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利用在线加压溶剂提取-超高效液相色谱-离子肼-飞行时间-质谱法直接分析中药草苁蓉的化学成分组 被引量:7
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作者 李婷 许霞 +4 位作者 常安琪 刘文静 宋青青 宋月林 屠鹏飞 《色谱》 CAS CSCD 北大核心 2020年第5期554-563,共10页
构建了在线加压溶剂提取-超高效液相色谱-离子肼-飞行时间质谱(online PLE-UHPLC-IT-TOF-MS)系统,并将其应用于草苁蓉化学组的快速、直接分析。将微量草苁蓉粉末(0.5 mg)置于空预柱芯中,空隙用正相硅胶填充,作为提取池;提取池置于预柱套... 构建了在线加压溶剂提取-超高效液相色谱-离子肼-飞行时间质谱(online PLE-UHPLC-IT-TOF-MS)系统,并将其应用于草苁蓉化学组的快速、直接分析。将微量草苁蓉粉末(0.5 mg)置于空预柱芯中,空隙用正相硅胶填充,作为提取池;提取池置于预柱套内,将其放入柱温箱(70℃),预柱套通过金属管线连接至UHPLC-IT-TOF-MS系统。通过引入一个二位六通阀将整个分析过程分为提取和洗脱两个阶段。以0.1%(v/v)甲酸水为溶剂,提取3 min。在洗脱阶段,以0.1%(v/v)甲酸水-0.1%(v/v)甲酸乙腈为流动相,梯度洗脱,将色谱柱前端所富集的提取物洗脱至IT-TOF-MS中进行检测。从草苁蓉中检测到48个化合物,结合对照品、文献、数据库以及质谱裂解规律,初步鉴定了其中的45个,包括10个苯乙醇苷类、14个环烯醚萜苷类以及21个苯丙醇苷类化合物。该研究为草苁蓉化学成分组成的阐明以及质量评价提供了可靠信息。同时,构建的online PLE-UHPLC-IT-TOF-MS系统为中药化学成分的快速、直接表征提供了有效方案。 展开更多
关键词 在线加压溶剂提取 草苁蓉 化学成分组 质谱裂解规律 苯丙醇苷
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利用在线加压溶剂提取-超高效液相色谱-离子阱-飞行时间-质谱法定性分析片仔癀化学成分组 被引量:7
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作者 李玮 蒋珍珍 +4 位作者 李菡 屠鹏飞 宋青青 于娟 宋月林 《色谱》 CAS CSCD 北大核心 2021年第5期478-487,共10页
片仔癀(Pien-Tze-Huang)是由三七、牛黄、蛇胆、麝香等名贵中药经加工精制而成的中药制剂。片仔癀中的三七皂苷、胆汁酸以及麝香酮等主要化学成分已被深入研究,然而其全方化学成分组成尚未被整体阐明。该文建立了在线加压溶剂提取-超高... 片仔癀(Pien-Tze-Huang)是由三七、牛黄、蛇胆、麝香等名贵中药经加工精制而成的中药制剂。片仔癀中的三七皂苷、胆汁酸以及麝香酮等主要化学成分已被深入研究,然而其全方化学成分组成尚未被整体阐明。该文建立了在线加压溶剂提取-超高效液相色谱-离子阱-飞行时间质谱(online PLE-UHPLC-IT-TOF-MS)法,快速、直接分析片仔癀化学成分组。将少量片仔癀粉末(0.3 mg)均匀地平铺于预柱芯尾端,之后用正相硅胶填充预柱芯,滤膜密封后构成提取池。提取池装入预柱套后置于70℃的柱温箱内,连接于UHPLC-IT-TOF-MS分析系统。通过引入一个二位六通电子阀,将整个分析过程自动在提取相和洗脱相间切换。提取相用时3 min,以0.1%(v/v)甲酸水为提取溶剂,流速为0.2 mL/min;洗脱相以0.1%(v/v)甲酸水和乙腈为流动相进行梯度洗脱,IT-TOF-MS检测。通过与对照品、相关文献和自建中药数据库对照,并总结相关质谱裂解规律,从片仔癀中共检测到73个化学成分,初步鉴定并归属了其中71个,36个来源于三七,15个来源于蛇胆,9个来源于牛黄,11个可能来源于牛黄与蛇胆,另有2个结构无法确定。该研究深入解析了片仔癀的化学成分组,为其质量分析提供了丰富的信息。同时,该文构建的online PLE-UHPLC-IT-TOF-MS分析系统为中药复杂体系快速、直接分析提供了可靠的工具。 展开更多
关键词 在线加压溶剂提取 片仔癀 化学成分组 质谱裂解途径 来源归属
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直接注射-多级质谱全扫描法快速分析枸杞子化学成分组 被引量:3
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作者 贾金茹 彭博 +5 位作者 李婷 刘文静 李菡 李波 赵云芳 宋月林 《质谱学报》 EI CAS CSCD 北大核心 2022年第3期300-311,共12页
由于色谱分离需要耗费大量的时间,导致传统LC-MS研究中药成分的分析通量较低,而多级质谱全扫描(MS/MS^(ALL))采用了气态分段技术(GPF),可以在直接注射(DI)模式下,采集每个表观质量数MS^(1)信号的MS^(2)图谱,实现MS^(1)-MS^(2)数据列表... 由于色谱分离需要耗费大量的时间,导致传统LC-MS研究中药成分的分析通量较低,而多级质谱全扫描(MS/MS^(ALL))采用了气态分段技术(GPF),可以在直接注射(DI)模式下,采集每个表观质量数MS^(1)信号的MS^(2)图谱,实现MS^(1)-MS^(2)数据列表的高通量构建。为快速表征枸杞子化学成分组,本研究采用DI-MS/MS^(ALL)全面采集枸杞子提取物中各化学成分的多级质谱数据,根据高分辨MS^(1)和MS^(2)碎片离子信息推导质谱裂解途径,结合数据库检索以及相关文献,从枸杞子中初步鉴定了38个化学成分,包括1个氨基酸类、19个有机酸类、2个糖脂类、6个苯丙素类、1个黄酮类、6个生物碱类以及3个酰胺类化合物。DI-MS/MS^(ALL)可作为中药等复杂体系快速全面定性分析的有力工具。 展开更多
关键词 直接注射-多级质谱全扫描(DI-MS/MS^(ALL)) 枸杞子 化学成分组 裂解途径 MS^(1)-MS^(2)数据列表
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利用~1H-NMR比较管花肉苁蓉野生品和栽培品的化学成分组 被引量:19
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作者 刘文静 刘瑶 +5 位作者 宋青青 颜昱 赵云芳 屠鹏飞 李军 宋月林 《中国中药杂志》 CAS CSCD 北大核心 2018年第17期3506-3512,共7页
管花肉苁蓉素有"沙漠人参"之称,为著名补益类中药。为了缓解管花肉苁蓉的资源问题并有效保护野生资源,我国在新疆的南疆地区大力推广管花肉苁蓉的人工栽培,目前已取得了可喜的成果。该文利用1H-NMR技术能够全面提供定性和定量信息的优... 管花肉苁蓉素有"沙漠人参"之称,为著名补益类中药。为了缓解管花肉苁蓉的资源问题并有效保护野生资源,我国在新疆的南疆地区大力推广管花肉苁蓉的人工栽培,目前已取得了可喜的成果。该文利用1H-NMR技术能够全面提供定性和定量信息的优点,深入地比较管花肉苁蓉野生品和栽培品的化学成分组,以期为栽培品替代野生品使用的科学性提供直接证据。野生品和栽培品药材提取后,平行采集1H-NMR图谱;通过直观比较,发现2组图谱间相似度较高;通过与对照品及数据库(如HMDB,BMRB等)比对,从典型图谱中初步鉴定了28个化学成分;利用多元统计学手段比较野生品和栽培品的1H-NMR图谱,发现两组样品间并不存在显著差异。统计结果表明,从化学成分组成而言,管花肉苁蓉的野生品与栽培品相似度高,一定程度上证明栽培品可以替代野生品使用。同时,1H-NMR技术能够反映中药提取物等复杂体系的定量化学成分组,在中药化学成分定性和定量分析领域具有较为广泛的应用前景。 展开更多
