Electric double-layer capacitors(EDLCs)with fast frequency response are regarded as small-scale alternatives to the commercial bulky aluminum electrolytic capacitors.Creating carbon-based nanoarray electrodes with pre...Electric double-layer capacitors(EDLCs)with fast frequency response are regarded as small-scale alternatives to the commercial bulky aluminum electrolytic capacitors.Creating carbon-based nanoarray electrodes with precise alignment and smooth ion channels is crucial for enhancing EDLCs’performance.However,controlling the density of macropore-dominated nanoarray electrodes poses challenges in boosting the capacitance of line-filtering EDLCs.Herein,a simple technique to finely adjust the vertical-pore diameter and inter-spacing in three-dimensional nanoporous anodic aluminum oxide(3D-AAO)template is achieved,and 3D compactly arranged carbon tube(3D-CACT)nanoarrays are created as electrodes for symmetrical EDLCs using nanoporous 3D-AAO template-assisted chemical vapor deposition of carbon.The 3D-CACT electrodes demonstrate a high surface area of 253.0 m^(2) g^(−1),a D/G band intensity ratio of 0.94,and a C/O atomic ratio of 8.As a result,the high-density 3D-CT nanoarray-based sandwich-type EDLCs demonstrate a record high specific areal capacitance of 3.23 mF cm^(-2) at 120 Hz and exceptional fast frequency response due to the vertically aligned and highly ordered nanoarray of closely packed CT units.The 3D-CT nanoarray electrode-based EDLCs could serve as line filters in integrated circuits,aiding power system miniaturization.展开更多
The occurrence of maize diseases was systematically studied at different growth stages of maize in different areas of Anhui Province. It was found that maize has a long optimal growth period in Anhui Province, and the...The occurrence of maize diseases was systematically studied at different growth stages of maize in different areas of Anhui Province. It was found that maize has a long optimal growth period in Anhui Province, and the maize planting structure is complex. The northern region is mainly planted with summer maize in large scale, while the southern region is mainly planted with spring maize in scattered pattern. In terms of diseases, the south spring maize suffered from more diverse diseases than the north summer maize. The main maize disease in Suzhou, Bozhou, Fuyang and Bengbu areas was southern rust, which was common with the highest diseased plant rate of 76%. The main maize diseases in Lu'an, Anqing, Chizhou, Tongling and Xuancheng were rust, maize rough dwarf virus(MRDV), southern leaf blight and sheath blight. Other diseases such as northern leaf blight, stalk rot and maize smut occurred commonly. The diseased plant rate of maize rust was in the range of 25%-47%.展开更多
In the present work, a novel porous, and chemically stable amine-based covalent organic polymer (POP-1) was designed and synthesized under solvothermal conditions. The porosity, crystallinity, chemical stability, el...In the present work, a novel porous, and chemically stable amine-based covalent organic polymer (POP-1) was designed and synthesized under solvothermal conditions. The porosity, crystallinity, chemical stability, electrochemical properties, and diffuse reflectance of POP-1 were investigated via N2 sorp- tion experiment, power X-ray diffraction, thermogravimetric analysis, cyclic voltammetry, and ultraviolet visible near infrared spectrometry, respectively. POP-I exhibits good chemical stability in both acidic and alkaline aqueous solutions, as well as in organic solvents. Undoped POP-1 can be directly used as a pho- tocatalyst for rhodamine B irradiation degradation under light-emitting diode and natural light. The Ea of POP-1 for RhB degradation is 82.37 kJ/mol. Furthermore, POP-1 can be reused as a catalyst in RhB degra- dation without degraded catalytic activity.展开更多
Organic heterostructures that can integrate the physiochemical properties of two or more substances have atracted widespread attention in the field of optoelectronics.However,the epitaxial growth process between diffe...Organic heterostructures that can integrate the physiochemical properties of two or more substances have atracted widespread attention in the field of optoelectronics.However,the epitaxial growth process between different organic material molecules is unpredictable,and the precise synthesis of organic heterostructures is stll particularly challenging.Herein,through the synergy approach of polymorphism and cocrystal engineering,a series of organic branched heterostructures have been successfully prepared.Interestingly,by simply adjusting the solvent ratio,different crystalline phases of perylene microplates can be epitaxilly grown on the perylene-OFN cocrystal microwires,which provides a feasible approach for the preparation of organic heterostructures.Meanwhile,these as-prepared organic branched heterostructures can realize multi-channel and multi-color emission,and act as optical logic gates,which promotes the multifunctional integrated optoelectronics.展开更多
基金supported by the National Natural Science Foundation of China(91963202,52072372,52372241,52232007,12325203)HFIPS Director’s Fund(BJPY2023A07,YZJJ-GGZX-2022-01).
