The growing correlation length prior to the moderate-great earthquakes occurred in Gansu Province and its nearby area since 1986 has been studied using the method of single-link cluster analysis (SLC). According to di...The growing correlation length prior to the moderate-great earthquakes occurred in Gansu Province and its nearby area since 1986 has been studied using the method of single-link cluster analysis (SLC). According to different conditions in the source area, the circular spatial window centered in the epicenter and the parallelgrammic spatial window along the fault belt have been selected. The results show that the phenomena of growing correlation length have been observed before the earthquakes studied in the paper.展开更多
Seismic correlation length for moderate earthquakes prior to two great earthquakes in the northern sea area of Sumatra Island (Mw9.1 in 2004 and MsS. 6 in 2012) has been studied, using method of Single- Link-Cluster...Seismic correlation length for moderate earthquakes prior to two great earthquakes in the northern sea area of Sumatra Island (Mw9.1 in 2004 and MsS. 6 in 2012) has been studied, using method of Single- Link-Cluster ( SLC ) analysis, and found to show a power-law growth about two years before their occurrences. No such growth was found for a magnitude 7 earthquake in the same area. This result suggests the occurrence of a physical process of critical-point characteristics in the source area before the great earthquakes.展开更多
We simulated the temporal correlation of sound transmission using a two-dimensional advective frozen-ocean model with temperature data from a temperature sensor array on a propagation path in the South China Sea (SCS...We simulated the temporal correlation of sound transmission using a two-dimensional advective frozen-ocean model with temperature data from a temperature sensor array on a propagation path in the South China Sea (SCS) Experiment 2009, and investigated the relationships of temporal correlation length, source-receiver range, and maximal sound speed fluctuation mainly caused by the solitary internal waves. We found that the temporal correlation length is -h2-power dependent on source-receiver range and -0.9-power dependent on maximal sound speed fluctuation. The empirical relationship is deduced from one-day environmental measurements in a limited area, needing more works and verification in the future with more acoustic data. But the relationship is useful in many applications in the area of SCS Experiment 2009.展开更多
We propose a new method to obtain the correlation length of gapped XXZ spin 1/2 antiferromagnetic chains. Following the relativistic quantum field theory in space-time dimensions, we use the exact dispersion of massi...We propose a new method to obtain the correlation length of gapped XXZ spin 1/2 antiferromagnetic chains. Following the relativistic quantum field theory in space-time dimensions, we use the exact dispersion of massive spinon to calculate the correlation length for XXZ spin 1/2 chain. We conjecture that the correlation length for other 1D lattice models can be obtained in the same way. Relation between dispersion and the oscillated correlation of gapped incommensurate lattice models is also discussed.展开更多
By establishing the Markov model for a long-range correlated time series (LRCS) and analysing its evolutionary characteristics, this paper defines a physical effective correlation length (ECL) T, which reflects th...By establishing the Markov model for a long-range correlated time series (LRCS) and analysing its evolutionary characteristics, this paper defines a physical effective correlation length (ECL) T, which reflects the predictability of the LRCS. It also finds that the ECL has a better power law relation with the long-range correlated exponent γ of the LRCS: T = Kexp(-γ/0.3) + Y, (0 〈 γ〈 1) the predictability of the LRCS decays exponentially with the increase of γ It is then applied to a daily maximum temperature series (DMTS) recorded at 740 stations in China between the years 1960-2005 and calculates the ECL of the DMTS. The results show the remarkable regional distributive feature that the ECL is about 10-14 days in west, northwest and northern China, and about 5-10 days in east, southeast and southern China. Namely, the predictability of the DMTS is higher in central-west China than in east and southeast China. In addition, the ECL is reduced by 1-8 days in most areas of China after subtracting the seasonal oscillation signal of the DMTS from its original DMTS; however, it is only slightly altered when the decadal linear trend is removed from the original DMTS. Therefore, it is shown that seasonal oscillation is a significant component of daily maximum temperature evolution and may provide a basis for predicting daily maximum temperatures. Seasonal oscillation is also significant for guiding general weather predictions, as well as seasonal weather predictions.展开更多
