This paper proposes a novel complex network with assortative property based on multi-center networks. The average path length and clustering coefficient of the network are calculated, and the impact on the network top...This paper proposes a novel complex network with assortative property based on multi-center networks. The average path length and clustering coefficient of the network are calculated, and the impact on the network topology is investigated. A simple dynamic system established on the proposed network is used to analyze how the assortative property of the network affects synchronization.展开更多
IEEE 802.11 distributed coordination function （DCF） is a distributed medium access scheme based on carrier sense multiple access with collision avoidance （CSMA/CA） protocol. Many literatures have analyzed the perf...IEEE 802.11 distributed coordination function （DCF） is a distributed medium access scheme based on carrier sense multiple access with collision avoidance （CSMA/CA） protocol. Many literatures have analyzed the performance of IEEE802.11 DCF. However, such literatures either used simulation methods or built the analytical models under the assumption that the saturation condition was satisfied. To overcome such a problem, in this paper, a hi-dimensional Markovian model has been introduced to depict the DCF mechanism. The proposed model introduced an idle stage and a discrete time M/G/1 queue to deduce the channel throughput under finite load traffic. Simulation results proved the accuracy of the proposed model.展开更多
The co-channel interference modeling is vital for evaluating the secrecy performance in random wireless networks,where the legitimate nodes and eavesdroppers are randomly distributed.In this paper,a new interference m...The co-channel interference modeling is vital for evaluating the secrecy performance in random wireless networks,where the legitimate nodes and eavesdroppers are randomly distributed.In this paper,a new interference model is proposed from the userdominant perspective.The model can provide a better analytical assessment of secrecy performance with interference coordination for the presence of eavesdroppers.The typical legitimate is assumed to be located at the origin,and chooses the closest base station(BS) as its serving BS.The field of interferers is obtained by excluding the desired BSs(including the serving BS and its cooperative BS(s)).In contract with the exiting interference model,it is assumed that desired BSs and interferers belong to the same Poisson Point Process(PPP),and eavesdroppers are distributed according to another independent PPP.Based on this model,the average secrecy transmission capacity is derived in simply analytical forms with interference coordination.Analysis and simulation results show that the secrecy performance can be significantly enhanced by exploiting interference coordination.Furthermore,the average secrecy transmission capacity increases with increasing number of cooperative BSs.展开更多
The performance of three wireless local-area network(WLAN) media access control(MAC) protocols is investigated and compared in the context of simulcast radioover-fiber-based distributed antenna systems(RoF-DASs) where...The performance of three wireless local-area network(WLAN) media access control(MAC) protocols is investigated and compared in the context of simulcast radioover-fiber-based distributed antenna systems(RoF-DASs) where multiple remote antenna units(RAUs) are connected to one access point(AP) with different-length fiber links.The three WLAN MAC protocols under investigation are distributed coordination function(DCF) in basic access mode,DCF in request/clear to send(RTS/CTS) exchange mode,and point coordination function(PCF).In the analysis,the inter-RAU hidden nodes problems and fiber-length difference effect are both taken into account.Results show that adaptive PCF mechanism has better throughput performances than the other two DCF modes,especially when the inserted fiber length is short.展开更多
Engineering the electronic properties of catalysts to target intermediate adsorption energy as well as harvest high selectivity represents a promising strategy to design advanced electrocatalysts for efficient CO_(2) ...Engineering the electronic properties of catalysts to target intermediate adsorption energy as well as harvest high selectivity represents a promising strategy to design advanced electrocatalysts for efficient CO_(2) electroreduction.Herein,a synergistical tuning on the electronic structure of the Cd Se nanorods is proposed for boosting electrochemical reduction of CO_(2) .The synergy of Ag doping coupled with Se vacancies tuned the electronic structure of the CdSe nanorods,which shows the metalloid characterization and thereby the accelerated electron transfer of CO_(2) electroreduction.Operando synchrotron radiation Fourier transform infrared spectroscopy and theoretical simulation revealed that the Ag doping and Se vacancies accelerated the CO_(2) activation process and lowered the energy barrier for the conversion from CO_(2) to;COOH;as a result,the performance of CO_(2) electroreduction was enhanced.The as-obtained metalloid Ag-doped CdSe nanorods exhibited a 2.7-fold increment in current density and 1.9-fold Faradaic efficiency of CO compared with the pristine CdSe nanorod.展开更多
