The critical behaviors of a mixed spin-1/2 and spin-sB Ising system with a transverse crystal field are studiedby use of the effective-field theory with correlations. The effect of the transverse crystal field on tran...The critical behaviors of a mixed spin-1/2 and spin-sB Ising system with a transverse crystal field are studiedby use of the effective-field theory with correlations. The effect of the transverse crystal field on transition temperaturesis investigated numerically for the honeycomb (z = 3) and square (z = 4) lattices. The results show that there is notricritical point for the system.展开更多
In the paper, taking the atomic EPR entanglement of quantum teleportation of atomic state in thermal environment damping-density operator approach, and the average fidelities are channel state |φ = (1/√2)(|00)...In the paper, taking the atomic EPR entanglement of quantum teleportation of atomic state in thermal environment damping-density operator approach, and the average fidelities are channel state |φ = (1/√2)(|00) + |11〉) is more robust than |φ| they are subject to the dissipative environments. states as quantum channel, we investigate the fidelity and vacuum reservoir by means of quantum theory of calculated, the results show that the atomic quantum = (1/√2)(|01〉 + |10〉) in teleportation process when they are subject to the dissipative environments.展开更多
Fiber-shaped energy storage devices are indispensable parts of wearable and portable electronics.Aqueous rechargeable Ni/Fe battery is a very appropriate energy storage device due to their good safety without organic ...Fiber-shaped energy storage devices are indispensable parts of wearable and portable electronics.Aqueous rechargeable Ni/Fe battery is a very appropriate energy storage device due to their good safety without organic electrolytes, high ionic conductivity, and low cost. Unfortunately, the low energy density,poor power density and cycling performance hinder its further practical applications. In this study, in order to obtain high performance negative iron-based material, we first synthesized a-iron oxide(α-Fe2O3) nanorods(NRs) with superstructures on the surface of highly conductive carbon nanotube fibers(CNTFs), then electrically conductive polypyrrole(PPy) was coated to enhance the electron, ion diffusion and cycle stability. The as-prepared α-Fe2O3@PPy NRs/CNTF electrode shows a high specific capacity of 0.62 Ah cm-3 at the current density of 1 A cm-3. Furthermore, the Ni/Fe battery that was assembled by the above negative electrode shows a maximum volumetric energy density of 15.47 mWh cm-3 with228.2 mW cm-3 at a current density of 1 A cm-3. The cycling durability and mechanical flexibility of the Ni/Fe battery were tested, which show good prospect for practical application. In summary, these merits make it possible for our Ni/Fe battery to have practical applications in next generation flexible energy storage devices.展开更多
Electrocatalytic reduction of CO_(2)is one of the most attractive approaches for converting CO_(2)into valuable chemical feedstocks and fuels.This work reports a catalyst comprising graphdiyne-decorated bismuth subcar...Electrocatalytic reduction of CO_(2)is one of the most attractive approaches for converting CO_(2)into valuable chemical feedstocks and fuels.This work reports a catalyst comprising graphdiyne-decorated bismuth subcarbonate(denoted as BOC@GDY)for efficient electroreduction of CO_(2)to formate.The BOC@GDY shows a stable current density of 200 mA cm^(-2)at–1.1 V in a flow cell configuration,with a faradaic efficiency of 93.5%for formate.Experimental results show that the synergistic effect in BOC@GDY is beneficial for the CO_(2)adsorption affinity,the reaction kinetics and the selectivity for formate.In addition,in-situ X-ray absorption and Raman spectroscopy indicate that the electron-rich GDY could facilitate the reduction from Bi(Ⅲ)to Bi(0),thus leading to more active sites.We also demonstrate that the promoting effect of GDY in CO_(2)electroreduction can be further extended to other metal catalysts.To the best of our knowledge,such general promoting functions of GDY for CO_(2)electroreduction have not been documented thus far.展开更多
Two-dimensional(2D)Dion-Jacobson(D-J)-type cesium lead iodide CsPbI_(3) perform remarkably in terms of stability.However,the complex interactions between spacer and inorganic layers limit its excellent progress in per...Two-dimensional(2D)Dion-Jacobson(D-J)-type cesium lead iodide CsPbI_(3) perform remarkably in terms of stability.However,the complex interactions between spacer and inorganic layers limit its excellent progress in perovskite solar cells(PSCs).Herein,starting from the considerable structural diversity of organic spacers,we engineer 2D CsPbI_(3) with fine-tuning functionalities.Specifically,for the first time we embedded fluorinated aromatic cations in 2D D-J CsPbI_(3),and successfully applied it into construction of high-performance PSCs.Compared with constitutive 1,4-diaminobenzene(PDA),the fluorinated 