蒸汽驱油机理

通过高升油田岩样仿真模型所进行的驱油实验．研究稠油蒸汽驱油机理和流体渗流规律，为汽驱方案设计和提高稠油采收率提供了科学依据。

远东济州岛尾流现象的GMS卫星遥测研究

在GMS静止气象卫星云图上常在济州岛南面出现一条向东南或西南方向延伸的黾流.通过对遥感资料和常规气象观测资料的分析发现,济州岛尾流现象为中高纬度海表面温度(SST)梯度较大的冷洋面上的一种独特的大气现象,该尾流大多发生在秋季和冬季,黾流的走向向南.济州岛上的汉拿山(Halla-San Mountain)海拔1950 m,它有效地阻挡北面来的低空气流,在地形的作用下,济州岛下游的气流形成低云涡旋,涡旋顺风而动,产生尾流现象.同时济州岛尾流的发生和演变与局地海-气相互作用、局地地形和大气背景场相互作用的关系密切,特别是洋面暖湿空气上升的冷凝作用和逆温层的出现对于尾流云层的形成和维持有重要作用,黾流云层在绕山气流的强迫下在济州岛下风方向形成稳定的Karman涡状尾流结构.

Role of the Nocturnal Low-level Jet in the Formation of the Morning Precipitation Peak over the Dabie Mountains

The diurnal variation of precipitation over the Dabie Mountains(DBM) in eastern China during the 2013 mei-yu season is investigated with forecasts of a regional convection-permitting model. Simulated precipitation is verified against surface rain-gauge observations. The observed morning precipitation peak on the windward(relative to the prevailing synoptic-scale wind) side of the DBM is reproduced with good spatial and temporal accuracy. The interaction between the DBM and a nocturnal boundary layer low-level jet(BLJ) due to the inertial oscillation mechanism is shown to be responsible for this precipitation peak. The BLJ is aligned with the lower-level southwesterly synoptic-scale flow that carries abundant moisture.The BLJ core is established at around 0200 LST upwind of the mountains. It moves towards the DBM and reaches maximum intensity at about 70 km ahead of the mountains. When the BLJ impinges upon the windward side of the DBM in the early morning, mechanical lifting of moist air leads to condensation and subsequent precipitation.

A Rotating Bose-Einstein Condensation in a Toroidal Trap

We have studied the ground state configurations of a rotating Bose-Einstein condensation in a toroidal trap as the radius of the central Ganssian potentiaJ expands adiabatically. Firstly, we observe that the vortices are devoured successively into the central hole of the condensate to form a giant vortex as the radius of the trap expands. When all the pre-existing vortices are absorbed, the angular momentum of the system still increase as the radius of the ganssian potential enlarges. When increasing the interaction strength, we find that more singly quantized vortices are squeezed into the condensate, but the giant vortex does not change.

Nonmonotonic Trust Region Algorithm via the Conjugate Gradient Path for Unconstrained Generalized Geometric Programming

In this paper,on the basis of making full use of the characteristics of unconstrained generalized geometric programming（GGP）,we establish a nonmonotonic trust region algorithm via the conjugate path for solving unconstrained GGP problem.A new type of condensation problem is presented,then a particular conjugate path is constructed for the problem,along which we get the approximate solution of the problem by nonmonotonic trust region algorithm,and further prove that the algorithm has global convergence and quadratic convergence properties.

Stability Analysis of Spatial Cubic Spline Geometric Nonlinear Beam Element Considering the Second-Order Effect

To analyze the stability problem of spatial beam structure more accurately, a spatial cubic spline geometric nonlinear beam dement was proposed considering the seeond-order effect. The deformation field was built with cubic spline function, and its curvature degree of freedom （DOF） was eliminated by static condensation method. Then we got the geometric nonlinear stiffness matrix of the new spatial two.node Euler-Bernouili beam dement. Several examples proved calculation accuracy of the critical load by meshing a bar to one element using the method of this paper was equivalent to mesh a bar to 3 or 4 traditional nonlinear beam dements.

Feasibility of developing composite action between concrete and cold-formed steel beam

Cold-formed steel structures are steel structure products constructed from sheets or coils using cold rolling, press brake or bending brake method. These structures are extensively employed in building construction industry due to their light mass, ductility by economic cold forming operations, favorable strength-to-mass ratio and other factors. The utilization of cold formed steel sections with concrete as composite can hugely reduce the construction cost. However, the use of cold formed steel members in composite concrete beams has been very limited. A comprehensive review of developments in composite beam with cold formed steel sections was introduced. It was revealed that employing cold-formed steel channel section to replace reinforcement bars in conventional reinforced concrete beam results in a significant cost reduction without reducing strength capacity. The use of composite beam consisting of cold-formed steel open or close box and filled concrete could also reduce construction cost. Lighter composite girder for bridges with cold-formed steel of U section was introduced. Moreover, types of shear connectors to provide composite action between cold-formed steel beam and concrete slab were presented. However, further studies to investigate the effects of metal decking on the behavior of composite beam with cold-formed steel section and introduction of ductile shear connectors were recommended.

