A field experiment was carried out to investigate the effects of different emitter discharge rates under drip irrigation on soil salinity distribution and cotton yield in an extreme arid region of Tarim River catchmen...A field experiment was carried out to investigate the effects of different emitter discharge rates under drip irrigation on soil salinity distribution and cotton yield in an extreme arid region of Tarim River catchment in Northwest China. Four treatments of emitter discharge rates, i.e. 1.8, 2.2, 2.6 and 3.2 L/h, were designed under drip irrigation with plastic mulch in this paper. The salt distribution in the range of 70-cm horizontal distance and 100-cm vertical distance from the emitter was measured and analyzed during the cotton growing season. The soil salinity is expressed in terms of electrical conductivity (dS/m) of the saturated soil extract (ECe), which was measured using Time Domain Reflector (TDR) 20 times a year, including 5 irrigation events and 4 measured times before/after an irrigation event. All the treatments were repeated 3 times. The groundwater depth was observed by SEBA MDS Dipper 3 automatically at three experimental sites. The results showed that the order of reduction in averaged soil salinity was 2.6 L/h 〉 2.2 L/h 〉 1.8 L/h 〉 3.2 L/h after the completion of irrigation for the 3-year cotton growing season. Therefore, the choice of emitter discharge rate is considerably important in arid silt loam. Usually, the ideal emitter discharge rate is 2.4-3.0 L/h for soil desalinization with plastic mulch, which is advisable mainly because of the favorable salt leaching of silt loam and the climatic conditions in the studied arid area. Maximum cotton yield was achieved at the emitter discharge rate of 2.6 L/h under drip irrigation with plastic mulch in silty soil at the study site. Hence, the emitter discharge rate of 2.6 L/h is recommended for drip irrigation with plastiic mulch applied in silty soil in arid regions.展开更多
The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, di...The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, discharge capacity and high rate dischargeability of the alloys are improved after physical and chemical modification as a result of the increase of the surface area and formation of the electrocatalysis layers, which increase both the electrochemical reaction rate on the alloy surface and H diffusion rate in the alloy bulk. It is also found that both the over-coarse and over-fine particle size increase the contact resistance of the electrode, resulting in a decrease of discharge capacity, deterioration of high rate dischargeability and lower discharge plateau. In another word, a suitable particle size distribution can enhance the alloy activity, discharge capacity and high rate dischargeability. In addition, the high rate dischargeability is enhanced by increasing La content and decreasing Ce content of the alloy composition because of enlargement of the unit cell volume and the improvement of the surface activity. Moreover, B additive resultes in the formation of the second phase, and makes the alloys easier pulverization, which greatly improves the activity, discharge capacity and high rate dischargeability.展开更多
Carbon-based electric double layer capacitors(EDLCs)hold tremendous potentials due to their high-power performance and excellent cycle stability.However,the practical use of EDLCs is limited by the low energy density ...Carbon-based electric double layer capacitors(EDLCs)hold tremendous potentials due to their high-power performance and excellent cycle stability.However,the practical use of EDLCs is limited by the low energy density in aqueous electrolyte and sluggish diffusion kinetics in organic or/and ionic liquids electrolyte.Herein,3D carbon frameworks(3DCFs)constructed by interconnected nanocages(10-20 nm)with an ultrathin wall of ca.2 nm have been fabricated,which possess high specific surface area,hierarchical porosity and good conductive network.After deoxidization,the deoxidized 3DCF(3DCFDO)exhibits a record low IR drop of 0.064 V at 100 A g^−1 and ultrafast charge/discharge rate up to 10 V s^−1.The related device can be charged up to 77.4%of its maximum capacitance in 0.65 s at 100 A g^−1 in 6 M KOH.It has been found that the 3DCF-DO has a great affinity to EMIMBF4,resulting in a high specific capacitance of 174 F g^−1 at 1 A g^−1,and a high energy density of 34 Wh kg^−1 at an ultrahigh power density of 150 kW kg^−1 at 4 V after a fast charge in 1.11 s.This work provides a facile fabrication of novel 3D carbon frameworks for supercapacitors with ultrafast charge/discharge rate and high energy-power density.展开更多
Application of amorphous V2O5/carbon/ncodymium oxide (Nd2O3) composite is one ot ways to surmount me lower electrical conductivity of V2O5. A new type of V2O5/carbon/Nd2O3 composite was prepared by mixing vanadium o...Application of amorphous V2O5/carbon/ncodymium oxide (Nd2O3) composite is one ot ways to surmount me lower electrical conductivity of V2O5. A new type of V2O5/carbon/Nd2O3 composite was prepared by mixing vanadium oxide hydrosol, acetone, carbon and Nd2O3 powder. High rate discharge/charge property of the composite electrode was tested electrochemically. This composite with Nd2O3 added shows the improvement of not only the discharge capacity but also cycle durability discharge capacity. The rate capability of the composite cathode also increases with the addition of Nd2O3. Even at 10 A·g^-1 current density, a capacity of about 250 mAh·g^-1 was obtained at 25 ℃. This enhanced rate capability and cycle life are probably caused by the increase in porosity of open pores and short diffusion length of the active material on the lithium-ion insertion.展开更多
