Diversified traffic participants and complex traffic environment(e.g.,roadblocks or road damage exist)challenge the decision-making accuracy of a single connected and autonomous vehicle(CAV)due to its limited sensing ...Diversified traffic participants and complex traffic environment(e.g.,roadblocks or road damage exist)challenge the decision-making accuracy of a single connected and autonomous vehicle(CAV)due to its limited sensing and computing capabilities.Using Internet of Vehicles(IoV)to share driving rules between CAVs can break limitations of a single CAV,but at the same time may cause privacy and safety issues.To tackle this problem,this paper proposes to combine IoV and blockchain technologies to form an efficient and accurate autonomous guidance strategy.Specifically,we first use reinforcement learning for driving decision learning,and give the corresponding driving rule extraction method.Then,an architecture combining IoV and blockchain is designed to ensure secure driving rule sharing.Finally,the shared rules will form an effective autonomous driving guidance strategy through driving rules selection and action selection.Extensive simulation proves that the proposed strategy performs well in complex traffic environment,mainly in terms of accuracy,safety,and robustness.展开更多
The growing demand for low delay vehicular content has put tremendous strain on the backbone network.As a promising alternative,cooperative content caching among different cache nodes can reduce content access delay.H...The growing demand for low delay vehicular content has put tremendous strain on the backbone network.As a promising alternative,cooperative content caching among different cache nodes can reduce content access delay.However,heterogeneous cache nodes have different communication modes and limited caching capacities.In addition,the high mobility of vehicles renders the more complicated caching environment.Therefore,performing efficient cooperative caching becomes a key issue.In this paper,we propose a cross-tier cooperative caching architecture for all contents,which allows the distributed cache nodes to cooperate.Then,we devise the communication link and content caching model to facilitate timely content delivery.Aiming at minimizing transmission delay and cache cost,an optimization problem is formulated.Furthermore,we use a multi-agent deep reinforcement learning(MADRL)approach to model the decision-making process for caching among heterogeneous cache nodes,where each agent interacts with the environment collectively,receives observations yet a common reward,and learns its own optimal policy.Extensive simulations validate that the MADRL approach can enhance hit ratio while reducing transmission delay and cache cost.展开更多
Polyoxymethylene dimethyl ethers(PODE)were synthesized from the reaction of paraformaldehyde with dimethoxymethane(DMM)over different acid catalysts at different conditions.Products were found to follow the Schulz-Flo...Polyoxymethylene dimethyl ethers(PODE)were synthesized from the reaction of paraformaldehyde with dimethoxymethane(DMM)over different acid catalysts at different conditions.Products were found to follow the Schulz-Flory distribution law.The chain propagation proceeds through the insertion of an individual segment of CH2O one by one,while the simultaneous insertion of a few CH2O segments or their assembly is unlikely.Due to the restriction of this law,it is difficult to increase the selectivity to the desired products(e.g.,PODE3 4).展开更多
The recent advances in wireless communication technology enable high-speed vehicles to download data from roadside units(RSUs). However, the data download volume of individual vehicle is rather restricted due to high ...The recent advances in wireless communication technology enable high-speed vehicles to download data from roadside units(RSUs). However, the data download volume of individual vehicle is rather restricted due to high mobility and limited transmission range of vehicles, bringing users poor performance. To address this issue, we exploit the combination of both clustering and carry-and-forward schemes in this paper. Our scheme coordinates the cooperation of multiple infrastructures, cluster formation in the same direction and data forwarding of reverse vehicles to facilitate the target vehicle to download large-size content in dark areas. The process of data dissemination and achievable data download volume are then derived and analyzed theoretically. Finally, we conduct extensive simulations to verify the performance of the proposed scheme. Results show significant benefits of the proposed scheme in terms of increasing data download volume and throughput.展开更多