流纹岩中球粒储集空间类型及主控因素

海拉尔盆地呼伦湖凹陷西界下白垩统上库力组球粒流纹岩中与球粒有关的油气储集空间类型包括球粒间缝、层间缝、球粒内部同心环状和网状微裂缝、空腔孔、溶蚀孔和脱玻化孔.球粒间缝和层间缝主要制约了球粒之间有效面孔率的大小.脱玻化孔、微裂缝和空腔孔以及球粒直径控制了球粒内部有效面孔率的大小.球粒内部微裂缝的发育程度和类型决定了溶蚀作用的程度.溶蚀作用从没有微裂缝→中等发育的放射状和环状微裂缝→非常发育的环状、网状微裂缝逐渐增强.环状、网状微裂缝的另外一个重要效应是沟通脱玻化孔,形成孔缝网络.冷凝收缩作用不仅控制了球粒间缝的形成与发育,还控制了微裂缝和空腔孔的形成和发育.球粒直径制约了冷凝收缩作用,尤其是当直径介于常见的球粒和石泡两者之间时,最有利于微裂缝和空腔孔的形成.脱玻化孔本身就是良好的储集空间,同时还能为地下水和有机质的溶蚀提供显微通道,而这一通道需要微裂缝的沟通才能更好的发挥作用.

Cdk phosphorylation licenses Kif4A chromosome localization required for early mitotic progression

The chromokinesin Kif4A controls proper chromosome condensation, congression/alignment, and cytokinesis to ensure faithful genetic inheritance. Here, we report that Cdk phosphorylation of human Kif4A at T1161 licenses Kif4A chromosomal localization, which, in turn, controls Kif4A early mitotic function. Phosphorylated Kif4A （Kif4A^WT） or Cdk phospho-mimetic Kif4A mutant （Kif4A^TE） associated with chromosomes and condensin I （non-SMC subunit CAP-G and core subunit SMC2） to regulate chromosome condensation, spindle morphology, and chromosome congression/alignment in early mitosis. In contrast, Cdk non-phosphorylatable Kif4A mutant （Kif4A^TA） could neither localize on chromosomes nor associate with CAP-G and SMC2. Furthermore, Kif4A^TA could not rescue defective chromosome condensation, spindle morphology, or chromosome congression/alignment in cells depleted of endogenous Kif4A, which activated a mitotic checkpoint and delayed early mitotic progression. However, targeting Kif4A^TA to chromosomes by fusion of Kif4A^TA with Histone H1 resulted in restoration of chromosome and spindle functions of Kif4A, similar to Kif4A^WT and Kif4A^TE, in cells depleted of endogenous Kif4A. Thus, our results demonstrate that Cdk phosphorylation-licensed chromosomal localization of Kif4A plays a critical role in regulating early mitotic functions of Kif4A that are important for early mitotic progression.

Metal-free synthesis of quinolines by direct condensation of amides with alkynes: revelation of N-aryl nitrilium intermediates by 2D NMR techniques

Employing triflic anhydride/2-fluoropyridine as an activation system, the coupling reactions of secondary N-aryl amides with terminal alkynes yielded substituted quinolines in moderate to excellent yields. The reaction tolerated both electron-donating and electron-withdrawing groups at the benzamide moiety. Electron-rich aryl acetylenes served as excellent coupling partners, and aliphatic terminal alkynes such as cyclopropyl and conjugate vinyl acetylenes could also be used as reaction partners. By means of 2 D NMR techniques(heteronuclear multiple bond correlation(HMBC), heteronuclear single quantum correlation(HSQC)),nitrilium ions were probed as reactive intermediates which are in contrast with that suggested by Movassaghi on the basis of in situ IR monitoring experiments. On the basis of these results, a plausible mechanism for the formation of quinolines was suggested.

Visualization Investigation on Flowing Condensation in Horizontal Small Channels with Liquid Separator

A simultaneous visualization and measurement experiment was carried out to investigate condensation flow pat- terns and condensing heat transfer characteristics of refrigerant R14 lb in parallel horizontal multi-channels with liquid-vapor separator. The hydraulic diameter of each channel was 1.5 mm and the channel length was 100 ram. The refrigerant vapor flowing in the small channels was cooled by cooling water. The parallel horizontal mul- ti-channels were covered with a transparent silica glass for visualization of flow patterns. Experiments were per- formed at different inlet superheat temperatures （ranging from 3~C to 7~C）. Mass velocity was in the range of 82.37 kg mZs1 to 35.56 kg m-2s1. It was found that there were three different flow patterns through the mul- ti-channels with the increase of mass velocity. The flow patterns in each channel pass almost tended to be same and all of them were annular flows.＇ The efficiency of the liquid-vapor separator with U-type was related to vapor mass velocity and the pressure in the small channels. It was also found that the heat transfer coefficient increased with the increase of the mass velocity while the cooling water mass flow rate increased. It increased to a top point and then decreased. It increased with the increase of superheat in the low superheat temperature region.

