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A Multi-Center Randomized Controlled Study UsingΔP_(CO2)/Ca-v_(O2)as the Target to Guide Early Tissue Hypoperfusion in Sepsis in Plateau Areas
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作者 Lianyu Zhang Fabin Zhang +6 位作者 Huanying Bai Huibin Yun Zhao Zheng Shuncai Liu Shenghua A Zhongshan Shi Yuhai Hu 《Journal of Clinical and Nursing Research》 2024年第1期187-195,共9页
Objective:To explore the value of using the venous-arterial carbon dioxide partial pressure difference and the arterial-venous oxygen content difference ratio(ΔP_(CO2)/Ca-v_(O2))as targets to guide early tissue hypop... Objective:To explore the value of using the venous-arterial carbon dioxide partial pressure difference and the arterial-venous oxygen content difference ratio(ΔP_(CO2)/Ca-v_(O2))as targets to guide early tissue hypoperfusion in sepsis in plateau areas.Methods:90 sepsis patients admitted to the Third People’s Hospital of Xining and Golmud People’s Hospital from June 2017 to December 2022 were selected as the research subjects,and they were divided into the Scv_(O2)(central venous oxygen saturation)group and theΔP_(CO2)/Ca-v_(O2)group,with 45 cases in each group.The two groups were treated with early shock resuscitation according to different protocols.The hemodynamic characteristics of the two groups of patients before and after resuscitation were observed,and the volume responsiveness was evaluated.The ROC(receiver operating characteristic)curve was used to analyze the significance ofΔP_(CO2)/Ca-v_(O2),Scv_(O2),lactate,lactate clearance,and urine output in evaluating patient prognosis and the correlation betweenΔP_(CO2)/Ca-v_(O2)and the above indicators was explored.Results:Compared with before resuscitation,after fluid resuscitation,the heart rate(HR),mean arterial pressure(MAP),central venous pressure(CVP),cardiac index(CI),lactate,lactate clearance rate,and urine output of the two groups of patients were significantly improved(P<0.05);in terms of therapeutic effect,the 28-day mortality rate,6-hour fluid balance,and lactic acid clearance of theΔP_(CO2)/Ca-v_(O2)group were better than the Scv_(O2)group.The ROC characteristic curve showed that theΔP_(CO2)/Ca-v_(O2)value can effectively predict the prognosis of patients(AUC=0.907,sensitivity was 97%,specificity was 72.4%,and critical value was 1.84).ΔP_(CO2)/Ca-v_(O2)significantly correlated with Scv_(O2),lactic acid,and lactic acid clearance rate.Conclusion:TheΔP_(CO2)/Ca-v_(O2)value can be used to guide fluid resuscitation in early hypoperfusion in sepsis in plateau areas,improve patients’hemodynamics,reduce lactate indicators,and increase urine output.ΔP_(CO2)/Ca-v_(O2)level>1.84 can effectively improve patient prognosis. 展开更多
关键词 ΔP_(co2)/Ca-v_(O2) Scv_(O2) SEPSIS Plateau area Prognosis
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Laboratory Experiments Do Not Support the Greenhouse Effect as Applicable to CO2
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作者 Michael D. Nelson 《International Journal of Geosciences》 CAS 2024年第10期809-839,共31页
