Two new furostanol glucosides, named tribufurosides G and H, were isolated from Tribulus terrestris L. The structures of the two new furostanol glucosides were elucidated as 26-O-β-D-glucopyranosyl-(25R)-5α-furost...Two new furostanol glucosides, named tribufurosides G and H, were isolated from Tribulus terrestris L. The structures of the two new furostanol glucosides were elucidated as 26-O-β-D-glucopyranosyl-(25R)-5α-furost12-one-3β,22α,26-tetraol-3-O-β-D-glucopyranosyl-( 1→2 )-β-D-glucopyranosyl-( 1→4 )-β-D-galactopyranoside( 1 ) and 26-O-β-D-glucopyranosyl-(25S)-5 α- 12-one-2 α,3,8,22 α,26-tetraol-3 -O-β-D-glucopyranosyl-( 1 → 2 )-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside(2) by 1 D, 2D NMR techniques, ESI-MS analysis as well as chemical methods.展开更多
基金Supported by the National Natural Science Foundation of China(No.30873357)the Program for New Century Excellent Talents in University of China(No.NCET-08-0746)
文摘Two new furostanol glucosides, named tribufurosides G and H, were isolated from Tribulus terrestris L. The structures of the two new furostanol glucosides were elucidated as 26-O-β-D-glucopyranosyl-(25R)-5α-furost12-one-3β,22α,26-tetraol-3-O-β-D-glucopyranosyl-( 1→2 )-β-D-glucopyranosyl-( 1→4 )-β-D-galactopyranoside( 1 ) and 26-O-β-D-glucopyranosyl-(25S)-5 α- 12-one-2 α,3,8,22 α,26-tetraol-3 -O-β-D-glucopyranosyl-( 1 → 2 )-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside(2) by 1 D, 2D NMR techniques, ESI-MS analysis as well as chemical methods.