2-fluorobenzene-1,4-diamine(F-PDA)component greatly expands the dipole moment from 0.59 D to 3.47 D,which reduces the exciton binding energy of the system.A theoretical study shows that the spacer layer and inorganic plane are more enriched with charge accumulation in(F-PDA)Csn±1 Pb_(n)I_(3n+1).The results show that(F-PDA)Csn±1Pb_(n)I_(3n+1) demonstrates more significant charge transfer between organic and inorganic layers than(PDA)Csn±1 Pb_(n)I_(3n+1),and it is confirmed in the femtosecond transient absorption experiment.Moreover,the interactions of the fluorinated spacer with the[PbI_(6)]_(4)-plane effectively manipulate the crystallization quality,and thus the ion migration and defect formation of target 2D CsPbI_(3) are inhibited.As a result,we obtained a record power conversion efficiency(PCE)beyond 15%for 2D D-J(F-PDA)Cs_(3)Pb_(4)I_(13)(n=4)PSCs with significantly improved environmental stability compared with the three-dimensional(3D)counterparts.展开更多
The crown-like zinc oxide(Zn O)samples,which are composed of a hexagonal cap and a tower-like shaft,are prepared by vapor transport method.The hexagonal cap,working as a whispering gallery mode(WGM)resonant cavity,dem...The crown-like zinc oxide(Zn O)samples,which are composed of a hexagonal cap and a tower-like shaft,are prepared by vapor transport method.The hexagonal cap,working as a whispering gallery mode(WGM)resonant cavity,demonstrates density-dependent ultraviolet(UV)lasing emission with a broadened and squared photoluminescence(PL)profile under UV excitation at 355 nm.Theoretical analyses based on Fermi golden rule show that the broadened spectrum profile results from the special optical mode density characteristics in a WGM micro-cavity,which is in agreement with the observed results.展开更多
Electron transport through short, phase-coherent metal-graphene-metal devices occurs via resonant transmission through particle-in-a-box-like states defined by the atomically-sharp metal leads. We study the spectrum o...Electron transport through short, phase-coherent metal-graphene-metal devices occurs via resonant transmission through particle-in-a-box-like states defined by the atomically-sharp metal leads. We study the spectrum of particle-in-a-box states for single- and bi-layer graphene, corresponding to massless and massive two-dimensional (2-D) fermions. The density of states D as a function of particle number n shows the expected relationships D(n) -n1/2 for massless 2-D fermions (electrons in single-layer graphene) and D(n) -constant for massive 2-D fermions (electrons in bi-layer graphene). The single parameters of the massless and massive dispersion relations are found, namely Fermi velocity vF = 1.1 × 10^6 m/s and effective mass m* = 0.032 me, where me, is the electron mass, in excellent agreement with theoretical expectations.展开更多
The rapid miniaturization of elect, ronic devices motivates research interests in quantum transport.Recently time-dependent quantum transport has become an important research topic. Here we re- view recent progresses ...The rapid miniaturization of elect, ronic devices motivates research interests in quantum transport.Recently time-dependent quantum transport has become an important research topic. Here we re- view recent progresses in the development of time-dependent density-functional theory for quantum transport including the theoretical foundation and numerical algorithms. In particular, the reducedsingle electron density matrix based hierarchical equation of motion, which can be derived from Liouville---von Neumann equation, is reviewed in details. The numerical implementation is discussed and simulation results of realistic devices will be given.展开更多
Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the ex...Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal electric field.We propose a heterojunction route to help suppress ion migration,thus improving the operational stability of the cell from the perspective of eliminating the electric field response in the perovskite absorber.A heavily doped p-type(p^(+))thin layer semiconductor is introduced between the electron transporting layer(ETL)and perovskite absorber.The heterojunction charge depletion and electric field are limited to the ETL and p^(+)layers,while the perovskite absorber and hole transporting layer remain neutral.The p^(+)layer has a variety of candidate materials and is tolerant of defect density and carrier mobility,which makes this heterojunction route highly feasible and promising for use in practical applications.展开更多
基金The project supported by Science Foundation of the Ministry of Education of China under Grant No.99026
文摘The critical behaviors of a mixed spin-1/2 and spin-sB Ising system with a transverse crystal field are studiedby use of the effective-field theory with correlations. The effect of the transverse crystal field on transition temperaturesis investigated numerically for the honeycomb (z = 3) and square (z = 4) lattices. The results show that there is notricritical point for the system.