The analysis of Greenhouse Effect experiments in the public domain indicated that the lab tests were primarily centered around illustrating the mechanics of conventional greenhouses. They used high-energy visible ligh... The analysis of Greenhouse Effect experiments in the public domain indicated that the lab tests were primarily centered around illustrating the mechanics of conventional greenhouses. They used high-energy visible light (such as sunlight), rather than addressing the Greenhouse Effect, which involves low-energy infrared radiation emitted by the Earth’s surface. Studies with argon, a non-greenhouse gas with similar density to CO2, showed thermal heat transfer as the dominant factor in the temperature profiles, with radiation absorption being undetected. The same conclusion was drawn by another study, which measured infrared back radiation. Experiments using exaggerated CO2 concentrations inadvertently illustrated the principle of the Popper Falsification Test by disproving the Greenhouse Effect applicable to CO2 within the troposphere. A straightforward kitchen test showed that a microwave oven cannot be used as a model for the Greenhouse Effect. 展开更多
关键词 Laboratory Experiment Climate Change Greenhouse Effect co2
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A Review on Technologies for the Use of CO2 as a Working Fluid in Refrigeration and Power Cycles
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作者 Orelien T. Boupda Hyacinthe D. Tessemo +3 位作者 Isidore B. Nkounda Fongang Francklin G. Nyami Frederic Lontsi Thomas Djiako 《Energy and Power Engineering》 2024年第6期217-256,共40页
The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its ther... The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its thermodynamic properties make it a fluid of choice in the efficient use of energy at low and medium temperatures in engine cycles. However, the performance of transcritical CO2 cycles weakens under high temperature and pressure conditions, especially in refrigeration systems;On the other hand, this disadvantage becomes rather interesting in engine cycles where CO2 can be used as an alternative to the organic working fluid in small and medium-sized electrical systems for low quality or waste heat sources. In order to improve the performance of systems operating with CO2 in the field of refrigeration and electricity production, research has made it possible to develop several concepts, of which this article deals with a review of the state of the art, followed by analyzes in-depth and critical of the various developments to the most recent modifications in these fields. Detailed discussions on the performance and technical characteristics of the different evolutions are also highlighted as well as the factors affecting the overall performance of the systems studied. Finally, perspectives on the future development of the use of CO2 in these different cycles are presented. 展开更多
关键词 Refrigeration Cycle Power Cycle System Performance Transcritical co2 Cycles Working Fluid
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Effects of Anthropogenic CO2 and Thermally-Induced CO2 on Global Warming
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作者 Masaharu Nishioka 《Atmospheric and Climate Sciences》 2024年第3期317-327,共11页
