[ Objective ] The paper was to explore a kind of zinc preparation suitable for injection on trees with fast, efficient and safe cure effect on physiological disease of zinc deficiency. [Method] Taking three years old ...[ Objective ] The paper was to explore a kind of zinc preparation suitable for injection on trees with fast, efficient and safe cure effect on physiological disease of zinc deficiency. [Method] Taking three years old apple, pear, peach and grape trees as the materials, the author studied the absorption condition of these trees to six kinds of zinc substances and their security. The sealed curative effects of the injected zinc substances which were harmful and could be absorbed steadily by the fruit trees against rosette disease were studied. [ Result] The results of absorption condition and security experiments showed that only zinc-mmnonia complex could be absorbed steadily and safely throughout four seasons. When apple, pear, peach and grape trees affected by rosette disease were injected with zinc- ammonia complex, the leaves of those trees started to grow obviously after 10 d; the internodes of diseased branches elongated, the leaves turned bigger, and the ap- pearance of branches became normal after about 25 d. [ Conclusion] The curative effect of perforated injection of zinc-ammonia complex on fruit tree rosette disease was remarkable. The results also provided a new way for the cure of deficiency diseases of other trace elements.展开更多
Methanol synthesis from hydrogenation of CO2 is investigated over Cu/ZnO/Al2O3 catalysts prepared by decomposition of M（Cu,Zn）-ammonia complexes （DMAC） at various temperatures.The catalysts were characterized in d...Methanol synthesis from hydrogenation of CO2 is investigated over Cu/ZnO/Al2O3 catalysts prepared by decomposition of M（Cu,Zn）-ammonia complexes （DMAC） at various temperatures.The catalysts were characterized in detail,including X-ray diffraction,N2 adsorption-desorption,N2O chemisorption,temperature-programmed reduction and evolved gas analyses.The influences of DMAC temperature,reaction temperature and specific Cu surface area on catalytic performance are investigated.It is considered that the aurichalcite phase in the precursor plays a key role in improving the physiochemical properties and activities of the final catalysts.The catalyst from rich-aurichalcite precursor exhibits large specific Cu surface area and high space time yield of methanol （212 g/（Lcat·h）;T=513 K,p=3MPa,SV=12000 h-1）.展开更多
Air stripping was adopted to treat nickel ammonia complex ion-containing wastewater in order to remove nickel and ammonia simultaneously in one technological process.The relationship among pH,the concentration of nick...Air stripping was adopted to treat nickel ammonia complex ion-containing wastewater in order to remove nickel and ammonia simultaneously in one technological process.The relationship among pH,the concentration of nickel ammonia complex ion and total ammonia concentration was analyzed theoretically.Influence of pH value,water temperature,airflow rate and time on air stripping was studied in detail by static experiment in laboratory.The results show that at pH 11,temperature of 60℃and airflow rate of 0.12 m3/h,NH3 and Ni 2+concentrations remained in wastewater are less than 2 and 0.2 mg/L,respectively,after blowing for 75 min,which reaches the standard of the state discharge.When the tail gas is absorbed by 0.5 mol/L H2SO4 in order to avoid the secondary pollution,the absorption rate can achieve 70%.展开更多
Heavy metals and ammonia are difficult to remove from wastewater,as they easily combine into refractory complexes.The struvite formation method（SFM） was applied for the complex decomposition and simultaneous removal...Heavy metals and ammonia are difficult to remove from wastewater,as they easily combine into refractory complexes.The struvite formation method（SFM） was applied for the complex decomposition and simultaneous removal of heavy metal and ammonia.The results indicated that ammonia deprivation by SFM was the key factor leading to the decomposition of the copper-ammonia complex ion.Ammonia was separated from solution as crystalline struvite,and the copper mainly co-precipitated as copper hydroxide together with struvite.Hydrogen bonding and electrostatic attraction were considered to be the main surface interactions between struvite and copper hydroxide.Hydrogen bonding was concluded to be the key factor leading to the co-precipitation.In addition,incorporation of copper ions into the struvite crystal also occurred during the treatment process.展开更多
The black nickel formation process in leaching solution containing ammonia and chloride was investigated in terms of cyclic voltammetric and galvanostatic reduction techniques. The structure of black nickel was examin...The black nickel formation process in leaching solution containing ammonia and chloride was investigated in terms of cyclic voltammetric and galvanostatic reduction techniques. The structure of black nickel was examined by means of X-ray diffraction technique. The results show that in the scanning region, two oxidization current peaks are observed during the positive sweep, one of which is attributed to a valence state transformation of Ni（OH）2 to high valence nickel compound（black nickel）, and the other is caused by nitrogen evolution. During the formation process of black nickel, γ-NiOOH probably tends to self-discharge with water to form α-Ni（OH）2. As a result, it is observed that Ipa/Ipc(Ipa—anodic peak current; Ipc—cathodic peak current) maintains at a constant with the scanning rate increasing. Two reduction current peaks in cyclic voltammogram and two potential plateaus in galvanostatic reduction curve for black nickel are ascribed to the reduction of various oxidization states of nickel oxide. The potential plateaus at about 0.75 V reach the maximum in galvanostatic reduction curves. Black nickel presents amorphous structure.展开更多
文摘[ Objective ] The paper was to explore a kind of zinc preparation suitable for injection on trees with fast, efficient and safe cure effect on physiological disease of zinc deficiency. [Method] Taking three years old apple, pear, peach and grape trees as the materials, the author studied the absorption condition of these trees to six kinds of zinc substances and their security. The sealed curative effects of the injected zinc substances which were harmful and could be absorbed steadily by the fruit trees against rosette disease were studied. [ Result] The results of absorption condition and security experiments showed that only zinc-mmnonia complex could be absorbed steadily and safely throughout four seasons. When apple, pear, peach and grape trees affected by rosette disease were injected with zinc- ammonia complex, the leaves of those trees started to grow obviously after 10 d; the internodes of diseased branches elongated, the leaves turned bigger, and the ap- pearance of branches became normal after about 25 d. [ Conclusion] The curative effect of perforated injection of zinc-ammonia complex on fruit tree rosette disease was remarkable. The results also provided a new way for the cure of deficiency diseases of other trace elements.
