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Differential utilization and speciation transformation of orthorhombic α-S_8 and amorphous μ-S by substrate-acclimated mesophilic Acidithiobacillus ferrooxidans 被引量:2
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作者 刘红昌 夏金兰 +3 位作者 聂珍媛 郑雷 马陈燕 赵屹东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第9期3096-3102,共7页
The utilization and speciation transformation of α-S8 and μ-S by the typical mesophilic acidophilic strain Acidithiobacillus ferrooxidans ATCC 23270 were investigated.A.ferrooxidans cells first acclimated to the ene... The utilization and speciation transformation of α-S8 and μ-S by the typical mesophilic acidophilic strain Acidithiobacillus ferrooxidans ATCC 23270 were investigated.A.ferrooxidans cells first acclimated to the energy source α-S8 or μ-S,respectively.The results of cell growth and sulfur oxidation behavior showed that the strain grown on α-S8 entered slowly(about 1 d later) into the exponential phase,while grew faster in the exponential phase and attained higher maximal cell density and lower p H value than that on μ-S.After bio-corrosion,both of the two sulfur samples were evidently eroded and modified by A.ferrooxidans cells.After growth of A.ferrooxidans,the surface composition of amorphous μ-S became 63.1% μ-S and 36.9% α-S8,and that of orthorhombic α-S8 became 68.3% α-S8 and 31.7% μ-S,while the surface compositions of α-S8 and μ-S in sterile experiment were not changed,indicating that these two elemental sulfur species can be interconverted by A.ferrooxidans. 展开更多
关键词 sulfur utilization sulfur speciation transformation α-s8 μ-s Acidithiobacillus ferrooxidans
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碳掺杂α-S_8的光学性质和弹性性质的第一性原理计算 被引量:1
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作者 阮林伟 朱玉俊 +1 位作者 裘灵光 卢运祥 《物理化学学报》 SCIE CAS CSCD 北大核心 2014年第5期845-854,共10页
采用第一性原理研究了C原子在光催化剂α-S8中掺杂后体系电子结构、能带结构、光学性质、弹性性质以及其各向异性的变化规律.结果表明C原子在α-S8中掺杂后新形成的C―S键键长变短、键的重叠布居数增加、电荷密度增加,表明新键的共价性... 采用第一性原理研究了C原子在光催化剂α-S8中掺杂后体系电子结构、能带结构、光学性质、弹性性质以及其各向异性的变化规律.结果表明C原子在α-S8中掺杂后新形成的C―S键键长变短、键的重叠布居数增加、电荷密度增加,表明新键的共价性变强.掺杂结构的带隙为2.64 eV,比纯α-S8的带隙小0.15 eV,表明掺杂后的结构导电性增强.掺杂结构的光吸收波长延长至650 nm左右,极大地提高了α-S8的光吸收效率.弹性性质计算表明C掺杂后α-S8的机械性能下降,但仍为脆性材料.各向异性的研究表明掺杂后的材料各向异性增强. 展开更多
关键词 α-s8掺杂 CASTEP 光学性质 弹性性质
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