According to Cisco, mobile multimedia services now account for more than half the total amount of Internet traffic. This trend is burdening mobile devices in terms of power consumption, and as a result, more effort is...According to Cisco, mobile multimedia services now account for more than half the total amount of Internet traffic. This trend is burdening mobile devices in terms of power consumption, and as a result, more effort is needed to devise a range of pow- er-saving techniques. While most power-saving techniques are based on sleep scheduling of network interfaces, little has been done to devise multimedia content adaptation techniques. In this paper, we propose a multiple linear regression model that predicts the battery voltage discharge rate for several video send bit rates in a VoIP application. The battery voltage dis- charge rate needs to be accurately estimated in order to esti- mate battery life in critical VoIP contexts, such as emergency communication. In our proposed model, the range of video send bitrates is carefully chosen in order to maintain an acceptable VoIP quality of experience. From extensive profiling, the empir- ical resuhs show that the model effectively saves power and pro- longs real-time VoIP sessions when deployed in power-driven adaptation schemes.展开更多
Thermal battery plays an important role in renewable energy utilization towards carbon neutrality.The novel absorption thermal battery(ATB)has excellent performance but suffers from serious capacity attenuation.To add...Thermal battery plays an important role in renewable energy utilization towards carbon neutrality.The novel absorption thermal battery(ATB)has excellent performance but suffers from serious capacity attenuation.To address this problem,two capacity regulation methods,i.e.,variable solution flow and variable cooling water flow,are proposed to achieve a demanded discharging rate.The effects of the two regulation strategies on the dynamic discharging characteristics and overall storage performance are comparatively investigated.To demon-strate the adjustability of the output capacity,several stable discharging rates are successfully maintained by the proposed methods.To maintain a higher discharging rate,the stable discharging time has to be sacrificed.As the demanded output increased from 0.5 kW to 6.0 kW,the stable discharging time decreased from 781.8 min to 27.9 min under variable solution flow and from 769.9 min to 30.7 min under variable cooling water flow.With the increase of solution or water flow rate,the energy storage density is improved,while the energy storage efficiency is slightly increased first and decreased later.The regulation method of variable water flow shows relatively lower energy storage efficiency due to the larger pump power.This study could facilitate reasonable development and application of ATB cycles.展开更多
The structure and electrochemical properties of a new low cobalt hydrogen storage electrode alloys La1-xLixNi3.2Co0.3Al0.3 (0≤x≤0.2) were investigated with a different additions of Li in replacement of La. With the ...The structure and electrochemical properties of a new low cobalt hydrogen storage electrode alloys La1-xLixNi3.2Co0.3Al0.3 (0≤x≤0.2) were investigated with a different additions of Li in replacement of La. With the increase of Li contents the maximum discharge capacity increases from 240 mAh·g-1(x=0) to 328.4 mAh·g-1(x=0.1) and the cycle stability is improved correspondingly. The capacity decay can remain 28.6% (x=0.2) after 230 charge/discharge cycles. The high rate discharge(HRD) ability of the alloys(x≤0.1) is improved and the best HRD is 34.1%(x=0.1) under the discharge current density 1200 mA·g-1. It is found that the prepared alloys are basically composed of LaNi5 as matrix phase and LaNi3 as second phase(x≤0.1). But the abundance of LaNi3 phase dramatically decreases with increasing x. When x=0.2, a new phase Al(NiCo)3 is formed.展开更多
This study examines the thermal runaway of a lithium ion battery caused by poor heat dissipation performances.The heat transfer process is analyzed on the basis of standard theoretical concepts.Water mist additives ar...This study examines the thermal runaway of a lithium ion battery caused by poor heat dissipation performances.The heat transfer process is analyzed on the basis of standard theoretical concepts.Water mist additives are considered as a tool to suppress the thermal runaway process.The ensuing behaviour of the battery in terms of surface temperature and heat generation is analyzed for different charge and discharge rates.It is found that when the remaining charge is 100%,the heat generation rate of the battery is the lowest,and the surface temperature with a 2C charge rate is higher than that obtained for a 0.5C charge rate.The experimental results show that when the additive concentration is 20%NaCl,its ability to inhibit the thermal runaway is the strongest.展开更多
Based on isentropic flow and thermal equilibrium assumptions, a model was derived to calculate discharge flow rate, which unified the rules of room temperature water discharge, high temperature and high pressure water...Based on isentropic flow and thermal equilibrium assumptions, a model was derived to calculate discharge flow rate, which unified the rules of room temperature water discharge, high temperature and high pressure water discharge, two-phase critical flow, saturated steam and superheated steam critical flow, and gave a method to calculate critical condition. Because of the influence of friction, the entropy is increased in the actual discharge process, and the discharge flow rate in thermal equilibrium condition can be obtained by the original model multiplied by an appropriate correction coefficient. The model calculated results agreed well with the experiment data of long nozzle critical flow.展开更多