基金Supported by the Natural Science Foundation of Hunan Province of China under Grant No.10JJ3088Funds of Hunan Education Bureau under Grant No.10C0616the Key Research Foundation of the Education Bureau of Hunan Province under Grant Nos.10A026 and 08A015
文摘In the paper, taking the atomic EPR entanglement of quantum teleportation of atomic state in thermal environment damping-density operator approach, and the average fidelities are channel state |φ = (1/√2)(|00) + |11〉) is more robust than |φ| they are subject to the dissipative environments. states as quantum channel, we investigate the fidelity and vacuum reservoir by means of quantum theory of calculated, the results show that the atomic quantum = (1/√2)(|01〉 + |10〉) in teleportation process when they are subject to the dissipative environments.
基金This work was supported by the National Natural Science Foundation of China (51972162 and 51703241)the Postdoctoral Foundation of Jiangsu Province (2019Z203 and 2019K001)the Science and Technology Project of Nanchang (2017-SJSYS008)
文摘Fiber-shaped energy storage devices are indispensable parts of wearable and portable electronics.Aqueous rechargeable Ni/Fe battery is a very appropriate energy storage device due to their good safety without organic electrolytes, high ionic conductivity, and low cost. Unfortunately, the low energy density,poor power density and cycling performance hinder its further practical applications. In this study, in order to obtain high performance negative iron-based material, we first synthesized a-iron oxide(α-Fe2O3) nanorods(NRs) with superstructures on the surface of highly conductive carbon nanotube fibers(CNTFs), then electrically conductive polypyrrole(PPy) was coated to enhance the electron, ion diffusion and cycle stability. The as-prepared α-Fe2O3@PPy NRs/CNTF electrode shows a high specific capacity of 0.62 Ah cm-3 at the current density of 1 A cm-3. Furthermore, the Ni/Fe battery that was assembled by the above negative electrode shows a maximum volumetric energy density of 15.47 mWh cm-3 with228.2 mW cm-3 at a current density of 1 A cm-3. The cycling durability and mechanical flexibility of the Ni/Fe battery were tested, which show good prospect for practical application. In summary, these merits make it possible for our Ni/Fe battery to have practical applications in next generation flexible energy storage devices.
基金the National Key R&D Program of China(2017YFA0700104)the National Natural Science Foundation of China(21790052,21805207,and 21931007)+1 种基金111 Project of China(D17003)the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(2018KJ129)。
文摘Electrocatalytic reduction of CO_(2)is one of the most attractive approaches for converting CO_(2)into valuable chemical feedstocks and fuels.This work reports a catalyst comprising graphdiyne-decorated bismuth subcarbonate(denoted as BOC@GDY)for efficient electroreduction of CO_(2)to formate.The BOC@GDY shows a stable current density of 200 mA cm^(-2)at–1.1 V in a flow cell configuration,with a faradaic efficiency of 93.5%for formate.Experimental results show that the synergistic effect in BOC@GDY is beneficial for the CO_(2)adsorption affinity,the reaction kinetics and the selectivity for formate.In addition,in-situ X-ray absorption and Raman spectroscopy indicate that the electron-rich GDY could facilitate the reduction from Bi(Ⅲ)to Bi(0),thus leading to more active sites.We also demonstrate that the promoting effect of GDY in CO_(2)electroreduction can be further extended to other metal catalysts.To the best of our knowledge,such general promoting functions of GDY for CO_(2)electroreduction have not been documented thus far.
