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(Ba_(1-x)Ca_x)(Ti_(0.82)Zr(0.18))O_3陶瓷结构与介电性能研究 被引量:5
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作者 那文菊 丁士华 +2 位作者 宋天秀 王久石 王岩 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2011年第6期655-658,共4页
采用固相反应法制备了(Ba1-xCax)(Ti0.82Zr0.18)O3(BCZT,0≤x≤0.26)陶瓷,研究了Ca2+掺杂对BCZT陶瓷微观结构和介电性能的影响.结果表明:当Ca2+掺杂量为0.16时,BCZT陶瓷出现第二相CaTiO3,其四方率c/a随Ca2+掺杂量的增加先减小再增大,当C... 采用固相反应法制备了(Ba1-xCax)(Ti0.82Zr0.18)O3(BCZT,0≤x≤0.26)陶瓷,研究了Ca2+掺杂对BCZT陶瓷微观结构和介电性能的影响.结果表明:当Ca2+掺杂量为0.16时,BCZT陶瓷出现第二相CaTiO3,其四方率c/a随Ca2+掺杂量的增加先减小再增大,当Ca2+掺杂量为0.06时达到最小值1.00276.通过容差因子和晶格参数的计算确认了Ca2+已进入到A位;随Ca2+掺杂量的增加,晶粒得到细化,居里温度向低温方向移动,介电峰被压低并展宽,且逐渐呈现铁电弥散性. 展开更多
关键词 BCZT陶瓷 固溶度 四方率c/a 介电性能
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甘氨酸对固相法合成钛酸钡粉体的影响
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作者 李雪梅 黄福祥 +3 位作者 龙敏 田中青 孟范成 罗晓阳 《无机盐工业》 CAS CSCD 北大核心 2023年第7期65-69,74,共6页
以BaCO_(3)和TiO_(2)为原料、甘氨酸为添加剂,采用固相法合成钛酸钡(BT)粉体。研究了不同合成温度和甘氨酸添加量对BT粉体性能的影响,利用XRD、BET、SEM、DSC、TG等手段对合成的BT粉体进行表征。结果表明,添加甘氨酸可以促进BaCO_(3)在... 以BaCO_(3)和TiO_(2)为原料、甘氨酸为添加剂,采用固相法合成钛酸钡(BT)粉体。研究了不同合成温度和甘氨酸添加量对BT粉体性能的影响,利用XRD、BET、SEM、DSC、TG等手段对合成的BT粉体进行表征。结果表明,添加甘氨酸可以促进BaCO_(3)在650℃附近分解,使BT粉体的合成温度降低50℃,在900℃就能得到纯相BT,在1000℃可以得到四方率(c/a)>1.010的BT粉体,但添加过量的甘氨酸使粉体粒径急剧增大反而会降低其性能;添加15%的甘氨酸在1000℃保温2 h可以得到c/a=1.0103、平均粒径为520 nm、k=9.00的BT粉体,其性能整体优于平均粒径为600 nm的商业BT粉。将二者在1280℃烧结2 h得到的陶瓷进行介电性能对比发现,商业粉室温和居里点介电常数略大于添加15%甘氨酸的合成粉,但室温下正交-四方的相变峰使介电损耗急剧增大。 展开更多
关键词 BaTiO_(3) 甘氨酸 四方率 k值 介电性能
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BiNbO_4掺杂对BaTiO_3陶瓷居里点的影响及微观性能研究
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作者 佘广益 张树人 +1 位作者 唐斌 周晓华 《材料开发与应用》 CAS 2009年第3期31-34,共4页
本文研究了BiNbO4掺杂对钛酸钡陶瓷居里点移动及微观性能的影响。实验结果表明,随着BiNbO4掺杂量的增加,钛酸钡陶瓷的四方率单调下降,而居里点先降低后升高,居里点的变化与陶瓷的微观应力变化一致。BiNbO4掺杂在0%-2%范围内时,... 本文研究了BiNbO4掺杂对钛酸钡陶瓷居里点移动及微观性能的影响。实验结果表明,随着BiNbO4掺杂量的增加,钛酸钡陶瓷的四方率单调下降,而居里点先降低后升高,居里点的变化与陶瓷的微观应力变化一致。BiNbO4掺杂在0%-2%范围内时,能有效抑制BaTiO3陶瓷晶粒的生长,有助于陶瓷烧结的致密化,但过分掺杂会使陶瓷晶粒间气孔率增加,并产生第二相。 展开更多
关键词 钛酸钡 四方率 微观应力 居里温度 铌酸铋
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A Four-Level Theory on Energy Transfer of the Light-Harvesting Complex Ⅱ in PS Ⅱ in Higher Plants 被引量:1
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作者 张舒 贺俊芳 +3 位作者 王水才 侯洵 李良璧 匡廷云 《Acta Botanica Sinica》 CSCD 2001年第8期795-800,共6页
With reference to the recent achivements about the structure, spectra and kinetics of light_harvesting complex (LHCⅡ) in PSⅡ of higher plants, a four_level model was provided to simulate the energy transfer process ... With reference to the recent achivements about the structure, spectra and kinetics of light_harvesting complex (LHCⅡ) in PSⅡ of higher plants, a four_level model was provided to simulate the energy transfer process from LHC Ⅱ to the reaction center. On the basis of this model, a set of rate equation was established. Analysis of its algebra solution led to a general picture of energy transfer process in LHC Ⅱ of higher plants and the strong interaction among pigment molecules in this process. Based on the spectra, kinetics and biological structural data providing some information of energy transfer path and energy dissipation mechanism, it has been found that energy transfer mainly happened between the pigments whose energy level was most closely adjacent, the loss of energy had a close relation to the process of energy transfer and tended to increase with the decrease of energy level. The protective mechanism of antenna system was also discussed. 展开更多
关键词 LHC four_level model rate equation energy transfer energy dissipation
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Debris Flow Susceptibility Assessment Using a Probabilistic Approach:A Case Study in the Longchi Area, Sichuan Province, China 被引量:18