关键词 ^1H-NMR技术 管花肉苁蓉 化学成分组 野生品 栽培品
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利用直接注射-多级质谱全扫描法快速分析片仔癀化学成分组 被引量:4
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作者 贾金茹 李菡 +3 位作者 屠鹏飞 于娟 赵云芳 宋月林 《中国中药杂志》 CAS CSCD 北大核心 2022年第13期3501-3510,共10页
名优中药片仔癀(Pien-Tze-Huang,PTH)为国家绝密配方,目前公布的组成药味包括三七、牛黄、蛇胆、麝香,具有清热解毒、凉血化瘀、消肿止痛等功效。阐明片仔癀的化学成分组成,是建立其质量标准、揭示体内药效物质和作用机制的前提。因此,... 名优中药片仔癀(Pien-Tze-Huang,PTH)为国家绝密配方,目前公布的组成药味包括三七、牛黄、蛇胆、麝香,具有清热解毒、凉血化瘀、消肿止痛等功效。阐明片仔癀的化学成分组成,是建立其质量标准、揭示体内药效物质和作用机制的前提。因此,该研究采用直接注射-多级质谱全扫描法(DI-MS/MS^(ALL))分析片仔癀样品,快速、深入地阐明片仔癀的化学成分组成。阐明中药化学成分组成的核心是构建MS^(1)-MS^(2)数据列表,并进一步根据多级质谱信息鉴定化学结构。多级质谱全扫描技术(MS/MS^(ALL))采用气态分段技术(GPF),结合质谱高灵敏度、高分辨率、特异性强的优势,可以在直接注射(DI)模式下采集每个表观质量数窗口的二级质谱图,快速实现MS^(1)-MS^(2)数据列表的构建,进而根据所得到的高分辨MS~1和MS~2质谱数据推导质谱裂解途径,并结合数据库检索以及相关文献数据匹配。从片仔癀中初步鉴定了52个化学成分的结构,包括16个皂苷类化合物、24个胆汁酸类化合物、9个脂肪酸类化合物、2个糖类化合物以及1个其他类化合物。与传统的LC-MS相比,DI-MS/MS^(ALL)分析时间短,可以同时检测不同极性的化学成分。因此,该研究采用DI-MS/MS^(ALL)技术全面、快速地阐明片仔癀的化学成分组成,同时为中药复方化学成分组成快速、全面定性分析提供了有力的分析工具。 展开更多
关键词 直接注射-多级质谱全扫描 片仔癀 化学成分组 MS^(1)-MS^(2)数据列表 质谱裂解途径
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基于HPLC特征图谱、UPLC-Q-TOF/MS定性及多成分定量的黄芩酒炙前后化学成分变化研究 被引量:40
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作者 柴冲冲 曹妍 +8 位作者 毛民 尹贻慧 王靖越 刘娜 李欣欣 张凯 魏龙吟 陈冬玲 李飞 《中草药》 CAS CSCD 北大核心 2020年第9期2436-2447,共12页
目的比较黄芩酒炙前后化学成分变化,为建立全面的黄芩饮片质量评价方法提供参考。方法HPLC法建立黄芩片、酒黄芩的特征图谱,并生成对照特征图谱,标定共有峰并进行相似度评价。采用UPLC-Q-TOF/MS定性分析黄芩酒炙前后化学成分,利用UPLC-T... 目的比较黄芩酒炙前后化学成分变化,为建立全面的黄芩饮片质量评价方法提供参考。方法HPLC法建立黄芩片、酒黄芩的特征图谱,并生成对照特征图谱,标定共有峰并进行相似度评价。采用UPLC-Q-TOF/MS定性分析黄芩酒炙前后化学成分,利用UPLC-TQMS对2种饮片中11种黄酮类成分(黄芩苷、黄芩素、汉黄芩苷、汉黄芩素、千层纸素A、千层纸苷、野黄芩苷、芹菜素、高车前素、木犀草苷、白杨素)进行定量分析,并以含量为变量进行多元统计分析。结果建立了黄芩片、酒黄芩的特征图谱,标定9个共有峰,2种饮片相似度均在0.947以上。在黄芩饮片中,共发现50种成分,通过多级质谱数据分析,保留时间匹配,并结合对照品及数据库检索,鉴定了其中44种成分。UPLC-TQMS定量结果显示酒炙后黄芩中黄芩苷、汉黄芩苷等黄酮苷类成分含量略有下降,黄芩素、汉黄芩素等黄酮苷元类成分含量稍有增加。经多元统计学分析,2种饮片有明显的分离趋势,载荷图结果表明黄芩苷、汉黄芩苷、千层纸苷的含量差异可能是引起黄芩酒炙前后化学成分变化的主要因素。结论黄芩酒炙后没有新增或消失成分,但成分含量有所变化。所建立黄芩饮片的定性、定量方法重现性好,分析快速、准确,可用于黄芩饮片酒炙前后的质量评价。 展开更多
关键词 黄芩 酒黄芩 HPLC 特征图谱 UPLC-Q-TOF/MS UPLC-TQMS 化学成分组 多元统计学分析 质量评价 相似度评价 黄芩苷 黄芩素 汉黄芩苷 汉黄芩素 千层纸素A 千层纸苷 野黄芩苷 芹菜素 高车前素 木犀草苷 白杨素
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Microstructure of TA2/TA15 graded structural material by laser additive manufacturing process 被引量:29
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作者 钱婷婷 刘栋 +2 位作者 田象军 刘长猛 王华明 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第9期2729-2736,共8页
TA2/TA15 graded structural material(GSM) was fabricated by the laser additive manufacturing(LAM) process. The chemical composition, microstructure and micro-hardness of the as-deposited GSM were investigated. The ... TA2/TA15 graded structural material(GSM) was fabricated by the laser additive manufacturing(LAM) process. The chemical composition, microstructure and micro-hardness of the as-deposited GSM were investigated. The results show that the TA2 part of exhibiting near-equiaxed grains was Widmanst?tten α-laths microstructure. The TA15 part containing large columnar grains was fine basket-weave microstructure. The graded zone was divided into four deposited layers with 3000 μm in thickness. As the distance from the TA2 part increases, the alloy element contents and the β phase volume fraction increase, the α phase volume fraction decreases and the microstructure shows the evolution from Widmanst?tten α-laths to basket-weave α-laths gradually. The micro-hardness increases from the TA2 part to the TA15 part due to the solid solution strengthening and grain boundary strengthening. 展开更多