文摘Electric double-layer capacitors(EDLCs)with fast frequency response are regarded as small-scale alternatives to the commercial bulky aluminum electrolytic capacitors.Creating carbon-based nanoarray electrodes with precise alignment and smooth ion channels is crucial for enhancing EDLCs’performance.However,controlling the density of macropore-dominated nanoarray electrodes poses challenges in boosting the capacitance of line-filtering EDLCs.Herein,a simple technique to finely adjust the vertical-pore diameter and inter-spacing in three-dimensional nanoporous anodic aluminum oxide(3D-AAO)template is achieved,and 3D compactly arranged carbon tube(3D-CACT)nanoarrays are created as electrodes for symmetrical EDLCs using nanoporous 3D-AAO template-assisted chemical vapor deposition of carbon.The 3D-CACT electrodes demonstrate a high surface area of 253.0 m^(2) g^(−1),a D/G band intensity ratio of 0.94,and a C/O atomic ratio of 8.As a result,the high-density 3D-CT nanoarray-based sandwich-type EDLCs demonstrate a record high specific areal capacitance of 3.23 mF cm^(-2) at 120 Hz and exceptional fast frequency response due to the vertically aligned and highly ordered nanoarray of closely packed CT units.The 3D-CT nanoarray electrode-based EDLCs could serve as line filters in integrated circuits,aiding power system miniaturization.
基金Supported by Discipline Construction of Anhui Academy of Agricultural Sciences(16A1133)
文摘The occurrence of maize diseases was systematically studied at different growth stages of maize in different areas of Anhui Province. It was found that maize has a long optimal growth period in Anhui Province, and the maize planting structure is complex. The northern region is mainly planted with summer maize in large scale, while the southern region is mainly planted with spring maize in scattered pattern. In terms of diseases, the south spring maize suffered from more diverse diseases than the north summer maize. The main maize disease in Suzhou, Bozhou, Fuyang and Bengbu areas was southern rust, which was common with the highest diseased plant rate of 76%. The main maize diseases in Lu'an, Anqing, Chizhou, Tongling and Xuancheng were rust, maize rough dwarf virus(MRDV), southern leaf blight and sheath blight. Other diseases such as northern leaf blight, stalk rot and maize smut occurred commonly. The diseased plant rate of maize rust was in the range of 25%-47%.
基金supported by the National Natural Science Foundation of China(21601109 and 21403130)the Natural Science Foundation of Shandong Province(ZR2014BQ028)
文摘In the present work, a novel porous, and chemically stable amine-based covalent organic polymer (POP-1) was designed and synthesized under solvothermal conditions. The porosity, crystallinity, chemical stability, electrochemical properties, and diffuse reflectance of POP-1 were investigated via N2 sorp- tion experiment, power X-ray diffraction, thermogravimetric analysis, cyclic voltammetry, and ultraviolet visible near infrared spectrometry, respectively. POP-I exhibits good chemical stability in both acidic and alkaline aqueous solutions, as well as in organic solvents. Undoped POP-1 can be directly used as a pho- tocatalyst for rhodamine B irradiation degradation under light-emitting diode and natural light. The Ea of POP-1 for RhB degradation is 82.37 kJ/mol. Furthermore, POP-1 can be reused as a catalyst in RhB degra- dation without degraded catalytic activity.
基金The authors acknowledge financial support from the National Natural Science Foundation of China(Nos.21703148,21971185)the Natural Science Foundation of Shandong Province(ZR2020MB054)+2 种基金Jjiangsu Key Laboratory for Carbon-Based Functional Materials&Devices,Soochow University(KJS2156)this project is also funded by the Collaborative Innovation Center of Suzhou Nano Science and Technology(CIC-Nano)by the"111"Project of The State Administration of Foreign Experts Affairs of China.
文摘Organic heterostructures that can integrate the physiochemical properties of two or more substances have atracted widespread attention in the field of optoelectronics.However,the epitaxial growth process between different organic material molecules is unpredictable,and the precise synthesis of organic heterostructures is stll particularly challenging.Herein,through the synergy approach of polymorphism and cocrystal engineering,a series of organic branched heterostructures have been successfully prepared.Interestingly,by simply adjusting the solvent ratio,different crystalline phases of perylene microplates can be epitaxilly grown on the perylene-OFN cocrystal microwires,which provides a feasible approach for the preparation of organic heterostructures.Meanwhile,these as-prepared organic branched heterostructures can realize multi-channel and multi-color emission,and act as optical logic gates,which promotes the multifunctional integrated optoelectronics.