Structure and Thermal Parameters of Ni_(20)Pd_(80) Alloy

The structure and thermal parameters of Ni20Pd80 alloy were studied by X-ray diffraction（XRD）. The diffraction experiments performed in the temperature range of 308-1100 K revealed that the alloy formed a face centered cubic （fcc） Al-type structure. The temperature dependence of the lattice parameters was investigated by using the Bragg line displacement method showing that the lattice parameter increases with the increase of temperature. The mean linear thermal expansion （MLTE（%））, coefficient of thermal expansion （CTE, α）, the characteristic Debye temperature （（θD） and mean square amplitudes of vibration were determined from XRD data. The value of Debye temperature was found to be 253 K. It was found that temperature factor was independent of the static displacements.

Parameterizing soil organic carbon's impacts on soil porosity and thermal parameters for Eastern Tibet grasslands

This study investigates the stratification of soil thermal properties induced by soil organic carbon (SOC) and its impacts on the parameterization of the thermal properties. Soil parameters were measured for alpine grassland stations and North China flux stations, with a total of 34 stations and 77 soil profiles. Measured data indicate that the topsoils of alpine grasslands contain high SOC contents than underlying soil layers, which leads to higher soil porosity values and lower thermal conductivity and bulk density values in the topsoils. However, this stratification is not evident at the lowland stations due to low SOC contents. Evaluations against measured data show that three thermal conductivity schemes used in land surface models severely overestimate the values for soils with high SOC content (i.e. topsoils of alpine grassland), but they are better for soils with low SOC content. A new parameterization is then developed to take the impacts of SOC into account. The new one can well estimate the soil thermal conductivity values in both low and high SOC content cases, and therefore, it is a potential candidate of thermal conductivity scheme to be used in land surface models.

Microstructure and Thermal Physical Parameters of Ni60-Cr_3C_2 Composite Coating by Laser Cladding

To satisfy performance and long life requirements for hot forging die,Ni60-Cr3C2 composite coatings were prepared on the high-speed steel W6Mo5Cr4V2 using laser cladding technology.Laser clad coatings with different ratios of Ni60：Cr3C2 were investigated by scanning electron microscopy（SEM）,X-ray diffraction（XRD）,energy-dispersive X-ray analysis（EDX） and micro-hardness tester,respectively.Specific heat capacity and thermal conductivity were measured by Laser Thermal Constant Meter.Thermal expansion coefficient and elastic modulus were measured by Dynamic Mechanical Thermal Analyzer and Electro-Hydraulic Servocontrolled Testing System,respectively.The results indicated that Ni60＋50wt% Cr3C2 composite coating had dense and homogeneous structure,as well as a metallurgical bonding with the substrate.With the increase of Cr3C2 content,volume of chromium-containing compounds in the composite coating increased,microhardness increased and microstructure refined.The thermal physical parameters results showed that Ni60＋50wt% Cr3C2 composite coating was overall worse than W6Mo5Cr4V2,but had a higher hot yield strength to alleviate hot fatigue and surface hot wear of hot forging die during hot forging and thus improve the service life of hot forging die.

Sensitivity Analysis of Thermal Equilibrium Parameters of MIKE 11 Model:A Case Study of Wuxikou Reservoir in Jiangxi Province of China

Sensitivity analysis of thermal equilibrium parameters in the reservoir module of MIKE 11 model was conducted for the Wuxikou Reservoir in Jiangxi Province of China in order to apply the module to the environmental impact assessment to accurately predict water temperature of reservoirs.Results showed that radiation parameter A and evaporation-first parameter were much more sensitive than other parameters.The values of the radiation parameter A ranged from 0.10 to 0.34.The values of evaporation-first parameter varied from 0 to 10.The sensitivity of solar absorption parameters was less than that of evaporation parameter,of which light attenuation values ranged from 0.5 to 0.7,and this parameter would not impact model results if it was more than 2.Constants in Beer's law ranged from 0.2 to 0.7.Radiation parameter B was not more sensitive than evaporation parameter and its reasonable range was higher than 0.48.The fitting curves showed consistent changing tendency for these parameters within the reasonable ranges.Additionally,all the thermal equilibrium parameters had much more important effects on surface water temperature than deep water temperature.Moreover,if no observed data could be obtained,the local empirical value would be used to input to the MIKE 11 model to simulate the changes in the discharged outflow-water temperature qualitatively.

