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Current optimization-based control of dual three-phase PMSM for low-frequency temperature swing reduction
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作者 Linlin Lu Xueqing Wang +3 位作者 Luhan Jin Qiong Liu Yun Zhang Yao Mao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期238-246,共9页
In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperatur... In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction. 展开更多
关键词 Dual three-phase PMSM Low-frequency temperature swing Copper loss Current optimization Connected neutral points
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Mathematical Simulation and Design of Three-Phase Bubble Column Reactor for Direct Synthesis of Dimethyl Ether from Syngas 被引量:3
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作者 Dianhua Liu Xing Hua Dingye Fang 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第2期193-199,共7页
A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas, considering both the influence of part inert c... A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows: diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger (Ф 38×2 mm), and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04. 展开更多
关键词 dimethyl ether SYNGAS three-phase reactor DME synthesis slurry bed mathematical simulation model
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Deciphering engineering principle of three-phase interface for advanced gas-involved electrochemical reactions 被引量:2
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作者 Yanzheng He Sisi Liu +3 位作者 Mengfan Wang Qiyang Cheng Tao Qian Chenglin Yan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第5期302-323,I0008,共23页
As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen e... As an alternative to conventional energy conversion and storage reactions,gas-involved electrochemical reactions,including the carbon dioxide reduction reaction(CO_(2)RR),nitrogen reduction reaction(NRR)and hydrogen evolution reaction(HER),have become an emerging research direction and have gained increasing attention due to their advantages of environmental friendliness and sustainability.Various studies have been designed to accelerate sluggish kinetics but with limited results.Most of them promote the reaction by modulating the intrinsic properties of the catalyst,ignoring the synergistic effect of the reaction as a whole.Due to the introduction of gas,traditional liquid-solid two-phase reactions are no longer applicable to future research.Since gas-involved electrochemical reactions mostly occur at the junctions of gaseous reactants,liquid electrolytes and solid catalysts,the focus of future research on reaction kinetics should gradually shift to three-phase reaction interfaces.In this review,we briefly introduce the formation and constraints of the three-phase interface and propose three criteria to judge its merit,namely,the active site,mass diffusion and electron mass transfer.Subsequently,a series of modulation methods and relevant works are discussed in detail from the three improvement directions of‘exposing more active sites,promoting mass diffusion and accelerating electron transfer’.Definitively,we provide farsighted insights into the understanding and research of three-phase interfaces in the future and point out the possible development direction of future regulatory methods,hoping that this review can broaden the future applications of the three-phase interface,including but not limited to gas-involved electrochemical reactions. 展开更多
关键词 three-phase reaction Surface reactions Mass diffusion Electron transfer Gas-involved electrochemical reactions
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Electrical characteristics of new three-phase traction power supply system for rail transit 被引量:1
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作者 Xiaohong Huang Hanlin Wang +4 位作者 Qunzhan Li Naiqi Yang Tao Ren You Peng Haoyang Li 《Railway Engineering Science》 2023年第1期75-88,共14页
A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.... A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%. 展开更多
关键词 three-phase AC power supply Two-stage power supply structure Electrical characteristics Current distribution Voltage losses Regenerative energy
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Application of CD34 expression combined with three-phase dynamic contrast-enhanced computed tomography scanning in preoperative staging of gastric cancer 被引量:1
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作者 Hua Liu Kang-Yan Zhao 《World Journal of Gastrointestinal Surgery》 SCIE 2023年第11期2513-2524,共12页
