CsPbI_(2)Br perovskite solar cell has been extensively studied due to its exceptional thermal stability and relatively stable perovskite phase structure.However,the presence of bromine leads to a rapid crystallization...CsPbI_(2)Br perovskite solar cell has been extensively studied due to its exceptional thermal stability and relatively stable perovskite phase structure.However,the presence of bromine leads to a rapid crystallization rate of CsPbI_(2)Br films,resulting in small grain size and high defect density.Additionally,CsPbI_(2)Br demonstrates poor light absorption due to its wide bandgap.Therefore,it is crucial to control the crystallization rate and increase the film thickness to reduce defect density,enhance light absorption,and improve photovoltaic performance.In this study,we utilized a PbAc_(2)-incorporated twice spincoating(PTS) process to address these issues.Initially,PbAc_(2) was added to the CsPbI_(2)Br precursor solution to form a CsPbI_(2)Br film,which was then coated with the CsPbI_(2)Br precursor solution to produce the PTS film,Ac^(-)can delay the perovskite crystallization,leading to the formation of thicker and denser CsPbI_(2)Br films.Moreover,lone-pair electrons of the oxygen atom provided by Ac^(-)formed coordination bonds with under-coordinated Pb~(2+) ions to fill halogen ion vacancies,thereby reducing the defect density.Ultimately,the PTS CsPbI_(2)Br device achieved a peak power conversion efficiency(PCE) of 16.19% and maintained 96.7% of its initial PCE over 1500 h at room temperature under 25% relative humidity without any encapsulation.展开更多
CsPbX_(3)-based(X=I,Br,Cl)inorganic perovskite solar cells(PSCs)prepared by low-temperature process have attracted much attention because of their low cost and excellent thermal stability.However,the high trap state d...CsPbX_(3)-based(X=I,Br,Cl)inorganic perovskite solar cells(PSCs)prepared by low-temperature process have attracted much attention because of their low cost and excellent thermal stability.However,the high trap state density and serious charge recombination between low-temperature processed TiO_(2)film and inorganic perovskite layer interface seriously restrict the performance of all-inorganic PSCs.Here a thin polyethylene oxide(PEO)layer is employed to modify TiO_(2)film to passivate traps and promote carrier collection.The impacts of PEO layer on microstructure and photoelectric characteristics of TiO_(2)film and related devices are systematically studied.Characterization results suggest that PEO modification can reduce the surface roughness of TiO_(2)film,decrease its average surface potential,and passivate trap states.At optimal conditions,the champion efficiency of CsPbI_(2)Br PSCs with PEO-modified TiO_(2)(PEO-PSCs)has been improved to 11.24%from 9.03%of reference PSCs.Moreover,the hysteresis behavior and charge recombination have been suppressed in PEO-PSCs.展开更多
Offshore carbon dioxide(CO_(2)) geological storage(OCGS) represents a significant strategy for addressing climate change by curtailing greenhouse gas emissions. Nonetheless, the risk of CO_(2) leakage poses a substant...Offshore carbon dioxide(CO_(2)) geological storage(OCGS) represents a significant strategy for addressing climate change by curtailing greenhouse gas emissions. Nonetheless, the risk of CO_(2) leakage poses a substantial concern associated with this technology. This study introduces an innovative approach for establishing OCGS leakage scenarios, involving four pivotal stages, namely, interactive matrix establishment, risk matrix evaluation, cause–effect analysis, and scenario development, which has been implemented in the Pearl River Estuary Basin in China. The initial phase encompassed the establishment of an interaction matrix for OCGS systems based on features, events, and processes. Subsequent risk matrix evaluation and cause–effect analysis identified key system components, specifically CO_(2) injection and faults/features. Building upon this analysis, two leakage risk scenarios were successfully developed, accompanied by the corresponding mitigation measures. In addition, this study introduces the application of scenario development to risk assessment, including scenario numerical simulation and quantitative assessment. Overall, this research positively contributes to the sustainable development and safe operation of OCGS projects and holds potential for further refinement and broader application to diverse geographical environments and project requirements. This comprehensive study provides valuable insights into the establishment of OCGS leakage scenarios and demonstrates their practical application to risk assessment, laying the foundation for promoting the sustainable development and safe operation of ocean CO_(2) geological storage projects while proposing possibilities for future improvements and broader applications to different contexts.展开更多
