Fiber products for microwave kilns were prepared using alumina fibers with alumina contents of 72 mass%and 80 mass%,and calcined alumina powder(4-6μm)as the main raw materials,silica sol as the binder,and cationic st...Fiber products for microwave kilns were prepared using alumina fibers with alumina contents of 72 mass%and 80 mass%,and calcined alumina powder(4-6μm)as the main raw materials,silica sol as the binder,and cationic starch as the flocculant.Effects of different raw materials and their additions on the wave transparency of fiber products were researched.The results show that as the alumina fiber(72%)addition increases,the heating rate of the samples first decreases and then increases,and the corresponding wave transparency of the sample first increases and then decreases.When the alumina fibers addition is 40 mass%and the alumina powder addition is 30 mass%,the prepared microwave kiln lining material has a higher mullite content,which improves the wave transparency of the sample.The sample prepared from alumina fibers with an alumina content of 80%has a suitable glass-mullite phase ratio,performs lower overall dielectric constant and good wave transparency,and is a suitable lining material for microwave kilns.展开更多
以尿素催化硅酸乙酯水解制得SiO2溶胶。采用29Si NMR、27 Al NMR、FT-IR、TEM、DTA、XRD和SEM等对SiO2溶胶、Al2O3凝胶纤维化学结构和微观结构研究结果表明,该SiO2溶胶稳定性好,含有大量的单硅酸Si(OH)4,能和Al2O3表面的Al—OH反应生成A...以尿素催化硅酸乙酯水解制得SiO2溶胶。采用29Si NMR、27 Al NMR、FT-IR、TEM、DTA、XRD和SEM等对SiO2溶胶、Al2O3凝胶纤维化学结构和微观结构研究结果表明,该SiO2溶胶稳定性好,含有大量的单硅酸Si(OH)4,能和Al2O3表面的Al—OH反应生成Al—O—Si键而有效地将其包裹,从而阻止了过渡态Al2O3微晶的相互接触,抑制了α-Al2O3的成核和生长。展开更多
The precursor sol of alumina was prepared by sol-gel method with aluminum nitrate and malic acid as raw materials.The effects of content of malic acid and polyvinylpyrrolidone （PVP） on sol spinnability were explored...The precursor sol of alumina was prepared by sol-gel method with aluminum nitrate and malic acid as raw materials.The effects of content of malic acid and polyvinylpyrrolidone （PVP） on sol spinnability were explored.The gel fibers with above 80 cm in length were obtained by mixing aluminum nitrate,malic acid and PVP on mass ratio of 10 3 1.5.Thermogravimetry-differential scanning calorimetry （TG-DSC）,Fourier transform infrared （FTIR） spectrum,X-ray diffractometry （XRD）,and scanning electron microscopy （SEM） were used to characterize the properties of the gel and ceramic fibers.The alumina fibers with a smooth surface and about 20μm in diameter were obtained by sintering at 1 200℃,and their main phase was indentified to be α-Al2O3.展开更多
采用同轴静电纺丝法制备了碳包覆纳米SnO2中空纤维超级电容器电极材料.利用X射线衍射(XRD)、拉曼光谱、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和比表面积分析仪(BET)对材料进行表征.结果表明,纤维呈现中空形貌,平均直径为1μm;SnO2...采用同轴静电纺丝法制备了碳包覆纳米SnO2中空纤维超级电容器电极材料.利用X射线衍射(XRD)、拉曼光谱、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和比表面积分析仪(BET)对材料进行表征.结果表明,纤维呈现中空形貌,平均直径为1μm;SnO2颗粒均匀分布于碳壳结构中,平均粒径为3–15 nm.材料的比表面积为565 m2 g–1.在三电极体系中,当电流密度为0.25 A g–1时,电极材料的比容量达397.5 F g–1;在1.0A g–1电流密度下,充放电循环3000次后比容量仍保持为初始值的88%.在对称型双电极体系中,电流密度为0.25 A g–1时,电极材料的比容量达162.0 F g–1,在1.0 A g–1电流密度下,充放电循环3000次后比容量仍保持为初始值的84%.展开更多
文摘Fiber products for microwave kilns were prepared using alumina fibers with alumina contents of 72 mass%and 80 mass%,and calcined alumina powder(4-6μm)as the main raw materials,silica sol as the binder,and cationic starch as the flocculant.Effects of different raw materials and their additions on the wave transparency of fiber products were researched.The results show that as the alumina fiber(72%)addition increases,the heating rate of the samples first decreases and then increases,and the corresponding wave transparency of the sample first increases and then decreases.When the alumina fibers addition is 40 mass%and the alumina powder addition is 30 mass%,the prepared microwave kiln lining material has a higher mullite content,which improves the wave transparency of the sample.The sample prepared from alumina fibers with an alumina content of 80%has a suitable glass-mullite phase ratio,performs lower overall dielectric constant and good wave transparency,and is a suitable lining material for microwave kilns.
文摘以尿素催化硅酸乙酯水解制得SiO2溶胶。采用29Si NMR、27 Al NMR、FT-IR、TEM、DTA、XRD和SEM等对SiO2溶胶、Al2O3凝胶纤维化学结构和微观结构研究结果表明,该SiO2溶胶稳定性好,含有大量的单硅酸Si(OH)4,能和Al2O3表面的Al—OH反应生成Al—O—Si键而有效地将其包裹,从而阻止了过渡态Al2O3微晶的相互接触,抑制了α-Al2O3的成核和生长。
基金Project(2010K10-21) supported by the Natural Science Foundation of Shaanxi Province,China
文摘The precursor sol of alumina was prepared by sol-gel method with aluminum nitrate and malic acid as raw materials.The effects of content of malic acid and polyvinylpyrrolidone （PVP） on sol spinnability were explored.The gel fibers with above 80 cm in length were obtained by mixing aluminum nitrate,malic acid and PVP on mass ratio of 10 3 1.5.Thermogravimetry-differential scanning calorimetry （TG-DSC）,Fourier transform infrared （FTIR） spectrum,X-ray diffractometry （XRD）,and scanning electron microscopy （SEM） were used to characterize the properties of the gel and ceramic fibers.The alumina fibers with a smooth surface and about 20μm in diameter were obtained by sintering at 1 200℃,and their main phase was indentified to be α-Al2O3.
文摘采用同轴静电纺丝法制备了碳包覆纳米SnO2中空纤维超级电容器电极材料.利用X射线衍射(XRD)、拉曼光谱、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和比表面积分析仪(BET)对材料进行表征.结果表明,纤维呈现中空形貌,平均直径为1μm;SnO2颗粒均匀分布于碳壳结构中,平均粒径为3–15 nm.材料的比表面积为565 m2 g–1.在三电极体系中,当电流密度为0.25 A g–1时,电极材料的比容量达397.5 F g–1;在1.0A g–1电流密度下,充放电循环3000次后比容量仍保持为初始值的88%.在对称型双电极体系中,电流密度为0.25 A g–1时,电极材料的比容量达162.0 F g–1,在1.0 A g–1电流密度下,充放电循环3000次后比容量仍保持为初始值的84%.
