Wormholes propagation for fractured-vuggy formation:Laboratory tests,numerical simulation and field application

The propagation of wormhole is vital important for matrix acidizing and acid fracturing in carbonate reservoirs.While the formation of acid dissolved wormhole is derived from heterogeneous physical and chemical transportations and reactions.Alveolate dissolved pores,krast caves,and natural fissures are the major reservoir spaces for the Sinian dolomite formation in the Anyue gas field of the Sichuan Basin.There were four categories of formation,which are matrix dominated,inter-breccia dissolved pore dominated,dissolved pore and cave dominated,and fissure and cave dominated,based on the development intensity and connectedness of caves and fissures.The caves and fissures make the wormhole formation and propagation particularly complicated.Firstly,the 3-D topological structure of dissolved pores,vugs,fissures and throats inside cores is quantitatively scanned by CT imaging technology for its feature of vivid and damage-free.Secondly,3-D patterns of wormhole are obtained with CT scanning after core flooding by acid.Additionally,the porethroat network model is reconstructed with digital cores technology.Then,the size and ratio of pore and throat before and after core flooding by acid is analyzed and the absolute permeability of pore scale flow is numerically simulated to understand the fundamental influence of pores and vugs distribution and connectedness on wormhole propagation.Lastly,the wormhole pattern gained by CT scanning and simulating with two-scale model is compared.Meanwhile,the corrected two-scale model is utilized to simulate the wormhole propagation for matrix acidizing and acid fracturing of Sinian fractured-vuggy dolomite in Anyue gas field,Sichuan Basin.The optimized injection rate and volume were in agreement with the characteristic matrix acidizing operating curve,which indicates that the two-scale model was suitable for matrix acidizing optimization design of such formations.In addition,the simulated acid etched fracture length with considering the dynamic wormhole leakoff was consistent with the well testing interpreted result.

Preparation and characterization of Pd/Fe bimetallic nanoparticles immobilized on Al_2O_3/PVDF membrane:Parameter optimization and dechlorination of dichloroacetic acid

Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy（SEM） and Transmission Electron Microscopy（TEM）. The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid（DCAA） dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.