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Synthesis and characterization of A1 doped δ-laminar crystal sodium silicate
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作者 Xue Jing Yang Ya Ling Yang +2 位作者 Wei Zhen Mou Sheng Liu Jun Hong Chai 《Chinese Chemical Letters》 SCIE CAS CSCD 2009年第4期462-464,共3页
An modified laminar crystal sodium silicate (A1-SKS-6) was synthesized by spray drying and high temperature crystallization using sodium silicate as silicon source, A1 atom as inorganic source and hexadecyltrimethy ... An modified laminar crystal sodium silicate (A1-SKS-6) was synthesized by spray drying and high temperature crystallization using sodium silicate as silicon source, A1 atom as inorganic source and hexadecyltrimethy ammonium bromide (CTMAB) as the structure template. The hydrothermal stability of product was at least 1 h. The synthesized material was characterized by XRD and SEM. The results indicated that shape and intensity of XRD diffraction peak at 20 took changes, but raw material 8 phase crystal form kept unchanged, and assured high Ca^2+ and Mg^2+ binding capacity of the products. The Ca^2+ and Mg^2+ binding capacity of product is up to 380 mg Ca/g and 410mg Mg/g respectively. It was found that the hole of product became smaller and appeared rod structure based on SEM. The hydrothermal stability was increased due to the pillaring of AI atom. 展开更多
关键词 A1 doping δ-laminar crystal sodium silicate Detergent builder STABILITY
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湖北神农架石笋年纹层与氧碳同位素关系 被引量:3
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作者 梁燕 孔兴功 汪永进 《中国岩溶》 CAS CSCD 北大核心 2008年第4期371-376,共6页
基于湖北神农架青天洞石笋U系测年和年纹层统计结果,分别建立了末次盛冰期(17474±174~16105±151aB.P.)和全新世大暖期(6935.4±33.8~6137±48aB.P.)长达1000余年的两个石笋年纹层生长序列。全新世大暖期年纹层平均... 基于湖北神农架青天洞石笋U系测年和年纹层统计结果,分别建立了末次盛冰期(17474±174~16105±151aB.P.)和全新世大暖期(6935.4±33.8~6137±48aB.P.)长达1000余年的两个石笋年纹层生长序列。全新世大暖期年纹层平均厚度(265μm)约为末次盛冰期(102μm)的2.5倍,说明在间冰期东亚季风增强时石笋沉积速率较大,冰期时则相反。两支分辨率为4~8年的石笋年纹层厚度与δ13C变化曲线对比显示:在百年尺度上,石笋年纹层厚度与δ13C变化曲线均呈良好的相关性(相关系数分别为-0.53和-0.60),说明两指标可能受洞穴上覆土壤带CO2产率这一主控因素的影响。当上覆土壤层生物活动增强,CO2分压较高时,导致石笋δ13C值偏负、生长速率增大。然而,在相同尺度上,两支石笋δ18O变化与对应的δ13C及年纹层厚度之间的相关性较弱,反映研究地点上覆土壤层CO2产率对东亚夏季风强弱变化响应关系比较复杂。 展开更多
关键词 石笋 年纹层厚度 碳同位素 生长速率 湖北神农架
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