关键词 laser additive manufacturing TA2/ TA15 graded structural material MICROSTRUCTURE chemical composition
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The automobile steel of the third generation in B-pillar reinforced panel 被引量:2
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作者 Du Huijun Li Shuli +2 位作者 Yang Jie Yang Hongxin Bai Kebin 《Engineering Sciences》 EI 2012年第6期20-22,共3页
The fundamental research and industry, trials of the third generation automobile steel QP980 were introduced in this paper, including chemical ingredient, mechanical properties, microstructure, forming limit and basic... The fundamental research and industry, trials of the third generation automobile steel QP980 were introduced in this paper, including chemical ingredient, mechanical properties, microstructure, forming limit and basic perform- ance parameters. The application of QP steel of the B-pillar was researched, and the QP980, DP600 and hot forming steel were compared in the aspect of formability, safety and cost. The resuhs showed that the QP980 replacing DP600 steel single piece carl reduce the weight by 2.4 kg. The security and performance is basically the same as that of hot forming steel using 22MnB5, and the cost is reduced by 30 %. 展开更多
关键词 the third generation automobile steel B-pillar reintorced panel boron steel
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Production and Quality Evaluation of Wild Peper (Erythrococoa anomala) Flavoured Chocolate Drinks 被引量:1
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作者 E. A. Akande D. D. Okunola 《Journal of Agricultural Science and Technology(A)》 2011年第5期672-677,共6页
Work on the production and quality evaluation ofE. anomala spiced chocolate drinks was reported. This is done in order to establish the best concentration of the spice to be adopted in the chocolate drinks production.... Work on the production and quality evaluation ofE. anomala spiced chocolate drinks was reported. This is done in order to establish the best concentration of the spice to be adopted in the chocolate drinks production. E. anomala seed powder was added into chocolate formulation in various concentrations [1%, 2%, 3%, 4%, as samples A, B, C, D with sample E as the control (no spice added)]. These samples were analyzed for difference quality attributes like: the proximate composition, minerals and chemical analysis, microbiological analysis, as well as the sensory evaluation using standard methods. The proximate composition showed the percentage moisture content ranging between 85.1 ±0.11 and 85.5± 0.10, ash content between 0.4 ± 0.00 and 0.5 ± 0.10, protein content between 1.0± 0.01 and 1.1 ± 0.11, fat content between 0.4 ± 0.1 land 0.5 ± 0.00 and carbohydrate content between 12.5 ±0.10 and 12.7 ±0.10. The minerals: 0.05 ±0.10 mg/kg, zinc: 0.01 4- 0.11 mg/kg, lead: 0.1 ± 0.10 mg/kg, and copper 0.1±0.1/l mg/kg, Mangeulese were obtained while cadmium was not detected at all. The chemical analysis gave between 5.03 ± 0. l t to 5.35 ±0.10, and pH 3.17 ± 0.10 to 3.67± 0.10, and total titratable acidity between 32.47 ± 0.10 to 32.50 ±0.10 tbr Brix. ttowever, sample C (3%) E. anomala spiced chocolate drink has the highest nutrients composition than all the other samples. All the samples have low microbial count, less than 3.5 ×10^3 load which is below the safe level of 1.0 ×10^3 but on the overall, sample C has the least value. Conclusively, smnple C, (chocolate spiced at 3% concentration) is established as the best sample nutritionally, microbiologically and on the overall acceptability. 展开更多
