Goethite, a typical iron-containing monomineral in red mud, was synthesized under the simulated Bayer digestion condition during the alumina production. The effects of dissolved organic compounds including sodium ...Goethite, a typical iron-containing monomineral in red mud, was synthesized under the simulated Bayer digestion condition during the alumina production. The effects of dissolved organic compounds including sodium formate, sodium acetate, sodium oxalate, sodium salicylate and disodium phthalate on the settling performance of goethite slurries were studied. The settling performance of the slurries was also investigated with the addition of self-made hydroxamated polyacrylamide flocculant （HCPAM）. The adsorption mechanism of dissolved organic compounds on the goethite surfaces was studied by FT-IR and XPS, respectively. The results show that the addition of organic compounds lowers the settling performance of the slurries and a deterioration in settling performance is observed in the order of sodium oxalate 〉 sodium salicylate （~ disodium phthalate） 〉 sodium formate 〉 sodium acetate. Moreover, HCPAM can efficiently eliminate the negative effects of sodium formate, sodium acetate and sodium oxalate on the settling performance of the goethite slurries, but it can only partially improve the settling performance of the goethite slurries containing sodium salicylate or disodium phthalate. FT-IR and XPS results show that these organic compounds are chemically adsorbed on the goethite surface.展开更多
This paper presents a case study of water inrush and mud burst occurring in a migmatite tunnel to study its formation mechanisms. The geological investigation and mineralogical analysis showed that water inrush and mu...This paper presents a case study of water inrush and mud burst occurring in a migmatite tunnel to study its formation mechanisms. The geological investigation and mineralogical analysis showed that water inrush and mud burst in the migmatite was closely related to the component of the host rock. High content of soluble minerals,e.g.,calcite and dolomite,would make the migmatite rock prone to be fragmentized,isintegrated and eventually form different sorts of connected or semi-connected veins. The field exploration revealed most cavities in the magmatite tunnel were eroded by groundwater and formed large interconnected networks. The two faults and the dike in the magmatite tunnel became the preferred paths and provided great convenience for plenty of precipitation and mud slurry. Due to high water pressure and blast disturbance,the cavities can soon connect each other as well as all sorts of veins,forming a complex ground channel for water inrush and mud burst. To estimate the potential occurrenceof water inrush and mud burst,the water bursting coefficient was employed. The results showed the water bursting coefficient of the magmatite tunnel was much bigger than the threshold values and it can be used to explain the accident of water inrush and mud burst occurring in the magmatite tunnel.展开更多
Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulv...Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulvic acid could promote leachability and vertical transference of all the mineral-bound Hg. Brown humic acid could retard the leaching and transferring processes of CaCO3-Hg, Fe2O3-Hg, MnO2-Hg and kaolinite Hg but not bentonite-Hg. Grey humic acid could greatly enhance residing ability of the mineral-bound Hg in the soil column and restrain them from vertical transferring. The effect of humus on leachability and transferring activity on the mineral-bound Hg was closely related to its ability to convert the mineral-bound Hg into organic-bound form and the transferability of the latter in the soil column. The characteristics of the mineral-bound Hg in speciation were the internal factors that determined the extent and rate of the influence of the humus.展开更多
The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial...The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial raw materials as a result of its processing, it was proposed to carry out a preliminary enrichment of the raw materials in order to produce secondary sublimates. Their further processing involves a combination of leaching soluble material with distillation of germanium in the form of tetrachloride. The resulting acidic solutions are trended to the gallium extraction. Optimum conditions of carrying out of processes are recommended.The chemical and phase composition of the resulting dump products and solutions have been defined. On the basis of it ways of their processing for the purpose of reception of alumina and building materials are recommended.展开更多
基金Projects(51174231,51134007)supported by the National Natural Science Foundation of China
文摘Goethite, a typical iron-containing monomineral in red mud, was synthesized under the simulated Bayer digestion condition during the alumina production. The effects of dissolved organic compounds including sodium formate, sodium acetate, sodium oxalate, sodium salicylate and disodium phthalate on the settling performance of goethite slurries were studied. The settling performance of the slurries was also investigated with the addition of self-made hydroxamated polyacrylamide flocculant （HCPAM）. The adsorption mechanism of dissolved organic compounds on the goethite surfaces was studied by FT-IR and XPS, respectively. The results show that the addition of organic compounds lowers the settling performance of the slurries and a deterioration in settling performance is observed in the order of sodium oxalate 〉 sodium salicylate （~ disodium phthalate） 〉 sodium formate 〉 sodium acetate. Moreover, HCPAM can efficiently eliminate the negative effects of sodium formate, sodium acetate and sodium oxalate on the settling performance of the goethite slurries, but it can only partially improve the settling performance of the goethite slurries containing sodium salicylate or disodium phthalate. FT-IR and XPS results show that these organic compounds are chemically adsorbed on the goethite surface.
基金support of the National Natural Science Foundation of China (Grant Nos.51379007,41130742)the support of the Chinese Fundamental Research (973)Program through the Grant No.2013CB036006
文摘This paper presents a case study of water inrush and mud burst occurring in a migmatite tunnel to study its formation mechanisms. The geological investigation and mineralogical analysis showed that water inrush and mud burst in the migmatite was closely related to the component of the host rock. High content of soluble minerals,e.g.,calcite and dolomite,would make the migmatite rock prone to be fragmentized,isintegrated and eventually form different sorts of connected or semi-connected veins. The field exploration revealed most cavities in the magmatite tunnel were eroded by groundwater and formed large interconnected networks. The two faults and the dike in the magmatite tunnel became the preferred paths and provided great convenience for plenty of precipitation and mud slurry. Due to high water pressure and blast disturbance,the cavities can soon connect each other as well as all sorts of veins,forming a complex ground channel for water inrush and mud burst. To estimate the potential occurrenceof water inrush and mud burst,the water bursting coefficient was employed. The results showed the water bursting coefficient of the magmatite tunnel was much bigger than the threshold values and it can be used to explain the accident of water inrush and mud burst occurring in the magmatite tunnel.
基金Project (No. 970601) supported by the State Education Commission, China.
文摘Effects of humus fractions (fulvic acid, brown humic acid and grey humic acid) on the leachability and transferring activity of five types of mineral-bound Hg were investigated. Under the acid leaching condition: fulvic acid could promote leachability and vertical transference of all the mineral-bound Hg. Brown humic acid could retard the leaching and transferring processes of CaCO3-Hg, Fe2O3-Hg, MnO2-Hg and kaolinite Hg but not bentonite-Hg. Grey humic acid could greatly enhance residing ability of the mineral-bound Hg in the soil column and restrain them from vertical transferring. The effect of humus on leachability and transferring activity on the mineral-bound Hg was closely related to its ability to convert the mineral-bound Hg into organic-bound form and the transferability of the latter in the soil column. The characteristics of the mineral-bound Hg in speciation were the internal factors that determined the extent and rate of the influence of the humus.
文摘The results to develop a complex technology of co-extraction of germanium and gallium from the ash-and-slag wastes of coal combustion in Ukraine were presented. Based on the study of phase changes occurring in initial raw materials as a result of its processing, it was proposed to carry out a preliminary enrichment of the raw materials in order to produce secondary sublimates. Their further processing involves a combination of leaching soluble material with distillation of germanium in the form of tetrachloride. The resulting acidic solutions are trended to the gallium extraction. Optimum conditions of carrying out of processes are recommended.The chemical and phase composition of the resulting dump products and solutions have been defined. On the basis of it ways of their processing for the purpose of reception of alumina and building materials are recommended.
