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Preparation and Properties of Lanthanum Trivalent Ion Doped TiO_2 Nanopowders by Liquid Plasma Spray 被引量:1
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作者 徐大鹏 冯拉俊 +1 位作者 雷阿利 朱广 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第S1期570-574,共5页
The lanthanum trivalent ion doped TiO2 nanopowders were prepared by liquid plasma spray with solution of titanium tetra-tert-butoxide and alcohol as feedstock and La(NO3)3·6H2O as doping component. The photocatal... The lanthanum trivalent ion doped TiO2 nanopowders were prepared by liquid plasma spray with solution of titanium tetra-tert-butoxide and alcohol as feedstock and La(NO3)3·6H2O as doping component. The photocatalytic activity of samples at different doping concentrations in photocatalytic degradation of methyl orange was discussed. The powders were characterized by Transmission Electron Microscopy (TEM) and X-Ray Diffraction (XRD), and the effect of doped ion on the pattern, phase composition and crystallite sizes were analyzed. The results indicated that lanthanum trivalent ion doped TiO2 nanopowders could be prepared by liquid plasma spray. Lanthanum trivalent ion doping increased the photocatalytic activity of TiO2 greatly, the optimal doping concentration was 0.5%. The doped powders were the mixture of anatase phase and rutile phase. The contents of anatase phase decreased firstly and then increased with an increase in the contents of lanthanum trivalent ion. Doping lanthanum trivalent ion could make the TiO2 nanopowders uniform and reduced its particle size. 展开更多
关键词 TiO_2 photocatalyst liquid plasma spray lanthanum trivalent ion doping rare earths
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