The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are inv...The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer(ICP) analysis and it testified to be 1:1:1. It is indicated that Ni3(PO4)2-coated Li Ni1/3Co1/3Mn1/3O2 has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy(EIS) results show that the current exchange density i0 of the coated sample is higher than that of Li Ni1/3Co1/3Mn1/3O2, which is beneficial to its electrochemical performances. All the conclusions show that the Ni3(PO4)2coating can prominently enhance the high rate performance of the Li Ni1/3Co1/3Mn1/3O2, especially at high cut-off voltage.展开更多
A lower granular temperature zone near the orifice in silos was found by speckle visibility spectroscopy technology.Surprisingly,the values of granular temperature in this area are inversely proportional to the mass d...A lower granular temperature zone near the orifice in silos was found by speckle visibility spectroscopy technology.Surprisingly,the values of granular temperature in this area are inversely proportional to the mass discharge rate(MDR).This finding that links the macroscopic MDR with mesoscopic dynamics temperature of the particle system,is obtained by looking at the effect that different outlet sizes of silos on MDR and granular temperature field.Apart from evidencing the relevance of a parameter that has been traditionally overlooked in silos,this relationship supposes a benchmark with which to explore the influence of small orifice sizes on MDR.Among these,we found that the frequency of intermittent clogging and their dependence on the size of the outlet.展开更多
Unmanned aerial vehicles(UAVs)are widely being used to spread granular fertilizer in China.Granular fertilizer spreaders equipped with UAVs are mainly centrifugal disc-type and pneumatic.The multichannel pneumatic gra...Unmanned aerial vehicles(UAVs)are widely being used to spread granular fertilizer in China.Granular fertilizer spreaders equipped with UAVs are mainly centrifugal disc-type and pneumatic.The multichannel pneumatic granular fertilizer spreaders(MPGFSs)have a banded fertilizer deposition distribution pattern,which are more suitable for variable rate fertilization with high precision requirement than the circular deposition distribution pattern of disc-type granular fertilizer spreaders(DGFSs).However,the existing MPGFS has the disadvantage of inconsistent discharge rate of each channel,which affects the uniformity of fertilization.In order to explore the causes of inconsistent discharge rate of each channel,the discrete element method(DEM)and bench test were performed to analysis the discharge process of the fluted roller fertilizing apparatus and distribution of fertilizer in axial direction of fluted roller.The computational fluid dynamics(CFD)was used to simulate the airflow field of pneumatic system to analyze the influence of airflow on the movement of fertilizer particles.The simulation results of the discharge process of the fluted roller fertilizing apparatus showed that the filling velocity at the axial ends of the fluted roller fertilizing apparatus was lower than that of the middle.The reason was that the filling capacity was weak near the wall.The simulated results of the airflow field without partitions showed that the airflow provided by the axial flow fan was rotational,and this caused the particles to move irregularly in the throat,resulting in inconsistency discharge rate of each channel.Based on the analysis of reasons of inconsistent discharge rate of each channel,a MPGFS with partitions in the throat was developed.The discharge rate bench tests were carried out to optimize the partition spacing parameters,and fertilization test was performed to test the performance of the improved MPGFS.The discharge rate test results showed better consistency with partition.The coefficient of variation(CV)of the discharge rate of each channel was 20.16%without the partition and 7.70%with the optimal partition.The fertilizer spreading uniformity bench test results shown that the CV of spreading uniformity of MPGFS without partitions was 15.32%,and that MPGFS with partitions was 8.69%.The partitions design was beneficial to improve the consistency of each channel discharge rate and the uniformity of fertilization.The finding can provide a strong reference to design the MPGFS.展开更多
For further improving the rate properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy,the alloy was annealed in high mag-netic fields(10 T).The results showed that the electrochemical properties and magnetic p...For further improving the rate properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy,the alloy was annealed in high mag-netic fields(10 T).The results showed that the electrochemical properties and magnetic properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy were considerably enhanced.And there was no change of the phase composition.The lattice constants of c and c/a ratio increased for the sample magnetically annealed,yielding uniaxial magnetic anisotropy along the c axis.The increase o...展开更多