基金supported by the National Basic Research Program of China (No. 2011CB201404)the financial support of the State Key Laboratory for Oxo Synthesis and Selective Oxidation (OSSO) of China
文摘Methanol synthesis from hydrogenation of CO2 is investigated over Cu/ZnO/Al2O3 catalysts prepared by decomposition of M（Cu,Zn）-ammonia complexes （DMAC） at various temperatures.The catalysts were characterized in detail,including X-ray diffraction,N2 adsorption-desorption,N2O chemisorption,temperature-programmed reduction and evolved gas analyses.The influences of DMAC temperature,reaction temperature and specific Cu surface area on catalytic performance are investigated.It is considered that the aurichalcite phase in the precursor plays a key role in improving the physiochemical properties and activities of the final catalysts.The catalyst from rich-aurichalcite precursor exhibits large specific Cu surface area and high space time yield of methanol （212 g/（Lcat·h）;T=513 K,p=3MPa,SV=12000 h-1）.
基金Project(08SK1002)supported by the Major Project of Scientific and Technological Department of Hunan Province,ChinaProject(50508044)supported by the National Natural Science Foundation of China
文摘Air stripping was adopted to treat nickel ammonia complex ion-containing wastewater in order to remove nickel and ammonia simultaneously in one technological process.The relationship among pH,the concentration of nickel ammonia complex ion and total ammonia concentration was analyzed theoretically.Influence of pH value,water temperature,airflow rate and time on air stripping was studied in detail by static experiment in laboratory.The results show that at pH 11,temperature of 60℃and airflow rate of 0.12 m3/h,NH3 and Ni 2+concentrations remained in wastewater are less than 2 and 0.2 mg/L,respectively,after blowing for 75 min,which reaches the standard of the state discharge.When the tail gas is absorbed by 0.5 mol/L H2SO4 in order to avoid the secondary pollution,the absorption rate can achieve 70%.
基金supported by the National Natural Science Foundation of China(No.51204213)the Key Project of Science and Technology of Hunan Province(No.2013WK2007)the Innovation Stimulating Program of Central South University(No.2015CX001)
文摘Heavy metals and ammonia are difficult to remove from wastewater,as they easily combine into refractory complexes.The struvite formation method（SFM） was applied for the complex decomposition and simultaneous removal of heavy metal and ammonia.The results indicated that ammonia deprivation by SFM was the key factor leading to the decomposition of the copper-ammonia complex ion.Ammonia was separated from solution as crystalline struvite,and the copper mainly co-precipitated as copper hydroxide together with struvite.Hydrogen bonding and electrostatic attraction were considered to be the main surface interactions between struvite and copper hydroxide.Hydrogen bonding was concluded to be the key factor leading to the co-precipitation.In addition,incorporation of copper ions into the struvite crystal also occurred during the treatment process.
基金Project(50004005) supported by the National Natural Science Foundation of China
文摘The black nickel formation process in leaching solution containing ammonia and chloride was investigated in terms of cyclic voltammetric and galvanostatic reduction techniques. The structure of black nickel was examined by means of X-ray diffraction technique. The results show that in the scanning region, two oxidization current peaks are observed during the positive sweep, one of which is attributed to a valence state transformation of Ni（OH）2 to high valence nickel compound（black nickel）, and the other is caused by nitrogen evolution. During the formation process of black nickel, γ-NiOOH probably tends to self-discharge with water to form α-Ni（OH）2. As a result, it is observed that Ipa/Ipc(Ipa—anodic peak current; Ipc—cathodic peak current) maintains at a constant with the scanning rate increasing. Two reduction current peaks in cyclic voltammogram and two potential plateaus in galvanostatic reduction curve for black nickel are ascribed to the reduction of various oxidization states of nickel oxide. The potential plateaus at about 0.75 V reach the maximum in galvanostatic reduction curves. Black nickel presents amorphous structure.
