO)为主体,构筑了低成本高性能全纳米线FETs.通过简单调节纳米线的直径,ITO实现了由导体向半导体的转变,基于最佳的ITO纳米线作为沟道和电极材料组建的FETs获得了较大的开关比(106)和较低阈值电压(0.6 V).此外,基于全静电纺丝工艺制备的增强型和耗尽型ITO纳米线FETs实现了非门逻辑及n型MOS(NMOS)电路.该方法为未来实现柔性透明光电子器件提供了可行方案. 展开更多
关键词 field-effect transistor NANOWIRE ELECTROSPINNING low-dimension lost-cost
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Weak UV‑Stimulated Synaptic Transistors Based on Precise Tuning of Gallium‑Doped Indium Zinc Oxide Nanofibers
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作者 Yuxiao Wang Ruifu Zhou +8 位作者 Haofei Cong Guangshou Chen Yanyan Ma Shuwen Xin Dalong Ge yuanbin qin Seeram Ramakrishna Xuhai Liu Fengyun Wang 《Advanced Fiber Materials》 SCIE EI CAS 2023年第6期1919-1933,共15页
In this work,a light-stimulated artificial synaptic transistor based on one-dimensional nanofibers of gallium-doped indium zinc oxides(IGZO)is demonstrated.The introduction of gallium into the nanofiber lattice can ef... In this work,a light-stimulated artificial synaptic transistor based on one-dimensional nanofibers of gallium-doped indium zinc oxides(IGZO)is demonstrated.The introduction of gallium into the nanofiber lattice can effectively alter the morphology and crystallinity,leading to a wider regulatory range of synaptic plasticity.The fabricated IGZO synaptic transistor with the optimal gallium concentration and low surface defects exhibits a superior photoresponsivity of 4300 A・W^(−1)and excellent photosensitivity,which can detect light signals as weak as 0.03 mW・cm^(−2).In particular,the paired-pulse facilitation index reaches up to 252%with over 2 h of enhanced memory retention exhibiting the long-term potentiation.Furthermore,the simulated image contrast and image recognition accuracy based on the newly designed IGZO synaptic transistors are successfully enhanced.These remarkable behaviors of light-stimulated synapses utilizing low-cost electrospun nanofibers have potential for ultraweak light applications in future artificial systems. 展开更多
关键词 INGAZNO NANOFIBER Artificial synaptic transistor Ultraviolet Photoresponsivity Phase transformation
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Quaternary pyrite-structured nickel/cobalt phosphosulfide nanowires on carbon cloth as efficient and robust electrodes for water electrolysis 被引量:8
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作者 Jiayuan Li Zhaoming Xia +3 位作者 Xuemei Zhou yuanbin qin Yuanyuan Ma Yongquan Qu 《Nano Research》 SCIE EI CAS CSCD 2017年第3期814-825,共12页
The strategy of element substitution is an effective way to tune the electronic structures of the active sites in catalysts, thereby leading to improvements in both the catalytic activity and stability. Herein, we des... The strategy of element substitution is an effective way to tune the electronic structures of the active sites in catalysts, thereby leading to improvements in both the catalytic activity and stability. Herein, we design and synthesize pyrite-type nickel/phosphorus co-doped CoS2 nanowires on carbon cloth (NiCoPS/CC) as efficient and durable electrodes for water electrolysis. Introduction of nickel and phosphorus produced stepwise and superb enhancement of the performance of the electrodes in the hydrogen evolution reaction due to regulation of the electronic structures of the active sites of the catalyst and accelerated charge transfer over a wide pH range (0-14). The NiCoPS/CC electrodes also delivered a nearly undecayed catalytic current density of 10 mA.cm-2 at a low overpotential of 230 mV for oxygen evolution due to in situ formation of surficial Ni-Co oxo/hydroxide in 1.0 M KOH. Thus, the NiCoPS/CC electrodes gave rise to a catalytic current density of 10 mA·cm-2 for overall water splitting at potentials as low as 1.54 V during operation over 100 h in 1.0 M KOH with a Faradic efficiency of ~100%. 展开更多
关键词 water electrolysis PYRITE heterogeneous catalysis NANOWIRE
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High-performance enhancement-mode thin-film transistors based on Mg-doped In2O3 nanofiber networks 被引量:2
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作者 Hongchao Zhang You Meng +7 位作者 Longfei Song Linqu Luo yuanbin qin Ning Han Zaixing Yang Lei Liu Johnny C. Ho Fengyun Wang 《Nano Research》 SCIE EI CAS CSCD 2018年第3期1227-1237,共11页
Although In2O3 nanofibers (NFs) are well-known candidates as active materials for next-generation, low-cost electronics, these NF based devices still suffer from high leakage current, insufficient on-off current rat... Although In2O3 nanofibers (NFs) are well-known candidates as active materials for next-generation, low-cost electronics, these NF based devices still suffer from high leakage current, insufficient on-off current ratios (Ion/Ioff), and large, negative threshold voltages (VTH), leading to poor device performance, parasitic energy consumption, and rather complicated circuit design. Here, instead of the conventional surface modification of In2O3 NFs, we present a one-step electrospinning process (i.e., without hot-press) to obtain controllable Mg-doped In2O3 NF networks to achieve high-performance enhancement-mode thin-film transistors (TFTs). By simply adjusting the Mg doping concentration, the device performance can be manipulated precisely. For the optimal doping concentration of 2 mol%, the devices exhibit a small VTH (3.2 V), high saturation current (1.1 × 10^-4 A), large on/off current ratio (〉 10^8), and respectable peak carrier mobility (2.04 cm2/(V.s)), corresponding to one of the best device performances among all 1D metal-oxide NFs based devices reported so far. When high-K HfOx thin films are employed as the gate dielectric, their electron mobility and VTH can be further improved to 5.30 cm^2/(V.s) and 0.9 V, respectivel), which demonstrates the promising prospect of these Mg-doped In2O3 NF networks for high- performance, large-scale, and low-power electronics. 展开更多
关键词 In2O3 nanofiber TRANSISTOR DOPING threshold voltage enhancement mode
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