According to many years of experimental summary, the technical demands, process control, seed test, seed quality and work record (ledger management) of cleaning processing of feeding millet seeds in Hebei Province w...According to many years of experimental summary, the technical demands, process control, seed test, seed quality and work record (ledger management) of cleaning processing of feeding millet seeds in Hebei Province were studied, and specific measures and technical indicators of the technical regulations were analyzed to provide normalized, standardized, industrial and marketization technical support for the cleaning processing of feeding millet seeds.展开更多
In this work, the results of a study of laser ablation cleaning process on ceramic artifacts are presented. The experiments were conducted on a "Carosello", a structural hollow element made of clay, placed in arches...In this work, the results of a study of laser ablation cleaning process on ceramic artifacts are presented. The experiments were conducted on a "Carosello", a structural hollow element made of clay, placed in arches, in domes or even in the walls of buildings such as churches and houses. Our results show that laser ablation techniques is able to remove the surface impurity patina from artifacts surface without changes the chemical composition and the optical properties of ceramic. Moreover, because the laser cleaning heats only locally the surface of the sample, this method don't preclude the possibility to apply on artifact the thermo-luminescence dating process.展开更多
Sodium chromate solubility is determined in the range of NaOH concentrations from 450 to 810 g/L andsolution temperatUres from 30 to 110℃. The optimized conditions to separate sodium chromate from NaOH inleached solu...Sodium chromate solubility is determined in the range of NaOH concentrations from 450 to 810 g/L andsolution temperatUres from 30 to 110℃. The optimized conditions to separate sodium chromate from NaOH inleached solution are resolved. It is first found the method to efficiently separate sbdium chromate from NaOH andsodium altuninate in crude sodium chromate. Bench-scale studies on the separating are performed. Finally, goodseparation results are achieved.展开更多
The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low c...The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning,which is a highly efficient,clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.展开更多
Striving for cleaner production is a sought-after manufacturing philosophy.Friction stir welding(FSW)is a joiningtechnique with par excellence and far less invasive to the environment than even best conventional weldi...Striving for cleaner production is a sought-after manufacturing philosophy.Friction stir welding(FSW)is a joiningtechnique with par excellence and far less invasive to the environment than even best conventional welding processes.It is energyefficient and free from consumables,affluent and radiations.It is,thus,accepted as a clean welding process that can produceacceptable quality joints.It suffers from some major challenges of defects of its own kind that subject the process open toimprovements so as to prove itself a reliable production process.This study presents a holistic characterization of defects commonlyfound in FSW joints.The finding of the present study reveals that most defects are caused by inadequate heat generation,impropermaterial movement around the pin and inadequate material consolidation behind the pin.The amount of heat generation andmaterial stirring depends on several FSW parameters which may lead to the defect formation,if not selected properly.The resultsreported in this work are derived from sound literature support and experimentation.Prescriptions are made in the form ofcharacteristics of defects such as likelihood of their location,main responsible parameters along with the recommendations forminimizing them.展开更多
The use of cool materials on the building envelope is one of the most cost-effective ways to increase indoor thermal comfort conditions in hot climates and decrease the cooling energy needs.Despite the benefit of redu...The use of cool materials on the building envelope is one of the most cost-effective ways to increase indoor thermal comfort conditions in hot climates and decrease the cooling energy needs.Despite the benefit of reducing cooling loads,researches have demonstrated that aging of roof coatings changes the initial solar reflectance(SR),which influences the long term building thermal and energy performance.Thus,this work presents preliminary natural weathering tests performed on samples of nine white coatings exposed to natural weathering for one year in the city of Sao Carlos,Brazil.Solar reflectances were measured with a spectrophotometer before and after exposure,every 3 months,for identifying the effect of aging along the time.The findings showed changes of 13%to 23%on SR after one year of natural weathering,with higher decrease on SR for rougher surfaces.The cleaning process restored from 90%to 100%of the original SR,which means maintenance can be an effective solution to restore the initial SR.Simulations indicated that roofs with higher solar reflectance increase indoor thermal comfort conditions and decrease the cooling energy need for buildings in hot climates,but the aging of white coatings increased the cooling energy needs along the time.展开更多