Highly enhanced visible-light photocatalytic NOx purification and conversion pathway on self-structurally modified g-C-3N4 nanosheets

The unmodified graphitic carbon nitride(g-C_3N_4) suffers from low photocatalytic activity because of the unfavourable structure.In the present work,we reported a simple self-structural modification strategy to optimize the microstructure of g-C_3N_4 and obtained graphene-like g-C_3N_4 nanosheets with porous structure.In contrast to traditional thermal pyrolysis preparation of g-C_3N_4,the present thermal condensation was improved via pyrolysis of thiourea in an alumina crucible without a cover,followed by secondary heat treatment.The popcorn-like formation and layer-by-layer thermal exfoliation of graphene-like porous g-C_3N_4 was proposed to explain the formation mechanism.The photocatalytic removal performance of both NO and NO_2 with the graphene-like porous g-C_3N_4 for was significantly enhanced by selfstructural modification.Trapping experiments and in-situ diffuse reflectance infrared fourier transform spectroscopy(DRIFTS) measurement were conducted to detect the active species during photocatalysis and the conversion pathway of g-C_3N_4 photocatalysis for NO_x purification was revealed.The photocatalytic activity of graphene-like porous g-C_3N_4 was highly enhanced due to the improved charge separation and increased oxidation capacity of the ·O_2^- radicals and holes.This work could not only provide a novel self-structural modification for design of highly efficient photocatalysts,but also offer new insights into the mechanistic understanding of g-C_3N_4 photocatalysis.

Applications of CBT-Cys click reaction: past, present, and future

Herein, we review the development, applications and potential prospects of CBT-Cys click reaction. This click condensation reaction is based on the condensation reaction between 2-cyanobenzothiazole(CBT) and D-cysteine(D-Cys) in fireflies and has high biocompatibility and controllability in physiological solutions. Under the control of p H, reduction, or enzyme, this CBTbased click reaction has been widely applied to a wide range of biomedical fields such as protein labeling, molecular imaging(e.g., optical imaging, nuclear imaging, magnetic resonance imaging and photoacoustic imaging), nanomaterial fabrication, cancer therapy, and other potentialities.

Annular Supersonic Swirling Flows with Heterogeneous Condensation

In recent years,separating and extracting technologies of condensate gas have been developed by combining a swirl flow with non-equilibrium condensation phenomena of condensate gas generated in a supersonic flow.The technology can reduce the size of the device and does not use chemicals.However,there are many unresolved problems for performance of the separation,extraction and operating principle.Therefore it is necessary to research further in order to improve the performance of the equipment.In the present study,the numerical study was carried out to clarify the effect of the heterogeneous condensation on the characteristics of the swirling flow field in a supersonic annular nozzle,and the differences between homogeneous condensation and heterogeneous condensation in the flow field.As the results,it is found that the condensation flow with a swirl affects the position of sonic line,the generating position of condensate and the radial distribution ratio of liquid phase.

A new power generation method utilizing a low grade heat source

Energy crisis make the effective use of low grade energy more and more urgent. It is still a worldwide difficult conundrum. To efficiently recover low grade heat, this paper deals with a theoretical analysis of a new power generation method driven by a low grade heat source. When the temperature of the low grade heat source exceeds the saturated temperature, it can heat the liquid into steam. If the steam is sealed and cooled in a container, it will lead to a negative pressure condition. The proposed power generation method utilizes the negative pressure condition in the sealed container, called as a condensator. When the condensator is connected to a liquid pool, the liquid will be pumped into it by the negative pressure condition. After the conden- sator is filled by liquid, the liquid flows back into the pool and drives the turbine to generate electricity. According to our analysis, for water, the head pressure of water pumped into the condensator could reach 9.5 m when the temperature of water in the pool is 25 ℃, and the steam temperature is 105 ℃. Theoretical thermal efficiency of this power generation system could reach 3.2% to 5.8% varying with the altitude of the condensator to the water level, ignoring steam leakage loss.

Condensation heat transfer characteristics of vapor flow in vertical small-diameter tube with variable wall temperature

To explore the condensation characteristics of vapor flow inside vertical small-diameter tubes, the classical Nusselt theory is revised and an analytical model with variable tube wall temperature is established by considering the effect of surface tension exerted by condensate film bending as well as the effect of shear stress on vapor-liquid interface. The effects of various factors including tube wall temperature and gravityon flow condensation in small-diameter tubes are analyzed theoretically to show the heat transfer characteristics. Comparison with the experimental data indicates that the proposed analytical model is fit to reveal the fundamental characteristics of flow condensation heat transfer in vertical small-diameter tube.