BACKGROUND Accurate preoperative staging of gastric cancer(GC),a common malignant tumor worldwide,is critical for appropriate treatment plans and prognosis.Dynamic three-phase enhanced computed tomography(CT)scanning ... BACKGROUND Accurate preoperative staging of gastric cancer(GC),a common malignant tumor worldwide,is critical for appropriate treatment plans and prognosis.Dynamic three-phase enhanced computed tomography(CT)scanning for preoperative staging of GC has limitations in evaluating tumor angiogenesis.CD34,a marker on vascular endothelial cell surfaces,is promising in evaluating tumor angiogenesis.We explored the value of their combination for preoperative staging of GC to improve the efficacy and prognosis of patients with GC.Medical records of 106 patients with GC treated at the First People's Hospital of Lianyungang between February 2021 and January 2023 were retrospectively studied.All patients underwent three-phase dynamic contrast-enhanced CT scanning before surgery,and CD34 was detected in gastroscopic biopsy specimens.Using surgical and pathological results as the gold standard,the diagnostic results of three-phase dynamic contrast-enhanced CT scanning at different T and N stages were analyzed,and the expression of CD34-marked microvessel density(MVD)at different T and N stages was determined.The specificity and sensitivity of three-phase dynamic contrast-enhanced CT and CD34 in T and N staging were calculated;those of the combined diagnosis of the two were evaluated in parallel.Independent factors affecting lymph node metastasis were analyzed using multiple logistic regression.RESULTS The accuracy of three-phase dynamic contrast-enhanced CT scanning in diagnosing stages T1,T2,T3 and T4 were 68.00%,75.00%,79.41%,and 73.68%,respectively,and for diagnosing stages N0,N1,N2,and N3 were 75.68%,74.07%,85.00%,and 77.27%,respectively.CD34-marked MVD expression increased with increasing T and N stages.Specificity and sensitivity of three-phase dynamic contrast-enhanced CT in T staging were 86.79%and 88.68%;for N staging,89.06%and 92.86%;for CD34 in T staging,64.15%and 88.68%;and for CD34 in N staging,84.38%and 78.57%,respectively.Specificity and sensitivity of joint diagnosis in T staging were 55.68%and 98.72%,and N staging were 75.15%and 98.47%,respectively,with the area under the curve for diagnosis improving accordingly.According to multivariate analysis,a longer tumor diameter,higher pathological T stage,lower differ-entiation degree,and higher expression of CD34-marked MVD were independent risk factors for lymph node metastasis in patients with GC.CONCLUSION With high accuracy in preoperatively determining the invasion depth and lymph node metastasis of GC,CD34 expression and three-phase dynamic contrast-enhanced CT can provide a reliable basis for surgical resection. 展开更多
关键词 CD34 three-phase dynamic contrast-enhanced computed tomography scanning Gastric cancer Preoperative staging INVASION Lymph node metastasis
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Speed Regulation Method Using Genetic Algorithm for Dual Three-phase Permanent Magnet Synchronous Motors 被引量:1
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作者 Xiuhong Jiang Yuying Wang Jiarui Dong 《CES Transactions on Electrical Machines and Systems》 CSCD 2023年第2期171-178,共8页
Dual three-phase Permanent Magnet Synchronous Motor(DTP-PMSM)is a nonlinear,strongly coupled,high-order multivariable system.In today’s application scenarios,it is difficult for traditional PI controllers to meet the... Dual three-phase Permanent Magnet Synchronous Motor(DTP-PMSM)is a nonlinear,strongly coupled,high-order multivariable system.In today’s application scenarios,it is difficult for traditional PI controllers to meet the requirements of fast response,high accuracy and good robustness.In order to improve the performance of DTP-PMSM speed regulation system,a control strategy of PI controller based on genetic algorithm is proposed.Firstly,the basic mathematical model of DTP-PMSM is established,and the PI parameters of DTP-PMSM speed regulation system are optimized by genetic algorithm,and the modeling and simulation experiments of DTP-PMSM control system are carried out by MATLAB/SIMULINK.The simulation results show that,compared with the traditional PI control,the proposed algorithm significantly improves the performance of the control system,and the speed output overshoot of the GA-PI speed control system is smaller.The anti-interference ability is stronger,and the torque and double three-phase current output fluctuations are smaller. 展开更多
关键词 Dual three-phase permanent magnet synchronous motor Genetic algorithm PI control Speed regulation