Changes in CO2 and temperature are correlated, but it is difficult to observe which is the cause and which is the effect. The release of CO2 dissolved in the ocean into the atmosphere depends on the atmospheric temper... Changes in CO2 and temperature are correlated, but it is difficult to observe which is the cause and which is the effect. The release of CO2 dissolved in the ocean into the atmosphere depends on the atmospheric temperature. However, examining the relationship between changes in CO2 caused by other phenomena and temperature is difficult. Studies of soil respiration (Rs) since the late 20th century have shown that CO2 emissions from soil respiration (Rs) are overwhelmingly greater than CO2 emissions from fossil fuel combustion. This is also noted in the IPCC carbon budget assessment. In this paper, the dependences of Rs on temperature, time, latitude, precipitation, seasons, etc., were investigated using the latest NASA database. The changes in temperature and Rs correlated well. There is also a good correlation between Rs and CO2 generation. Therefore, an increase in temperature results in an increase in CO2. On the other hand, there is no evidence other than model calculations that an increase in anthropogenic CO2 is mainly linked to a rise in temperature. The idea that global warming is caused by anthropogenic CO2 production is still a hypothesis. For these reasons, the relationship between global warming and anthropogenic CO2 should be reconsidered based on physical evidence without preconceptions. . 展开更多
关键词 Global Warming Anthropogenic co2 Thermally-Induced co2 Soil Respiration Carbon Cycles
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CO2 Back-Radiation Sensitivity Studies under Laboratory and Field Conditions
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作者 Ernst Hammel Martin Steiner +4 位作者 Christoph Marvan Matthias Marvan Klaus Retzlaff Werner Bergholz Axel Jacquine 《Atmospheric and Climate Sciences》 2024年第4期407-428,共22页
We measured the IR back radiation using a relatively low-cost experimental setup and a test chamber with increasing CO2 concentrations starting with a pure N2 atmosphere against a temperature-controlled black referenc... We measured the IR back radiation using a relatively low-cost experimental setup and a test chamber with increasing CO2 concentrations starting with a pure N2 atmosphere against a temperature-controlled black reference background. The results confirm estimations within this work and previous finding about CO2-induced infrared radiation saturation within realistic atmospheric conditions. We used this setup also to study thermal forcing effects with stronger and rare greenhouse gases against a clear night sky. Our results and their interpretation are another indication for having a more critical approach in climate modelling and against monocausal interpretation of climate indices only caused by anthropogenic greenhouse gas emissions. Basic physics combined with measurements and data taken from the literature allow us to conclude that CO2 induced infrared back-radiation must follow an asymptotic logarithmic-like behavior, which is also widely accepted in the climate-change community. The important question of climate sensitivity by doubling current CO2 concentrations is estimated to be below 1˚C. This value is important when the United Nations consider climate change as an existential threat and many governments intend rigorously to reduce net greenhouse gas emissions, led by an ambitious European Union inspired by IPCC assessments is targeting for more than 55% in 2030 and up to 100% in 2050 [1]. But probably they should also listen to experts [2] [3] who found that all these predictions have considerable flaws in basic models, data and impact scenarios. 展开更多