An experimental study on the gravity driven discharge of cohesive particles from a silo with two outlets was performed.The discharge behaviors under the conditions that a single outlet was open and two outlets were op...An experimental study on the gravity driven discharge of cohesive particles from a silo with two outlets was performed.The discharge behaviors under the conditions that a single outlet was open and two outlets were open were investigated by varying the moisture content of the particles and the filling height of the particles in the silo.The results show that the discharge rate of the cohesive particles increases gradually at the beginning,then almost keeps constant,and finally drops obviously.The discharge rate in case of two openings is around 1.1–1.6 times that in case of a single opening.Larger filling height leads to lower discharge rate in case of a single opening but results in higher discharge rate in case of two openings.Furthermore,the avalanche dynamics in case of a single opening was examined,and the mixing behavior of the cohesive particles was evaluated.It is observed that the discharge flow is promoted by the avalanche phenomenon in the silo,generating a general trend that the normalized mass of discharge increases with the filling height at higher moisture contents.In case of a single opening,the transition from mass flow to funnel flow favors the particle mixing,resulting in an increasing mixing index as the moisture content increases.In general,a better performance of mixing can be achieved in case of a single opening compared with in case of two openings.This study provides vital information for fundamental understanding of the gravity driven discharge of cohesive particles from the silo with multiple outlets.展开更多
Granular material discharge from a flat-bottomed silo has been simulated by using continuum modeling and a three-dimensional discrete-element method (DEM). The predictive abilities of three commonly used frictional ...Granular material discharge from a flat-bottomed silo has been simulated by using continuum modeling and a three-dimensional discrete-element method (DEM). The predictive abilities of three commonly used frictional viscosity models (Schaeffer, S-S, and μ(I)) were evaluated by comparing them with the DEM data. The funnel-flow pattern (type C) and the semi-mass-flow pattern (type B) that was predicted by DEM simulations can be represented when the Schaeffer orμ(I) model is used, whereas the S-S model gives a consistent type-B flow pattern. All three models over-estimate the discharge rate compared with the DEM. The profiles of the solids volume fraction and the vertical velocity above the outlet show that the larger discharge rates given by the Schaeffer and μ(I) model result from an over-estimation of volume fraction, whereas the deviation in the S-S model stems from the failure to predict a solid vertical velocity and a volume fraction.展开更多
The present study aims to improve electrochemical properties of the La-Mg-Ni-based hydrogen storage alloys through partial substitution for La by mischmetal(MM).The La_(0.8-x)MM_xMg_(0.2)Ni_(3.1)Co_(0.3)Al_...The present study aims to improve electrochemical properties of the La-Mg-Ni-based hydrogen storage alloys through partial substitution for La by mischmetal(MM).The La_(0.8-x)MM_xMg_(0.2)Ni_(3.1)Co_(0.3)Al_(0.1)(x=0,0.1,0.2,0.3)alloys were prepared by inductive melting,and their phase structures and electrochemical properties were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),energy-dispersive X-ray spectrometry(EDX)and electrochemical tests.Results show that the alloys mainly consist of La_2Ni_7-type phase,La_5Ni_(19)-type phase,LaNi_5-type phase and LaNi_3-type phase.The addition of MM does not change the phase compositions,while it leads to more uniform phase distribution and obviously promotes the formation of La_2Ni_7-type phase which possesses favorable electrochemical properties.Electrochemical studies indicate that the substitution for La by MM could effectively improve the high rate dischargeability(HRD)of the alloy electrode,and the optimal value of HRD_(1500)(HRD at 1500 mA·g^(-1))increases from 40.63%(x=0)to 60.55%(x=0.3).Although the activation properties of the alloy electrodes keep almost unchanged,both the maximum discharge capacity(C_(max))and the cycling stability are significantly improved by MM addition.展开更多
Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the p...Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the precise design and operation of BTES systems.This study conducts a sensitivity analysis of BTES modeling by employing a comparative investigation of five distinct parameters on a wedge-shaped model,with implications extendable to a cylindrical configuration.The parameters examined included two design factors(well spacing and grout thermal conductivity),two operational variables(charging and discharging rates),and one geological attribute(soil thermal conductivity).Finite element simulations were carried out for the sensitivity analysis to evaluate the round-trip efficiency,both on a per-cycle basis and cumulatively over three years of operation,serving as performance metrics.The results showed varying degrees of sensitivity across different models to changes in these parameters.In particular,the round-trip efficiency exhibited a greater sensitivity to changes in spacing and volumetric flow rate.Furthermore,this study underscores the importance of considering the impact of the soil and grout-material thermal conductivities on the BTES-system performance over time.An optimized scenario is modelled and compared with the base case,over a comparative assessment based on a 10-year simulation.The analysis revealed that,at the end of the 10-year period,the optimized BTES model achieved a cycle efficiency of 83.4%.This sensitivity analysis provides valuable insights into the merits and constraints of diverse BTES modeling methodologies,aiding in the selection of appropriate modeling tools for BTES system design and operation.展开更多