关键词 CHOCOLATE wild peper (Erythrococoa anomala) NUTRIENTS microbial SENSORY
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Properties of Bio-oil from Fast Pyrolysis of Rice Husk 被引量:14
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作者 郭秀娟 王树荣 +2 位作者 王琦 郭祚刚 骆仲泱 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第1期116-121,共6页
Physicochemical properties of bio-oil obtained from fast pyrolysis of rice husk were studied in the present work.Molecular distillation was used to separate the crude bio-oil into three fractions viz.light fraction,mi... Physicochemical properties of bio-oil obtained from fast pyrolysis of rice husk were studied in the present work.Molecular distillation was used to separate the crude bio-oil into three fractions viz.light fraction,middle fraction and heavy fraction.Their chemical composition was analyzed by gas chromatograph and mass spectrometer(GC-MS).The thermal behavior,including evaporation and decomposition,was investigated using thermogravimetric analyzer coupled with Fourier transform infrared spectrometer(TG-FTIR).The product distribution was significantly affected by contents of cellulose,hemicellulose and lignin.The bio-oil yield was 46.36%(by mass) and the yield of gaseous products was 27%(by mass).The chemicals in the bio-oil included acids,aldehydes,ketones,alcohols,phenols,sugars,etc.The light fraction was mainly composed of acids and compounds with lower boiling point temperature,the middle and heavy fractions were consisted of phenols and levoglucosan.The thermal stability of the bio-oil was determined by the interactions and intersolubility of compounds.It was found that the thermal stability of bio-oil was better than the light fraction,but worse than the middle and heavy fractions. 展开更多
关键词 biochemical engineering BIO-OIL fast pyrolysis DECOMPOSITION DISTILLATION
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The Effect of Urea Treatment on the Chemical Composition and Rumen Degradability of Sorghum Stover
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作者 Selma A. B. Abdallah Amir M. Salih 《Journal of Agricultural Science and Technology(A)》 2012年第4期489-494,共6页
The objectives of the study were to investigate the effects of different levels of urea treatments on chemical composition, nutritional value and rumen degradability of sorghum stover. Two groups of animals were used ... The objectives of the study were to investigate the effects of different levels of urea treatments on chemical composition, nutritional value and rumen degradability of sorghum stover. Two groups of animals were used in this experiment. The first group, which served as control, was offered untreated sorghum stover. The other, the experiment group recived sorghum stover to which was added 2%, or 4% urea. Crude protein (CP) content of the treated sorghum