The viscosities of a series of Cu–Ag melts in a temperature range from 1473 K to nearly liquid temperatures are measured by using an oscillating viscometer. At the same temperature, the value of viscosity increases f...The viscosities of a series of Cu–Ag melts in a temperature range from 1473 K to nearly liquid temperatures are measured by using an oscillating viscometer. At the same temperature, the value of viscosity increases first with silver content increasing, and reaches a maximum value at the eutectic component Cu40Ag60, then decreases. All the temperature dependences of the viscosities of Cu–Ag melts conform with the Arrhenius equation. The parameters of correlation length D of the studied Cu–Ag melts are calculated according to the experimental results of x-ray diffraction. The temperature dependence of correlation length D shows an exponential decay function, which is similar to the Arrhenius equation. Based on the values of viscosities and correlation length D, a direct correlation between viscosity and liquid structure is found for the investigated Cu–Ag melts through comparative analysis.展开更多
A high-precision pseudo-noise ranging system is often required in satellite-formation missions. But in an actual PN ranging system, digital signal processing limits the ranging accuracy, only level up with meter-scale...A high-precision pseudo-noise ranging system is often required in satellite-formation missions. But in an actual PN ranging system, digital signal processing limits the ranging accuracy, only level up with meter-scale. Using non-integer chip to sample time ratio, noncommensurate sampling was seen as an effective solution to cope with the drawback of digital effects. However, researchers only paid attention to selecting specific ratios or giving a simulation model to verify the effectiveness of the noncommensurate ratios. A qualitative analysis model is proposed to characterize the relationship between the range accuracy and the noncommensurate sampling parameters. Moreover, a method is also presented which can be used to choose the noncommensurate ratio and the correlation length to get higher phase delay distinguishability and lower range jitter. The simulation results indicate the correctness of our analyses and the optimal ranging accuracy can be up to centimeter-level with the proposed approach.展开更多
The influence of the inhomogeneous tissue layer on the generation of acoustic vortices (AV) is studied theoretically and experimentally based on the phase screen model. By considering the time-shift of a random phas...The influence of the inhomogeneous tissue layer on the generation of acoustic vortices (AV) is studied theoretically and experimentally based on the phase screen model. By considering the time-shift of a random phase screen, the formula of acoustic pressure for the AV beam generated by a circular array of eight planar piston sources is derived. With the actual correlation length of the abdominal wall, numerical simulations before and after the insertion of the inhomogeneous tissue layer are conducted, and also demonstrated by experimental measurements. It is proved that, when the thickness variation of the phase screen is less than one wavelength, no significant influence on the generation of AVs can be produced. The variations of vortex nodes and antinodes in terms of the location, shape, and size of AVs are not obvious. Although the circular pressure distribution might be deformed by the phase interference with a larger thickness variation, AVs can still be generated around the center axis with perfect phase spirals in a reduced effective radius. The favorable results provide the feasibility of AV generation inside the human body and suggest the application potential of AVs in object manipulation for biomedical engineering.展开更多
Based on the regularities of temperature fluctuation,the atmo- sphere below an altitude of 71km above ground is divided into 6 sublayers. For each of them the calculation formulae of temperature and pressure are deriv...Based on the regularities of temperature fluctuation,the atmo- sphere below an altitude of 71km above ground is divided into 6 sublayers. For each of them the calculation formulae of temperature and pressure are derived.The calculated results at any altitude in the range under considera- tion agree well with the values laid down in the table of“U.S.Standard At- mosphere”.From this the formula for the refractive-index structure coeffi- cient C_N^2,of much importance in the research of adaptive optics,is obtained for the corresponding altitudes.展开更多
Dust-free semidilute and concentrated polystyrene(PS)solutions in different solvents were prepared by slow evaporation and in situ anionic polymerization,which removes the effects of troublesome artifacts such as dust...Dust-free semidilute and concentrated polystyrene(PS)solutions in different solvents were prepared by slow evaporation and in situ anionic polymerization,which removes the effects of troublesome artifacts such as dust contamination and concentration gradient.The dynamics was reexamined by a combination of static and dynamic laser light scattering.In benzene and toluene(good solvents for PS),only one fast diffusive mode of polymer chains can be observed when the concentration(c)is up to 20%,which is attribut...展开更多