The leaching kinetics of niobium from a low-grade niobium-tantalum ore by concentrated KOH solu-tion under atmospheric pressure has been studied. Significant effects of reaction temperature, KOH concentration, stirrin...The leaching kinetics of niobium from a low-grade niobium-tantalum ore by concentrated KOH solu-tion under atmospheric pressure has been studied. Significant effects of reaction temperature, KOH concentration, stirring speed, particle size and inass ratio of alkali-to-ore on the dissolution rate of niobium were examined. The experimental data of the leaching rates and the observed effects of the relevant operating variables were well in-terpreted with a shrinking core model under diffusion control. By using the Arrhenius expression, the apparent activation energy for the dissolution of niobium was evaluated. Finally, on the base of the shrinking core model, the rate equation was established.展开更多
Chemical Manganese Dioxide (CMD) was prepared by an alkali-oxidation method. There are several virtues to this environmental friendly and clean process, including the nontoxic and harmless reagents and products, eas...Chemical Manganese Dioxide (CMD) was prepared by an alkali-oxidation method. There are several virtues to this environmental friendly and clean process, including the nontoxic and harmless reagents and products, easy operations, no pollutants, easily obtained raw materials and moderate reaction conditions. The synthesized manganese dioxide was characterized by XRD and SEM. The particles were small, consisting primarily of α-MnO2 and γ-MnO2. Experimental results showed that the optimum conditions were: MnSOa.H20 to NaOH ratio, 1.0:2.4; catalyst concentration (catalyst TF-2), 6% of the MnSO4; initial solution pH, 11; reaction time and temperature, 20 min and 80 ℃; air flow, 0.20 m3/h; and, agitation rate, 700 r/rain. The conversion of MnSO4 can exceed 80% under these optimum conditions.展开更多
In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction in...In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction intensity under control. The reaction performances with respect to apparent kinetics and selectivity are determined to explore optimized reaction conditions and confirm potentials for enhancing productivity in one batch. The dissolution and liquid phase reaction mechanism and instant reaction assumption are proposed and verified through process analysis. A process design towards free additional water is schematically figured out to manipulate solid NaOH, by-product,and unreacted starting materials to realize a nearly closed circuit. This process allows high selectivity over 97% and complete DCP conversion at 323.2 K within a reaction time less than 20 min. Other advantages include near-zero wastewater emission, economically possible NaOH regeneration from NaCl, and robust operating condition window.展开更多
基金Supported by Special Fund for Agro-scientific Research in the Public Interest(20120304201)~~
文摘According to many years of experimental summary, the technical demands, process control, seed test, seed quality and work record (ledger management) of cleaning processing of feeding millet seeds in Hebei Province were studied, and specific measures and technical indicators of the technical regulations were analyzed to provide normalized, standardized, industrial and marketization technical support for the cleaning processing of feeding millet seeds.
文摘In this work, the results of a study of laser ablation cleaning process on ceramic artifacts are presented. The experiments were conducted on a "Carosello", a structural hollow element made of clay, placed in arches, in domes or even in the walls of buildings such as churches and houses. Our results show that laser ablation techniques is able to remove the surface impurity patina from artifacts surface without changes the chemical composition and the optical properties of ceramic. Moreover, because the laser cleaning heats only locally the surface of the sample, this method don't preclude the possibility to apply on artifact the thermo-luminescence dating process.
文摘Sodium chromate solubility is determined in the range of NaOH concentrations from 450 to 810 g/L andsolution temperatUres from 30 to 110℃. The optimized conditions to separate sodium chromate from NaOH inleached solution are resolved. It is first found the method to efficiently separate sbdium chromate from NaOH andsodium altuninate in crude sodium chromate. Bench-scale studies on the separating are performed. Finally, goodseparation results are achieved.
文摘The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal,low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning,which is a highly efficient,clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.