was enhanced (P 〈 0.05) over the untreated one, and ranked as 7.30% and 6.05% CP for 4% and 2% respectively. Nutrient detergent fiber (NDF) content was decreased (P 〈 0.05) from 92.5% (control) to 89.8% and 87.8% for 2% and 4% urea respectively.Ether extract (EE) content was decreased (P 〈 0.05) from 1.77% (control) to 1.63% and 0.82% for 2% and 4% respectively. The rumen degradability was increased (P 〈 0.05) from 59.2% (control) to 64.2%, and 67.2% for 2%, and 4% sorghum and in hours 0, 4, 8, 16, 24, 48, 72 and 96. 展开更多
关键词 Sorghum stover urea treatment rumen degradability
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Research on the integration of the mathematical culture into the mathematical teaching in universities
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作者 Ying Cao Yuan Qingshan Xu Xin 《International English Education Research》 2015年第1期11-13,共3页
In the university education, the mathematical teaching is an important and indispensable part. And now the integration of the mathematical culture in the university teaching is the effective method to improve the time... In the university education, the mathematical teaching is an important and indispensable part. And now the integration of the mathematical culture in the university teaching is the effective method to improve the timeliness of the teaching and the enthusiasm of the students, and it also can effectively alleviate the problem of the disconnection in the university mathematical teaching, with the successful implementation of the transition. The university mathematics has very high demands in the teaching contents, the teaching ideas and the teaching methods, so the reasonable integration of the mathematical culture into the university mathematics is very important. The mathematical culture in the teaching of college mathematics is discussed and analyzed in this paper. 展开更多
关键词 University mathematical teaching mathematical culture RESEARCH
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Cultural Orientation Through Public Speaking Contests
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作者 Lyudmila Chikileva 《Sino-US English Teaching》 2013年第10期806-811,共6页
Learning about culture is an integral part of learning a fbreign language. Participating in speech contests gives language learners a good opportunity to know more about the culture of the target language. Such contes... Learning about culture is an integral part of learning a fbreign language. Participating in speech contests gives language learners a good opportunity to know more about the culture of the target language. Such contests allow students to learn how to write a speech for a particular audience, how to introduce a speaker, how to deliver a speech, and how to say "thank you" to the speaker. Participation in speech contests can promote insight and understanding through a comparison of American culture and the students' native culture. Such comparison is intended to promote better understanding of both cultures. 展开更多
关键词 public speaking speech contests communication goals sociocultural education intercultural communication
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On the Social Influences of News Photography
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作者 CHENG Yu DENG Kaifa 《International English Education Research》 2016年第12期12-14,共3页