L2 reading is not only an important channel for people to obtain information and knowledge,but also the main way for people to learn a foreign language.Reading information processing can be divided into controlled pro...L2 reading is not only an important channel for people to obtain information and knowledge,but also the main way for people to learn a foreign language.Reading information processing can be divided into controlled processing and automatic processing.Controlled information processing is a conscious and resource-intensive processing model,while automatic information processing is an unconscious and automatic processing model.This study investigates the characteristics and interactivity of controlled and automatic information processing in L2 reading,and explores the roles of controlled and automatic information processing strategies in improving L2 reading ability.The findings are as follows:(a)controlled and automatic information processing is interactive in L2 reading;and(b)the uses of controlled and automatic information processing strategies are beneficial to the improvement of the reading ability of L2 learners.This study has important theoretical and practical value in improving the efficiency of L2 reading teaching and learning.展开更多
Geomagnetic storm events have a strong influence on the ionosphere–thermosphere(I-T)coupling system.Analyzing the regional response process of the I-T system and its differences across the northern and southern hemis...Geomagnetic storm events have a strong influence on the ionosphere–thermosphere(I-T)coupling system.Analyzing the regional response process of the I-T system and its differences across the northern and southern hemispheres is an important but challenging task.In this study,we used a combination of multiple observations and a model simulation to examine the north–south hemispheric difference in the I-T coupling system in the American and Asian sectors during the geomagnetic superstorm that occurred in May 2024.Observations of the total electron content(TEC)showed that the Asian sector had negative storms in the northern hemisphere and positive storms in the southern hemisphere,a process that exacerbated the hemispheric differences in the TEC.However,both hemispheres of the American sector showed negative storms.The thermospheric composition changes also differed between the two sectors,and their variation could partially explain the hemispheric differences caused by positive and negative storms.Moreover,the influence of the thermospheric density change was less than that of the thermospheric composition.Finally,the dynamic effect of the thermospheric wind and the plasma transport processes strongly modulated the north–south differences in the TEC at nighttime in the American and Asian sectors,respectively,during this superstorm.展开更多
[Objectives] This study was conducted to solve the prominent problems in the treatment of domestic sewage in southern rural areas of China. [Methods] An integrated process treatment mode of anaerobic/anoxic/aerobic mo...[Objectives] This study was conducted to solve the prominent problems in the treatment of domestic sewage in southern rural areas of China. [Methods] An integrated process treatment mode of anaerobic/anoxic/aerobic moving bed biofilm reactor (A 2O-MBBR) was proposed to analyze and study its operating effect and influencing factors. [Results] The A^(2)O-MBBR mode had good COD removal efficiency and nitrogen and phosphorus removal performance, and the water quality index of the effluent met the Class A standard of GB181918-2002. This mode is suitable for treating rural domestic sewage, and has high treatment effects in different operating periods. In spring, the average removal rates of COD, NH_(4)^(+)-N, TN, TP and SS reached (83.53 ± 2.15)%, (89.44 ± 4.97)%, (67.36±18.53)%, (88.22±11.21)% and (91.73±2.25)%, respectively;In the autumn period, the average removal rates of COD, NH_(4)^(+)-N, TN, TP and SS were (83.49±2.64)%, (89.26±9.19)%, (66.05±17.00)%, (87.48±9.68)%, and (91.13±2.35)%. [Conclusions] This study provides theoretical reference and technical support for the popularization and application of A^(2)O-MBBR integrated process.展开更多
The morphology and the formation of Y2BaCuO5 phase in powder melting processed YBa2Cu3O7-x superconductors were investigated. The experimental results show the heat treatment can not change the shape of Y2BaCuO5 parti...The morphology and the formation of Y2BaCuO5 phase in powder melting processed YBa2Cu3O7-x superconductors were investigated. The experimental results show the heat treatment can not change the shape of Y2BaCuO5 particles in powder melting processed samples. The formation of round Y2BaCuO5 phase is due to relative content of each constitution of precursor powders in powder melting process. For powder melting process, the excessive liquid phase is eliminated, which restrains the preferred growth of Y2BaCuO5 particles.展开更多