In the paper, we introduce Allegre's scaling-rule theory of rock fracture and the probability to develop a method for predicting earthquake occurrence time on its basis. As an example, we study the characteristics of...In the paper, we introduce Allegre's scaling-rule theory of rock fracture and the probability to develop a method for predicting earthquake occurrence time on its basis. As an example, we study the characteristics of seismological precursors (seismic spatial correlation length and coda Qc) associated with the earthquake (M=6.1) occurred in Shandan-Minle, Gansu Province. The results show an increasing trend of seismic spatial correlation length and coda Qc before the earthquake. And a power exponent relation is used to fit the increasing variation form of these two parameters. The study has provided a basis for creating a method and finding indexes to predict the earthquake occurrence time by using the monitored seismic spatial correlation length and coda Qc.展开更多
The magnetic properties of two-dimensional antiferromagnet NiGa2S4 have attracted much attention and yet some problems are far from being solved. We investigate the magnetic properties of NiGa2S4 by Monte Carlo simula...The magnetic properties of two-dimensional antiferromagnet NiGa2S4 have attracted much attention and yet some problems are far from being solved. We investigate the magnetic properties of NiGa2S4 by Monte Carlo simulations. A new spin-interacting model is proposed to describe the system, and the specific heat together with the doping effect of nonmagnetic impurity is studied by simulations. The double peaks of the specific heat as well as other behaviors are well reproduced. We also compare our results with those of other models, and the underlying physics is discussed.展开更多
This study was carried out to evaluate the expression of yellow endosperm color in the progeny of Psy-2A-Crt I(β-carotene gene, PAC) transgenic plants crossed with IR36. The selected 25 lines of F2 progeny exhibite...This study was carried out to evaluate the expression of yellow endosperm color in the progeny of Psy-2A-Crt I(β-carotene gene, PAC) transgenic plants crossed with IR36. The selected 25 lines of F2 progeny exhibited stable expression of yellow endosperm color and high agronomic characteristics. IR36 and PAC transgenic plant of the grain length, width and ratio showed the same tendency of normal distribution. For progeny selection, colorimeters were as employed to distinguish differing visible colors. Correlation analysis was conducted to investigate the relationship between b* value and the expression of specific genes. b* value was associated with the relative expression of the PAC-Rev and MAR product by real-time PCR and t-test revealed significant difference. Based on this study, correlation between colorimetric values and real-time PCR was effective to detect gene expression. Yellow endosperm progenies represent a new genetic pool that might be useful to increase the genetic diversity of yellow endosperm rice.展开更多
It is still a formidable challenge to simultaneously switch single-chain magnet(SCM)behavior via ligand modification and light irradiation in the field of molecular spintronics.Herein,we present a ligandbridged layer{...It is still a formidable challenge to simultaneously switch single-chain magnet(SCM)behavior via ligand modification and light irradiation in the field of molecular spintronics.Herein,we present a ligandbridged layer{[pzTpFe(CN)3]4Co2(Bib)4}·3H2O(1;pzTp,tetra-kis(1-pyrazolyl)borate;Bib,1,4-bis-(1Himidazol-1-yl)benzene)and a well-isolated double chain{[pzTpFe(CN)3]2Co(Bpi)2}·CH3CN·4H2O(2;Bpi,1-Biphenyl-4-yl-1H-imidazole)that display reversible metal-to-metal charge transfer(MMCT)between FeIII LS(μ-CN)CoII HS(μ-NC)FeIII LS(LS,low spin;HS,high spin)and FeIII LS(μ-CN)CoIII LS(μ-NC)FeII LS linkages under alternating irradiation with 808 and 532 nm lasers.The bidirectional light irradiations induces significant changes in anisotropy and intrachain magnetic interactions,resulting in the on/off switching of SCM behavior with observable hysteresis loops by 808 and 532 nm light irradiations for both compounds.Because of the ligand modification,the SCM property of 2 with the monodentate ligand is greatly improved with a correlation length increased to 83,which is the largest correlation length among all reported light actuated SCMs.Furthermore,the influence of ligand modification on their thermally induced MMCT is also discussed.This study provides a rational approach for the swift and reversible control of SCM behavior via ligand modified and light induced MMCT,which is crucial to the future technological demand for high-density data storage and processing.展开更多