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Hydrodynamics and Mass Transfer in a Modified Three-phase Airlift Loop Reactor 被引量:5
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作者 Liu Mengxi Lu Chunxi +2 位作者 Shi Mingxian Ge Baoli Huang Jie 《Petroleum Science》 SCIE CAS CSCD 2007年第3期91-96,共6页
A modified internal-loop airlif reactor (MIALR) with a continuous slurry phase was studied to investigate the local hydrodynamic characteristics, including gas holdup, bubble size, bubble rise velocity and local mas... A modified internal-loop airlif reactor (MIALR) with a continuous slurry phase was studied to investigate the local hydrodynamic characteristics, including gas holdup, bubble size, bubble rise velocity and local mass transfer properties. Based on the analysis of geometrical construction and fluid properties of gas and slurry, MIALR was divided into six flow regions. In these flow regions, the local hydrodynamic characteristics were investigated over a wide range of operating variables. Furthermore, a new method was developed to measure the dissolved oxygen concentration. The volumetric mass-transfer coefficient in six flow regions was also calculated for comparison. 展开更多
关键词 Airlift loop reactor HYDRODYNAMICS mass transfer FLUIDIZATION multiphase flow
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Reactor field reconstruction from sparse and movable sensors using Voronoi tessellation-assisted convolutional neural networks 被引量:1
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作者 He-Lin Gong Han Li +1 位作者 Dunhui Xiao Sibo Cheng 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期173-185,共13页
The aging of operational reactors leads to increased mechanical vibrations in the reactor interior.The vibration of the incore sensors near their nominal locations is a new problem for neutronic field reconstruction.C... The aging of operational reactors leads to increased mechanical vibrations in the reactor interior.The vibration of the incore sensors near their nominal locations is a new problem for neutronic field reconstruction.Current field-reconstruction methods fail to handle spatially moving sensors.In this study,we propose a Voronoi tessellation technique in combination with convolutional neural networks to handle this challenge.Observations from movable in-core sensors were projected onto the same global field structure using Voronoi tessellation,holding the magnitude and location information of the sensors.General convolutional neural networks were used to learn maps from observations to the global field.The proposed method reconstructed multi-physics fields(including fast flux,thermal flux,and power rate)using observations from a single field(such as thermal flux).Numerical tests based on the IAEA benchmark demonstrated the potential of the proposed method in practical engineering applications,particularly within an amplitude of 5 cm around the nominal locations,which led to average relative errors below 5% and 10% in the L_(2) and L_(∞)norms,respectively. 展开更多
关键词 Voronoi tessellation Field reconstruction Nuclear reactors reactor physics On-line monitoring
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Dynamic simulation analysis of molten salt reactor-coupled air-steam combined cycle power generation system 被引量:2
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作者 Jing-Lei Huang Guo-Bin Jia +3 位作者 Li-Feng Han Wen-Qian Liu Li Huang Zheng-Han Yang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期222-233,共12页
A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the mol... A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power system.This model considers the impact of thermal properties of fluid variation on accuracy and has been validated with Simulink.This study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet parameters.Meanwhile,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also analyzed.The results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial values.This simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability. 展开更多
关键词 Molten salt reactor Combined cycle Dynamic characteristic CONTROL
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Review on synergistic damage effect of irradiation and corrosion on reactor structural alloys 被引量:1
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作者 Hui Liu Guan-Hong Lei He-Fei Huang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第3期109-141,共33页