Parameterized thermal model of a mixed mantle convection

Simple parameterized models, either whole mantle convection or layered mantleconvection, cannot explain the tectonic characteristics of the Earth's evolution history, therefore a mixed mantle convection model has been carried out in this paper. We introduce a time-dependent parameter F, which denotes the ratio betWeen the mantle material involved in whole mantle convection and the material of the entire mantle, and introduce a local Rayleigh number Raloc as well as two critical numbers Ra1 and Ra2. These parameters are used to describe the stability of the phase boundary between the upper and lower mantle. The result shows that the mixed mantle convection model is able to simulate the episodic tectonic evolution of the Earth.

Calculation of thermal physical parameters of dissociated air by the dissociation degree method

The high temperature gas occurs behind shock or near the wall surface of vehicle in the hypersonic flight. As the temperature exceeds 2 000 K, 4 000 K, respectively, O2 and N2 molecules are successively dissociated. Because of variable components at dif- ferent temperatures and pressures, the dissociated air is no longer a perfect gas, In this paper, a new method is developed to calculate accurate thermal physical parameters with the dissociation degree providing the thermochemical equilibrium procedure. Based on the dissociation degree, it is concluded that few numbers of equations and the solutions are easily obtained. In addition, a set of formulas relating the parameter to the dissociation degree are set up four-species, O2 molecule The thermodynamic properties of dissociated air containing and N2 molecule, O atom and N atom, are studied with the new method, and the results are consistent with those with the traditional equilibrium constant method. It is shown that this method is reliable for solving thermal physical parameters easily and directly.

Properties and appropriate conditions of stress reduction factor and thermal shock resistance parameters for ceramics

Through introducing the analytical problem of the plate with convection into the solution of the transient heat conduction thermal stress field model of the elastic plate, the stress reduction factor is presented explicitly in its dimensionless form. A new stress reduction factor is introduced for the purpose of comparison. The proper- ties and appropriate conditions of the stress reduction factor, the first and second ther- mal shock resistance （TSR） parameters for the high and low Biot numbers, respectively, and the approximation formulas for the intermediate Blot number-interval are discussed. To investigate the TSR of ceramics more accurately, it is recommended to combine the heat transfer theory with the theory of thermoelasticity or fracture mechanics or use a numerical method. The critical rupture temperature difference and the critical rup- ture dimensionless time can be used to characterize the TSR of ceramics intuitively and legibly.

Thermal and piezoelectric properties of Bi_(3.15)Nd_(0.85)Ti_3O_(12) thin film prepared by metal organic decomposition

Bi3.15Nd0.85Ti3O12 （BNT） powder and thin film were prepared by metal organic decomposition （MOD） method. The heat flow curve of BNT powder was measured with a modulated temperature differential scanning calorimeter, and thermal physical parameters such as thermal conductivity coefficient and thermal diffusion coefficient were obtained from the heat flow curve. The phase identification, ferroelectric, and piezoelectric properties of BNT thin film annealed at 700℃ were investigated with X-ray diffractometer, ferroelectric analyzer, and scanning probe microscope. The results show that the thin films consisting of a single phase of bismuth-layered perovskite are polycrystalline, without a preferred orientation. Remnant polarization 2Pr is 63.2 μC/cm2 under 530 kV/cm applied field, and the effective piezoelectric coefficient d33 is 30 pm/V.

Influence of Prospecting and Crude Oil Production on Geoecological Parameters of Permafrost

The large reserves ofoil are disposed in zones of permafrost in shelf and continental fields. In Europe the subarctic and arctic tundra are abundant only in Nenetsky autonomous area and in the north-east of the republic of Komi. Oil and gas production activity has threatened richest biological resources and health of the population of the region. A singularity of petroliferous fields of the north of Russia is the existence of the thick strata of permafrost. On top of them different heat-insulating overlying layers （snow, biogenic covers） reside. State and dynamics of permafrost cause progressing dangerous exogenic geoecological processes, which are exhibited completely. State of permafrost is instituted by exchange of heat in near-surface strata of a geological section. During the development of oil fields there is a disturbance of a temperature schedule of permafrost. For estimation of technical attack the analytical computational method of influence of the different factors on value of annual heat exchange and prediction of geocryological conditions is proposed. It is shown, that such dangerous phenomena as degradation of permafrost and thermokarst would develop in the first place, which would cause the destruction of natural ecosystems.

