Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiomet...Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiometer (Analytical Spectral Devices, Inc., USA) under laboratory condition. Partial least square regression (PLSR) models were constructed for predicting soil metal concentrations. The data pre-processing methods, first and second derivatives (FD and SD), baseline correction (BC), standard normal variate (SNV), multiplicative scatter correction (MSC), and continuum removal (CR), were used for the spectral reflectance data pretreatments. Then, the prediction results were evaluated by relative root mean square error (RRMSE) and coefficients of determination (R 2 ). According to the criteria of minimal RRMSE and maximal R 2 , the PLSR models with the FD pretreatment (RRMSE = 0.24, R 2 = 0.61), SNV pretreatment (RRMSE = 0.08, R 2 = 0.78), and BC-pretreatment (RRMSE = 0.20, R 2 = 0.41) were considered as the final models for predicting As, Fe, and Cu, respectively. Wavebands at around 460, 1 400, 1 900, and 2 200 nm were selected as important spectral variables to construct final models. In conclusion, concentrations of heavy metals in contaminated soils could be indirectly assessed by soil spectra according to the correlation between the spectrally featureless components and Fe; therefore, spectral reflectance would be an alternative tool for monitoring soil heavy metals contamination.展开更多
With the development of Internet technologies, Internet Based Information System (IBIS) arises with more advantages: Firstly, it is convenient for users to use owing to the introduction of Internet technologies. Secon...With the development of Internet technologies, Internet Based Information System (IBIS) arises with more advantages: Firstly, it is convenient for users to use owing to the introduction of Internet technologies. Secondly, it benefits greatly the data dissemination and data sharing based on Internet. The most important but not the last is that we can establish the information service network supported by its technologies and the facilities of information highway. So, it would be significant to design IBIS to realize the data collection, sharing and dissemination on Internet. There are many factors affecting regional environment. So it is not easy to realize the integrated environmental monitoring. Given this, we designed the Internet based environmental monitoring information system. By the virtue of the Internet based environmental monitoring information system, the management and storage of environmental monitoring data would be easier, which lays the foundation to actualize the environmental monitoring efficiently.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 40571130)the Natural Science Foundation of Shanghai, China (No. 07ZR14032)
文摘Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiometer (Analytical Spectral Devices, Inc., USA) under laboratory condition. Partial least square regression (PLSR) models were constructed for predicting soil metal concentrations. The data pre-processing methods, first and second derivatives (FD and SD), baseline correction (BC), standard normal variate (SNV), multiplicative scatter correction (MSC), and continuum removal (CR), were used for the spectral reflectance data pretreatments. Then, the prediction results were evaluated by relative root mean square error (RRMSE) and coefficients of determination (R 2 ). According to the criteria of minimal RRMSE and maximal R 2 , the PLSR models with the FD pretreatment (RRMSE = 0.24, R 2 = 0.61), SNV pretreatment (RRMSE = 0.08, R 2 = 0.78), and BC-pretreatment (RRMSE = 0.20, R 2 = 0.41) were considered as the final models for predicting As, Fe, and Cu, respectively. Wavebands at around 460, 1 400, 1 900, and 2 200 nm were selected as important spectral variables to construct final models. In conclusion, concentrations of heavy metals in contaminated soils could be indirectly assessed by soil spectra according to the correlation between the spectrally featureless components and Fe; therefore, spectral reflectance would be an alternative tool for monitoring soil heavy metals contamination.
基金Knowledge Innovation Project of CAS No. KZCX02-308
文摘With the development of Internet technologies, Internet Based Information System (IBIS) arises with more advantages: Firstly, it is convenient for users to use owing to the introduction of Internet technologies. Secondly, it benefits greatly the data dissemination and data sharing based on Internet. The most important but not the last is that we can establish the information service network supported by its technologies and the facilities of information highway. So, it would be significant to design IBIS to realize the data collection, sharing and dissemination on Internet. There are many factors affecting regional environment. So it is not easy to realize the integrated environmental monitoring. Given this, we designed the Internet based environmental monitoring information system. By the virtue of the Internet based environmental monitoring information system, the management and storage of environmental monitoring data would be easier, which lays the foundation to actualize the environmental monitoring efficiently.