The synergistic damage effect of irradiation and corrosion of reactor structural materials has been a prominent research focus.This paper provides a comprehensive review of the synergistic effects on the third-and fou... The synergistic damage effect of irradiation and corrosion of reactor structural materials has been a prominent research focus.This paper provides a comprehensive review of the synergistic effects on the third-and fourth-generation fission nuclear energy structural materials used in pressurized water reactors and molten salt reactors.The competitive mechanisms of multiple influencing factors,such as the irradiation dose,corrosion type,and environmental temperature,are summarized in this paper.Conceptual approaches are proposed to alleviate the synergistic damage caused by irradiation and corrosion,thereby promoting in-depth research in the future and solving this key challenge for the structural materials used in reactors. 展开更多
关键词 Irradiation and corrosion Synergistic effect Austenitic stainless steels Nickel-based alloys reactors
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Optimization of Control Loops and Operating Parameters for Three-Phase Separators Used in Oilfield Central Processing Facilities
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作者 Zhenfeng Li Yaqiao Li Guangjun Wei 《Fluid Dynamics & Materials Processing》 EI 2023年第3期635-649,共15页
In this study,the Stokes formula is used to analyze the separation effect of three-phase separators used in a Oilfield Central Processing Facility.The considered main influencing factors include(but are not limited to... In this study,the Stokes formula is used to analyze the separation effect of three-phase separators used in a Oilfield Central Processing Facility.The considered main influencing factors include(but are not limited to)the typical size of oil and water droplets,the residence time and temperature of fluid and the dosage of demulsifier.Using the“Specification for Oil and Gas Separators”as a basis,the control loops and operating parameters of each separator are optimized Considering the Halfaya Oilfield as a testbed,it is shown that the proposed approach can lead to good results in the production stage. 展开更多
关键词 Distributed control system(DCS) three-phase separator control loop operating parameter
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Purification of Moringa oleifera Leaves Protease by Three-Phase Partitioning and Investigation of Its Potential Antibacterial Activity
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作者 Adam Abdoulaye Agossou D. P. Noumavo +6 位作者 Durand Dah-Nouvlessounon Messan A. B. Ohin Hasan Bayraktar Farid T. Bade Honoré S. Bankole Lamine Baba-Moussa Farid Baba-Moussa 《American Journal of Plant Sciences》 CAS 2023年第1期64-76,共13页
One of plant-based products for dental care is plant-based proteolytic enzymes which are principally proteases. In order not to damage the protein and bioactive content, an efficient method should be employed for thei... One of plant-based products for dental care is plant-based proteolytic enzymes which are principally proteases. In order not to damage the protein and bioactive content, an efficient method should be employed for their purifications. As such, three-phase partitioning (TPP) was used to purify protease from moringa (Moringa oleifera). TPP is an emerging, promising, non-chromatographic and economical technology which is simple, quick, efficient and often one-step process for the separation and purification of bioactive molecules from natural sources. It involves the addition of salt (ammonium sulphate) to the crude extract followed by the addition of an organic solvent (butanol). The protein appears as an interfacial precipitate between upper organic solvent and lower aqueous phases. The various conditions such as ammonium sulphate, ratio of crude extract to t-butanol and pH which are required for attaining efficient purification of the protease fractions were optimized. Under optimized conditions, it was seen that, 35% of ammonium sulphate saturation with 1:0.75 ratio of crude extract to t-butanol at pH 7 gave 4.94-fold purification with 96.20% activity yield of protease in the middle phase of the TPP system. The purified enzyme from Moringa oleifera has no antimicrobial effect on the pathogenic bacteria tested. However, this purified enzyme, can be considered as a promising agent, cheap, and safe source which is suitable for using in various industries. 展开更多
关键词 three-phase Partitioning Moringa oleifera PROTEASE Protein Purification ANTIMICROBIAL
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High-resolution neutronics model for ^(238)Pu production in high-flux reactors 被引量:1
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作者 Qing-Quan Pan Qing-Fei Zhao +4 位作者 Lian-Jie Wang Bang-Yang Xia Yun Cai Jin-Biao Xiong Xiao-Jing Liu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期226-236,共11页
