Carbon Fiber Breakage Mechanism in Aluminum(Al)/Carbon Fibers(CFs) Composite Sheet during Accumulative Roll Bonding(ARB) Process

We put forward a method of fabricating Aluminum(Al)/carbon fibers(CFs) composite sheets by the accumulative roll bonding(ARB) method. The finished Al/CFs composite sheet has CFs and pure Al sheets as sandwich and surface layers. After cross-section observation of the Al/CFs composite sheet, we found that the CFs discretely distributed within the sandwich layer. Besides, the tensile test showed that the contribution of the sandwich CFs layer to tensile strength was less than 11% compared with annealed pure Al sheet. With ex-situ observation of the CFs breakage evolution with-16%,-32%, and-45% rolling reduction during the ARB process, the plastic instability of the Al layer was found to bring shear damages to the CFs. At last, the bridging strengthening mechanism introduced by CFs was sacrificed. We provide new insight into and instruction on Al/CFs composite sheet preparation method and processing parameters.

Evaluation of the effects of EPS composite soil replacement on the dynamic performance of caisson structure using shaking table tests

The seismic performance of a caisson structure under two types of models with a saturated sandy foundation(CSS)and an expanded polystyrene(EPS)composite soil foundation(CES)are studied using shaking table tests.The macro phenomena of the two different foundation models are described and analyzed.The effects of the replacement of EPS composite soil on seismic-induced liquefaction of backfill and the dynamic performance of a caisson structure are evaluated in detail.The results show that the excess pore water pressure generation in the CES is significantly slower than that in the CSS during the shaking.The dynamic earth pressure acting on the caisson has a triangular shape.The response of horizontal acceleration,displacement,settlement,and rotation angle of the caisson in the CES is smaller than that in the CSS,which means the caisson in the CES has a better seismic performance.Furthermore,the out-of-phase phenomenon between dynamic earth thrust and inertial force in the CES is more obvious than that in the CSS,which is beneficial to reduce the lateral force and improve the stability of the caisson structure.

Preparation and Arc Erosion Resistance of C_f/Cu Composite by Vacuum Melting Infiltration

Cf/Cu composite was prepared by vacuum melting infiltration. Ti and Cr were doped to the Cu alloy to improve the wettability between Cu and carbon. The microstrueture was investigated by XRD, SEM and EDS. The arc erosion rate of Cf/Cu composite was investigated in vacuum. The results showed that the Ti and Cr could improve the wettability between Cu and C/C preform and the infiltration ability of Cu into C/ C preform greatly. A TiC interface formed between the fibers and matrix. The good bonding between the fiber and matrix guaranteed that part of the Cu matrix can still be bonded on the fibers even when the material was exposed to the plasma. Consequently, the carbon fibers were protected from the erosion. In comparison, Cu was completely consumed by the arc erosion. Hence, the graphite was eroded and presented a cauliflower-like morphology. Therefore, the prepared C/Cu bad better ability to resist the arc erosion, compared with common Cu-C material.

RELATIONS BETWEEN INTERFACE OF CF/Al-4.5 Cu COMPOSITE AND SOLIDIFICATION PROCESSING

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Dependence of dielectric properties on BT particle size in EP/BT composites

The polymer-ceramic composites of epoxy resin (EP) and barium titanate (BT) were prepared. BT powders of different BT particle sizes from 100 nm to 1 μm were used in the preparation. The dielectric properties, such as dielectric constant, dielectric loss and electrical breakdown strength, of the EP/BT composites were studied. The morphology of the composites was characterized by the means of scanning electron microscopy (SEM). The results show that the dielectric constant of the composites is much higher than the epoxy matrix at frequency range from 1 kHz to 10 MHz, and it is also obviously dependent on the size of BT particles. The electrical breakdown strength of the composites decreases with the increase of the BT content. The dependence of electrical breakdown strength on BT particle sizes was also discussed.

Ballistic Performance and Damage Characteristics of Chemical Vapor Infiltration Quasi 3D-Cf/SiC Composites

To investigate the ballistic performance and damage characteristics of quasi threedimensional（3D） needle-punched Cf/SiC composites prepared by chemical vapor infiltration（CVI）,penetration experiments were conducted by using 7.62 mm armor piercing incendiary（API）.Macro and micro fracture morphologies were then observed on recycled targets.The results show that the protection coefficient of 3D Cf/SiC composites is 2.54.High porosity and many micro thermal stress cracks may directly lead to the lower ballistic performance.Flat fracture morphology was observed on the crater surface.The low dynamic fracture strength along layer direction may be attributed to the voids and microcracks caused by residual thermal stress.The damage characteristics of Cf/Si C composites include matrix cracking,fiber bundle cracking,interfacial debonding,fiber fracture,and fiber bundle pull-out.And interfacial debonding and fiber fracture may play major roles in energy absorption.