Distribution of sterane maturity parameters in a lacustrine basin and their control factors:A case study from the Dongying Sag,East China

Fifty samples from the source rocks in Member 3 and Member 4 of the Paleogene Shahejie Formation in the Bohai Bay Basin, East China, were analyzed to investigate the distribution, evolution of the molecular maturity ratios C29ββ/（ββ＋αα） and C2920S/（20S＋20R） and their control factors in the natural geological profile and sequence. The results showed that progressive changes in molecular maturity parameters are associated with major changes in thermal evolution of related biomarkers. Increases in the C29ββ/（ββ＋αα） and C2920S/（20S＋20R） ratios result from the difference in the relative rate between generation and thermal degradation of isomers involved. The samples from a hyper-saline environment below 3.5 km in which evaporitic rocks deposited shows high response of Sr/Ba, Sr/Ca, Fe/ Mn, Pr/n-C17, Ph/n-C18 and gammacerane and low response of Pr/Ph. There presents negative reversal of biomarker maturity C29ββ/（ββ＋αα, C29ββ/（ββ＋αα） and Ts/（Ts＋Ym） in the samples from hypersaline environment, reflecting that the gypsum- halite have negative effect on the isomerization of biomarker and thermal evolution of organic matter. The minerals in evaporites also retard the conventional thermal indicators including vitrinite reflectance （Ro） and pyrolysis peak temperature Tmax at the depth below 3.4 km （i.e. 〉3.4 km）, and these parameters also show the inhibition from overpressure in the range of 2.4-3.4 kin. This result will be helpful in the interpretation and application of molecular maturity parameters for similar saline lacustrine basins.

Head Curvature of Pure Titanium Sheet Influenced by Process Parameters and Controlling in Hot Rolling Process

We investigated the influences of process parameters on the head curvature of pure titanium sheet in hot rolling process and proposed the controlling means. First, the thermal simulation experiments for pure titanium TA1 were carried out to investigate the hot deformation behaviors of pure titanium in the temperature range of 700-800 ℃ with strain rate range of 1-20 S-1, and the processing map was established to determine optimized deformation parameters. Then, the finite element model has been constructed and used to analyze the effect of process parameters on the direction and severity of head curvature of pure titanium sheet. The process parameters considered in the present study include workpiece temperature, work roll diameter, pass reduction, oxide scale thickness of workpiece surface, and interface friction coefficient. The simulation results show that the workpiece temperature and the interface friction coefficient are the two main factors. The proposed controlling means was carried out on a hot rolling production line and solved the head curvature problem effectively. The rolling practices indicate that the rolling yield is improved greatly.

Calibration of Discrete Element Heat Transfer Parameters by Central Composite Design

The efficiency and precision of parameter calibration in discrete element method （DEM） are not satisfactory, and parameter calibration for granular heat transfer is rarely involved. Accordingly, parameter calibration for granular heat transfer with the DEM is studied. The heat transfer in granular assemblies is simulated with DEM, and the effective thermal conductivity （ETC） of these granular assemblies is measured with the transient method in simulations. The measurement testbed is designed to test the ETC of the granular assemblies under normal pressure and a vacuum based on the steady method. Central composite design （CCD） is used to simulate the impact of the DEM parameters on the ETC of granular assemblies, and the heat transfer parameters are calibrated and compared with experimental data. The results show that, within the scope of the considered parameters, the ETC of the granular assemblies increases with an increasing particle thermal conductivity and decreases with an increasing particle shear modulus and particle diameter. The particle thermal conductivity has the greatest impact on the ETC of granular assemblies followed by the particle shear modulus and then the particle diameter. The calibration results show good agreement with the experimental results. The error is less than 4%, which is within a reasonable range for the scope of the CCD parameters. The proposed research provides high efficiency and high accuracy parameter calibration for granular heat transfer in DEM.