基金supported by the National Basic Research Program of China (2009CB421302)the National Natural Science Foundation of China (41071026,51069017)
文摘A field experiment was carried out to investigate the effects of different emitter discharge rates under drip irrigation on soil salinity distribution and cotton yield in an extreme arid region of Tarim River catchment in Northwest China. Four treatments of emitter discharge rates, i.e. 1.8, 2.2, 2.6 and 3.2 L/h, were designed under drip irrigation with plastic mulch in this paper. The salt distribution in the range of 70-cm horizontal distance and 100-cm vertical distance from the emitter was measured and analyzed during the cotton growing season. The soil salinity is expressed in terms of electrical conductivity (dS/m) of the saturated soil extract (ECe), which was measured using Time Domain Reflector (TDR) 20 times a year, including 5 irrigation events and 4 measured times before/after an irrigation event. All the treatments were repeated 3 times. The groundwater depth was observed by SEBA MDS Dipper 3 automatically at three experimental sites. The results showed that the order of reduction in averaged soil salinity was 2.6 L/h 〉 2.2 L/h 〉 1.8 L/h 〉 3.2 L/h after the completion of irrigation for the 3-year cotton growing season. Therefore, the choice of emitter discharge rate is considerably important in arid silt loam. Usually, the ideal emitter discharge rate is 2.4-3.0 L/h for soil desalinization with plastic mulch, which is advisable mainly because of the favorable salt leaching of silt loam and the climatic conditions in the studied arid area. Maximum cotton yield was achieved at the emitter discharge rate of 2.6 L/h under drip irrigation with plastic mulch in silty soil at the study site. Hence, the emitter discharge rate of 2.6 L/h is recommended for drip irrigation with plastiic mulch applied in silty soil in arid regions.
文摘The effects of surface treatment, particle size distribution,rare earth composition and B additive on the high rate discharge performance of hydrogen storage alloys were investigated. It is found that the activity, discharge capacity and high rate dischargeability of the alloys are improved after physical and chemical modification as a result of the increase of the surface area and formation of the electrocatalysis layers, which increase both the electrochemical reaction rate on the alloy surface and H diffusion rate in the alloy bulk. It is also found that both the over-coarse and over-fine particle size increase the contact resistance of the electrode, resulting in a decrease of discharge capacity, deterioration of high rate dischargeability and lower discharge plateau. In another word, a suitable particle size distribution can enhance the alloy activity, discharge capacity and high rate dischargeability. In addition, the high rate dischargeability is enhanced by increasing La content and decreasing Ce content of the alloy composition because of enlargement of the unit cell volume and the improvement of the surface activity. Moreover, B additive resultes in the formation of the second phase, and makes the alloys easier pulverization, which greatly improves the activity, discharge capacity and high rate dischargeability.
基金the financial support from the National Natural Science Foundation of China(51672033,U1610255,U1703251).
文摘Carbon-based electric double layer capacitors(EDLCs)hold tremendous potentials due to their high-power performance and excellent cycle stability.However,the practical use of EDLCs is limited by the low energy density in aqueous electrolyte and sluggish diffusion kinetics in organic or/and ionic liquids electrolyte.Herein,3D carbon frameworks(3DCFs)constructed by interconnected nanocages(10-20 nm)with an ultrathin wall of ca.2 nm have been fabricated,which possess high specific surface area,hierarchical porosity and good conductive network.After deoxidization,the deoxidized 3DCF(3DCFDO)exhibits a record low IR drop of 0.064 V at 100 A g^−1 and ultrafast charge/discharge rate up to 10 V s^−1.The related device can be charged up to 77.4%of its maximum capacitance in 0.65 s at 100 A g^−1 in 6 M KOH.It has been found that the 3DCF-DO has a great affinity to EMIMBF4,resulting in a high specific capacitance of 174 F g^−1 at 1 A g^−1,and a high energy density of 34 Wh kg^−1 at an ultrahigh power density of 150 kW kg^−1 at 4 V after a fast charge in 1.11 s.This work provides a facile fabrication of novel 3D carbon frameworks for supercapacitors with ultrafast charge/discharge rate and high energy-power density.
文摘Application of amorphous V2O5/carbon/ncodymium oxide (Nd2O3) composite is one ot ways to surmount me lower electrical conductivity of V2O5. A new type of V2O5/carbon/Nd2O3 composite was prepared by mixing vanadium oxide hydrosol, acetone, carbon and Nd2O3 powder. High rate discharge/charge property of the composite electrode was tested electrochemically. This composite with Nd2O3 added shows the improvement of not only the discharge capacity but also cycle durability discharge capacity. The rate capability of the composite cathode also increases with the addition of Nd2O3. Even at 10 A·g^-1 current density, a capacity of about 250 mAh·g^-1 was obtained at 25 ℃. This enhanced rate capability and cycle life are probably caused by the increase in porosity of open pores and short diffusion length of the active material on the lithium-ion insertion.
