Process Optimization of Effective Partition Constant in Progressive Freeze Concentration of Wastewater

Response surface methodology (RSM) was employed to optimize the process parameters for effective partition constant (K) in progressive freeze concentration (PFC) of wastewater. The effects of coolant temperature, circulation flowrate, initial solution concentration and circulation time on the effective partition constant were observed. Results show that the data were adequately fitted into a second-order polynomial model. The linear and quadratic of independent variables, coolant temperature, circulation flowrate, initial solution concentration and circulation time as well as their interactions have significant effects on the effective partition constant. It was predicted that the optimum process parameters within the experimental ranges for the best K would be with coolant temperature of -8.8℃, circulation flowrate of 1051.1 ml/min, initial solution concentration of 6.59 mg/ml and circulation time of 13.9 minutes. Under these conditions, the effective partition constant is predicted to be 0.17.

Effective dynamics for a spin-1/2 particle constrained to a curved layer with inhomogeneous thickness

We derive an effective Hamiltonian for a spin-1/2 particle confined within a curved thin layer with non-uniform thickness using the confining potential approach.Our analysis reveals the presence of a pseudo-magnetic field and effective spin–orbit interaction(SOI)arising from the curvature,as well as an effective scalar potential resulting from variations in thickness.Importantly,we demonstrate that the physical effect of additional SOI from thickness fluctuations vanishes in low-dimensional systems,thus guaranteeing the robustness of spin interference measurements to thickness imperfection.Furthermore,we establish the applicability of the effective Hamiltonian in both symmetric and asymmetric confinement scenarios,which is crucial for its utilization in one-side etching systems.

Research on the path of effective management of participation in joint-venture railway companies by China railway group

Purpose-Following the regional restructuring,the number of joint-venture railway companies in which the Group participates has significantly increased.This paper aims to explore the challenges faced by China Railway Group in managing participation in joint-venture railway companies.The study seeks to propose specific approaches to ensure the effective management of these companies,thereby maximizing the benefits of the regional restructuring and supporting the development of a strong transportation country and a modern infrastructure system.Design/methodology/approach-Based on the change in the shareholding relationship between China Railway Group and the joint-venture railway companies,and considering the current situation of the regional restructuring of these companies,as well as the insights from existing literature and typical case studies,this paper proposes some specific paths for effective management of joint-stock railway companies which China Railway Group participated in.Findings-The problems in participation management are the unclear dual leadership role of the party committee,the lack of discourse power,the lack of synergy between shareholders,the increasing risk of sustainable operation of the loss-making companies and the role of dispatched personnel is not fully played.Based on the theories,combined with the existing research and practical cases,the paper proposed specific approaches,such as perfecting top-level system design,maintaining the discourse power,carrying out differentiated management,arranging personnel rationally,arranging shareholders synergy,and innovating methods to provide references for China Railway Group’s subsequent management of joint venture railway companies.Originality/value-This paper contributes to the existing literature by providing a comprehensive analysis of the challenges faced by China Railway Group in managing participation in joint-venture railway companies following the regional restructuring.The study offers novel insights and practical recommendations for addressing these challenges.The findings can serve as valuable references for China Railway Group’s subsequent management of joint-venture railway companies which participated in,as well as for other stateowned enterprises facing similar challenges in managing their joint ventures.

Statistical Analysis of Students’Learning Effectiveness in Online Courses Offered by British Partners in China-UK Joint Education Program

In the context of internationalization,China-UK Joint Education Programs are receiving increasing attention from universities.Based on the difficulties faced in China-UK Joint Education Program,this paper adopts a questionnaire survey method to study the learning effectiveness of students majoring in digital media technology in the China-UK Joint Education Program at Guangxi University of Finance and Economics,focusing on four aspects:learning materials,learning content,teacher conditions,and student learning outcomes.The research analysis in this paper not only provides strong support for the construction of China-UK Joint Education Program but also offers references for other China-UK Joint Education Programs.

Prediction of the dynamic effective properties of particle-reinforced composite materials

The prediction behaviors of some coherent plane wave equations for the effective velocities and attenuations of the coherent plane waves propagating through a composite material and for the effective elastic moduli of the composites are studied. The numerical results obtained by Waterman & Truell's, Twersky's and Gubernatis's equations for Glass-Epoxy composites with various volume fractions are compared. It is found that the predictions by both Twersky's and Gubernatis's equations underestimate the effective velocities and the effective elastic moduli when compare with the predictions by Waterman & Truell's equation. Furthermore, the deviations are more evident for the shear wave than that for the longitudinal wave. But these deviations decrease gradually with the increase of the frequency and increase gradually with the increase of the volume fraction.