It is a great challenge to prepare non-noble metal electrocatalysts toward hydrogen evolution reaction(HER)with large current density.Synergistic electronic and morphological structures of the catalyst have been consi...It is a great challenge to prepare non-noble metal electrocatalysts toward hydrogen evolution reaction(HER)with large current density.Synergistic electronic and morphological structures of the catalyst have been considered as an effective method to improve the catalytic performance,due to the enhanced intrinsic activity and enlarged accessible active sites.Herein,we present novel ternary Co_(1-x)V_(x)P nanoneedle arrays with modulated electronic and morphological structures as an electrocatalyst for highly efficient HER in alkaline solution.The NF@Co1-xVxP catalyst shows a remarkable catalytic ability with low overpotentials of 46 and 226 mV at current densities of 10 and 400 mA cm^(-2),respectively,as well as a small Tafel slope and superior stability.Combining the experimental and computational study,the excellent catalytic performance was attributed to the improved physical and chemical properties(conductivity and surface activity),large active surface area,and fast reaction kinetics.Furthermore,the assembled Co–V based electrolyzer(NF@Co_(1-x)V_(x)–HNNs(+)||NF@Co_(1-x)V_(x)P(-))delivers small full-cell voltages of 1.58,1.75,and 1.92 V at 10,100,and 300 mA cm^(-2),respectively.Our findings provide a systematic understanding on the V–incorporation strategy to promote highly efficient ternary electrocatalysts via synergistic control of morphology and electronic structures.展开更多
基金The project supported by National Natural Science Foundation of China Under Grant Nos. 10672093, 10372054t and 70431002
文摘This paper proposes a novel complex network with assortative property based on multi-center networks. The average path length and clustering coefficient of the network are calculated, and the impact on the network topology is investigated. A simple dynamic system established on the proposed network is used to analyze how the assortative property of the network affects synchronization.
文摘IEEE 802.11 distributed coordination function （DCF） is a distributed medium access scheme based on carrier sense multiple access with collision avoidance （CSMA/CA） protocol. Many literatures have analyzed the performance of IEEE802.11 DCF. However, such literatures either used simulation methods or built the analytical models under the assumption that the saturation condition was satisfied. To overcome such a problem, in this paper, a hi-dimensional Markovian model has been introduced to depict the DCF mechanism. The proposed model introduced an idle stage and a discrete time M/G/1 queue to deduce the channel throughput under finite load traffic. Simulation results proved the accuracy of the proposed model.
基金This work is supported by the National Natural Science Foundation for Distinguished Young Scholar of China under Grant No. 61325006 and the National High-tech Research and Development Program of China under Grant No. 2014AA01A701.
文摘The co-channel interference modeling is vital for evaluating the secrecy performance in random wireless networks,where the legitimate nodes and eavesdroppers are randomly distributed.In this paper,a new interference model is proposed from the userdominant perspective.The model can provide a better analytical assessment of secrecy performance with interference coordination for the presence of eavesdroppers.The typical legitimate is assumed to be located at the origin,and chooses the closest base station(BS) as its serving BS.The field of interferers is obtained by excluding the desired BSs(including the serving BS and its cooperative BS(s)).In contract with the exiting interference model,it is assumed that desired BSs and interferers belong to the same Poisson Point Process(PPP),and eavesdroppers are distributed according to another independent PPP.Based on this model,the average secrecy transmission capacity is derived in simply analytical forms with interference coordination.Analysis and simulation results show that the secrecy performance can be significantly enhanced by exploiting interference coordination.Furthermore,the average secrecy transmission capacity increases with increasing number of cooperative BSs.