基金funding from the European Union Seventh Framework Programme (FP7/2007-2013) undergrant agreement No. 284863 (FP7 SEC GERYON)
文摘According to Cisco, mobile multimedia services now account for more than half the total amount of Internet traffic. This trend is burdening mobile devices in terms of power consumption, and as a result, more effort is needed to devise a range of pow- er-saving techniques. While most power-saving techniques are based on sleep scheduling of network interfaces, little has been done to devise multimedia content adaptation techniques. In this paper, we propose a multiple linear regression model that predicts the battery voltage discharge rate for several video send bit rates in a VoIP application. The battery voltage dis- charge rate needs to be accurately estimated in order to esti- mate battery life in critical VoIP contexts, such as emergency communication. In our proposed model, the range of video send bitrates is carefully chosen in order to maintain an acceptable VoIP quality of experience. From extensive profiling, the empir- ical resuhs show that the model effectively saves power and pro- longs real-time VoIP sessions when deployed in power-driven adaptation schemes.
基金The authors gratefully acknowledge the supports from the Research Grants Council of Hong Kong(Project number:CityU 21201119,CityU 11212620,CityU 11215621)City University of Hong Kong(Project number:9610408).
文摘Thermal battery plays an important role in renewable energy utilization towards carbon neutrality.The novel absorption thermal battery(ATB)has excellent performance but suffers from serious capacity attenuation.To address this problem,two capacity regulation methods,i.e.,variable solution flow and variable cooling water flow,are proposed to achieve a demanded discharging rate.The effects of the two regulation strategies on the dynamic discharging characteristics and overall storage performance are comparatively investigated.To demon-strate the adjustability of the output capacity,several stable discharging rates are successfully maintained by the proposed methods.To maintain a higher discharging rate,the stable discharging time has to be sacrificed.As the demanded output increased from 0.5 kW to 6.0 kW,the stable discharging time decreased from 781.8 min to 27.9 min under variable solution flow and from 769.9 min to 30.7 min under variable cooling water flow.With the increase of solution or water flow rate,the energy storage density is improved,while the energy storage efficiency is slightly increased first and decreased later.The regulation method of variable water flow shows relatively lower energy storage efficiency due to the larger pump power.This study could facilitate reasonable development and application of ATB cycles.
基金This work was financially supported by the Industrial Project of Science and Technology Office of Shannxi Prov-ince (2003K07G11)State Key Project of Education Ministry(104266)
文摘The structure and electrochemical properties of a new low cobalt hydrogen storage electrode alloys La1-xLixNi3.2Co0.3Al0.3 (0≤x≤0.2) were investigated with a different additions of Li in replacement of La. With the increase of Li contents the maximum discharge capacity increases from 240 mAh·g-1(x=0) to 328.4 mAh·g-1(x=0.1) and the cycle stability is improved correspondingly. The capacity decay can remain 28.6% (x=0.2) after 230 charge/discharge cycles. The high rate discharge(HRD) ability of the alloys(x≤0.1) is improved and the best HRD is 34.1%(x=0.1) under the discharge current density 1200 mA·g-1. It is found that the prepared alloys are basically composed of LaNi5 as matrix phase and LaNi3 as second phase(x≤0.1). But the abundance of LaNi3 phase dramatically decreases with increasing x. When x=0.2, a new phase Al(NiCo)3 is formed.
文摘This study examines the thermal runaway of a lithium ion battery caused by poor heat dissipation performances.The heat transfer process is analyzed on the basis of standard theoretical concepts.Water mist additives are considered as a tool to suppress the thermal runaway process.The ensuing behaviour of the battery in terms of surface temperature and heat generation is analyzed for different charge and discharge rates.It is found that when the remaining charge is 100%,the heat generation rate of the battery is the lowest,and the surface temperature with a 2C charge rate is higher than that obtained for a 0.5C charge rate.The experimental results show that when the additive concentration is 20%NaCl,its ability to inhibit the thermal runaway is the strongest.
文摘Based on isentropic flow and thermal equilibrium assumptions, a model was derived to calculate discharge flow rate, which unified the rules of room temperature water discharge, high temperature and high pressure water discharge, two-phase critical flow, saturated steam and superheated steam critical flow, and gave a method to calculate critical condition. Because of the influence of friction, the entropy is increased in the actual discharge process, and the discharge flow rate in thermal equilibrium condition can be obtained by the original model multiplied by an appropriate correction coefficient. The model calculated results agreed well with the experiment data of long nozzle critical flow.