关键词 Climate Change Greenhouse Gases co2 Backscatter IR Radiation
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Capturing CO2 Emissions in the George C. Wallace Tunnel: A Case Study
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作者 Gabe Canitz Cole Ciesta +4 位作者 Klint Green Justin Sanders Jason Valencia Jeremy Willingham Daniel Fonseca 《Intelligent Control and Automation》 2024年第3期83-94,共12页
This paper describes the design of a ventilation system to be paired with a carbon capture system. The ventilation system utilizes the geometry of the George C. Wallace tunnel, located in the City of Mobile, Alabama, ... This paper describes the design of a ventilation system to be paired with a carbon capture system. The ventilation system utilizes the geometry of the George C. Wallace tunnel, located in the City of Mobile, Alabama, USA to capture and redirect emissions to a direct air capture (DAC) device to sequester 25% of the total CO2 mass generated from inside the tunnel. The total CO2 mass rate for the westbound traffic between the week-day hours of 7 a.m. and 6 p.m. has been estimated between 2,300 to 3,000 lbs./hr. By sequestering these emissions, the overall surrounding air quality was shown to be improved to a level that mirrors that from the pre-US industrial era of 270 ppm. 展开更多
关键词 co2 Capture Tunnel Ventilation Air Flow Analysis Jet Fan Sizing
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Cross-Correlation between Global Temperature and Atmospheric CO2 with a Temperature-Leading Time Lag
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作者 Masaharu Nishioka 《Atmospheric and Climate Sciences》 2024年第4期484-494,共11页
The temperature change and rate of CO2 change are correlated with a time lag, as reported in a previous paper. The correlation was investigated by calculating a correlation coefficient r of these changes for selected ... The temperature change and rate of CO2 change are correlated with a time lag, as reported in a previous paper. The correlation was investigated by calculating a correlation coefficient r of these changes for selected ENSO events in this study. Annual periodical increases and decreases in the CO2 concentration were considered, with a regular pattern of minimum values in August and maximum values in May each year. An increased deviation in CO2 and temperature was found in response to the occurrence of El Niño, but the increase in CO2 lagged behind the change in temperature by 5 months. This pattern was not observed for La Niña events. An increase in global CO2 emissions and a subsequent increase in global temperature proposed by IPCC were not observed, but an increase in global temperature, an increase in soil respiration, and a subsequent increase in global CO2 emissions were noticed. This natural process can be clearly detected during periods of increasing temperature specifically during El Niño events. The results cast strong doubts that anthropogenic CO2 is the cause of global warming. 展开更多