Synthesis, Characterization and Flame-retardant Properties of Epoxy Resins and AACHH Composites

Flame retardant epoxy resins were prepared by a simple mixed method using ammonium aluminum carbonate hydroxy hydrate （AACHH） as a halogen-free flame retardant. The prepared samples were characterized by X-ray diffraction, thermogravimetric and differential scanning calorimetry, scanning electron microscope and limiting oxygen index（LOI） experiments. Effects of AACHH content on LOI of epoxy resins/AACHH composite and flame retardant mechanism were investigated and discussed. Results show that AACHH exhibites excellent flame-retardant properties in epoxy resin（EP）. When the content of AACHH was 47.4%, the LOI of EP reached 32.2%. Moreover, the initial and terminal decomposition temperature of EP increased by 48 ℃ and 40 ℃, respectively. The flame retarded mechanism of AACHH is due to the synergic flame retardant effects of diluting, cooling, decomposition resisting and obstructing.

上浆剂对CF/EP界面粘结的影响

本文通过单纤维碎裂法 ,分别对未上浆及不同上浆剂处理的碳纤维与基体的界面粘结性进行表征。结果表明 ,不同上浆剂对界面粘结的影响不同。含活性基团较多的上浆剂可改善界面粘结 。

超临界水/正丁醇混合流体对CF/EP复合材料的降解作用

采用水/正丁醇混合流体降解碳纤维/环氧树脂(CF/EP)复合材料以回收高性能CF,分析了水、正丁醇和水/正丁醇混合流体对EP基体的降解能力,研究了水/正丁醇的体积比例、温度、时间及KOH浓度等对EP基体的降解率影响。结果表明:混合流体对EP基体的降解能力优于水和正丁醇;临界条件下,水的含量越高,混合流体对EP基体的降解能力越强;EP基体的降解率与温度、时间及KOH浓度呈正相关性;350℃、30min条件下,采用水含量为50%的水/正丁醇混合流体作为反应溶剂时,EP基体的降解率达到93.4%,与纯组分的水和正丁醇相比,CF/EP复合材料的降解率分别提高10.9%和24.6%;与原碳纤维相比,混合流体回收的CF单丝拉伸强度保持率在97%以上,且韦氏模数相近。

洋葱伯克霍尔德菌(Burkholderia cepacia)CF-66发酵生产新型抗菌物质CF66I培养基的优化

利用基于统计学的实验设计RSM(Responsesurfacemethodology)优化了BurkholderiacepaciaCF-66产新型抗菌活性物质CF66I的发酵培养基组成。首先,用部分重复因子实验对培养基组分NH4Cl,MgSO4·7H2O,柠檬酸钠及酵母粉浓度对菌株产CF66I的影响进行评价,找出主要影响因子为柠檬酸钠和酵母粉。两者均为正影响,其他组分对CF66I活性的影响不显著。其次用最陡爬坡路径逼近最大响应区域。最后用中心组合设计及响应面分析确定主要影响因子的最佳浓度。菌株在优化培养基中培养较初始培养基CF66I活性提高了约两倍。

EPS混合土地基-沉箱抗震性能振动台模型试验

采用振动台试验研究了饱和砂土地基(CSS)和EPS混合土地基(CES)两种地基模型下沉箱结构的抗震性能。对比了两种不同地基模型下土体动力响应特征及沉箱结构动力稳定性,探讨了动力作用下沉箱的受力状态及失稳机制,分析了EPS混合土地基对上部沉箱结构地震稳定性的影响。试验结果表明:振动过程中CES工况的超孔压发展速率明显低于CSS,EPS混合土可显著提高模型抗液化性能。墙后填土作用于沉箱的动土压力沿深度方向呈三角形分布,沉箱中部位置动土压力最大。CES工况沉箱动力响应,包括加速度、位移及转动角等均小于CSS,表现出更好的抗震性能。CES沉箱所受动土推力与惯性力存在明显的相位差,有利于提高沉箱结构的稳定性。