基金Supported by the National Natural Science Foundation of China(51074096)
文摘The Li Ni1/3Co1/3Mn1/3O2 is first obtained by the controlled crystallization method and then coated with Ni3(PO4)2particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer(ICP) analysis and it testified to be 1:1:1. It is indicated that Ni3(PO4)2-coated Li Ni1/3Co1/3Mn1/3O2 has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy(EIS) results show that the current exchange density i0 of the coated sample is higher than that of Li Ni1/3Co1/3Mn1/3O2, which is beneficial to its electrochemical performances. All the conclusions show that the Ni3(PO4)2coating can prominently enhance the high rate performance of the Li Ni1/3Co1/3Mn1/3O2, especially at high cut-off voltage.
基金This work was supported by the National Natural Science Foundation of China(grant Nos.11972212,11902190,12072200,12002213)the Natural Science Foundation of Shanghai(grant No.20ZR1438800)Science and Technology Commission of Shanghai Municipality(grant No,19142201500).
文摘A lower granular temperature zone near the orifice in silos was found by speckle visibility spectroscopy technology.Surprisingly,the values of granular temperature in this area are inversely proportional to the mass discharge rate(MDR).This finding that links the macroscopic MDR with mesoscopic dynamics temperature of the particle system,is obtained by looking at the effect that different outlet sizes of silos on MDR and granular temperature field.Apart from evidencing the relevance of a parameter that has been traditionally overlooked in silos,this relationship supposes a benchmark with which to explore the influence of small orifice sizes on MDR.Among these,we found that the frequency of intermittent clogging and their dependence on the size of the outlet.
基金supported by the Laboratory of Lingnan Modern Agriculture Project(Grant No.NT2021009)the Project of key R&D program of Guangzhou of China(Grant No.202206010149)+2 种基金in part by Science and Technology Plan of Jian City of China(Grant No.20211-055316 and[2020]83)Science and Technology Plan of Guangdong Province of China(2023B10564002 and 2021B 1212040009)Innovative Research Team of Agricultural and Rural Big Data in Guangdong Province of China(2019KJ138)。
文摘Unmanned aerial vehicles(UAVs)are widely being used to spread granular fertilizer in China.Granular fertilizer spreaders equipped with UAVs are mainly centrifugal disc-type and pneumatic.The multichannel pneumatic granular fertilizer spreaders(MPGFSs)have a banded fertilizer deposition distribution pattern,which are more suitable for variable rate fertilization with high precision requirement than the circular deposition distribution pattern of disc-type granular fertilizer spreaders(DGFSs).However,the existing MPGFS has the disadvantage of inconsistent discharge rate of each channel,which affects the uniformity of fertilization.In order to explore the causes of inconsistent discharge rate of each channel,the discrete element method(DEM)and bench test were performed to analysis the discharge process of the fluted roller fertilizing apparatus and distribution of fertilizer in axial direction of fluted roller.The computational fluid dynamics(CFD)was used to simulate the airflow field of pneumatic system to analyze the influence of airflow on the movement of fertilizer particles.The simulation results of the discharge process of the fluted roller fertilizing apparatus showed that the filling velocity at the axial ends of the fluted roller fertilizing apparatus was lower than that of the middle.The reason was that the filling capacity was weak near the wall.The simulated results of the airflow field without partitions showed that the airflow provided by the axial flow fan was rotational,and this caused the particles to move irregularly in the throat,resulting in inconsistency discharge rate of each channel.Based on the analysis of reasons of inconsistent discharge rate of each channel,a MPGFS with partitions in the throat was developed.The discharge rate bench tests were carried out to optimize the partition spacing parameters,and fertilization test was performed to test the performance of the improved MPGFS.The discharge rate test results showed better consistency with partition.The coefficient of variation(CV)of the discharge rate of each channel was 20.16%without the partition and 7.70%with the optimal partition.The fertilizer spreading uniformity bench test results shown that the CV of spreading uniformity of MPGFS without partitions was 15.32%,and that MPGFS with partitions was 8.69%.The partitions design was beneficial to improve the consistency of each channel discharge rate and the uniformity of fertilization.The finding can provide a strong reference to design the MPGFS.
基金supported by the National Natural Science Foundation of China (50471011,50525101)
文摘For further improving the rate properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy,the alloy was annealed in high mag-netic fields(10 T).The results showed that the electrochemical properties and magnetic properties of Nd0.8Mg0.2(Ni0.8Co0.2)3.8 hydrogen storage alloy were considerably enhanced.And there was no change of the phase composition.The lattice constants of c and c/a ratio increased for the sample magnetically annealed,yielding uniaxial magnetic anisotropy along the c axis.The increase o...