关键词 Global Warming Thermally-Induced co2 Soil Respiration Cross-Correlation Coefficient Time Lag El Niño
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深部煤层CO_(2)地质封存量化评估及案例研究 被引量:1
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作者 刘操 赵春辉 +2 位作者 钟福平 秦书杰 韦沧龙 《煤炭科学技术》 EI CAS CSCD 北大核心 2024年第S01期288-298,共11页
地质封存CO_(2)作为理想的减碳技术,有望成为缓解温室效应的重要手段,因此量化评估深部煤层CO_(2)地质封存潜力与研究超临界CO_(2)与深部煤岩之间相互作用成为了“双碳”背景下的研究热点。以焦作矿区九里山煤样为试验研究对象,分析了... 地质封存CO_(2)作为理想的减碳技术,有望成为缓解温室效应的重要手段,因此量化评估深部煤层CO_(2)地质封存潜力与研究超临界CO_(2)与深部煤岩之间相互作用成为了“双碳”背景下的研究热点。以焦作矿区九里山煤样为试验研究对象,分析了深部煤层超临界CO_(2)吸附与封存机理,分别开展了35和45℃下煤样的CO_(2)等温吸附试验,解释并校正了CO_(2)吸附等温线高压异常下拐现象,得到了不同温度下煤样的CO_(2)实际吸附量。提出了一种新方法计算CO_(2)地质封存量,能够校正吸附相体积造成的封存量计算误差,并能精确评估不同埋深煤层CO_(2)理论和有效封存量。研究结果表明:①当高压吸附饱和时,煤样表面所有的吸附位被完全占据,此时吸附相体积和密度不再发生改变,吸附量应趋于稳定,但实验室测得的吸附量却在高压饱和阶段随压力增大而减小,这并不符合Langmuir吸附原理,因此必须对实验室测试的吸附等温线进行校正,才能应用于深部煤层CO_(2)封存量评估;②煤中CO_(2)封存量主要由吸附和游离封存量组成,吸附封存量需要采用吸附相密度和Gibbs吸附量进行反算,游离封存量则需要掌握煤中游离相占据的孔隙体积,它只能根据煤中孔隙总体积减去吸附相体积进行计算,因此,吸附相是精确评估吸附和游离封存量的决定性因素;③采用修正的煤层CO_(2)地质封存量化方法,以焦作修武研究区800~2000 m深部煤层为例,得出其单位质量煤中CO_(2)理论封存量为1.52~2.16 mmol/g,CO_(2)有效封存总量为11.19×10^(9)m^(3),换算为封存总质量为21.97 Mt。本研究案例不仅校正了吸附试验数据的物质平衡错误,而且考虑了吸附相占据孔隙空间对游离封存量的影响,这对深部煤层CO_(2)地质封存量精准评估具有重要的应用意义。 展开更多
关键词 CO_(2)地质封存 深部煤层 CO_(2)吸附试验 吸附相 评估方法
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S型异质结光催化剂ZnFe_(2)O_(4)/WO_(3)的构筑及光催化还原CO_(2)性能 被引量:1
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作者 刘平 朱成才 +1 位作者 李艳阳 要红昌 《无机化学学报》 SCIE CSCD 北大核心 2024年第1期197-208,共12页
通过在WO_(3)纳米片表面负载ZnFe_(2)O_(4)纳米颗粒,构建了一系列S型异质结光催化剂ZnFe_(2)O_(4)/WO_(3),并研究了其光催化CO_(2)还原性能。在没有助催化剂和牺牲剂的条件下,所制备的ZnFe_(2)O_(4)/WO_(3)复合材料可对CO_(2)与水蒸汽... 通过在WO_(3)纳米片表面负载ZnFe_(2)O_(4)纳米颗粒,构建了一系列S型异质结光催化剂ZnFe_(2)O_(4)/WO_(3),并研究了其光催化CO_(2)还原性能。在没有助催化剂和牺牲剂的条件下,所制备的ZnFe_(2)O_(4)/WO_(3)复合材料可对CO_(2)与水蒸汽进行光催化反应。优化后的材料光照5 h后CO_(2)还原产物CO和CH_(4)的产量分别为7.87和4.88μmol·g^(-1)。相对于单相组分,CO和CH_(4)的产量明显提高。光催化活性的提高,归因于ZnFe_(2)O_(4)和WO_(3)异质结的形成以及光生载流子的S型电荷传输模式。 展开更多
关键词 CO_(2)还原 光催化活性 ZnFe_(2)O_(4)/WO_(3) 异质结 S型电荷传输模式
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The Influence of Heat Source IR Radiation on Black-Body Heating/Cooling with Increased CO2 Concentration
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作者 Thorstein O. Seim Borgar T. Olsen 《Atmospheric and Climate Sciences》 CAS 2023年第2期240-254,共15页
This study deal with interactions between thermal and radiative energy flow in experimental situations of varying complexity. Of special interest is how IR energy, re-emitted from CO<sub>2</sub> gas, behav... This study deal with interactions between thermal and radiative energy flow in experimental situations of varying complexity. Of special interest is how IR energy, re-emitted from CO<sub>2</sub> gas, behaves in an earth/atmosphere simulated setup. Such an experiment was performed by Hermann Harde and Michael Schnell where they show that IR radiation emitted from CO<sub>2</sub> can warm a small black-body metal plate. In a control experiment, we verified this result. However, in their experiment, the amount of IR radiation from the heating element was strongly