采用液液萃取(liquid-liquid extraction,LLE)和顶空固相微萃取(headspace solid-phase microextraction,HS-SPME)结合全二维气相色谱-飞行时间质谱(comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometr...采用液液萃取(liquid-liquid extraction,LLE)和顶空固相微萃取(headspace solid-phase microextraction,HS-SPME)结合全二维气相色谱-飞行时间质谱(comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry,GC×GC-TOFMS)技术解析了天龙泉米香型白酒挥发性组分特征。采用该技术并结合多种检索比对方式在天龙泉米香型白酒中鉴定出挥发性化合物505种,其中339种为天龙泉米香型白酒的潜在香气活性组分,包括86种酯类、50种芳香族、42种醇类、40种醛类、32种含氧杂环化合物、30种酮类、25种萜烯类、19种有机酸类、11种含硫化合物和4种含氮杂环化合物,表明了米香型白酒中香气成分的多样性和复杂性。在挥发性香气化合物含量角度上,不同贮存期的米香型白酒样品呈现明显差异,在时间维度上具有一定规律。其中,变化较大的化合物是醇类化合物、酯类化合物和醛类化合物,可能是受到了企业生产工艺的调整和陈化过程中发生的化学反应共同影响。该研究更深入地认识了米香型白酒的挥发性风味物质,丰富了米香型白酒风味化学的研究体系。展开更多
The effects of aging treatments on the tensile properties and compressive behavior of a thin-walled 6005 aluminum alloy tube were studied.Samples after three natural aging(NA)conditions were subsequently aged at 180℃...The effects of aging treatments on the tensile properties and compressive behavior of a thin-walled 6005 aluminum alloy tube were studied.Samples after three natural aging(NA)conditions were subsequently aged at 180℃ for 0.5−12.0 h artificial aging(AA).Tensile and compressive tests were performed after AA.The results show that for samples with the same NA,the longer the AA time is,the higher the strengths alloy owns,and at the same time the material shows a much lower elongation and faster process from plastic deformation to fracture.However,with NA prolonging,the alloy exhibits much better plastic deformation ability after AA,though its strength is decreased.The major cause of strength and plasticity variation induced by changing NA time is that the size of the main strengtheningβ''precipitates is larger and the density is lower.This character is evaluated by the strain hardening exponent n.Compressive results show that the optimum energy absorption characteristics can be acquired at a moderate n(14<n<17).Large n(n≥18)results in the fracture of tube during axial compression while low n(n≤13)causes lower energy absorption.展开更多
文摘采用液液萃取(liquid-liquid extraction,LLE)和顶空固相微萃取(headspace solid-phase microextraction,HS-SPME)结合全二维气相色谱-飞行时间质谱(comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry,GC×GC-TOFMS)技术解析了天龙泉米香型白酒挥发性组分特征。采用该技术并结合多种检索比对方式在天龙泉米香型白酒中鉴定出挥发性化合物505种,其中339种为天龙泉米香型白酒的潜在香气活性组分,包括86种酯类、50种芳香族、42种醇类、40种醛类、32种含氧杂环化合物、30种酮类、25种萜烯类、19种有机酸类、11种含硫化合物和4种含氮杂环化合物,表明了米香型白酒中香气成分的多样性和复杂性。在挥发性香气化合物含量角度上,不同贮存期的米香型白酒样品呈现明显差异,在时间维度上具有一定规律。其中,变化较大的化合物是醇类化合物、酯类化合物和醛类化合物,可能是受到了企业生产工艺的调整和陈化过程中发生的化学反应共同影响。该研究更深入地认识了米香型白酒的挥发性风味物质,丰富了米香型白酒风味化学的研究体系。
基金Project(2019JJ50054)supported by the Natural Science Foundation of Hunan Province,ChinaProjects(51975201,U1664252)supported by the National Natural Science Foundation of China。
文摘The effects of aging treatments on the tensile properties and compressive behavior of a thin-walled 6005 aluminum alloy tube were studied.Samples after three natural aging(NA)conditions were subsequently aged at 180℃ for 0.5−12.0 h artificial aging(AA).Tensile and compressive tests were performed after AA.The results show that for samples with the same NA,the longer the AA time is,the higher the strengths alloy owns,and at the same time the material shows a much lower elongation and faster process from plastic deformation to fracture.However,with NA prolonging,the alloy exhibits much better plastic deformation ability after AA,though its strength is decreased.The major cause of strength and plasticity variation induced by changing NA time is that the size of the main strengtheningβ''precipitates is larger and the density is lower.This character is evaluated by the strain hardening exponent n.Compressive results show that the optimum energy absorption characteristics can be acquired at a moderate n(14<n<17).Large n(n≥18)results in the fracture of tube during axial compression while low n(n≤13)causes lower energy absorption.
