The activity of Co-SrTiO3 for photocatalytic decomposition of water into hydr ogen was studied, and the reason for improvement of activity of supported cataly sts by first reduction in H2 at a higher temperature and t...The activity of Co-SrTiO3 for photocatalytic decomposition of water into hydr ogen was studied, and the reason for improvement of activity of supported cataly sts by first reduction in H2 at a higher temperature and then reoxidation in oxy gen at a lower temperature was analyzed. The mechanism of the photocatalysis of Co-SrTiO3-R-O and Ni-SrTiO3-R-O catalyst was investigated. The metal, Ni o r Co deposited at the interface between the P-type semiconductor, NiO or CoO, a nd the N-type semiconductor, SiTiO3, which may act as the trapped site of elect ron and hole from the N-type semiconductor and the P-type semiconductor respec tively, suppresses the recombination of electron and hole in the bulk of semicon ductor, and furthermore increase the catalytic activity of the catalyst. A highe r activity of Co-SrTiO3-R-O for water decomposition than that of Ni-SrTiO3- R-O is mainly due to CoO having a narrower band gap and a wider range of light absorbance, compared with NiO.展开更多
The photocalytic degradation of Rhodamine B by nano TiO 2 was studied under irradiation of 4W UV lamp in Rhodamine B aqueous directly with different initial concentration of Rhodamine B and different amount of catalys...The photocalytic degradation of Rhodamine B by nano TiO 2 was studied under irradiation of 4W UV lamp in Rhodamine B aqueous directly with different initial concentration of Rhodamine B and different amount of catalysis.The results of the experiments indicated that the reaction rate increases with the increase of the initial concentration of Rhodamine B,and the reaction rate increases with the increase of the amount of catalysis.The photocalytic degradation of Rhodamine B is a complex reaction.The total reaction is a first order kinetic model.展开更多
文摘The activity of Co-SrTiO3 for photocatalytic decomposition of water into hydr ogen was studied, and the reason for improvement of activity of supported cataly sts by first reduction in H2 at a higher temperature and then reoxidation in oxy gen at a lower temperature was analyzed. The mechanism of the photocatalysis of Co-SrTiO3-R-O and Ni-SrTiO3-R-O catalyst was investigated. The metal, Ni o r Co deposited at the interface between the P-type semiconductor, NiO or CoO, a nd the N-type semiconductor, SiTiO3, which may act as the trapped site of elect ron and hole from the N-type semiconductor and the P-type semiconductor respec tively, suppresses the recombination of electron and hole in the bulk of semicon ductor, and furthermore increase the catalytic activity of the catalyst. A highe r activity of Co-SrTiO3-R-O for water decomposition than that of Ni-SrTiO3- R-O is mainly due to CoO having a narrower band gap and a wider range of light absorbance, compared with NiO.
文摘The photocalytic degradation of Rhodamine B by nano TiO 2 was studied under irradiation of 4W UV lamp in Rhodamine B aqueous directly with different initial concentration of Rhodamine B and different amount of catalysis.The results of the experiments indicated that the reaction rate increases with the increase of the initial concentration of Rhodamine B,and the reaction rate increases with the increase of the amount of catalysis.The photocalytic degradation of Rhodamine B is a complex reaction.The total reaction is a first order kinetic model.