attenuated. In a modified experiment, where IR emission from the heating source is present, no heating but a slight cooling of a black object is found when air is replaced by CO<sub>2</sub>. The modified experimental situation is also more like the earth/atmosphere situation. The presence of IR radiation from a heated surface (like when the sun heats the earth’s surface) strongly attenuates the heating ability of increasing backscatter from increased amount of CO<sub>2</sub> in the atmosphere. This result has consequences for the climate change models used by IPCC. 展开更多
关键词 Greenhouse Effect co2 Backscatter IR Radiation
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我国发展二氧化碳驱油技术的路径思考 被引量:1
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作者 庞敏 张益畅 《西南石油大学学报(社会科学版)》 2024年第4期1-9,共9页
当前,气候变化给人类社会发展带来了严峻的挑战。二氧化碳驱油作为一种能够有效提高油田采收率和减少二氧化碳排放的技术,在保障国家能源安全、创造社会经济价值、实现生态环境目标方面具有重要意义,是我国实现双碳目标的关键手段。在中... 当前,气候变化给人类社会发展带来了严峻的挑战。二氧化碳驱油作为一种能够有效提高油田采收率和减少二氧化碳排放的技术,在保障国家能源安全、创造社会经济价值、实现生态环境目标方面具有重要意义,是我国实现双碳目标的关键手段。在中国,二氧化碳驱油技术已经表现出广阔的应用前景,但是大规模推广应用还需要较长时间;同时,全球低碳合作和能源市场转型为中国发展二氧化碳驱油技术提供了机遇,但是也面临着经济成本高和环境风险大的挑战。今后,中国要全面发展和推广二氧化碳驱油技术,需要从构建产业法律体系、促进技术研发创新、完善合作交流机制、提高环境风险管理等方面持续发力。 展开更多
关键词 碳达峰 碳中和 二氧化碳驱油 二氧化碳埋存 态势分析法
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森林土壤不同粒径颗粒的碳矿化研究
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作者 马红亮 陈灿灿 +1 位作者 尹云锋 高人 《土壤学报》 CAS CSCD 北大核心 2024年第5期1247-1259,共13页
土壤是由不同粒径颗粒组成的,各粒径颗粒的性质差异大、在土壤中的空间位置不同。为了研究它们各自碳的变化差异,评估这些颗粒在土壤有机碳稳定和周转中的作用。选择亚热带阔叶林土壤,采用物理分组的方法,获得不同粒径土壤颗粒(>2000... 土壤是由不同粒径颗粒组成的,各粒径颗粒的性质差异大、在土壤中的空间位置不同。为了研究它们各自碳的变化差异,评估这些颗粒在土壤有机碳稳定和周转中的作用。选择亚热带阔叶林土壤,采用物理分组的方法,获得不同粒径土壤颗粒(>2000、2000~250、250~53、<53、53~20、20~2、<2μm),与全土等质量开展矿化试验,研究碳矿化量差异、主要碳形态变化及其相互关系,反向探究不同粒径颗粒在全土壤中的作用。结果表明,不同粒径颗粒按照质量比例作为权重计算的CO_(2)累积排放量、全碳、C/N、芳香性指数、游离氧化铁含量占全土的95.0%~101.8%。<2μm和20~2μm土壤颗粒CO_(2)累积排放量显著高于其他颗粒和全土。全土及各颗粒土壤CO_(2)累积排放量与比表面积、总孔隙体积、全碳、土壤可溶性有机碳(DOC,Dissolved organic carbon)、土壤微生物生物量碳(Soil microbial biomass carbon,MBC)、易氧化有机碳、游离氧化铁呈正相关性,而与C/N呈负相关性。通过对不同粒径颗粒16个指标降维分析,综合特征指数显示<2μm和20~2μm颗粒最高,即它们的综合作用最大。因此,全土壤的碳变化可追溯到土壤不同粒径颗粒碳的不同变化及关系,且土壤小粒径的团聚或被大粒径颗粒包闭可能是降低全土碳矿化的机理之一,有利于维持全土壤碳的稳定或增加保存。 展开更多
关键词 亚热带森林土壤 物理分组 碳稳定 碳矿化 CO_(2)排放
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土壤固碳微生物的绝对定量检测实验设计
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作者 付小花 陈皓 +2 位作者 张华 周磊 唐贤春 《实验室研究与探索》 CAS 北大核心 2024年第4期18-22,共5页
为了定量检测土壤中的固碳微生物,设计以功能基因cbbL为靶标的固碳微生物微滴数字聚合酶链式反应(ddPCR)检测方法。选择合适的引物探针,从退火温度、探针浓度以及引物浓度进行反应条件的优化,分析ddPCR检测方法的线性范围、敏感性、重... 为了定量检测土壤中的固碳微生物,设计以功能基因cbbL为靶标的固碳微生物微滴数字聚合酶链式反应(ddPCR)检测方法。选择合适的引物探针,从退火温度、探针浓度以及引物浓度进行反应条件的优化,分析ddPCR检测方法的线性范围、敏感性、重复性和特异性。结果显示,当退火温度为55.8℃、探针与引物浓度分别为350、750 nmol/L时,建立的cbbL-ddPCR扩增反应效率最高,阴阳性微滴分布界限最明显,平均拷贝数较高;检测的线性范围为2.3×10^(0)~2.3×10^(5)copies/μL-DNA,曲线方程y=0.1077x-95.562,相关系数R^(2)为0.9997,检出限为0.5 copy/μL-DNA,21个重复的变异系数仅为3.92%,与其他4种非固碳微生物DNA未发生交叉反应。所建立的cbbL-ddPCR方法可用于土壤微生物固碳潜能测定。 展开更多
关键词 微滴数字聚合酶链式反应 固碳微生物 cbbL基因 反应条件优化
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超临界CO2萃取制备澳洲坚果油的工艺优化
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作者 刘姚 杨光 +2 位作者 卓佳良 陈宇飞 吴世军 《当代农业(中英文版)》 2023年第1期16-25,共10页
