Co-Mo-based catalysts supported on mixed oxide supports MgO-Al2O3 with different Mg/Al atom ratios for water gas shift reaction were studied by means of TPR, Raman, XPS and ESR. It was found that the octahedral Mo spe...Co-Mo-based catalysts supported on mixed oxide supports MgO-Al2O3 with different Mg/Al atom ratios for water gas shift reaction were studied by means of TPR, Raman, XPS and ESR. It was found that the octahedral Mo species in oxidized Co-Mo/MgO（x）-Al2O3 catalyst and the contents of Mo^5＋, Mo^4＋, S^2- and S^2-2 species in the functioning catalysts increased with increasing the Mg/Al atom ratio of the support under the studied experimental conditions. This is favorable for the formation of the active Co-Mo-S phase of the catalysts. Catalytic performance testing results showed that the catalysts Co-Mo/MgO-Al2O3 with the Mg/Al atom ratio of the support in the range of 0.475-0.525 exhibited optimal catalytic activity for the reaction.展开更多
The available studies in the literature on physical and mathematical modeling of the argon oxygen decarburization (AOD) process of stainless steel have briefly been reviewed. The latest advances made by the author wi...The available studies in the literature on physical and mathematical modeling of the argon oxygen decarburization (AOD) process of stainless steel have briefly been reviewed. The latest advances made by the author with his research group have been summarized. Water modeling was used to investigate the fluid flow and mixing characteristics in the bath of an 18 t AOD vessel, as well as the 'back attack' action of gas jets and its effects on the erosion and wear of the refractory lining, with sufficiently full kinematic similarity. The non rotating and rotating gas jets blown through two annular tuyeres, respectively of straight tube and spiral flat tube type, were employed in the experiments. The geometric similarity ratio between the model and its prototype (including the straight tube type tuyeres) was 1:3. The influences of the gas flow rate, the angle included between the two tuyeres and other operating parameters, and the suitability of the spiral tuyere as a practical application, were examined. These latest studies have clearly and successfully brought to light the fluid flow and mixing characteristics in the bath and the overall features of the back attack phenomena of gas jets during the blowing, and have offered a better understanding of the refining process. Besides, mathematical modeling for the refining process of stainless steel was carried out and a new mathematical model of the process was proposed and developed. The model performs the rate calculations of the refining and the mass and heat balances of the system. Also, the effects of the operating factors, including adding the slag materials, crop ends, and scrap, and alloy agents; the non isothermal conditions; the changes in the amounts of metal and slag during the refining; and other factors were all considered. The model was used to deal with and analyze the austenitic stainless steel making (including ultra low carbon steel) and was tested on data of 32 heats obtained in producing 304 grade steel in an 18 t AOD vessel. The changes in the bath composition and temperature during the refining process with time can be accurately predicted using this model. The model can provide some very useful information and a reliable basis for optimizing the process practice of the refining of stainless steel and control of the process in real time and online.展开更多
文摘Co-Mo-based catalysts supported on mixed oxide supports MgO-Al2O3 with different Mg/Al atom ratios for water gas shift reaction were studied by means of TPR, Raman, XPS and ESR. It was found that the octahedral Mo species in oxidized Co-Mo/MgO（x）-Al2O3 catalyst and the contents of Mo^5＋, Mo^4＋, S^2- and S^2-2 species in the functioning catalysts increased with increasing the Mg/Al atom ratio of the support under the studied experimental conditions. This is favorable for the formation of the active Co-Mo-S phase of the catalysts. Catalytic performance testing results showed that the catalysts Co-Mo/MgO-Al2O3 with the Mg/Al atom ratio of the support in the range of 0.475-0.525 exhibited optimal catalytic activity for the reaction.
文摘The available studies in the literature on physical and mathematical modeling of the argon oxygen decarburization (AOD) process of stainless steel have briefly been reviewed. The latest advances made by the author with his research group have been summarized. Water modeling was used to investigate the fluid flow and mixing characteristics in the bath of an 18 t AOD vessel, as well as the 'back attack' action of gas jets and its effects on the erosion and wear of the refractory lining, with sufficiently full kinematic similarity. The non rotating and rotating gas jets blown through two annular tuyeres, respectively of straight tube and spiral flat tube type, were employed in the experiments. The geometric similarity ratio between the model and its prototype (including the straight tube type tuyeres) was 1:3. The influences of the gas flow rate, the angle included between the two tuyeres and other operating parameters, and the suitability of the spiral tuyere as a practical application, were examined. These latest studies have clearly and successfully brought to light the fluid flow and mixing characteristics in the bath and the overall features of the back attack phenomena of gas jets during the blowing, and have offered a better understanding of the refining process. Besides, mathematical modeling for the refining process of stainless steel was carried out and a new mathematical model of the process was proposed and developed. The model performs the rate calculations of the refining and the mass and heat balances of the system. Also, the effects of the operating factors, including adding the slag materials, crop ends, and scrap, and alloy agents; the non isothermal conditions; the changes in the amounts of metal and slag during the refining; and other factors were all considered. The model was used to deal with and analyze the austenitic stainless steel making (including ultra low carbon steel) and was tested on data of 32 heats obtained in producing 304 grade steel in an 18 t AOD vessel. The changes in the bath composition and temperature during the refining process with time can be accurately predicted using this model. The model can provide some very useful information and a reliable basis for optimizing the process practice of the refining of stainless steel and control of the process in real time and online.