Soil spatial variability is difficult to evaluate due to insufficient test data.An alternative option is estimation by indirect methods such as inverse analysis.In this paper,two examples are presented to demonstrate ...Soil spatial variability is difficult to evaluate due to insufficient test data.An alternative option is estimation by indirect methods such as inverse analysis.In this paper,two examples are presented to demonstrate the capability and accuracy of the probabilistic estimation method to characterize soil spatial variability with displacement responses.The first example is a soil slope subject to a surcharge load,in which the spatially varied field of the elastic modulus is estimated with displacements.The results show that estimations based on horizontal displacements were more accurate than those based on vertical displacements.The accuracy of the estimated field was substantially reduced by increasing variance of elastic modulus.However,the estimation was generally acceptable as the error was not more than 10%,even for the high variance case(COV^l.5).The accuracy of estimation was also affected by the type of covariance function and the correlation length.When the correlation length decreased,the accuracy of estimation was reduced.The second example is a validation of laboratory model tests where a horizontal load was applied on a layered ground.The estimated thicknesses of soil layers were close to those in the real situation,which demonstrates the capacity of the estimation method.展开更多
This paper uses the spectral stochastic finite element method(SSFEM)for analyzing reinforced concrete(RC)beam/slab problems.In doing so,it presents a new framework to study how the correlation length of a random field...This paper uses the spectral stochastic finite element method(SSFEM)for analyzing reinforced concrete(RC)beam/slab problems.In doing so,it presents a new framework to study how the correlation length of a random field(RF)with uncertain parameters will affect modeling uncertainties and reliability evaluations.It considers:1)different correlation lengths for uncertainty parameters,and 2)dead and live loads as well as the elasticity moduli of concrete and steel as a multi-dimensional RF in concrete structures.To show the SSFEM’s efficiency in the study of concrete structures and to evaluate the sensitivity of the correlation length effects in evaluating the reliability,two examples of RC beams and slabs have been investigated.According to the results,the RF correlation length is effective in modeling uncertainties and evaluating reliabilities;the longer the correlation length,the greater the dispersion range of the structure response and the higher the failure probability.展开更多
Up to now the chirality is seldom studied in the diluted spin glass although many investigations have been performed on the site-ordered Edwards-Anderson model. By simulation, we investigate the dynamicaJ properties o...Up to now the chirality is seldom studied in the diluted spin glass although many investigations have been performed on the site-ordered Edwards-Anderson model. By simulation, we investigate the dynamicaJ properties of both the spin-glass and the chiral-glass phases in a diluted dipolar system, which was manifested to have a spin-glass transition by recent numerical study. By scaling we find that both phases have the same aging behavior and closer aging parameterμ. Similarly, the domains grow in the same way and both phases have a closer barrier exponent g2. It means that both the spins and the chirality have the same dynamical properties and they may freeze at the same temperature.展开更多
基金Joint Seismological Science Foundation of China (95-07-436)
文摘The growing correlation length prior to the moderate-great earthquakes occurred in Gansu Province and its nearby area since 1986 has been studied using the method of single-link cluster analysis (SLC). According to different conditions in the source area, the circular spatial window centered in the epicenter and the parallelgrammic spatial window along the fault belt have been selected. The results show that the phenomena of growing correlation length have been observed before the earthquakes studied in the paper.
文摘Seismic correlation length for moderate earthquakes prior to two great earthquakes in the northern sea area of Sumatra Island (Mw9.1 in 2004 and MsS. 6 in 2012) has been studied, using method of Single- Link-Cluster ( SLC ) analysis, and found to show a power-law growth about two years before their occurrences. No such growth was found for a magnitude 7 earthquake in the same area. This result suggests the occurrence of a physical process of critical-point characteristics in the source area before the great earthquakes.
基金Supported by the Knowledge Innovation Program of Chinese Academy of Sciences (No.KZCX1-YW-12-02)the National Natural Science Foundation of China (Nos.10974218,10734100)
文摘We simulated the temporal correlation of sound transmission using a two-dimensional advective frozen-ocean model with temperature data from a temperature sensor array on a propagation path in the South China Sea (SCS) Experiment 2009, and investigated the relationships of temporal correlation length, source-receiver range, and maximal sound speed fluctuation mainly caused by the solitary internal waves. We found that the temporal correlation length is -h2-power dependent on source-receiver range and -0.9-power dependent on maximal sound speed fluctuation. The empirical relationship is deduced from one-day environmental measurements in a limited area, needing more works and verification in the future with more acoustic data. But the relationship is useful in many applications in the area of SCS Experiment 2009.