Influences of interphase on dynamic effective properties of composites reinforced by dispersed spherical particles

The influences of interphase on dynamic effective properties of composites reinforced by randomly dispersed spherical particles were studied. A thin homogeneous elastic interphase with different shear and bulk moduli, located between the reinforced particle and the host matrix, was introduced to model the interfacial bonding state. The effects of such an interphase on the coherent plane waves were studied numerically. Numerical simulations were carried out for SiC-Al composites with four typical cases of interphase. It was found that the property of interphase has significant influences on the effective propagation constants of coherent waves and the dynamic effective elastic moduli of the composites. The influences on the coherent longitudinal wave and the coherent shear waves were different and dependent upon the frequency range. Moreover, several imperfect interface models, i.e., the spring model, mass model, and spring-mass model, were studied numerically and compared with the interphase model, It was found that the spring model is a more suitable model than the mass model for the light and weak interphase whereas the mass model is a more suitable model than the spring model for the heavy and strong interphase.

INTERFACE EFFECT ON THE EFFECTIVE BULK MODULUS OF A PARTICLE-REINFORCED COMPOSITE

Classical micromechanical methods for calculating the effective moduli of a heteroge- neous material are generalized to include the interface(surface)effect.By using Hashin's Composite Sphere Assemblage(CSA)model,a new expression of the bulk modulus for a particle-reinforced com- posite is derived.It is emphasized that the present study is within the finite-deformation framework such that the effective properties are not influenced by the interface stress itself solely,but influenced by the change of the interface stress due to changes of the shape and size of the interface.Hence some inadequacies in previous papers are pointed out.

A Fractal Model for the Effective Thermal Conductivity of Granular Flow with Non—uniform Particles

The equipartition of energy applied in binary mixture of granular flow is extended to granular flow withnon-uniform particles. Based on the fractal characteristic of granular flow with non-uniform particles as well as energyequipartition, a fractal velocity distribution function and a fractal model of effective thermal conductivity are derived.Thermal conduction resulted from motions of particles in the granular flow, as well as the effect of fractal dimension oneffective thermal conductivity, is discussed.

The Study on the Conductivity Performance and Shielding Effectiveness of Electro-magnetic Radiation of Polyethylene Film with Different Content of Carbon Black Particles

With the help of the testing apparatus made by ourselves for shielding electromagnetic radiation, the electric conductivity and shielding effectiveness of electromagnetic radiation of polyethylene film contained different content of carbon particles was systematically studied in this paper. The results indicate that the electric conductivity and shielding effectiveness of electromagnetic radiation of polyethylene /carbon film have closely relations with content of carbon black particles, which exists a critical content value as 14%～30% and its properties will have a tremendous change.

Efficiency and Effectiveness Concepts Applied in Shell and Tube Heat Exchanger Using Ethylene Glycol-Water Based Fluid in the Shell with Nanoparticles of Copper Oxide (CuO)

This article consists of an analytical solution for obtaining the outlet temperatures of the hot and cold fluids in a shell and tube heat exchanger. The system analyzed through the concepts of efficiency, effectiveness (ε-NTU), and irreversibility consisted of a shell and tube heat exchanger, with cold nanofluid flowing in the shell and hot water flowing in the tube. The nanofluid consists of 50% of ethylene glycol and water as the base fluid and copper oxide (CuO) nanoparticles in suspension. The volume fractions of the nanoparticles range from 0.1 to 0.5. The flow rate in the nanofluid ranges from 0.0331 to 0.0568 Kg/s, while two mass flow rates, from 0.0568 and 0.5 Kg/s, for the hot fluid, are used as parameters for analysis. Results for the efficiency, effectiveness, irreversibility, heat transfer rate, and outlet temperatures for cold and hot fluids were obtained graphically. The flow laminarization effect was observed through the results obtained and had significant relevance in the results.

Effect of Geometry of Filler Particles on the Effective Thermal Conductivity of Two-Phase Systems

The present paper deals with the effect of geometry of filler particles on the effective thermal conductivity for polymer composites. In the earlier models, less emphasis has been given on the shape of filler particles. In this paper, expressions for effective thermal conductivity has been derived using the law of minimal thermal resistance and equal law of the specific equivalent thermal conductivity for three different shapes i.e. spherical, elliptical and hexagonal of filler particles respectively. Calculated values of effective thermal conductivity for various samples using the derived expressions then compared with experimental data available and other models developed in the literature. The results calculated are in good agreement with the earlier experimental data and the deviation, is least in our expressions showing the success of the model.