基金support from the National Natural Science Foundation of China(grant No.51976130)Science and Technology Commission of Shanghai Municipality,China(grant No.13DZ2260900)。
文摘An experimental study on the gravity driven discharge of cohesive particles from a silo with two outlets was performed.The discharge behaviors under the conditions that a single outlet was open and two outlets were open were investigated by varying the moisture content of the particles and the filling height of the particles in the silo.The results show that the discharge rate of the cohesive particles increases gradually at the beginning,then almost keeps constant,and finally drops obviously.The discharge rate in case of two openings is around 1.1–1.6 times that in case of a single opening.Larger filling height leads to lower discharge rate in case of a single opening but results in higher discharge rate in case of two openings.Furthermore,the avalanche dynamics in case of a single opening was examined,and the mixing behavior of the cohesive particles was evaluated.It is observed that the discharge flow is promoted by the avalanche phenomenon in the silo,generating a general trend that the normalized mass of discharge increases with the filling height at higher moisture contents.In case of a single opening,the transition from mass flow to funnel flow favors the particle mixing,resulting in an increasing mixing index as the moisture content increases.In general,a better performance of mixing can be achieved in case of a single opening compared with in case of two openings.This study provides vital information for fundamental understanding of the gravity driven discharge of cohesive particles from the silo with multiple outlets.
基金This work is supported financially by the National Natural Science Foundation of China, grant No. 21576265. Xiaoxing Liu acknowledges the financial support from the Hundred Talents Pro- gram of Chinese Academy of Sciences.
文摘Granular material discharge from a flat-bottomed silo has been simulated by using continuum modeling and a three-dimensional discrete-element method (DEM). The predictive abilities of three commonly used frictional viscosity models (Schaeffer, S-S, and μ(I)) were evaluated by comparing them with the DEM data. The funnel-flow pattern (type C) and the semi-mass-flow pattern (type B) that was predicted by DEM simulations can be represented when the Schaeffer orμ(I) model is used, whereas the S-S model gives a consistent type-B flow pattern. All three models over-estimate the discharge rate compared with the DEM. The profiles of the solids volume fraction and the vertical velocity above the outlet show that the larger discharge rates given by the Schaeffer and μ(I) model result from an over-estimation of volume fraction, whereas the deviation in the S-S model stems from the failure to predict a solid vertical velocity and a volume fraction.
基金financially supported by State Key Laboratory of Advanced Metals and Materials(No.2011-ZD06)Beijing Municipal Science and Technology Commission(No.Z131100003213019)+1 种基金the RiXin Talents Plan of Beijing University of Technology(2014-RX-L07)Beijing Natural Science Foundation(No.2144043)
文摘The present study aims to improve electrochemical properties of the La-Mg-Ni-based hydrogen storage alloys through partial substitution for La by mischmetal(MM).The La_(0.8-x)MM_xMg_(0.2)Ni_(3.1)Co_(0.3)Al_(0.1)(x=0,0.1,0.2,0.3)alloys were prepared by inductive melting,and their phase structures and electrochemical properties were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),energy-dispersive X-ray spectrometry(EDX)and electrochemical tests.Results show that the alloys mainly consist of La_2Ni_7-type phase,La_5Ni_(19)-type phase,LaNi_5-type phase and LaNi_3-type phase.The addition of MM does not change the phase compositions,while it leads to more uniform phase distribution and obviously promotes the formation of La_2Ni_7-type phase which possesses favorable electrochemical properties.Electrochemical studies indicate that the substitution for La by MM could effectively improve the high rate dischargeability(HRD)of the alloy electrode,and the optimal value of HRD_(1500)(HRD at 1500 mA·g^(-1))increases from 40.63%(x=0)to 60.55%(x=0.3).Although the activation properties of the alloy electrodes keep almost unchanged,both the maximum discharge capacity(C_(max))and the cycling stability are significantly improved by MM addition.
文摘Borehole thermal energy storage(BTES)systems have garnered significant attention owing to their efficacy in storing thermal energy for heating and cooling applications.Accurate modeling is paramount for ensuring the precise design and operation of BTES systems.This study conducts a sensitivity analysis of BTES modeling by employing a comparative investigation of five distinct parameters on a wedge-shaped model,with implications extendable to a cylindrical configuration.The parameters examined included two design factors(well spacing and grout thermal conductivity),two operational variables(charging and discharging rates),and one geological attribute(soil thermal conductivity).Finite element simulations were carried out for the sensitivity analysis to evaluate the round-trip efficiency,both on a per-cycle basis and cumulatively over three years of operation,serving as performance metrics.The results showed varying degrees of sensitivity across different models to changes in these parameters.In particular,the round-trip efficiency exhibited a greater sensitivity to changes in spacing and volumetric flow rate.Furthermore,this study underscores the importance of considering the impact of the soil and grout-material thermal conductivities on the BTES-system performance over time.An optimized scenario is modelled and compared with the base case,over a comparative assessment based on a 10-year simulation.The analysis revealed that,at the end of the 10-year period,the optimized BTES model achieved a cycle efficiency of 83.4%.This sensitivity analysis provides valuable insights into the merits and constraints of diverse BTES modeling methodologies,aiding in the selection of appropriate modeling tools for BTES system design and operation.