文摘We propose a new method to obtain the correlation length of gapped XXZ spin 1/2 antiferromagnetic chains. Following the relativistic quantum field theory in space-time dimensions, we use the exact dispersion of massive spinon to calculate the correlation length for XXZ spin 1/2 chain. We conjecture that the correlation length for other 1D lattice models can be obtained in the same way. Relation between dispersion and the oscillated correlation of gapped incommensurate lattice models is also discussed.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.40930952,40875040,and 41005043)the Special Project for Public Welfare Enterprises(Grant No.GYHY200806005)the National Science/Technology Support Program of China(Grant Nos.2007BAC29B01 and 2009BAC51B04)
文摘By establishing the Markov model for a long-range correlated time series (LRCS) and analysing its evolutionary characteristics, this paper defines a physical effective correlation length (ECL) T, which reflects the predictability of the LRCS. It also finds that the ECL has a better power law relation with the long-range correlated exponent γ of the LRCS: T = Kexp(-γ/0.3) + Y, (0 〈 γ〈 1) the predictability of the LRCS decays exponentially with the increase of γ It is then applied to a daily maximum temperature series (DMTS) recorded at 740 stations in China between the years 1960-2005 and calculates the ECL of the DMTS. The results show the remarkable regional distributive feature that the ECL is about 10-14 days in west, northwest and northern China, and about 5-10 days in east, southeast and southern China. Namely, the predictability of the DMTS is higher in central-west China than in east and southeast China. In addition, the ECL is reduced by 1-8 days in most areas of China after subtracting the seasonal oscillation signal of the DMTS from its original DMTS; however, it is only slightly altered when the decadal linear trend is removed from the original DMTS. Therefore, it is shown that seasonal oscillation is a significant component of daily maximum temperature evolution and may provide a basis for predicting daily maximum temperatures. Seasonal oscillation is also significant for guiding general weather predictions, as well as seasonal weather predictions.
基金Project supported by the Science and Technology Development Program of Shandong Province,China(Grant No.2011YD03099)the Natural Science Foundation of Shandong Province,China(Grant No.ZR2014EL001)
文摘The viscosities of a series of Cu–Ag melts in a temperature range from 1473 K to nearly liquid temperatures are measured by using an oscillating viscometer. At the same temperature, the value of viscosity increases first with silver content increasing, and reaches a maximum value at the eutectic component Cu40Ag60, then decreases. All the temperature dependences of the viscosities of Cu–Ag melts conform with the Arrhenius equation. The parameters of correlation length D of the studied Cu–Ag melts are calculated according to the experimental results of x-ray diffraction. The temperature dependence of correlation length D shows an exponential decay function, which is similar to the Arrhenius equation. Based on the values of viscosities and correlation length D, a direct correlation between viscosity and liquid structure is found for the investigated Cu–Ag melts through comparative analysis.
基金Project(60904090) supported by the National Natural Science Foundation of China
文摘A high-precision pseudo-noise ranging system is often required in satellite-formation missions. But in an actual PN ranging system, digital signal processing limits the ranging accuracy, only level up with meter-scale. Using non-integer chip to sample time ratio, noncommensurate sampling was seen as an effective solution to cope with the drawback of digital effects. However, researchers only paid attention to selecting specific ratios or giving a simulation model to verify the effectiveness of the noncommensurate ratios. A qualitative analysis model is proposed to characterize the relationship between the range accuracy and the noncommensurate sampling parameters. Moreover, a method is also presented which can be used to choose the noncommensurate ratio and the correlation length to get higher phase delay distinguishability and lower range jitter. The simulation results indicate the correctness of our analyses and the optimal ranging accuracy can be up to centimeter-level with the proposed approach.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61575095,11374155,and 11674173)
文摘The influence of the inhomogeneous tissue layer on the generation of acoustic vortices (AV) is studied theoretically and experimentally based on the phase screen model. By considering the time-shift of a random phase screen, the formula of acoustic pressure for the AV beam generated by a circular array of eight planar piston sources is derived. With the actual correlation length of the abdominal wall, numerical simulations before and after the insertion of the inhomogeneous tissue layer are conducted, and also demonstrated by experimental measurements. It is proved that, when the thickness variation of the phase screen is less than one wavelength, no significant influence on the generation of AVs can be produced. The variations of vortex nodes and antinodes in terms of the location, shape, and size of AVs are not obvious. Although the circular pressure distribution might be deformed by the phase interference with a larger thickness variation, AVs can still be generated around the center axis with perfect phase spirals in a reduced effective radius. The favorable results provide the feasibility of AV generation inside the human body and suggest the application potential of AVs in object manipulation for biomedical engineering.