Two acidic carbon materials (H-PRC and HS-C) were used as catalysts for the condensation reaction of methanol with formaldehyde to produce dimethoxymethane (DMM) in aqueous solution (hydrophilic system) and for ...Two acidic carbon materials (H-PRC and HS-C) were used as catalysts for the condensation reaction of methanol with formaldehyde to produce dimethoxymethane (DMM) in aqueous solution (hydrophilic system) and for the etherification of isopentene with methanol to produce tert amyl methyl ether (TAME) in toluene solution (lipophilic system). Microcalorimetric adsorptions of water and benzene showed that the HS-C was highly hydrophilic without the lipophilicity, while the H-PRC exhibited both the hydrophilicity and lipophilicity. Thus, the HS-C was well dispersed in aqueous solution and difficult to separate from it. On the other hand, the H-PRC was highly active, more active than the acidic resin (D008) and sulfuric acid, for the synthesis of DMM in aqueous solution. The H-PRC was also highly active, more active than the HS-C, for the etherification of isopentene with methanol to produce TAME in toluene solution, probably owing to its amphiphilic surface property as well as its strong surface acidity as measured by the microcalorirnetric adsorption of NH3.展开更多
The combination of integrated sensing and communication(ISAC)with mobile edge computing(MEC)enhances the overall safety and efficiency for vehicle to everything(V2X)system.However,existing works have not considered th...The combination of integrated sensing and communication(ISAC)with mobile edge computing(MEC)enhances the overall safety and efficiency for vehicle to everything(V2X)system.However,existing works have not considered the potential impacts on base station(BS)sensing performance when users offload their computational tasks via uplink.This could leave insufficient resources allocated to the sensing tasks,resulting in low sensing performance.To address this issue,we propose a cooperative power,bandwidth and computation resource allocation(RA)scheme in this paper,maximizing the overall utility of Cramer-Rao bound(CRB)for sensing accuracy,computation latency for processing sensing information,and communication and computation latency for computational tasks.To solve the RA problem,a twin delayed deep deterministic policy gradient(TD3)algorithm is adopted to explore and obtain the effective solution of the RA problem.Furthermore,we investigate the performance tradeoff between sensing accuracy and summation of communication latency and computation latency for computational tasks,as well as the relationship between computation latency for processing sensing information and that of computational tasks by numerical simulations.Simulation demonstrates that compared to other benchmark methods,TD3 achieves an average utility improvement of 97.11%and 27.90%in terms of the maximum summation of communication latency and computation latency for computational tasks and improves 3.60 and 1.04 times regarding the maximum computation latency for processing sensing information.展开更多
基金supported by the National Natural Science Foundation of China(62231020,62101401)the Fundamental Research Funds for the Central Universities(ZYTS23178)the Youth Innovation Team of Shaanxi Universities。
文摘Diversified traffic participants and complex traffic environment(e.g.,roadblocks or road damage exist)challenge the decision-making accuracy of a single connected and autonomous vehicle(CAV)due to its limited sensing and computing capabilities.Using Internet of Vehicles(IoV)to share driving rules between CAVs can break limitations of a single CAV,but at the same time may cause privacy and safety issues.To tackle this problem,this paper proposes to combine IoV and blockchain technologies to form an efficient and accurate autonomous guidance strategy.Specifically,we first use reinforcement learning for driving decision learning,and give the corresponding driving rule extraction method.Then,an architecture combining IoV and blockchain is designed to ensure secure driving rule sharing.Finally,the shared rules will form an effective autonomous driving guidance strategy through driving rules selection and action selection.Extensive simulation proves that the proposed strategy performs well in complex traffic environment,mainly in terms of accuracy,safety,and robustness.
基金supported by the National Natural Science Foundation of China(62231020,62101401)the Youth Innovation Team of Shaanxi Universities。
文摘The growing demand for low delay vehicular content has put tremendous strain on the backbone network.As a promising alternative,cooperative content caching among different cache nodes can reduce content access delay.However,heterogeneous cache nodes have different communication modes and limited caching capacities.In addition,the high mobility of vehicles renders the more complicated caching environment.Therefore,performing efficient cooperative caching becomes a key issue.In this paper,we propose a cross-tier cooperative caching architecture for all contents,which allows the distributed cache nodes to cooperate.Then,we devise the communication link and content caching model to facilitate timely content delivery.Aiming at minimizing transmission delay and cache cost,an optimization problem is formulated.Furthermore,we use a multi-agent deep reinforcement learning(MADRL)approach to model the decision-making process for caching among heterogeneous cache nodes,where each agent interacts with the environment collectively,receives observations yet a common reward,and learns its own optimal policy.Extensive simulations validate that the MADRL approach can enhance hit ratio while reducing transmission delay and cache cost.