The continuous development of the society gave birth to the photography technologies, and the science and technology has provided the impetus and support for the enhancement of the levels of the photography technologi... The continuous development of the society gave birth to the photography technologies, and the science and technology has provided the impetus and support for the enhancement of the levels of the photography technologies. The news photography, as an important part of the photography, contains a wealth of the cultural connotations, which have a great impact on all areas of the society. With the development of the photography technologies, their impact on the society is more in-depth, and the author of this paper carries out the analysis and research from several aspects. 展开更多
关键词 News photography social impact DEVELOPMENT
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On the Status and Role of Physical Education in the Construction of Campus Culture
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作者 Qian LIU - 《International Journal of Technology Management》 2015年第4期21-23,共3页
Physical education is an important part of campus culture construction, is the most widely used form of contact with teachers and students with most dynamic, most innovative culture. This paper analyzes the content of... Physical education is an important part of campus culture construction, is the most widely used form of contact with teachers and students with most dynamic, most innovative culture. This paper analyzes the content of physical education, form, composition and structure of the campus culture, to clarify the position and role of school physical education in the construction of campus culture, so that physical education plays a greater role in the construction of campus culture. 展开更多
关键词 Action Sports Culture Status Education Campus
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Research on organization and planning of non-art department's large-scale theatrical show in colleges
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作者 Xinyuan Guo 《International Journal of Technology Management》 2013年第7期4-6,共3页
College gala, as an important part of campus culture, is one of the important channels to advance the college students' cultural level and artistic taste and play an important role in creating a cultural atmosphere i... College gala, as an important part of campus culture, is one of the important channels to advance the college students' cultural level and artistic taste and play an important role in creating a cultural atmosphere in college. Gala as a widely popular form loved by college students brings together a variety of art forms, with its rich content and distinctive style, which enables viewers to watch different forms of performance in a short period of time. Universities gala melts artistic, entertaining and educational role in one and combines ideological guidance with lively art forms to actively promote the construction of campus culture, disseminate correct, positive and healthy ideas and culture, show the campus features with contemporary characteristics to society, create a healthy educational environment and establish a good image of college. 展开更多
关键词 ORGANIZATION planning large-scale theatrical show.