The ultrafine powders of YBa2Cu3O7-x with the size of 100nm were synthesized by Sol-Gel process using cit-rate as complex and ammonium hydroxide to adjust pH of solu-tion. The process of Sol formation and Gel polymeri...The ultrafine powders of YBa2Cu3O7-x with the size of 100nm were synthesized by Sol-Gel process using cit-rate as complex and ammonium hydroxide to adjust pH of solu-tion. The process of Sol formation and Gel polymerization of YBa2Cu3O7-x in the Sol-Gel synthetic reaction has bee studied. The particle size ,pruity, sintering activity and superconducting properties of YBa2Cu3O7-x prepared by Sol-Gel method are better than by solid state reaction.展开更多
YBa2Cu3O7-δ-Agx composite superconductors were prepared by hybrid sintering process using YBa2Cu3O7-δ-Agx ultrafine powder and Ag2O finepower, which were prepared by sol-gel process and precipitation process respect...YBa2Cu3O7-δ-Agx composite superconductors were prepared by hybrid sintering process using YBa2Cu3O7-δ-Agx ultrafine powder and Ag2O finepower, which were prepared by sol-gel process and precipitation process respectively. The effect of the Ag content on superconducting crictical transition temperature of YBa2Cu3O7-δ-Agx was not evident as long as YBa2Cu3O7-δ-Agx can form continuous network. But Ag can increase superconduction crictical current and density of the composite superconductors. The normal state (i.e. non-superconducting state at room temperature) resistivity shows a percolation threshold at 20%-30% Ag, whereas the superconducting net-work shows a percolationthreshold at 70% -80% Ag.展开更多
In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase ...In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase analysis for the sample treated in vacuum condition were made.The results showed that the temperature of phase transition is related to oxygen content in the sample and in general,is 100℃ to 120℃ lower in vacu- um condition than in air.At 320℃ to 350℃ twin bands begin to disappear,and some Cu_2O are formed on the surface of the sample and transit from orthorhombic YBa_2Cu_3O_(7-x) to arthorhombic Y_2BaCuO_5 compound. This transition was completed at about 500℃.Above 900℃,this compound consists of the Y_2BaCuO_5, BaCuO_2,Y_2O_3 and some other minor compounds.No phase transition was observed during cooling the sample.展开更多
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-speciality grout. Dicalcium silicate （Ca2SiO4） is the primary constituent ...Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-speciality grout. Dicalcium silicate （Ca2SiO4） is the primary constituent of a number of different types of cement. The β-Ca2SiO4 phase is metastable at room temperature and will transform into β-Ca2SiO4 at 663K. In this work, Portland cement is annealed at a temperature of 950K under pressures in the range of 0-5.5 CPa. The high pressure experiments are carried out in an apparatus with six anvil tops. The effect of high pressure on the obtaining nano-size β-Ca2SiO4 （C2S） process is investigated by x-ray diffraction and transmission electron microscopy. Experimental results show that the grain size of the C2S decreases with the increase of pressure. The volume fraction of the C2S phase increases with the pressure as the pressure is below 3 CPa, and then decreases （P 〉 3 GPa）. The nano-effect is very important to the stabilization of β-Ca2SiO4. The mechanism for the effects of the high pressure on the annealing process of the Portland cement is also discussed.展开更多
基金supported by the National Natural Science Foundation of China (U22A20142)the Fundamental Research Funds for the Central Universities (2023JC007)。
文摘CsPbI_(2)Br perovskite solar cell has been extensively studied due to its exceptional thermal stability and relatively stable perovskite phase structure.However,the presence of bromine leads to a rapid crystallization rate of CsPbI_(2)Br films,resulting in small grain size and high defect density.Additionally,CsPbI_(2)Br demonstrates poor light absorption due to its wide bandgap.Therefore,it is crucial to control the crystallization rate and increase the film thickness to reduce defect density,enhance light absorption,and improve photovoltaic performance.In this study,we utilized a PbAc_(2)-incorporated twice spincoating(PTS) process to address these issues.Initially,PbAc_(2) was added to the CsPbI_(2)Br precursor solution to form a CsPbI_(2)Br film,which was then coated with the CsPbI_(2)Br precursor solution to produce the PTS film,Ac^(-)can delay the perovskite crystallization,leading to the formation of thicker and denser CsPbI_(2)Br films.Moreover,lone-pair electrons of the oxygen atom provided by Ac^(-)formed coordination bonds with under-coordinated Pb~(2+) ions to fill halogen ion vacancies,thereby reducing the defect density.Ultimately,the PTS CsPbI_(2)Br device achieved a peak power conversion efficiency(PCE) of 16.19% and maintained 96.7% of its initial PCE over 1500 h at room temperature under 25% relative humidity without any encapsulation.