文摘Based on the regularities of temperature fluctuation,the atmo- sphere below an altitude of 71km above ground is divided into 6 sublayers. For each of them the calculation formulae of temperature and pressure are derived.The calculated results at any altitude in the range under considera- tion agree well with the values laid down in the table of“U.S.Standard At- mosphere”.From this the formula for the refractive-index structure coeffi- cient C_N^2,of much importance in the research of adaptive optics,is obtained for the corresponding altitudes.
基金the Chinese Academy of Sciences(CAS)Special Grant(No.KJCX2-SW-H14)the National Natural Scientific Foundation of China(Nos.20534020 and 20574065)the Hong Kong Special Administration Region(HKSAR)Earmarked Project(CUHK4025/04P,2160242)
文摘Dust-free semidilute and concentrated polystyrene(PS)solutions in different solvents were prepared by slow evaporation and in situ anionic polymerization,which removes the effects of troublesome artifacts such as dust contamination and concentration gradient.The dynamics was reexamined by a combination of static and dynamic laser light scattering.In benzene and toluene(good solvents for PS),only one fast diffusive mode of polymer chains can be observed when the concentration(c)is up to 20%,which is attribut...
基金National Natural Science Foundation of China (40574026).
文摘In the paper, we introduce Allegre's scaling-rule theory of rock fracture and the probability to develop a method for predicting earthquake occurrence time on its basis. As an example, we study the characteristics of seismological precursors (seismic spatial correlation length and coda Qc) associated with the earthquake (M=6.1) occurred in Shandan-Minle, Gansu Province. The results show an increasing trend of seismic spatial correlation length and coda Qc before the earthquake. And a power exponent relation is used to fit the increasing variation form of these two parameters. The study has provided a basis for creating a method and finding indexes to predict the earthquake occurrence time by using the monitored seismic spatial correlation length and coda Qc.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11247428,11247210,10974228,and 61274101)the Natural Science Foundation of Liaoning Province,China(Grant No.20121078)the Education Office of Liaoning Province,China(Grant No.L201197)
文摘The magnetic properties of two-dimensional antiferromagnet NiGa2S4 have attracted much attention and yet some problems are far from being solved. We investigate the magnetic properties of NiGa2S4 by Monte Carlo simulations. A new spin-interacting model is proposed to describe the system, and the specific heat together with the doping effect of nonmagnetic impurity is studied by simulations. The double peaks of the specific heat as well as other behaviors are well reproduced. We also compare our results with those of other models, and the underlying physics is discussed.
基金the support of the Cooperative Research Program for Agriculture&Technology Development,Rural Development Administration,Republic of Korea(PJ011257012015)
文摘This study was carried out to evaluate the expression of yellow endosperm color in the progeny of Psy-2A-Crt I(β-carotene gene, PAC) transgenic plants crossed with IR36. The selected 25 lines of F2 progeny exhibited stable expression of yellow endosperm color and high agronomic characteristics. IR36 and PAC transgenic plant of the grain length, width and ratio showed the same tendency of normal distribution. For progeny selection, colorimeters were as employed to distinguish differing visible colors. Correlation analysis was conducted to investigate the relationship between b* value and the expression of specific genes. b* value was associated with the relative expression of the PAC-Rev and MAR product by real-time PCR and t-test revealed significant difference. Based on this study, correlation between colorimetric values and real-time PCR was effective to detect gene expression. Yellow endosperm progenies represent a new genetic pool that might be useful to increase the genetic diversity of yellow endosperm rice.
基金supported by the National Natural Science Foundation of China(grant nos.21901133,22171155,22035003,91856124,22025101,91961114,21871039,and 22173015)China National Postdoctoral Program for Innovative Talents(grant no.BX20180147).