Evaluation on the Thermal Stability and Hazards Behaviors of ADVN Using Green Thermal Analysis Approach

ADVN （2,2＇-Azobis （2,4-dimethyl） valeronitrile）, a free radical initiator, is widely applied for the polymerization reaction of polymers in the chemical industries. When ADVN releases free radical during the decomposition process, it can accompany abundant heat and huge pressure to increase the possibility of thermal runaway and hazard, causing unacceptable thermal explosion or fire accidents. To develop an inherently safer process for ADVN, the thermal stability parameters of ADVN were obtained to investigate thermal decomposition characteristics using a DSC （differential scanning calorimetry） and TG （thermogravimetry）. We used various kinetic models to completely depict the kinetic behavior and determine the thermal safety parameters for ADVN. The green thermal analysis approach could be used to substitute for complicated procedures and large-scale experiments of traditional thermal analysis methods, avoiding environmental pollution and energy depletion.

Finite Element Simulation of Thermal Field in Double Wire Welding

In this paper, the thermal field of double wire welding is simulated by using ANSYS software. Simulation results were shown that the total heat input (E) is the most significant parameters to change the value of t8/5;By the mean of rationally controlling the proportion of the front arc heat input (E1) in the total heat input (E) and appropriately selecting double wire spacing (L), It is effective means to get the double wire welding thermal cycle. By the way of simulation, it is possible to manage the thermal input in the double welding wires and to control the temperature field and cooling rate that are fundamental for the final joint quality, it is great importance guidance to optimize the double wire welding process parameters.

面对面角接触球轴承装置热力耦合仿真分析

在研究轴承时为了方便计算简化模型,一般将组合装置中的两个轴承简化成一个轴承进行分析,这样会带来一定的误差,因此这里分析了面对面球轴承组合装置中两个轴承的热特性耦合。这里首先分析了角接触球轴承的摩擦力矩,根据混合润滑机理,考虑了混合热阻影响,计算了轴承在发生摩擦时生成的热量,通过ANSYS的APDL命令流将进行参数化建模,建立了面对面轴承组合装置仿真模型,再利用APDL命令流循环计算出组合装置不同时刻下的温度场和在不同时刻温度场下的热膨胀诱导的力,从而分析出组合装置中的两个轴承预紧力和发热量的时变耦合特性。实验结果表明,这里模型与实验数据吻合,验证了本模型的正确性。

状态方程参数化耦合制冷工质热导率性质预测模型

针对准确的制冷工质热导率性质有益于制冷热泵系统的设计和优化,引入标准化参数化方案,得到扰动链统计缔合流体理论状态方程(PC-SAFT)的输入参数,结合剩余熵标度理论(RES),预测了包括氢氟烯烃(HFOs)、氢氟烃(HFCs)、烷烃(HCs)和CO_(2)(R744)在内的11种常见制冷工质的热导率性质,使用自助法,获得了标准化参数化方案与常规参数化方案输入参数的不确定度,并展开不确定度分析。通过与文献实验结果及已报道热导率性质模型比对,所提热导率性质模型与实验数据的总体平均相对偏差为3.32%。结果表明:所提热导率性质预测模型的整体表现优于常规参数化热导率模型和CE参考项热导率模型,且标准化参数化方案有潜力为混合工质体系的研发和推广提供可靠的基础物性数据;两种参数化方案输入参数在不确定度范围内波动时,对气相迁移性质的预测影响程度相似,但标准化参数化方案在液相迁移性质的预测上表现更优;此外,基于标准化参数化方案预测迁移性质需特别关注偏心因子的精度。

青藏高原中部土壤热传导率参数化方案的确立及在数值模式中的应用

本文针对模式发展的需要,在Farouki土壤热传导率参数化方案的基础上,综合Johansen和C(?)té的参数化方案,发展了一个用于青藏高原中部的土壤热传导率参数化方案,用"全球协调加强观测计划之亚澳季风青藏高原试验计划(CAMP/Tibet)"中那曲布交(BJ)站实际资料对该方案进行了检验,并将它用于公共陆面模式(CoLM)中,对青藏高原那曲地区进行了单点数值模拟试验.结果表明:在未冻结及冻结土壤中,新方案比Farouki方案计算的土壤热传导率小,更接近实测值.加入新方案的CoLM模式对土壤温度模拟的准确性比原模式有一定的提高.