基金supported in part by National 973 Program(2012CB315705)NSFC Program(61302086,61271042,61107058, 61302016,and 61335002)+2 种基金Specialized Research Fund for the Doctoral Program of Higher Education(20130005120007)Program for New Century Excellent Talents in University(NCET-13-0682)Fundamental Research Funds for the Central Universities
文摘The performance of three wireless local-area network(WLAN) media access control(MAC) protocols is investigated and compared in the context of simulcast radioover-fiber-based distributed antenna systems(RoF-DASs) where multiple remote antenna units(RAUs) are connected to one access point(AP) with different-length fiber links.The three WLAN MAC protocols under investigation are distributed coordination function(DCF) in basic access mode,DCF in request/clear to send(RTS/CTS) exchange mode,and point coordination function(PCF).In the analysis,the inter-RAU hidden nodes problems and fiber-length difference effect are both taken into account.Results show that adaptive PCF mechanism has better throughput performances than the other two DCF modes,especially when the inserted fiber length is short.
基金supported by the National Natural Science Foundation of China(12025505 and 21873050)China Ministry of Science and Technology(2017YFA0208300)+1 种基金the Open Fund Project of State Key Laboratory of Environmentally Friendly Energy Materials(20KFHG08)the Youth Innovation Promotion Association CAS(CX2310007007 and CX2310000091)。
文摘Engineering the electronic properties of catalysts to target intermediate adsorption energy as well as harvest high selectivity represents a promising strategy to design advanced electrocatalysts for efficient CO_(2) electroreduction.Herein,a synergistical tuning on the electronic structure of the Cd Se nanorods is proposed for boosting electrochemical reduction of CO_(2) .The synergy of Ag doping coupled with Se vacancies tuned the electronic structure of the CdSe nanorods,which shows the metalloid characterization and thereby the accelerated electron transfer of CO_(2) electroreduction.Operando synchrotron radiation Fourier transform infrared spectroscopy and theoretical simulation revealed that the Ag doping and Se vacancies accelerated the CO_(2) activation process and lowered the energy barrier for the conversion from CO_(2) to;COOH;as a result,the performance of CO_(2) electroreduction was enhanced.The as-obtained metalloid Ag-doped CdSe nanorods exhibited a 2.7-fold increment in current density and 1.9-fold Faradaic efficiency of CO compared with the pristine CdSe nanorod.
基金the National Natural Science Foundation of China(21671096,21603094 and21905180)the Natural Science Foundation of Guangdong Province(2018B030322001 and 2018A030310225)+4 种基金Shenzhen Peacock Plan(KQTD2016022620054656)Shenzhen Key Laboratory Project(ZDSYS201603311013489)the Basic Research Project of the Science and Technology Innovation Commission of Shenzhen(JCYJ20190809115413414)the Science and Technology Development Fund from Macao SAR(FDCT–0102/2019/A2,FDCT–0035/2019/AGJ and FDCT–0154/2019/A3)the Multi-Year Research Grants(MYRG2017–00027–FST and MYRG2018–00003–IAPME)from the University of Macao。
文摘It is a great challenge to prepare non-noble metal electrocatalysts toward hydrogen evolution reaction(HER)with large current density.Synergistic electronic and morphological structures of the catalyst have been considered as an effective method to improve the catalytic performance,due to the enhanced intrinsic activity and enlarged accessible active sites.Herein,we present novel ternary Co_(1-x)V_(x)P nanoneedle arrays with modulated electronic and morphological structures as an electrocatalyst for highly efficient HER in alkaline solution.The NF@Co1-xVxP catalyst shows a remarkable catalytic ability with low overpotentials of 46 and 226 mV at current densities of 10 and 400 mA cm^(-2),respectively,as well as a small Tafel slope and superior stability.Combining the experimental and computational study,the excellent catalytic performance was attributed to the improved physical and chemical properties(conductivity and surface activity),large active surface area,and fast reaction kinetics.Furthermore,the assembled Co–V based electrolyzer(NF@Co_(1-x)V_(x)–HNNs(+)||NF@Co_(1-x)V_(x)P(-))delivers small full-cell voltages of 1.58,1.75,and 1.92 V at 10,100,and 300 mA cm^(-2),respectively.Our findings provide a systematic understanding on the V–incorporation strategy to promote highly efficient ternary electrocatalysts via synergistic control of morphology and electronic structures.