We proposed and compared three methods(filter burnup,single energy burnup,and burnup extremum analysis)to build a high-resolution neutronics model for 238Pu production in high-flux reactors.The filter burnup and singl... We proposed and compared three methods(filter burnup,single energy burnup,and burnup extremum analysis)to build a high-resolution neutronics model for 238Pu production in high-flux reactors.The filter burnup and single energy burnup methods have no theoretical approximation and can achieve a spectrum resolution of up to~1 eV,thereby constructing the importance curve and yield curve of the full energy range.The burnup extreme analysis method combines the importance and yield curves to consider the influence of irradiation time on production efficiency,thereby constructing extreme curves.The three curves,which quantify the transmutation rate of the nuclei in each energy region,are of physical significance because they have similar distributions.A high-resolution neutronics model for ^(238)Pu production was established based on these three curves,and its universality and feasibility were proven.The neutronics model can guide the neutron spectrum optimization and improve the yield of ^(238)Pu by up to 18.81%.The neutronics model revealed the law of nuclei transmutation in all energy regions with high spectrum resolution,thus providing theoretical support for high-flux reactor design and irradiation production of ^(238)Pu. 展开更多
关键词 ^(238)Pu Neutronics model High-flux reactor Spectrum resolution Spectrum optimization
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Local Gas Phase Flow Characteristics of a Gas-Liquid-Solid Three-Phase Reversed Flow Jet Loop Reactor 被引量:2
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作者 闻建平 周怀 陈云琳 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第1期119-122,共4页
The local gas-phase flow characteristics such as local gas holdup(εg), local bubble velocity (V_b) and local bubble mean diameter(d_b) at a specified point in a gas-liquid-solid three-phase reversedflow jet loop reac... The local gas-phase flow characteristics such as local gas holdup(εg), local bubble velocity (V_b) and local bubble mean diameter(d_b) at a specified point in a gas-liquid-solid three-phase reversedflow jet loop reactor was experimentally investigated by a five-pointconductivity probe. The effects of gas jet flow rate, liquid jet flowrate, solid loading, nozzle diameter and axial position on the localεg, V_b and d_b profiles were discussed. The presence of solids atlow solid concentrations not only increased the local εg and V_b,but also decreased the local d_b. The optimum solid loading for themaximum local εg and V_b together with the minimum local d_b was0.16×10^-3 m^3, corresponding to a solid volume fraction ε_S=2.5/100. 展开更多
关键词 local gas holdup local bubble velocity local bubble mean diameter gas-liquid-solid three-phase
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Hydrodynamics and bubble behaviour in a three-phase two-stage internal loop airlift reactor 被引量:3
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作者 Dan Li Kai Guo +4 位作者 Jingnan Li Yiping Huang Junchao Zhou Hui Liu Chunjiang Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第6期1359-1369,共11页
Local hydrodynamics of a gas–liquid–solid system,such as bubble circulation regime,gas holdup,liquid velocity and axial profile of solid concentration,are studied in a two-stage internal loop airlift reactor.Empiric... Local hydrodynamics of a gas–liquid–solid system,such as bubble circulation regime,gas holdup,liquid velocity and axial profile of solid concentration,are studied in a two-stage internal loop airlift reactor.Empirical correlations for gas holdup and liquid velocity are proposed to ease the reactor design and scale-up.Different bubble circulation regimes were displayed in the first(lower) and second(upper) stages.Increasing superficial gas velocity and solid loading can promote regime transition of the second stage,and the gas holdup of the second stage is higher than that of the lower stage.In addition,the effects of solid loading on bubble behaviour are experimentally investigated for each stage.It is found that bubble size in the downcomer decreases with the presence of solid particles,and bubble size distribution widens under higher superficial gas velocity and lower solid loading. 展开更多
关键词 Two-stage internal loop airlift reactor HYDRODYNAMICS BUBBLE Multiphase flow
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Vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers under blast load
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作者 Quoc-Hoa Pham Van Ke Tran Trung Thanh Tran 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第6期148-163,共16页