EP/CNTs-CF复合材料制备及工艺优化

为提高碳纤维(CF)复合材料层间剪切强度,探索了在CF二维织物上直接沉积碳纳米管(CNTs)制备准三维结构增强体的研究,利用扫描电子显微镜、比表面积及孔径分析仪研究了碳纳米管-碳纤维(CNTs-CF)结构,采用热熔胶膜法制备CNTs-CF织物环氧树脂(EP)预浸料,制备了生长CNTs前后两种二维织物增强EP复合材料,分析了两种复合材料结构和力学性能的差异,并优化了EP/CNTs-CF复合材料的成型工艺。结果表明,在80℃,0.490 MPa保压4 min的条件下,能够制备浸渍较完全、表面平整的CNTs-CF预浸料;相比CF/EP复合材料成型,EP/CNTs-CF复合材料成型过程中需要提前加压并提高成型压力,经过工艺优化后,EP/CNTs-CF的层间剪切强度较CF/EP的层间剪切强度提高10.2%。

X型号滑翔增程弹EP/CF复合材料弹翼的研制工艺探讨

介绍了X型号滑翔增程弹EP/CF复合材料弹翼的研制过程,根据设计指标,分别采用纤维缠绕/模压和手糊/模压两种成型工艺进行了试验。结果表明,在满足弹翼性能指标要求的前提下,手糊/模压成型工艺生产的EP/CF复合材料弹翼周期短、工序少、过程简单、原材料浪费少、质量容易控制,更适合该弹翼的制造。

Evaluation of Tribological Performance of PTFE Composite Filled with Rare Earths Treated Carbon Fibers under Water-Lubricated Condition

Carbon fibers （CFs） were surface treated with air-oxidation, rare earths （RE） after air-oxidation, and rare earths, respectively. Erichsen test was conducted to study the interfacial adhesion of PTFE composites filled with carbon fibers treated with different treatment methods. Tribological properties of the PTFE composites, sliding against GCr15 steel under water-lubricated condition, were investigated on a reciprocating ball-on-disk UMT-2MT tribometer. The worn surfaces of the composites were examined using scanning electron microscopy. Experimental results reveal that RE treatment is superior to air oxidation in promoting tribological properties of CF reinforced PTFE （CF/PTFE） composite. The friction and wear properties of PTFE composite filled with RE treated CF are the best of the PTFE composites. RE treatment is more effective than air oxidation to improve the tribological properties of CF/PTFE composite owing to the effective improvement of interfacial adhesion between carbon fibers and PTFE matrix.

Effect of rare earths surface treatment on tribological properties of carbon fibers reinforced PTFE composite under oil-lubricated condition

The effect of rare earths （RE） surface treatment of carbon fibers （CF） on tribological properties of CF reinforced polytetrafluoroethylene （PTFE） composites under oil-lubricated condition was investigated. Experimental results revealed that RE treated CF reinforced PTFE （CF/PTFE） composite had the lowest friction coefficient and wear under various applied loads and sliding speeds compared with untreated and air-oxidated composites. X-ray photoelectron spectroscopy （XPS） study of carbon fiber surface showed that, after RE treatment, oxygen concentration increased obviously, and the amount of oxygen-containing groups on CF surfaces were largely increased. The increase in the amount of oxygen-containing groups enhanced interfacial adhesion between CF and PTFE matrix. With strong interfacial adhesion of the composite, stress could be effectively transmitted to carbon fibers; carbon fibers were strongly bonded with VITE matrix, and large scale rubbing-off of PTFE be prevented, therefore, tribological properties of the composite was improved.

Improved wettability and mechanical properties of metal coated carbon fiber-reinforced aluminum matrix composites by squeeze melt infiltration technique

In order to improve the wettability and bonding performance of the interface between carbon fiber and aluminum matrix,nickel-and copper-coated carbon fiber-reinforced aluminum matrix composites were fabricated by the squeeze melt infiltration technique.The interface wettability,microstructure and mechanical properties of the composites were compared and investigated.Compared with the uncoated fiber-reinforced aluminum matrix composite,the microstructure analysis indicated that the coatings significantly improved the wettability and effectively inhibited the interface reaction between carbon fiber and aluminum matrix during the process.Under the same processing condition,aluminum melt was easy to infiltrate into the copper-coated fiber bundles.Furthermore,the inhibited interface reaction was more conducive to maintain the original strength of fiber and improve the fiber−matrix interface bonding performance.The mechanical properties were evaluated by uniaxial tensile test.The yield strength,ultimate tensile strength and elastic modulus of the copper-coated carbon fiber-reinforced aluminum matrix composite were about 124 MPa,140 MPa and 82 GPa,respectively.In the case of nickel-coated carbon fiber-reinforced aluminum matrix composite,the yield strength,ultimate tensile strength and elastic modulus were about 60 MPa,70 MPa and 79 GPa,respectively.The excellent mechanical properties for copper-coated fiber-reinforced composites are attributed to better compactness of the matrix and better fiber−matrix interface bonding,which favor the load transfer ability from aluminam matrix to carbon fiber under the loading state,giving full play to the bearing role of carbon fiber.