利用单因素实验及响应面法优化超临界CO2萃取澳洲坚果油的工艺,并利用GC/MS、Folin-Ciocalteui法等国标方法,分析最优条件下坚澳洲坚果油的脂肪酸组成、多酚等活性成分。结果表明:各因素影响程度依次为:萃取温度(A)>萃取压力(B)>... 利用单因素实验及响应面法优化超临界CO2萃取澳洲坚果油的工艺,并利用GC/MS、Folin-Ciocalteui法等国标方法,分析最优条件下坚澳洲坚果油的脂肪酸组成、多酚等活性成分。结果表明:各因素影响程度依次为:萃取温度(A)>萃取压力(B)>萃取时间(C);交互项中AB、AC和BC对澳洲坚果油得率没有显著影响,AB、AC和BC对澳洲坚果油得率的影响表现为AC>BC>AB。响应面法优化得到的澳洲坚果油最佳工艺条件为萃取温度为51℃,压力为28 MPa,萃取时间为2.6 h,在此条件下,澳洲坚果油理论预测得率为73.35%,实际得率为72.55%,理论预测值与实际测定值基本一致。澳洲坚果油经GC/MS分析,共鉴定出13种脂肪酸,其中油酸、棕榈油酸、棕榈酸含量相对较高,分别为34.572%、9.001%和5.876%。经测定,澳洲坚果油的酸价和过氧化值分别为0.4 mg/g、4.13 mmol/kg,符合我国食用油标准,甾醇、多酚和角鲨烯含量分别为0.24 g/100g、26.4μg/g和37.3 mg/100g,未检出叶绿素和维生素E。本研究结果可为后续开发澳洲坚果油产品提供一定的参考依据。 展开更多
关键词 澳洲坚果油 超临界co2萃取 响应面试验 品质分析
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页岩油注CO_(2)过程中重有机质沉积预测
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作者 赵凤兰 王鹏 黄世军 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第3期134-144,共11页
综合考虑页岩基质纳米孔隙中吸附引发的限域效应、毛管压力作用及极性分子间的缔合作用,建立页岩油重有机质沉积预测模型及求解方法,并选取典型区块页岩油样开展重有机质沉积预测,对比分析页岩油重有机质沉积相边界的变化规律及CO_(2)... 综合考虑页岩基质纳米孔隙中吸附引发的限域效应、毛管压力作用及极性分子间的缔合作用,建立页岩油重有机质沉积预测模型及求解方法,并选取典型区块页岩油样开展重有机质沉积预测,对比分析页岩油重有机质沉积相边界的变化规律及CO_(2)注入对重有机质沉积相边界的影响。结果表明:缔合作用加剧低温区间的重有机质沉积风险,而高压区间内的重有机质沉积现象受纳米限域效应的影响更加显著;考虑耦合效应时,典型油样在CO_(2)注入量(摩尔分数)仅为5%时的重有机质沉积压力上限可达26.57 MPa,相比于未注气的情况下提高3 MPa;页岩油注CO_(2)过程中的重有机质沉积风险最大,控制CO_(2)注入量和避免地层压力降低过快是潜在的规避重有机质沉积风险的有效手段。 展开更多
关键词 页岩油 CO_(2)注入 重有机质沉积 预测方法
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CO_(2)快速吞吐提高页岩油采收率现场试验
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作者 姚红生 高玉巧 +3 位作者 郑永旺 邱伟生 龚月 钱洋慧 《天然气工业》 EI CAS CSCD 北大核心 2024年第3期10-19,共10页
页岩油注CO_(2)吞吐提高采收率技术处于探索阶段,目前面临着CO_(2)与页岩储层及流体相互作用机制不明确、数值模拟技术不成熟、缺乏规模注采及低成本回收工艺等技术难题。为探索页岩油注CO_(2)提高采收率主控机理,以苏北盆地溱潼凹陷古... 页岩油注CO_(2)吞吐提高采收率技术处于探索阶段,目前面临着CO_(2)与页岩储层及流体相互作用机制不明确、数值模拟技术不成熟、缺乏规模注采及低成本回收工艺等技术难题。为探索页岩油注CO_(2)提高采收率主控机理,以苏北盆地溱潼凹陷古近系阜宁组二段页岩油为对象开展了超临界CO_(2)水岩反应实验,分析了高温高压条件下页岩矿物溶蚀作用及其对孔隙度和渗透率的影响,并通过注CO_(2)恒质膨胀实验、最小混相压力测试评价了地层超压条件下注CO_(2)后原油高压物性变化特征,并在此基础上开展考虑多因素数值模拟研究优化了设计注入参数,最终通过矿场试验验证了技术可行性。研究结果表明:(1) CO_(2)水岩反应以碳酸质矿物溶蚀占主导,长英质矿物部分溶解,生成中大孔隙;(2)在地层原油中注入适量的CO_(2),显著萃取了原油中间烃组分,原油黏度从5.151 mPa·s下降到1.250 mPa·s,且CO_(2)首先萃取轻烃组分,随生产时间增加萃取组分逐渐变为重烃;(3)基于人工压裂与天然缝网混合介质组分数模模型,优化设计单井吞吐注气量1.7×10~4 t,注气速度500~600 t/d,焖井时间50 d;(4)低压侧加热的页岩油CO_(2)吞吐地面工艺,可依据CO_(2)注入地面工艺多参数数据模型,实现精准控温,避免注入管线冻堵及井下油管和套管材料低温脆断问题;(5)产出气CO_(2)浓度高于80%时,采用气相回收直注工艺,实现产出气回收成本降至104元/t。结论认为,CO_(2)快速吞吐有效提高了页岩油采收率,形成的机理认识和技术系列可为页岩油注CO_(2)吞吐开发提供参考和借鉴。 展开更多
关键词 页岩油 注CO_(2) 水岩反应 机理 混合介质组分数模 快速吞吐 地面工艺 现场试验
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地热储能技术研究进展及未来展望
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作者 芮振华 刘月亮 +1 位作者 张政 李根生 《石油科学通报》 CAS 2024年第2期260-281,共22页
地热储能技术是以地下流体为热载体,利用地下多孔介质空间存储能量,在必要时将其采至地面进行综合利用的一类技术。该技术从20世纪六十年代至今不断发展,针对不同行业的取能及减排需求,形成了基于不同热载体、不同规模、不同储能方式的... 地热储能技术是以地下流体为热载体,利用地下多孔介质空间存储能量,在必要时将其采至地面进行综合利用的一类技术。该技术从20世纪六十年代至今不断发展,针对不同行业的取能及减排需求,形成了基于不同热载体、不同规模、不同储能方式的技术体系,在技术创新过程中,在地热储能理念上实现了从“地球电池”的单一储能形式向“地球充电/热宝”多能互补储/供能系统的转变,充分利用地热储能技术“规模大、应用广、跨季节以及成本低”的特点,具有储热空间大、热利用效率高、安全性好以及绿色低碳等优点,目前全球范围内已经有多个项目试验了工业余热以及可再生能源的地热化存储并取得了良好的效果,展现了较好的技术实用性和广阔的发展空间。对能源的稳定供应和高效利用意义重大。地热储能与热提取的主要机理有热传导、对流换热、热弥散、热虹吸效应以及物理化学作用等,同时通过流体与岩石之间的热—流—固耦合作用实现能量在地下的储存、传递与转换,因此地热储能的效果取决于流体—岩石相互作用以及地热储能的方式等,且储热层内流体类型越多,所涉及到的机理越复杂。本文首先阐述了地热储能技术在国内外的发展历程,归纳总结了地热储能过程中基于流体—岩石相互作用的传热与储能机理,在总结前人工作的基础上对地热储层过程中储热层选址、含水层深度选取以及储能载体选择等关键技术难题及其研究现状进行了分析,同时对全球范围内主要的地热储能项目概况及运营现状进行了梳理和总结。研究认为,储热层的孔隙度、渗透率、厚度、各向异性及非均质性等参数对其储热效率及规模有较大影响,在选址过程中应当综合考虑储热层性质、热载体性质以及与地面热源的匹配程度。在此基础上,本文对地热储能技术的应用前景进行了展望,同时从储热机理上指出了该技术可能面临的一系列挑战,认为未来地热储能技术的研究突破点在于与碳捕集、利用与封存技术以及风、光、电等可持续能源的联合存储与利用,寻找隔热性能好的地下空间,研发和利用高性能的热能载体以及防堵塞与腐蚀技术的攻关等。作为对现有能源体系的进一步高效利用方式以及有益补充,地热储能以其在削峰填谷、节能减排以及能源综合利用等方面的独特优势,具有巨大的潜在资源量与市场潜力,是未来低碳地质能源发展方向。 展开更多