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Effects of Physical Education on Campus Culture Construction
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作者 Qinggui HUANG 《International Journal of Technology Management》 2015年第5期50-52,共3页
Physical education is an important part of campus culture of the body, it has become one of the main ways for modem college students to relax, and it has a positive impact on construction of campus culture. So attenti... Physical education is an important part of campus culture of the body, it has become one of the main ways for modem college students to relax, and it has a positive impact on construction of campus culture. So attention to sports participation of college students and promoting college students actively to join in sports activities has become an important part of the construction of campus culture. Universities undertake the mission to train highly qualified personnel, it should guide students to participate in various forms of physical activity related to local conditions, and we establish certain style and taste of the campus culture. This paper aims to identify the impact of college students' physical conditions to construction of campus culture, so as to develop and improve the main sports participation consciousness of students in sport, we hope that we can comprehensively improve the quality of university education for better college students sports activities and to create a harmonious, strong campus culture. 展开更多
关键词 physical education campus culture IMPACT
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Mineral weathering and element cycling in soil-microorganism-plant system 被引量:16
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作者 ZHU YongGuan DUAN GuiLan +3 位作者 CHEN BaoDong PENG XinHua CHEN Zheng SUN GuoXin 《Science China Earth Sciences》 SCIE EI CAS 2014年第5期888-896,共9页
Soil is an essential part of the critical zone,and soil-microbe-plant system serves as a key link among lithosphere,biosphere,atmosphere and hydrosphere.As one of the habitats with the richest biodiversity,soil plays ... Soil is an essential part of the critical zone,and soil-microbe-plant system serves as a key link among lithosphere,biosphere,atmosphere and hydrosphere.As one of the habitats with the richest biodiversity,soil plays a critical role in element biogeochemistry on the earth surface(weathered crust).Here we review the soil biological processes that are relevant to mineral weathering,element cycling,and transformation,with an emphasis on rock weathering mediated by soil microbes,plant root and the rhizosphere. 展开更多
关键词 SOIL PLANT MICROORGANISM GEOBIOLOGY
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Synthesis and self-assembly of novel oxacalix[2]arene[2]triazine amphiphiles 被引量:1
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作者 Ruibin Xu Baoyong Hou +1 位作者 Dexian Wang Meixiang Wang 《Science China Chemistry》 SCIE EI CAS CSCD 2016年第10期1306-1310,共5页
Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-altern... Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-alternate conformation and can be easily functionalized. Taking it as a platform, a series of oxacalix[2]arene[2]triazine-based amphiphiles bearing long alkyl chains were synthesized through post-macrocyclization functionalization or 3+1 fragment coupling protocols. The self-assembly behavior of these arnphiphiles in a mixture of tetrahydrofuran (THF) and water was investigated. Dynamic light scattering (DLS) measurements revealed that the size of the self-assembled aggregates is dependent on the structure of the amphiphiles. The long alkyl chain substituents and/or interrnolecular hydrogen bonds were found to promote the self-assembly. 展开更多
关键词 arene[2]triazine heteracalixaromatics AMPHIPHILE SELF-ASSEMBLY
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Applications of pillarenes, an emerging class of synthetic macrocycles 被引量:1
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作者 SONG Nan YANG Ying-Wei 《Science China Chemistry》 SCIE EI CAS 2014年第9期1185-1198,共14页
Synthetic macrocycles, a typical type of building block for molecular recognition and self-assembly, are crucial to supramolecular chemistry and materials science. Since 2008, a new generation of synthetic macrocyclic... Synthetic macrocycles, a typical type of building block for molecular recognition and self-assembly, are crucial to supramolecular chemistry and materials science. Since 2008, a new generation of synthetic macrocyclic hosts, pillarenes and their abundant derivatives, which consist of hydroquinone units linked by methylene bridges at 2,5-positions, have been the focus of much research. Numerous studies on their host-guest properties and the fabrication of supramolecular assemblies have demon- strated that pillarenes and their derivatives possess many advantages that facilitate their applications in many research fields. Herein we summarize and classitfy the applications of pillarenes in terms of artificial transmembrane channels, controlled delivery systems, dispersion of carbon hybrid materials, extraction and absorption, liquid crystals, metal-organic frameworks, sensing and detection, stabilization of nanoparticles (Au/Ag/CdTe), and other typical biological applications. We also provide an overview of future developments in pillarene chemistry. 展开更多
关键词 drug delivery host-guest interactions macrocycles pillarenes supramolecular materials
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