Impact of effective stress on permeability for carbonate fractured-vuggy rocks

To gain insight into the flow mechanisms and stress sensitivity for fractured-vuggy reservoirs,several core models with different structural characteristics were designed and fabricated to investigate the impact of effective stress on permeability for carbonate fractured-vuggy rocks(CFVR).It shows that the permeability performance curves under different pore and confining pressures(i.e.altered stress conditions)for the fractured core models and the vuggy core models have similar change patterns.The ranges of permeability variation are significantly wider at high pore pressures,indicating that permeability reduction is the most significant during the early stage of development for fractured-vuggy reservoirs.Since each obtained effective stress coefficient for permeability(ESCP)varies with the changes in confining pressure and pore pressure,the effective stresses for permeability of four representative CFVR show obvious nonlinear characteristics,and the variation ranges of ESCP are all between 0 and 1.Meanwhile,a comprehensive ESCP mathematical model considering triple media,including matrix pores,fractures,and dissolved vugs,was proposed.It is proved theoretically that the ESCP of CFVR generally varies between 0 and 1.Additionally,the regression results showed that the power model ranked highest among the four empirical models mainly applied in stress sensitivity characterization,followed by the logarithmic model,exponential model,and binomial model.The concept of“permeability decline rate”was introduced to better evaluate the stress sensitivity performance for CFVR,in which the one-fracture rock is the strongest,followed by the fracture-vug rock and two-horizontalfracture rock;the through-hole rock is the weakest.In general,this study provides a theoretical basis to guide the design of development and adjustment programs for carbonate fractured-vuggy reservoirs.

EFFECTIVE DIFFUSION AND EFFECTIVE DRAG COEFFICIENT OF A BROWNIAN PARTICLE IN A PERIODIC POTENTIAL

We study the stochastic motion of a Brownian particle driven by a constant force over a static periodic potential. We show that both the effective diffusion and the effective drag coefficient are mathematically well-defined and we derive analytic expressions for these two quantities. We then investigate the asymptotic behaviors of the effective diffusion and the effective drag coefficient, respectively, for small driving force and for large driving force. In the case of small driving force, the effective diffusion is reduced from its Brownian value by a factor that increases exponentially with the amplitude of the potential. The effective drag coefficient is increased by approximately the same factor. As a result, the Einstein relation between the diffusion coefficient and the drag coefficient is approximately valid when the driving force is small. For moderately large driving force, both the effective diffusion and the effective drag coefficient are increased from their Brownian values, and the Einstein relation breaks down. In the limit of very large driving force, both the effective diffusion and the effective drag coefficient converge to their Brownian values and the Einstein relation is once again valid.

INFLUENCE OF CHEMICAL ADSORPTION ON THE EFFECTIVE ANISOTROPY CONSTANT OF α-Fe_2O_3 FINE PARTICLES

The properties of α-Fe2O3 fine particles with and without adsorbed pyridine were studied by Mossbauer spectra. The effective anisotropy constant K were calculated. The K of pyridine- adsorbed a -Fe2O3 particles is smaller than that of pure α-Fe2O3 particles. A probable mechanism of the decreasing effective anisotropy constant K is discussed.

Effect of residual interface stress on effective thermal expansion coefficient of particle-filled thermoelastic nanocomposite

The surface/interface energy theory based on three configurations proposed by Huang et al. is used to study the effective properties of thermoelastic nanocomposites. The particular emphasis is placed on the discussion of the influence of the residual inter- face stress on the thermal expansion coefficient of a thermoelastic composite filled with nanoparticles. First, the thermo-elastic interface constitutive relations expressed in terms of the first Piola-Kirchhoff interface stress and the Lagrangian description of the gen- eralized Young-Laplace equation are presented. Second, the Hashin＇s composite sphere assemblage （CSA） is taken as the representative volume element （RVE）, and the residual elastic field induced by the residual interface stress in this CSA at reference configuration is determined. Elastic deformations in the CSA from the reference configuration to the current configuration are calculated. Prom the above calculations, analytical expressions of the effective bulk modulus and the effective thermal expansion coefficient of thermoelastic composite are derived. It is shown that the residual interface stress has a significant effect on the thermal expansion properties of thermoelastic nanocomposites.