基金financially supported by the Guangzhou Basic and Applied Basic Research Foundation,China(No.303523)。
文摘CsPbX_(3)-based(X=I,Br,Cl)inorganic perovskite solar cells(PSCs)prepared by low-temperature process have attracted much attention because of their low cost and excellent thermal stability.However,the high trap state density and serious charge recombination between low-temperature processed TiO_(2)film and inorganic perovskite layer interface seriously restrict the performance of all-inorganic PSCs.Here a thin polyethylene oxide(PEO)layer is employed to modify TiO_(2)film to passivate traps and promote carrier collection.The impacts of PEO layer on microstructure and photoelectric characteristics of TiO_(2)film and related devices are systematically studied.Characterization results suggest that PEO modification can reduce the surface roughness of TiO_(2)film,decrease its average surface potential,and passivate trap states.At optimal conditions,the champion efficiency of CsPbI_(2)Br PSCs with PEO-modified TiO_(2)(PEO-PSCs)has been improved to 11.24%from 9.03%of reference PSCs.Moreover,the hysteresis behavior and charge recombination have been suppressed in PEO-PSCs.
文摘Offshore carbon dioxide(CO_(2)) geological storage(OCGS) represents a significant strategy for addressing climate change by curtailing greenhouse gas emissions. Nonetheless, the risk of CO_(2) leakage poses a substantial concern associated with this technology. This study introduces an innovative approach for establishing OCGS leakage scenarios, involving four pivotal stages, namely, interactive matrix establishment, risk matrix evaluation, cause–effect analysis, and scenario development, which has been implemented in the Pearl River Estuary Basin in China. The initial phase encompassed the establishment of an interaction matrix for OCGS systems based on features, events, and processes. Subsequent risk matrix evaluation and cause–effect analysis identified key system components, specifically CO_(2) injection and faults/features. Building upon this analysis, two leakage risk scenarios were successfully developed, accompanied by the corresponding mitigation measures. In addition, this study introduces the application of scenario development to risk assessment, including scenario numerical simulation and quantitative assessment. Overall, this research positively contributes to the sustainable development and safe operation of OCGS projects and holds potential for further refinement and broader application to diverse geographical environments and project requirements. This comprehensive study provides valuable insights into the establishment of OCGS leakage scenarios and demonstrates their practical application to risk assessment, laying the foundation for promoting the sustainable development and safe operation of ocean CO_(2) geological storage projects while proposing possibilities for future improvements and broader applications to different contexts.
文摘L2 reading is not only an important channel for people to obtain information and knowledge,but also the main way for people to learn a foreign language.Reading information processing can be divided into controlled processing and automatic processing.Controlled information processing is a conscious and resource-intensive processing model,while automatic information processing is an unconscious and automatic processing model.This study investigates the characteristics and interactivity of controlled and automatic information processing in L2 reading,and explores the roles of controlled and automatic information processing strategies in improving L2 reading ability.The findings are as follows:(a)controlled and automatic information processing is interactive in L2 reading;and(b)the uses of controlled and automatic information processing strategies are beneficial to the improvement of the reading ability of L2 learners.This study has important theoretical and practical value in improving the efficiency of L2 reading teaching and learning.
基金supported by the National Natural Science Foundation of China (Grant Nos. 42030202, 42241115, and 42174204)the China Postdoctoral Science Foundation (Grant No. 2023M743467)+2 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. Y202021)the National Key R&D Program of China (Grant No. 2022YFF0504400)the Opening Funding of the Chinese Academy of Sciences dedicated to the Chinese Meridian Project
文摘Geomagnetic storm events have a strong influence on the ionosphere–thermosphere(I-T)coupling system.Analyzing the regional response process of the I-T system and its differences across the northern and southern hemispheres is an important but challenging task.In this study,we used a combination of multiple observations and a model simulation to examine the north–south hemispheric difference in the I-T coupling system in the American and Asian sectors during the geomagnetic superstorm that occurred in May 2024.Observations of the total electron content(TEC)showed that the Asian sector had negative storms in the northern hemisphere and positive storms in the southern hemisphere,a process that exacerbated the hemispheric differences in the TEC.However,both hemispheres of the American sector showed negative storms.The thermospheric composition changes also differed between the two sectors,and their variation could partially explain the hemispheric differences caused by positive and negative storms.Moreover,the influence of the thermospheric density change was less than that of the thermospheric composition.Finally,the dynamic effect of the thermospheric wind and the plasma transport processes strongly modulated the north–south differences in the TEC at nighttime in the American and Asian sectors,respectively,during this superstorm.