关键词 地热储能 储热层选址 含水层 热能载体 CO_(2)封存
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煤矿采动影响体微生物采残煤与CO_(2)-粉煤灰协同充填关键技术
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作者 苏现波 赵伟仲 +2 位作者 王乾 周艺璇 汪露飞 《煤炭学报》 EI CAS CSCD 北大核心 2024年第1期400-414,共15页
煤矿采空区是我国实现“双碳”目标的重要突破口,煤炭开采形成的、能够富集煤层气、为后期微生物活动和矿化充填提供底物和空间的地质体定义为采动影响体。以采动影响体为研究对象,提出了采动影响体微生物采残煤与CO_(2)-粉煤灰协同矿... 煤矿采空区是我国实现“双碳”目标的重要突破口,煤炭开采形成的、能够富集煤层气、为后期微生物活动和矿化充填提供底物和空间的地质体定义为采动影响体。以采动影响体为研究对象,提出了采动影响体微生物采残煤与CO_(2)-粉煤灰协同矿化充填关键技术,并从必要性和可行性2个方面阐述了该技术在采动影响体资源二次开发、CO_(2)安全封存以及燃煤电厂粉煤灰固废高效处置等的广阔前景。其总体思路是将采动影响体作为一个厌氧发酵“工厂”,高产高效产甲烷菌群作为“劳动者”对“工厂”已有的原材料——残煤、薄煤层和分散有机质以及注入的CO_(2)进行加工,其“产品”是甲烷,进而实现微生物采残煤和CO_(2)资源化。同时,CO_(2)与碱性的粉煤灰结合,在实现了CO_(2)矿化封存的同时,也实现了采动影响体的充填。该技术涉及的关键科学问题包括采动影响体类型划分与有机质特征、采动影响体原位条件下厌氧发酵产甲烷机制、微生物-CO_(2)-粉煤灰协同矿化/固化机制以及微生物采残煤与充填关键技术示范工程建设。实验室物理模拟采动影响体原位条件实验表明其中残煤和富含有机质的泥页岩能够在微生物作用下生成生物甲烷,且添加少量的粉煤灰能够进一步强化甲烷的产出。物理模拟地下水补给的动态实验表明营养物质的补给对厌氧发酵系统的影响尤为重要,补给循环周期为14 d的厌氧发酵系统恰与产甲烷菌群繁殖的周期一致,能够保证厌氧发酵系统的持续高效运行。高钙粉煤灰-CO_(2)-矿井水协同胶结的试件经过28 d的养护后抗压强度为12.31 MPa,其矿化封存潜力约为21.99 m3 CO_(2)/t(粉煤灰),说明粉煤灰在实现采空区固化的同时能够实现CO_(2)减排。此外,基于微生物采残煤与粉煤灰充填目的对工程试验靶区进行优选,地下水滞留区是CO_(2)矿化和粉煤灰充填的最佳场所,因采掘活动自然形成的自然圈闭和人工充填形成的圈闭是较有利的工程试验靶区之一。针对这些靶区提出了微生物采残煤与CO_(2)-粉煤灰协同充填关键技术,旨在为中国碳减排和采空区生态环境治理提供一条新的技术路径。 展开更多
关键词 煤矿采动影响体 微生物采残煤 CO_(2)封存 粉煤灰胶结充填 动静态特征 有机质特征
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脱水耦合逆水气变换制一氧化碳过程研究
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作者 熊果 胡黄灿 +3 位作者 刘桥云 曾力 徐文婷 杨宏昀 《当代化工研究》 CAS 2024年第19期185-187,共3页
逆水气变换制是CO为CO_(2)加氢二步法合成甲醇过程中的第一步。本文在逆水气变换反应过程引入脱水耦合反应,突破该反应在低温下的平衡限制。本文考察了脱水剂性能、脱水剂含量、H2与CO进料比等对该反应的影响,证明添加20%的脱水剂即可... 逆水气变换制是CO为CO_(2)加氢二步法合成甲醇过程中的第一步。本文在逆水气变换反应过程引入脱水耦合反应,突破该反应在低温下的平衡限制。本文考察了脱水剂性能、脱水剂含量、H2与CO进料比等对该反应的影响,证明添加20%的脱水剂即可至少提高商用催化剂低温(220~330℃)活性4~5倍,并获得远超平衡限制的CO_(2)转化率。 展开更多
关键词 碳中和 RWGS反应 二氧化碳加氢 脱水剂
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双碳战略中煤气共采技术发展路径的思考 被引量:6
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作者 李树刚 张静非 +5 位作者 林海飞 丁洋 白杨 周雨璇 朱冰 戴政 《煤炭科学技术》 EI CAS CSCD 北大核心 2024年第1期138-153,共16页
自提出“双碳”目标以来,我国生态文明建设已进入以降碳为重点战略方向的关键时期。煤炭作为兜底能源的地位短期内不会改变,能耗“双控”向碳排放总量和强度“双控”转变的核心即为CH_(4)-CO_(2)协同减排。在精准分析碳达峰、碳中和阶... 自提出“双碳”目标以来,我国生态文明建设已进入以降碳为重点战略方向的关键时期。煤炭作为兜底能源的地位短期内不会改变,能耗“双控”向碳排放总量和强度“双控”转变的核心即为CH_(4)-CO_(2)协同减排。在精准分析碳达峰、碳中和阶段煤矿CH_(4)-CO_(2)双重碳减排面临挑战的基础上,明确了双碳战略中煤气共采技术发展需结合现状需求-技术攻关-政策驱动的核心原则,制定了双碳战略中煤气共采技术的发展路径,论述了其中的关键技术问题。碳达峰阶段,CH_(4)减排以排放源管控为基础视角,核心为瓦斯抽采-利用全周期碳减排关键技术,包含瓦斯富集区靶向精准抽采技术、低渗煤层增透及注气驱替增流抽采技术、关闭矿井瓦斯逃逸通道封堵减碳技术、瓦斯富集-提浓-利用一体化技术,目的是大幅提升高浓度瓦斯抽采-利用效率,减少低浓度及通风瓦斯碳排放;CO_(2)减排以“CCUS+生态碳汇”全域负碳排放技术为核心,包含煤层CO_(2)封存、工业固废采空区充填协同CO_(2)地质封存、煤矿碳封存区域土壤-地表-大气异常监测及生态碳汇技术,进一步吸纳烟道气或纯CO_(2)排放。碳中和阶段核心任务是实现CH_(4)-CO_(2)(近)零碳排放,CO_(2)减排应当由技术攻关示范工程转变为规模化应用阶段,并建立全生命周期煤矿CH_(4)-CO_(2)排放智能监测及动态管控技术体系,实现监测管控技术手段与碳排放环节深度匹配、碳排放监测管控云平台与煤矿全局监控系统深度对接。最后对未来煤气共采体系绿色低碳发展提出了自身见解与思考:(1)继续深化“高效精准抽采+全浓度梯级利用”煤矿CH_(4)零排放技术模式;(2)持续攻关“CO_(2)工程封存+生态碳汇”CO_(2)零排放技术体系;(3)积极探索煤矿“零碳智慧园区”综合解决方案,形成激励和倒逼并重的煤矿碳减排政策支持体系。 展开更多
关键词 双碳目标 CH_(4)-CO_(2)协同减排 煤气共采 发展路径 绿色低碳
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