THE EFFECTIVE PROPERTIES OF PIEZOCOMPOSITES, PART Ⅱ: THE EFFECTIVE ELECTROELASTIC MODULI

Since piezoelectric ceramic/polymer composites have been widely used as smart materials and smart structures, it is more and more important to obtain the closed-from solutions of the effective properties of piezocomposites with piezoelectric ellipsoidal inclusions. Based on the closed-from solutions of the electroe- lastic Eshelby's tensors obtained in the part I of this paper and the generalized Bu- diansky's energy-equivalence framework, the closed-form general relations of effective electroelastic moduli of the piezocomposites with piezoelectric ellipsoidal inclusions are given. The relations can be applicable for several micromechanics models, such as the dilute solution and the Mori-Tanaka's method. The difference among the various models is shown to be the way in which the average strain and the average electric field of the inclusion phase are evaluated. Comparison between predicted and exper- imental results shows that the theoretical values in this paper agree quite well with the experimental results. These expressions can be readily utilized in analysis and design of piezocomposites.

Probing nucleon effective mass splitting with light particle emission

The main objective of this study was to investigate the impact of effective mass splitting on heavy-ion-collision observables.We first analyzed correlations between different nuclear matter parameters obtained from 119 effective Skyrme interaction sets.The values of the correlation coefficients illustrate that the magnitude of effective mass splitting is crucial for tight constraints on the symmetry energy via heavy-ion collisions.The^(86)Kr+^(208)Pb system at beam energies ranging from 25 to 200A MeV was simulated within the framework of the improved quantum molecular dynamics model(ImQMD-Sky).Our calculations show that the slopes of the spectra of ln[Y(n)/Y(p)]and ln[Y(t)/Y(^(3)He)],which are the logarithms of the neutron to proton and triton to helium-3 yield ratios,are directly related to effective mass splitting and can be used to probe the effective mass splitting.

Particles inside electrolytes with ion-specific interactions, their effective charge distributions, and effective interactions

In this work, we explore the statistical physics of colloidal particles that interact with electrolytes via ion-specific interactions. Firstly we study particles interacting weakly with electrolyte using linear response theory. We find that the mean potential around a particle is linearly determined by the effective charge distribution of the particle, which depends both on the bare charge distribution and on ion-specific interactions. We also discuss the effective interaction between two such particles and show that, in the far field regime, it is bilinear in the effective charge distributions of two particles. We subsequently generalize the above results to the more complicated case where particles interact strongly with the electrolyte.Our results indicate that in order to understand the statistical physics of non-dilute electrolytes, both ion-specific interactions and ionic correlations have to be addressed in a single unified and consistent framework.

Some features of effective radius and variance of dust particles in numerical simulations of the dust climate on Mars

Airborne dust is an important constituent in the Martian atmosphere because of its radiative interaction with the atmospheric circulation.Dust size is one crucial factor in determining this effect.In reality dust sizes are varied;however,in numerical modeling of dust processes,dust size has usually been described by choice of a particular size distribution function,or by use of fixed values of effective radius(ER)and effective variance(EV).In this work,we present analytical expressions that have been derived to specify ER and EV for Nbin dust schemes,based on a model-calculated dust mixing ratio.Numerical simulations based on this approach thus would consider the effects of variable ER on the atmospheric radiation and their interaction.Results have revealed some interesting features of the dust distribution parameters,such as seasonal and spatial variation of ER and EV,which are generally consistent with some previous observational and modeling studies.Compared with the usual approach of using a fixed ER,simulation results from the present approach suggest that the variability of ER can have significant effects on the simulated thermal field of the Martian atmosphere.

Understanding the Relationship Between Shrinking Cities and Land Prices:Spatial Pattern,Effectiveness,and Policy Implications

Urban shrinkage has emerged as a widespread phenomenon globally and has a significant impact on land,particularly in terms of land use and price.This study focuses on 2851 county-level cities in China in 2005–2018(excluding Hong Kong,Macao,Taiwan,and‘no data’areas in Qinhai-Tibet Plateau)as the fundamental units of analysis.By employing nighttime light(NTL)data to identify shrinking cities,the propensity score matching(PSM)model was used to quantitatively examine the impact of shrinking cities on land prices,and evaluate the magnitude of this influence.The findings demonstrate the following:1)there were 613 shrinking cities in China,with moderate shrinkage being the most prevalent and severe shrinkage being the least.2)Regional disparities are evident in the spatial distribution of shrinking cities,especially in areas with diverse terrain.3)The spatial pattern of land price exhibits a significant correlated to the economic and administrative levels.4)Shrinking cities significantly negatively impact on the overall land price(ATT=–0.1241,P<0.05).However,the extent of the effect varies significantly among different spatial regions.This study contributes novel insights into the investigation of land prices and shrinking cities,ultimately serving as a foundation for government efforts to promote the sustainable development of urban areas.