In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order... In this article,vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers subjected to blast load are studied.Higher-order ES-MITC3 element based on higher-order shear deformation theory(HSDT)to achieve the governing equations.The sandwich plates with the ultra-light feature of the auxetic honeycomb core layer(negative Poisson’s ratio)and reinforced by two laminated three-phase skin layers.The obtained results in our work are compared with other previously published to confirm accuracy and reliability.In addition,the effects of parameters such as geometrical and material parameters on the vibration characteristics of sandwich plates with an auxetic honeycomb core and laminated three-phase skin layers are fully investigated. 展开更多
关键词 Laminated three-phase Sandwich plate Auxetic honeycomb ES-MITC3 element High-order shear deformation theory
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Enhancing ammonia production rates from electrochemical nitrogen reduction by engineering three-phase boundary with phosphorus-activated Cu catalysts
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作者 Jeehye Kim Cho Hee Lee +5 位作者 Yong Hyun Moon Min Hee Lee Eun Hyup Kim Sun Hee Choi Youn Jeong Jang Jae Sung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期394-401,共8页
Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to i... Electrochemical N_(2) reduction reaction(eNRR) over Cu-based catalysts suffers from an intrinsically low activity of Cu for activation of stable N_(2) molecules and the limited supply of N_(2) to the catalyst due to its low solubility in aqueous electrolytes.Herein,we propose phosphorus-activated Cu electrocatalysts to generate electron-deficient Cu sites on the catalyst surface to promote the adsorption of N_(2) molecules.The eNRR system is further modified using a gas diffusion electrode(GDE) coated with polytetrafluoroethylene(PTFE) to form an effective three-phase boundary of liquid water-gas N_(2)-solid catalyst to facilitate easy access of N_(2) to the catalytic sites.As a result,the new catalyst in the flow-type cell records a Faradaic efficiency of 13.15% and an NH_(3) production rate of 7.69 μg h^(-1) cm^(-2) at-0.2 V_(RHE),which represent 3.56 and 59.2 times increases from those obtained with a pristine Cu electrode in a typical electrolytic cell.This work represents a successful demonstration of dual modification strategies;catalyst modification and N_(2) supplying system engineering,and the results would provide a useful platform for further developments of electrocatalysts and reaction systems. 展开更多
关键词 Electrochemical nitrogen reduction reaction Ammonia production Phosphorous modified copper electrodes Gas diffusion electrodes three-phase boundary PTFE coating
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Automatic measurement of three-phase contact angles in pore throats based on digital images
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作者 ZANG Chuanzhen WANG Lida +3 位作者 ZHOU Kaihu YU Fuwei JIANG Hanqiao LI Junjian 《Petroleum Exploration and Development》 SCIE 2023年第2期442-449,共8页
With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flood... With the help of digital image processing technology, an automatic measurement method for the three-phase contact angles in the pore throats of the microfluidic model was established using the microfluidic water flooding experiment videos as the data source. The results of the new method were verified through comparing with the manual measurement data.On this basis, the dynamic changes of the three-phase contact angles under flow conditions were clarified by the contact angles probability density curve and mean value change curve. The results show that, for water-wetting rocks, the mean value of the contact angles is acute angle during the early stage of the water flooding process, and it increases with the displacement time and becomes obtuse angle in the middle-late stage of displacement as the dominant force of oil phase gradually changes from viscous force to capillary force. The droplet flow in the remaining oil occurs in the central part of the pore throats, without three-phase contact angle. The contact angles for the porous flow and the columnar flow change slightly during the displacement and present as obtuse angles in view of mean values, which makes the remaining oil poorly movable and thus hard to be recovered. The mean value of the contact angle for the cluster flow tends to increase in the flooding process, which makes the remaining oil more difficult to be recovered. The contact angles for the membrane flow are mainly obtuse angles and reach the highest mean value in the late stage of displacement, which makes the remaining oil most difficult to be recovered. After displacement, the remaining oils under different flow regimes are just subjected to capillary force, with obtuse contact angles, and the wettability of the pore throat walls in the microfluidic model tends to be oil-wet under the action of crude oil. 展开更多