Study on Anticorrosive Cerium Conversion Coating of C_f/6061A1 Composite Surface

The optimum chemical passivation process of the rare earth metal (REM) conversion coating on the Cf/6061Al composite surface was introduced in this paper and its polarization curves properties were investigated. Ridge-like coatings were found by scanning electro microscope (SEM) observations, and the Al matrix and carbon fibre reinforcement were both coated with Ce conversion coatings, with some minor cracks. The energy dispersive spectroscopy (EDS) plane scan analysis indicates that the major elements in the coating are Ce, O, Si, Al and the Ce content reaches 47.48% (mass fraction). The Ce conversion coatings increase the corrosion resisting properties of Cf/6061A1 composite, with a higher free corrosion potential (Ecorr) and a lower free corrosion current density (icorr) for the coated composite than those of the bare composite. And the Boehmite-treatment would enhance the corrosion resistance of the REM conversion coating. The ca-thodic polarization and anodic polarization were retarded by REM conversion coating, resulting in an improved corrosion resistance.

Feasibility Study on Cryogenic Milling of Carbon Fiber Reinforced Silicon Carbide Composites

Carbon fiber reinforced silicon carbide matrix(Cf/SiC)composites have the most potential application for high-temperature components of aerospace high-end equipment.However,high cutting temperature,rapid tool wear and severe surface damages are the main problems in dry cutting Cf/SiC composites process.The feasibility study on cryogenic milling of Cf/SiC composites using liquid nitrogen as coolant is investigated.Influences of milling parameters and coolant on temperature,cutting force,surface quality and tool wear are investigated,which is compared with dry cutting.Experimental results reveal that the cutting temperature in cryogenic milling of Cf/SiC composites is reduced by about 40%—60%compared with dry cutting.The milling force increases gradually with the increase of spindle speed,feed rate,depth and width of milling in cryogenic milling process.In addition,the machined surface quality in cryogenic milling is superior to that in dry cutting process.Fiber fracture,matrix damage and fiber matrix debonding are main material removal mechanisms.Flank face wear is the main wear form of the polycrystalline diamond(PCD)end mills.The tool life is prolonged in the cryogenic milling process because the reduced temperature inhibits the softening of Co binder and phase transition of diamond in the PCD end mills.

Study on vacuum brazing of C_f/C composites

Vacuum brazing experiments of Cf/C composites were carried out using pure Al and Al-5 Ti-B as brazing fillers , and shearing strength of the joints was measured. The microstructures of the brazed joints were studied by means of scanning electron microscopy （SEM） and energy dispersive X-ray spectrometer. The results indicate that the brazing temperature is the important processing parameter affecting the quality of the brazed joints. Vacuum brazing of Cf/C composites can be achieved employing the pure Al and AI-S Ti-B brazing fillers at a brazing temperature of 730 ℃ or 750 ℃ , respectively. Moreover, the joints have excellent microstructures with shear strength reaching the level of practical applications.

EPS颗粒混凝土改性现状及其发展趋势研究

EPS颗粒混凝土是当前热门的绿色环保轻质建材,EPS颗粒混凝土改性是提高EPS颗粒混凝土强度和研发高性能EPS颗粒混凝土的有效途径。首先,将EPS颗粒混凝土改性方法分为EPS颗粒改性、胶凝材料改性两大类,仔细梳理了已有EPS颗粒混凝土改性工艺和改性效果;其次,基于EPS颗粒改性和胶凝材料改性的综合讨论,提出了能够扬长避短的复合改性方法;最后,整理了当前EPS颗粒混凝土改性方法存在问题,对未来改性方法的发展进行了思考和展望。研究发现,EPS颗粒改性包括化学改性、裹砂改性、造壳改性;胶凝材料改性包括纤维改性、掺合料改性、外加剂改性;将EPS颗粒改性和胶凝材料改性有机结合的复合改性可以有效提高EPS颗粒混凝土性能,但技术复杂,需进一步研究;同时纳米材料改性、EPS陶粒改性、微胶囊改性、新养护工艺是EPS颗粒混凝土改性的未来发展方向,但新技术高昂的成本亟待降本增效研究。综上,可以为高性能EPS颗粒混凝土研发提供参考,具有较高的参考价值。