基金supported by the National Natural Science Foundation of China(52073131,51902148,and 12047501)the Fundamental Research Funds for the Central Universities(lzujbky-2021-it31,lzujbky-2021-59,lzujbky-2021-ct15,lzujbky2021-ct01,and lzujbky-2021-sp69)supported by Supercomputing Center of Lanzhou University。
文摘Two-dimensional(2D)Dion-Jacobson(D-J)-type cesium lead iodide CsPbI_(3) perform remarkably in terms of stability.However,the complex interactions between spacer and inorganic layers limit its excellent progress in perovskite solar cells(PSCs).Herein,starting from the considerable structural diversity of organic spacers,we engineer 2D CsPbI_(3) with fine-tuning functionalities.Specifically,for the first time we embedded fluorinated aromatic cations in 2D D-J CsPbI_(3),and successfully applied it into construction of high-performance PSCs.Compared with constitutive 1,4-diaminobenzene(PDA),the fluorinated 2-fluorobenzene-1,4-diamine(F-PDA)component greatly expands the dipole moment from 0.59 D to 3.47 D,which reduces the exciton binding energy of the system.A theoretical study shows that the spacer layer and inorganic plane are more enriched with charge accumulation in(F-PDA)Csn±1 Pb_(n)I_(3n+1).The results show that(F-PDA)Csn±1Pb_(n)I_(3n+1) demonstrates more significant charge transfer between organic and inorganic layers than(PDA)Csn±1 Pb_(n)I_(3n+1),and it is confirmed in the femtosecond transient absorption experiment.Moreover,the interactions of the fluorinated spacer with the[PbI_(6)]_(4)-plane effectively manipulate the crystallization quality,and thus the ion migration and defect formation of target 2D CsPbI_(3) are inhibited.As a result,we obtained a record power conversion efficiency(PCE)beyond 15%for 2D D-J(F-PDA)Cs_(3)Pb_(4)I_(13)(n=4)PSCs with significantly improved environmental stability compared with the three-dimensional(3D)counterparts.
基金supported by the National Natural Science Foundation of China(Nos.60725413 and 61401173)the National Spark Program(No.2013GA690405)+1 种基金the Natural Science Foundation of Education Bureau of Jiangsu Province(Nos.12KJD510003 and 13KJD510002)the Natural Science Foundation of Anhui Province in China(No.11040606M10)
文摘The crown-like zinc oxide(Zn O)samples,which are composed of a hexagonal cap and a tower-like shaft,are prepared by vapor transport method.The hexagonal cap,working as a whispering gallery mode(WGM)resonant cavity,demonstrates density-dependent ultraviolet(UV)lasing emission with a broadened and squared photoluminescence(PL)profile under UV excitation at 355 nm.Theoretical analyses based on Fermi golden rule show that the broadened spectrum profile results from the special optical mode density characteristics in a WGM micro-cavity,which is in agreement with the observed results.
文摘Electron transport through short, phase-coherent metal-graphene-metal devices occurs via resonant transmission through particle-in-a-box-like states defined by the atomically-sharp metal leads. We study the spectrum of particle-in-a-box states for single- and bi-layer graphene, corresponding to massless and massive two-dimensional (2-D) fermions. The density of states D as a function of particle number n shows the expected relationships D(n) -n1/2 for massless 2-D fermions (electrons in single-layer graphene) and D(n) -constant for massive 2-D fermions (electrons in bi-layer graphene). The single parameters of the massless and massive dispersion relations are found, namely Fermi velocity vF = 1.1 × 10^6 m/s and effective mass m* = 0.032 me, where me, is the electron mass, in excellent agreement with theoretical expectations.
文摘The rapid miniaturization of elect, ronic devices motivates research interests in quantum transport.Recently time-dependent quantum transport has become an important research topic. Here we re- view recent progresses in the development of time-dependent density-functional theory for quantum transport including the theoretical foundation and numerical algorithms. In particular, the reducedsingle electron density matrix based hierarchical equation of motion, which can be derived from Liouville---von Neumann equation, is reviewed in details. The numerical implementation is discussed and simulation results of realistic devices will be given.
基金supported by the National Natural Science Foundation of China(52072402,11874402,51627803,51421002,91733301,51761145042,and 51872321)the International Partnership Program of Chinese Academy of Sciences(112111KYSB20170089)。
文摘Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal electric field.We propose a heterojunction route to help suppress ion migration,thus improving the operational stability of the cell from the perspective of eliminating the electric field response in the perovskite absorber.A heavily doped p-type(p^(+))thin layer semiconductor is introduced between the electron transporting layer(ETL)and perovskite absorber.The heterojunction charge depletion and electric field are limited to the ETL and p^(+)layers,while the perovskite absorber and hole transporting layer remain neutral.The p^(+)layer has a variety of candidate materials and is tolerant of defect density and carrier mobility,which makes this heterojunction route highly feasible and promising for use in practical applications.