Photocatalytic hydrogen(H_(2))evolution using covalent organic frameworks(COFs)is an attractive and promising avenue for exploration,but one of its big challenges is low photo-induced charge separation.In this study,w...Photocatalytic hydrogen(H_(2))evolution using covalent organic frameworks(COFs)is an attractive and promising avenue for exploration,but one of its big challenges is low photo-induced charge separation.In this study,we present a straightforward and facile dipole polarization engineering strategy to enhance charge separation efficiency,achieved through atomic modulation(O,S,and Se)of the COF monomer.Our findings demonstrate that incorporating atoms with varying electronegativities into the COF matrix significantly influences the local dipole moment,thereby affecting charge separation efficiency and photostability,which in turn affects the rates of photocatalytic H_(2) evolution.As a result,the newly developed TMT-BO-COF,which contains highly electronegative O atoms,exhibits the lowest exciton binding energy,the highest efficiency in charge separation and transportation,and the longest lifetime of the active charges.This leads to an impressive average H_(2) production rate of 23.7 mmol g^(−1) h^(−1),which is 2.5 and 24.5 times higher than that of TMT-BS-COF(containing S atoms)and TMT-BSe-COF(containing Se atoms),respectively.A novel photocatalytic hydrogen evolution mechanism based on proton-coupled electron transfer on N in the structure of triazine rings in vinylene-linked COFs is proposed by theoretical calculations.Our findings provide new insights into the design of highly photoactive organic framework materials for H_(2) evolution and beyond.展开更多
In this paper, a co-polarized, co-located electric and magnetic dipoles(CCEMD) with high isolation is presented. The antenna consists of a loop based on segmented line and two independent feeding ports. Two modes of t...In this paper, a co-polarized, co-located electric and magnetic dipoles(CCEMD) with high isolation is presented. The antenna consists of a loop based on segmented line and two independent feeding ports. Two modes of the antenna are exited separately, the first one has a radiation pattern equivalent to an electric dipole by exciting anti-phase current with symmetric distribution, and the second one is like a magnetic dipole by exciting uniform and in-phase currents along the loop. The antenna is fabricated and tested. Its measured common-10 d B impedance bandwidth at two ports is 280 MHz(2.32-2.6 GHz) with isolation better than 41 d B. Its MIMO performance in terms of capacity gain(CG) over the SISO system is investigated in a multipath rich environment containing two parallel PEC planes by both measurements and image theory based simulations. Results show that, in free space, the CG results are just slightly larger than 1, however, in the multipath rich channel, the CG values are very close to 2, which indicates that two separate subchannels can be achieved by the proposed CCEMD. The measured results of CG agree well with that obtained by simulation.展开更多
Minimax programming problems involving generalized （p, r）-invex functions are consid- ered. Parametric sufficient optimality conditions and duality results are established under the aforesaid assumptions on the obje...Minimax programming problems involving generalized （p, r）-invex functions are consid- ered. Parametric sufficient optimality conditions and duality results are established under the aforesaid assumptions on the objective and constraint functions.展开更多
文摘Photocatalytic hydrogen(H_(2))evolution using covalent organic frameworks(COFs)is an attractive and promising avenue for exploration,but one of its big challenges is low photo-induced charge separation.In this study,we present a straightforward and facile dipole polarization engineering strategy to enhance charge separation efficiency,achieved through atomic modulation(O,S,and Se)of the COF monomer.Our findings demonstrate that incorporating atoms with varying electronegativities into the COF matrix significantly influences the local dipole moment,thereby affecting charge separation efficiency and photostability,which in turn affects the rates of photocatalytic H_(2) evolution.As a result,the newly developed TMT-BO-COF,which contains highly electronegative O atoms,exhibits the lowest exciton binding energy,the highest efficiency in charge separation and transportation,and the longest lifetime of the active charges.This leads to an impressive average H_(2) production rate of 23.7 mmol g^(−1) h^(−1),which is 2.5 and 24.5 times higher than that of TMT-BS-COF(containing S atoms)and TMT-BSe-COF(containing Se atoms),respectively.A novel photocatalytic hydrogen evolution mechanism based on proton-coupled electron transfer on N in the structure of triazine rings in vinylene-linked COFs is proposed by theoretical calculations.Our findings provide new insights into the design of highly photoactive organic framework materials for H_(2) evolution and beyond.
基金supported by the National Natural Science Foundations of China (61771435)
文摘In this paper, a co-polarized, co-located electric and magnetic dipoles(CCEMD) with high isolation is presented. The antenna consists of a loop based on segmented line and two independent feeding ports. Two modes of the antenna are exited separately, the first one has a radiation pattern equivalent to an electric dipole by exciting anti-phase current with symmetric distribution, and the second one is like a magnetic dipole by exciting uniform and in-phase currents along the loop. The antenna is fabricated and tested. Its measured common-10 d B impedance bandwidth at two ports is 280 MHz(2.32-2.6 GHz) with isolation better than 41 d B. Its MIMO performance in terms of capacity gain(CG) over the SISO system is investigated in a multipath rich environment containing two parallel PEC planes by both measurements and image theory based simulations. Results show that, in free space, the CG results are just slightly larger than 1, however, in the multipath rich channel, the CG values are very close to 2, which indicates that two separate subchannels can be achieved by the proposed CCEMD. The measured results of CG agree well with that obtained by simulation.
文摘Minimax programming problems involving generalized （p, r）-invex functions are consid- ered. Parametric sufficient optimality conditions and duality results are established under the aforesaid assumptions on the objective and constraint functions.