文摘Polyoxymethylene dimethyl ethers(PODE)were synthesized from the reaction of paraformaldehyde with dimethoxymethane(DMM)over different acid catalysts at different conditions.Products were found to follow the Schulz-Flory distribution law.The chain propagation proceeds through the insertion of an individual segment of CH2O one by one,while the simultaneous insertion of a few CH2O segments or their assembly is unlikely.Due to the restriction of this law,it is difficult to increase the selectivity to the desired products(e.g.,PODE3 4).
基金supported by the National Natural Science Foundation of China under Grant No.61571350Key Research and Development Program of Shaanxi(Contract No.2017KW-004,2017ZDXM-GY-022)the 111 Project(B08038)
文摘The recent advances in wireless communication technology enable high-speed vehicles to download data from roadside units(RSUs). However, the data download volume of individual vehicle is rather restricted due to high mobility and limited transmission range of vehicles, bringing users poor performance. To address this issue, we exploit the combination of both clustering and carry-and-forward schemes in this paper. Our scheme coordinates the cooperation of multiple infrastructures, cluster formation in the same direction and data forwarding of reverse vehicles to facilitate the target vehicle to download large-size content in dark areas. The process of data dissemination and achievable data download volume are then derived and analyzed theoretically. Finally, we conduct extensive simulations to verify the performance of the proposed scheme. Results show significant benefits of the proposed scheme in terms of increasing data download volume and throughput.
文摘Two acidic carbon materials (H-PRC and HS-C) were used as catalysts for the condensation reaction of methanol with formaldehyde to produce dimethoxymethane (DMM) in aqueous solution (hydrophilic system) and for the etherification of isopentene with methanol to produce tert amyl methyl ether (TAME) in toluene solution (lipophilic system). Microcalorimetric adsorptions of water and benzene showed that the HS-C was highly hydrophilic without the lipophilicity, while the H-PRC exhibited both the hydrophilicity and lipophilicity. Thus, the HS-C was well dispersed in aqueous solution and difficult to separate from it. On the other hand, the H-PRC was highly active, more active than the acidic resin (D008) and sulfuric acid, for the synthesis of DMM in aqueous solution. The H-PRC was also highly active, more active than the HS-C, for the etherification of isopentene with methanol to produce TAME in toluene solution, probably owing to its amphiphilic surface property as well as its strong surface acidity as measured by the microcalorirnetric adsorption of NH3.
基金supported by the National Natural Science Foundation of China(62231020)Innovation Capability Support Program of Shaanxi(2024RS-CXTD-01).
文摘The combination of integrated sensing and communication(ISAC)with mobile edge computing(MEC)enhances the overall safety and efficiency for vehicle to everything(V2X)system.However,existing works have not considered the potential impacts on base station(BS)sensing performance when users offload their computational tasks via uplink.This could leave insufficient resources allocated to the sensing tasks,resulting in low sensing performance.To address this issue,we propose a cooperative power,bandwidth and computation resource allocation(RA)scheme in this paper,maximizing the overall utility of Cramer-Rao bound(CRB)for sensing accuracy,computation latency for processing sensing information,and communication and computation latency for computational tasks.To solve the RA problem,a twin delayed deep deterministic policy gradient(TD3)algorithm is adopted to explore and obtain the effective solution of the RA problem.Furthermore,we investigate the performance tradeoff between sensing accuracy and summation of communication latency and computation latency for computational tasks,as well as the relationship between computation latency for processing sensing information and that of computational tasks by numerical simulations.Simulation demonstrates that compared to other benchmark methods,TD3 achieves an average utility improvement of 97.11%and 27.90%in terms of the maximum summation of communication latency and computation latency for computational tasks and improves 3.60 and 1.04 times regarding the maximum computation latency for processing sensing information.