基金Supported by Scientific Research Project of Hunan Provincial Department of Education(22C0083)。
文摘[Objectives] This study was conducted to solve the prominent problems in the treatment of domestic sewage in southern rural areas of China. [Methods] An integrated process treatment mode of anaerobic/anoxic/aerobic moving bed biofilm reactor (A 2O-MBBR) was proposed to analyze and study its operating effect and influencing factors. [Results] The A^(2)O-MBBR mode had good COD removal efficiency and nitrogen and phosphorus removal performance, and the water quality index of the effluent met the Class A standard of GB181918-2002. This mode is suitable for treating rural domestic sewage, and has high treatment effects in different operating periods. In spring, the average removal rates of COD, NH_(4)^(+)-N, TN, TP and SS reached (83.53 ± 2.15)%, (89.44 ± 4.97)%, (67.36±18.53)%, (88.22±11.21)% and (91.73±2.25)%, respectively;In the autumn period, the average removal rates of COD, NH_(4)^(+)-N, TN, TP and SS were (83.49±2.64)%, (89.26±9.19)%, (66.05±17.00)%, (87.48±9.68)%, and (91.13±2.35)%. [Conclusions] This study provides theoretical reference and technical support for the popularization and application of A^(2)O-MBBR integrated process.
基金Funded by the National Natural Science Foundation of China (50432050)the National High Technology Research and Development Program of China(2007AA03Z241)
文摘The morphology and the formation of Y2BaCuO5 phase in powder melting processed YBa2Cu3O7-x superconductors were investigated. The experimental results show the heat treatment can not change the shape of Y2BaCuO5 particles in powder melting processed samples. The formation of round Y2BaCuO5 phase is due to relative content of each constitution of precursor powders in powder melting process. For powder melting process, the excessive liquid phase is eliminated, which restrains the preferred growth of Y2BaCuO5 particles.
文摘The ultrafine powders of YBa2Cu3O7-x with the size of 100nm were synthesized by Sol-Gel process using cit-rate as complex and ammonium hydroxide to adjust pH of solu-tion. The process of Sol formation and Gel polymerization of YBa2Cu3O7-x in the Sol-Gel synthetic reaction has bee studied. The particle size ,pruity, sintering activity and superconducting properties of YBa2Cu3O7-x prepared by Sol-Gel method are better than by solid state reaction.
文摘YBa2Cu3O7-δ-Agx composite superconductors were prepared by hybrid sintering process using YBa2Cu3O7-δ-Agx ultrafine powder and Ag2O finepower, which were prepared by sol-gel process and precipitation process respectively. The effect of the Ag content on superconducting crictical transition temperature of YBa2Cu3O7-δ-Agx was not evident as long as YBa2Cu3O7-δ-Agx can form continuous network. But Ag can increase superconduction crictical current and density of the composite superconductors. The normal state (i.e. non-superconducting state at room temperature) resistivity shows a percolation threshold at 20%-30% Ag, whereas the superconducting net-work shows a percolationthreshold at 70% -80% Ag.
文摘In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase analysis for the sample treated in vacuum condition were made.The results showed that the temperature of phase transition is related to oxygen content in the sample and in general,is 100℃ to 120℃ lower in vacu- um condition than in air.At 320℃ to 350℃ twin bands begin to disappear,and some Cu_2O are formed on the surface of the sample and transit from orthorhombic YBa_2Cu_3O_(7-x) to arthorhombic Y_2BaCuO_5 compound. This transition was completed at about 500℃.Above 900℃,this compound consists of the Y_2BaCuO_5, BaCuO_2,Y_2O_3 and some other minor compounds.No phase transition was observed during cooling the sample.
基金Supported by the National Natural Science Foundation of China under Grant No 11674274
文摘Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-speciality grout. Dicalcium silicate （Ca2SiO4） is the primary constituent of a number of different types of cement. The β-Ca2SiO4 phase is metastable at room temperature and will transform into β-Ca2SiO4 at 663K. In this work, Portland cement is annealed at a temperature of 950K under pressures in the range of 0-5.5 CPa. The high pressure experiments are carried out in an apparatus with six anvil tops. The effect of high pressure on the obtaining nano-size β-Ca2SiO4 （C2S） process is investigated by x-ray diffraction and transmission electron microscopy. Experimental results show that the grain size of the C2S decreases with the increase of pressure. The volume fraction of the C2S phase increases with the pressure as the pressure is below 3 CPa, and then decreases （P 〉 3 GPa）. The nano-effect is very important to the stabilization of β-Ca2SiO4. The mechanism for the effects of the high pressure on the annealing process of the Portland cement is also discussed.