关键词 microfluidic model water flooding experiment digital image processing three-phase contact angle measure-ment method flow regime of the remaining oil
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Experimental evaluation and modeling of liquid jet penetration to estimate droplet size in a three-phase riser reactor 被引量:1
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作者 Ali Akbar Jamali Shahrokh Shahhosseini Yaghoub Behjat 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第2期293-309,共17页
In this work, the effects of injecting an evaporating liquid jet into solid-gas flow are experimentally investigated. A new model (SHED model) and a supplementary model (spray model) have also been proposed to inv... In this work, the effects of injecting an evaporating liquid jet into solid-gas flow are experimentally investigated. A new model (SHED model) and a supplementary model (spray model) have also been proposed to investigate some flow-field characteristics in three-phase fluidized bed with the mean relative error 4.3% between model and measured results. Some experiments were conducted to study the influences of flow-field parameters such as liquid volumetric flow rate, injection velocity, jet angle and gas superficial velocity as well as solid mass flux on the jet penetration depth (JPD). In addition, independent variables were experimentally employed to propose two empirical correlations for JPD by using multiple regression method and spray cone angle (SCA) by using dimensional analysis technique. The mean relative errors between the JPD and SCA correlations versus ex- perimental data were 7.5% and 3.9%, respectively. In addition, in order to identify the variable effect, a parametric study was carried out. Applying the proposed model can avoid direct use of expensive devices to measureJPD and to nredict dronlet size. 展开更多
关键词 FC-C riser reactor Hydrod ynamics Heterogeneous vaporization Jet penetration depth (JPD) Spray cone angle (SCA)
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Proposal of a Deuterium-Deuterium Fusion/PWR Fission Hybrid Reactor
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作者 Patrick Lindecker 《World Journal of Nuclear Science and Technology》 CAS 2024年第4期190-233,共44页
This article proposes to associate a Deuterium-Deuterium (D-D) fusion reactor with a PWR (fission Pressurized Water Reactor) in a hybrid reactor. Even if the mechanical gain (Q factor) of the D-D fusion reactor is bel... This article proposes to associate a Deuterium-Deuterium (D-D) fusion reactor with a PWR (fission Pressurized Water Reactor) in a hybrid reactor. Even if the mechanical gain (Q factor) of the D-D fusion reactor is below the unity and consequently consumes more energy than it supplies, due to the high energy amplification factor of the PWR fission reactor, the global yield is widely superior to 1. As the energy supplied by the fusion reactor is relatively low and as the neutrons supplied are mainly issued from D-D fusions (at 2.45 MeV), the problems of heat flux and neutrons damage connected with materials, as with D-T fusion reactors are reduced. Of course, there is no need to produce Tritium with this D-D fusion reactor. This type of reactor is able to incinerate any mixture of natural Uranium, natural Thorium and depleted Uranium (waste issued from enrichment plants), with natural Thorium being the best choice. No enriched fuel is needed. So, this type of reactor could constitute a source of energy for several thousands of years because it is about 90 more efficient than a standard fission reactor, such as a PWR or a Candu one, by extracting almost completely the energy from the fertile materials U238 and Th232. For the fission part, PWR technology is mature. For the fusion part, it is based on a reasonable hypothesis done on present Stellarators projects. The working of this reactor is continuous, 24 hours a day. In this paper, it will be targeted a reactor able to provide net electric power of about 1400 MWe, as a big fission power plant. 展开更多
关键词 Fusion reactor Fission reactor Hybrid reactor Nuclear Energy Deuterium-Deuterium reactor DEUTERIUM Colliding Beams Racetrack STELLARATOR Power Plant PWR
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