A series of nitrogen-doped SrMoO_(4) with different Sr/N mole ratio (R=0,0.05,0.10,0.15,0.20,0.40,and 0.60) were synthesized using urea as the N source via the vapor-thermal method.The photocatalytic degradation abili...A series of nitrogen-doped SrMoO_(4) with different Sr/N mole ratio (R=0,0.05,0.10,0.15,0.20,0.40,and 0.60) were synthesized using urea as the N source via the vapor-thermal method.The photocatalytic degradation ability of all samples was evaluated using methylene blue (MB) as a target contaminant.The band gaps of N-doped samples are all higher than that of pristine ones,which is only 3.12 eV.BET specific surface area S_(BET) and pore volume are increased due to the N doping.And the greater increase of S_(BET),the faster the photodegradation speed of methylene blue on SrMoO_(4).More specifically,the degradation efficiency of MB is improved up to 87%in 100 min.展开更多
The Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composites were solvothermally synthesized and characterized by X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),and(high resolution)transmission electr...The Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composites were solvothermally synthesized and characterized by X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),and(high resolution)transmission electron microscopy((HR)TEM).The Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composites exhibited higher photocatalytic activity than pure Bi_(2)MoO_(6).100%of the Rh B dye molecules could be decomposed over Bi_(2)MoO_(6)/Ag/TiO_(2)composite in 120 min.The enhanced photocatalytic activity of Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composite was attributed to the efficient separation of photoinduced electrons and holes.The mechanism for the enhanced photocatalytic activity is discussed.展开更多
TiO_(2)/graphene composite was synthesized in the vapor environment of isopropanol.In order to improve the properties of composite,N-doped of TiO_(2)/graphene with different N/Ti molar ratio was prepared in the vapor ...TiO_(2)/graphene composite was synthesized in the vapor environment of isopropanol.In order to improve the properties of composite,N-doped of TiO_(2)/graphene with different N/Ti molar ratio was prepared in the vapor environment of deionized water and used urea as the source of nitrogen.The N-doped occupies in the interstitial sites of TiO_(2) lattice,substitutes for O element in TiO_(2) and for C element in graphene,and simultaneously changes the chemical states of Ti and O elements in TiO_(2).N-doped changes the morphology of TiO_(2) from nano-sheets to nanoparticles,accompanying with the decrease in specific surface area of the composites,first increases the particle size of TiO_(2) and then decreases,and alters the vibration modes of Ti-OTi.The composite with RN/Ti=2 exhibits the enhanced photocatalytic degradation performance to methylene blue,and the degradation rate increases from 7.7×10^(−2) min^(−1) for the undoped composite to 9.6×10^(−2) min^(−1).展开更多
基金Funded by National Key Research and Development Program of China (No.2021YFA1600203)。
文摘A series of nitrogen-doped SrMoO_(4) with different Sr/N mole ratio (R=0,0.05,0.10,0.15,0.20,0.40,and 0.60) were synthesized using urea as the N source via the vapor-thermal method.The photocatalytic degradation ability of all samples was evaluated using methylene blue (MB) as a target contaminant.The band gaps of N-doped samples are all higher than that of pristine ones,which is only 3.12 eV.BET specific surface area S_(BET) and pore volume are increased due to the N doping.And the greater increase of S_(BET),the faster the photodegradation speed of methylene blue on SrMoO_(4).More specifically,the degradation efficiency of MB is improved up to 87%in 100 min.
基金National Training Programs of Innovation and Entrepreneurship for Undergraduates(Nos.202010357021,202010357296)Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials,Anhui University+1 种基金Anhui Provincial Natural Science Foundation(No.1308085MA04)the Higher Educational Natural Science Foundation of Anhui Province(No.KJ2013A031)。
文摘The Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composites were solvothermally synthesized and characterized by X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),and(high resolution)transmission electron microscopy((HR)TEM).The Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composites exhibited higher photocatalytic activity than pure Bi_(2)MoO_(6).100%of the Rh B dye molecules could be decomposed over Bi_(2)MoO_(6)/Ag/TiO_(2)composite in 120 min.The enhanced photocatalytic activity of Bi_(2)MoO_(6)/TiO_(2)and Bi_(2)MoO_(6)/Ag/TiO_(2)composite was attributed to the efficient separation of photoinduced electrons and holes.The mechanism for the enhanced photocatalytic activity is discussed.
基金Funded by the Natural Science Research Project of Anhui Educational Committee (KJ2021A0062)the National Natural Science Foundation of China (No. 51471001)the Open Fund for Discipline Construction,Institute of Physical Science and Information Technology.
文摘TiO_(2)/graphene composite was synthesized in the vapor environment of isopropanol.In order to improve the properties of composite,N-doped of TiO_(2)/graphene with different N/Ti molar ratio was prepared in the vapor environment of deionized water and used urea as the source of nitrogen.The N-doped occupies in the interstitial sites of TiO_(2) lattice,substitutes for O element in TiO_(2) and for C element in graphene,and simultaneously changes the chemical states of Ti and O elements in TiO_(2).N-doped changes the morphology of TiO_(2) from nano-sheets to nanoparticles,accompanying with the decrease in specific surface area of the composites,first increases the particle size of TiO_(2) and then decreases,and alters the vibration modes of Ti-OTi.The composite with RN/Ti=2 exhibits the enhanced photocatalytic degradation performance to methylene blue,and the degradation rate increases from 7.7×10^(−2) min^(−1) for the undoped composite to 9.6×10^(−2) min^(−1).
