In order to develop the liquid phase sintering process of WC-Ni3Al-B composites,the preparation process of WC+Ni3Al prealloyed powder by reaction synthesis of carbonyl Ni,analytical purity Al and coarse WC powders wa...In order to develop the liquid phase sintering process of WC-Ni3Al-B composites,the preparation process of WC+Ni3Al prealloyed powder by reaction synthesis of carbonyl Ni,analytical purity Al and coarse WC powders was investigated.DSC and XRD were adopted to study the procedure of phase transformation for the 3Ni+Al and 70%WC+(3Ni+Al) mixed powders in temperature ranges of 550-1200 °C and 25-1400 °C,respectively.The results demonstrate that the formation mechanism of Ni3Al depends on the reaction temperature.Besides WC phase,there exist Ni2Al3,NiAl and Ni3Al intermetallics in the powder mixture after heat treatment at 200-660 °C,while only NiAl and Ni3Al exist at 660-1100 °C.Homogeneous WC+Ni3Al powder mixture can be obtained in the temperature range of 1100-1200 °C.The WC-30%(Ni3Al-B) composites prepared from the mixed powders by conventional powder metallurgy technology show nearly full density and the shape of WC is round.WC-30%(Ni3Al-B) composites exhibit higher hardness of 9.7 GPa,inferior bending strength of 1800 MPa and similar fracture toughness of 18 MPa-m1/2 compared with commercial cemented carbides YGR45(WC-30%(Co-Ni-Cr)).展开更多
Three Ti-6Al-4V alloy powders with median diameters of 103, 66 and 44 pm, respectively, were pressed by high-velocity compaction (HVC) technology and then sintered in vacuum. The effects of particle sizes on forming...Three Ti-6Al-4V alloy powders with median diameters of 103, 66 and 44 pm, respectively, were pressed by high-velocity compaction (HVC) technology and then sintered in vacuum. The effects of particle sizes on forming as well as properties of sintered samples were investigated. The results show that fine powders are more difficult to press than coarse powders and its compact density is lower too. But the sintered density of fine powders is obviously higher than that of coarse powders. Compared with the powders with 103 and 66 ~un in diameter, the green density with 44 ~rn diameter powders is lower, which is 85.1% of theoretical density (TD) at an impact energy of 913 J. After sintering at 1300 ~C for 2,5 h, the sintered density of the compacts with 44 pm diameter powders is the highest, and reaches 98.2% of TD. Moreover, the sintered sample with 44 pan in diameter has the highest hardness and compressive strength, which are HV 354 and 1265 MPa, respectively.展开更多
基金Project (2012CB723906) supported by the National Basic Research Program of China
文摘In order to develop the liquid phase sintering process of WC-Ni3Al-B composites,the preparation process of WC+Ni3Al prealloyed powder by reaction synthesis of carbonyl Ni,analytical purity Al and coarse WC powders was investigated.DSC and XRD were adopted to study the procedure of phase transformation for the 3Ni+Al and 70%WC+(3Ni+Al) mixed powders in temperature ranges of 550-1200 °C and 25-1400 °C,respectively.The results demonstrate that the formation mechanism of Ni3Al depends on the reaction temperature.Besides WC phase,there exist Ni2Al3,NiAl and Ni3Al intermetallics in the powder mixture after heat treatment at 200-660 °C,while only NiAl and Ni3Al exist at 660-1100 °C.Homogeneous WC+Ni3Al powder mixture can be obtained in the temperature range of 1100-1200 °C.The WC-30%(Ni3Al-B) composites prepared from the mixed powders by conventional powder metallurgy technology show nearly full density and the shape of WC is round.WC-30%(Ni3Al-B) composites exhibit higher hardness of 9.7 GPa,inferior bending strength of 1800 MPa and similar fracture toughness of 18 MPa-m1/2 compared with commercial cemented carbides YGR45(WC-30%(Co-Ni-Cr)).
基金Project (51004040) supported by the National Natural Science Foundation of ChinaProject (20110952K) supported by Open Research Fund of State Key Laboratory of Powder Metallurgy of Central South University, China
文摘Three Ti-6Al-4V alloy powders with median diameters of 103, 66 and 44 pm, respectively, were pressed by high-velocity compaction (HVC) technology and then sintered in vacuum. The effects of particle sizes on forming as well as properties of sintered samples were investigated. The results show that fine powders are more difficult to press than coarse powders and its compact density is lower too. But the sintered density of fine powders is obviously higher than that of coarse powders. Compared with the powders with 103 and 66 ~un in diameter, the green density with 44 ~rn diameter powders is lower, which is 85.1% of theoretical density (TD) at an impact energy of 913 J. After sintering at 1300 ~C for 2,5 h, the sintered density of the compacts with 44 pm diameter powders is the highest, and reaches 98.2% of TD. Moreover, the sintered sample with 44 pan in diameter has the highest hardness and compressive strength, which are HV 354 and 1265 MPa, respectively.