火星和月球热历史的参量化模型研究

通过类地行星热历史的比较研究，可以更全面地了解它们的热演化过程．火星和月球不具有板块构造，研究它们的热演化过程时，考虑了岩石层逐渐加厚对行星内部对流的影响，同时也考虑了由对流传热转变为传导传热对它们热历史的影响．参量化模型计算结果表明：火星和月球岩石层随温度的逐渐降低目前大约分别增厚到320km和250km左右;并且，火星幔和月幔分别于1．6Ga前和3Ga前停止热对流，这与天文和空间探测资料一致．

Crystallization Behaviour and Mechanical Properties of Zr_(65)Cu_(18)Ni_9Al_8 Bulk Metallic Glass

Designing and synthesis of cost effective bulk metallic glasses （BMGs） has been of considerable interest during the last decade so that they can be made commercially viable. Among these, Zr-based BMGs have been reported extensively due to their attractive properties, An alloy having composition Zr65Cu18Ni9A18 was designed and synthesized using 2-3 N pure materials by Cu mould casting. The alloy was characterized by X- ray diffraction （XRD）, scanning electron microscopy （SEM）, energy dispersive X-ray spectroscopy （EDS） and high temperature differential scanning calorimetry （DSC）. Thermal parameters like supercooled liquid region △Tx, reduced glass transition temperature Trg, γ and δ parameters were evaluated. Mechanical properties like microhardness, nanohardness, elastic modulus and fracture strength were measured. The alloy showed wide supercooled liquid region of 129＋1 K with improved thermal stability. The alloy has considerable fracture strength along with fair amount of ductility.

太湖对周边城市热环境影响的模拟

太湖微气候条件及局地热环境的研究对于太湖周边城市地区可持续发展以及大气宏观调控具有重要意义。为了更准确模拟太湖湖-气交换,将CLM4-LISSS浅水湖泊陆面过程参数化方案耦合进入WRF中的Noah陆面过程模型。采用太湖湖上平台及岸边陆上测站观测的数据,评估了CLM4-LISSS浅水湖泊过程方案对太湖区域近地层气象条件的模拟性能。并基于耦合模型模拟研究了太湖对周边城市区域热环境的影响。结果表明,CLM4-LISSS湖泊陆面过程方案模拟的湖表面温度能反映真实温度的变化趋势。两种陆面过程方案在2 m气温的模拟值也存在一定的差异。CLM4-LISSS与Noah方案计算所得湖上2 m气温的模拟值与观测值的平均均方根误差分别为1.77和2.22℃,平均相关系数分别为0.88和0.84;模拟10 m风速的平均均方根误差分别为1.93和2.78 m/s,平均相关系数为0.72和0.68。太湖对周边城市热环境存在明显的影响。8月太湖对周边地区15时(北京时)近地层平均降温0.5—0.7℃,影响范围达60 km。06时太湖导致周边近地层平均升温达0.7—1℃,影响范围达50 km。湖风带来的冷空气抑制了城市热岛的垂直运动,在高温天气下使得苏州、无锡和常州城市地区昼间边界层下降高度可达300、400和100 m。无锡地区边界层内气温最高降幅可达0.5—0.7℃。通过选取无锡地区2015年8月28日高温小风天气作为背景条件,分析该地区湖风对城市热岛环流的影响机制。结果表明湖风能够破坏无锡地区的热岛环流结构,改变近地面热量和水汽的分布,抑制城市热岛的垂直发展,并影响至整个无锡地区。局地热力环流的变化对于局地气候以及污染物质的输送与扩散有可能产生重要影响,准确的湖泊陆面过程参数化方案对于天气预报、空气污染模拟,以及气候模拟研究等均具有重要意义。