基金the University Grants Commission (UGC) for its financial assistance (vide sanction order No. F.3-40/2012(SAP-Ⅱ)) under its SAP (DRS-Ⅰ) sanctioned to the Department of Mechanical Engineering for the project entitled Friction Stir Welding and Ultrasonic Machiningfinancially supported by the King Saud University, Vice Deanship of Research Chairs
文摘Striving for cleaner production is a sought-after manufacturing philosophy.Friction stir welding(FSW)is a joiningtechnique with par excellence and far less invasive to the environment than even best conventional welding processes.It is energyefficient and free from consumables,affluent and radiations.It is,thus,accepted as a clean welding process that can produceacceptable quality joints.It suffers from some major challenges of defects of its own kind that subject the process open toimprovements so as to prove itself a reliable production process.This study presents a holistic characterization of defects commonlyfound in FSW joints.The finding of the present study reveals that most defects are caused by inadequate heat generation,impropermaterial movement around the pin and inadequate material consolidation behind the pin.The amount of heat generation andmaterial stirring depends on several FSW parameters which may lead to the defect formation,if not selected properly.The resultsreported in this work are derived from sound literature support and experimentation.Prescriptions are made in the form ofcharacteristics of defects such as likelihood of their location,main responsible parameters along with the recommendations forminimizing them.
基金This work was funded by The State of São Paulo Research Foundation(FAPESP,Nº08/58700-0)and the National Council for Scientific and Technological Development(CNPq,N°402720/2016-4).
文摘The use of cool materials on the building envelope is one of the most cost-effective ways to increase indoor thermal comfort conditions in hot climates and decrease the cooling energy needs.Despite the benefit of reducing cooling loads,researches have demonstrated that aging of roof coatings changes the initial solar reflectance(SR),which influences the long term building thermal and energy performance.Thus,this work presents preliminary natural weathering tests performed on samples of nine white coatings exposed to natural weathering for one year in the city of Sao Carlos,Brazil.Solar reflectances were measured with a spectrophotometer before and after exposure,every 3 months,for identifying the effect of aging along the time.The findings showed changes of 13%to 23%on SR after one year of natural weathering,with higher decrease on SR for rougher surfaces.The cleaning process restored from 90%to 100%of the original SR,which means maintenance can be an effective solution to restore the initial SR.Simulations indicated that roofs with higher solar reflectance increase indoor thermal comfort conditions and decrease the cooling energy need for buildings in hot climates,but the aging of white coatings increased the cooling energy needs along the time.
基金Supported by the National Natural Science Foundation of China (No. 50234040 and No. 20306031).
文摘The leaching kinetics of niobium from a low-grade niobium-tantalum ore by concentrated KOH solu-tion under atmospheric pressure has been studied. Significant effects of reaction temperature, KOH concentration, stirring speed, particle size and inass ratio of alkali-to-ore on the dissolution rate of niobium were examined. The experimental data of the leaching rates and the observed effects of the relevant operating variables were well in-terpreted with a shrinking core model under diffusion control. By using the Arrhenius expression, the apparent activation energy for the dissolution of niobium was evaluated. Finally, on the base of the shrinking core model, the rate equation was established.
基金National Natural Science Foundation of China (No50704036)the Natural Science Foundation of Hunan Province (No08JJ3027) for their financial support
文摘Chemical Manganese Dioxide (CMD) was prepared by an alkali-oxidation method. There are several virtues to this environmental friendly and clean process, including the nontoxic and harmless reagents and products, easy operations, no pollutants, easily obtained raw materials and moderate reaction conditions. The synthesized manganese dioxide was characterized by XRD and SEM. The particles were small, consisting primarily of α-MnO2 and γ-MnO2. Experimental results showed that the optimum conditions were: MnSOa.H20 to NaOH ratio, 1.0:2.4; catalyst concentration (catalyst TF-2), 6% of the MnSO4; initial solution pH, 11; reaction time and temperature, 20 min and 80 ℃; air flow, 0.20 m3/h; and, agitation rate, 700 r/rain. The conversion of MnSO4 can exceed 80% under these optimum conditions.
基金Supported by the National Natural Science Foundation of China(21176136,21422603)the National Science and Technology Support Program of China(2011BAC06B01)
文摘In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction intensity under control. The reaction performances with respect to apparent kinetics and selectivity are determined to explore optimized reaction conditions and confirm potentials for enhancing productivity in one batch. The dissolution and liquid phase reaction mechanism and instant reaction assumption are proposed and verified through process analysis. A process design towards free additional water is schematically figured out to manipulate solid NaOH, by-product,and unreacted starting materials to realize a nearly closed circuit. This process allows high selectivity over 97% and complete DCP conversion at 323.2 K within a reaction time less than 20 min. Other advantages include near-zero wastewater emission, economically possible NaOH regeneration from NaCl, and robust operating condition window.