文摘It is still a formidable challenge to simultaneously switch single-chain magnet(SCM)behavior via ligand modification and light irradiation in the field of molecular spintronics.Herein,we present a ligandbridged layer{[pzTpFe(CN)3]4Co2(Bib)4}·3H2O(1;pzTp,tetra-kis(1-pyrazolyl)borate;Bib,1,4-bis-(1Himidazol-1-yl)benzene)and a well-isolated double chain{[pzTpFe(CN)3]2Co(Bpi)2}·CH3CN·4H2O(2;Bpi,1-Biphenyl-4-yl-1H-imidazole)that display reversible metal-to-metal charge transfer(MMCT)between FeIII LS(μ-CN)CoII HS(μ-NC)FeIII LS(LS,low spin;HS,high spin)and FeIII LS(μ-CN)CoIII LS(μ-NC)FeII LS linkages under alternating irradiation with 808 and 532 nm lasers.The bidirectional light irradiations induces significant changes in anisotropy and intrachain magnetic interactions,resulting in the on/off switching of SCM behavior with observable hysteresis loops by 808 and 532 nm light irradiations for both compounds.Because of the ligand modification,the SCM property of 2 with the monodentate ligand is greatly improved with a correlation length increased to 83,which is the largest correlation length among all reported light actuated SCMs.Furthermore,the influence of ligand modification on their thermally induced MMCT is also discussed.This study provides a rational approach for the swift and reversible control of SCM behavior via ligand modified and light induced MMCT,which is crucial to the future technological demand for high-density data storage and processing.
基金the National Natural Science Foundation of China(Nos.51979158,51639008,51679135,and 51422905)the Program of Shanghai Academic Research Leader(No.19XD1421900),China。
文摘Soil spatial variability is difficult to evaluate due to insufficient test data.An alternative option is estimation by indirect methods such as inverse analysis.In this paper,two examples are presented to demonstrate the capability and accuracy of the probabilistic estimation method to characterize soil spatial variability with displacement responses.The first example is a soil slope subject to a surcharge load,in which the spatially varied field of the elastic modulus is estimated with displacements.The results show that estimations based on horizontal displacements were more accurate than those based on vertical displacements.The accuracy of the estimated field was substantially reduced by increasing variance of elastic modulus.However,the estimation was generally acceptable as the error was not more than 10%,even for the high variance case(COV^l.5).The accuracy of estimation was also affected by the type of covariance function and the correlation length.When the correlation length decreased,the accuracy of estimation was reduced.The second example is a validation of laboratory model tests where a horizontal load was applied on a layered ground.The estimated thicknesses of soil layers were close to those in the real situation,which demonstrates the capacity of the estimation method.
文摘This paper uses the spectral stochastic finite element method(SSFEM)for analyzing reinforced concrete(RC)beam/slab problems.In doing so,it presents a new framework to study how the correlation length of a random field(RF)with uncertain parameters will affect modeling uncertainties and reliability evaluations.It considers:1)different correlation lengths for uncertainty parameters,and 2)dead and live loads as well as the elasticity moduli of concrete and steel as a multi-dimensional RF in concrete structures.To show the SSFEM’s efficiency in the study of concrete structures and to evaluate the sensitivity of the correlation length effects in evaluating the reliability,two examples of RC beams and slabs have been investigated.According to the results,the RF correlation length is effective in modeling uncertainties and evaluating reliabilities;the longer the correlation length,the greater the dispersion range of the structure response and the higher the failure probability.
基金Supported by National Natural Science Foundation of China under Grant Nos.11247428,61274101Natural Science Foundation of Liaoning Province under Grant No.20121078
文摘Up to now the chirality is seldom studied in the diluted spin glass although many investigations have been performed on the site-ordered Edwards-Anderson model. By simulation, we investigate the dynamicaJ properties of both the spin-glass and the chiral-glass phases in a diluted dipolar system, which was manifested to have a spin-glass transition by recent numerical study. By scaling we find that both phases have the same aging behavior and closer aging parameterμ. Similarly, the domains grow in the same way and both phases have a closer barrier exponent g2. It means that both the spins and the chirality have the same dynamical properties and they may freeze at the same temperature.