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作者 CHANG Ming TANG Chuan +1 位作者 ZHANG Dan-dan MA Guo-chao 《Journal of Mountain Science》 SCIE CSCD 2014年第4期1001-1014,共14页
The Longchi area with the city of Dujiangyan, in the Sichuan province of China, is composed of Permian stone and diorites and Triassic sandstones and mudstones intercalated with slates. An abundance of loose co-seismi... The Longchi area with the city of Dujiangyan, in the Sichuan province of China, is composed of Permian stone and diorites and Triassic sandstones and mudstones intercalated with slates. An abundance of loose co-seismic materials were present on the slopes after the May 12, 2008 Wenchuan earthquake, which in later years served as source material for rainfall-induced debris flows or shallow landslides. A total of 48 debris flows, all triggered by heavy rainfall on 13th August 20l0, are described in this paper. Field investigation, supported by remote sensing image interpretation, was conducted to interpret the co-seismic landslides in the debris flow gullies. Specific characteristics of the study area such as slope, aspect, elevation, channel gradient, lithology, and gully density were selected for the evaluation of debris flow susceptibility. A score was given to all the debris flow gullies based on the probability of debris flow occurrence for the selected factors. In order to get the contribution of the different factors, principal component analyses were applied. A comprehensive score was obtained for the 48 debris flow gullies which enabled us to make a susceptibility map for debris flows with three classes. Twenty-two gullies have a high susceptibility, twenty gullies show a moderate susceptibility and six gullies have a low susceptibility for debris flows. 展开更多
关键词 Debris flow LANDSLIDE PROBABILITY Susceptibility assessment Grey correlation
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An Efficient and Accurate Spectral Method for Acoustic Scattering in Elliptic Domains
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作者 Qirong Fang Jie Shen Li-Lian Wang 《Numerical Mathematics(Theory,Methods and Applications)》 SCIE 2009年第3期258-274,共17页
An efficient and accurate method for solving the two-dimensional Helmholtz equation in domains exterior to elongated obstacles is developed in this paper.The method is based on the so called transformed field expansio... An efficient and accurate method for solving the two-dimensional Helmholtz equation in domains exterior to elongated obstacles is developed in this paper.The method is based on the so called transformed field expansion(TFE) coupled with a spectral-Galerkin solver for elliptical domain using Mathieu functions.Numerical results are presented to show the accuracy and stability of the proposed method. 展开更多
关键词 Acoustic scattering high-order methods boundary perturbations spectral-Galerkinmethods.
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Growth of Sr_2CuO_(3+δ) superconductor single crystals at high pressure 被引量:1
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作者 LIANG Wen LIU QingQing +3 位作者 LIU Liang KAKESHITA Teruhisa UCHIDA Shinichi JIN ChangQing 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2013年第4期691-693,共3页
We have successfully synthesized Sr 2 CuO3+δ single crystals under high pressure and high temperature for the first time. The structure analysis show that this material crystallizes into tetragonal structure isostruc... We have successfully synthesized Sr 2 CuO3+δ single crystals under high pressure and high temperature for the first time. The structure analysis show that this material crystallizes into tetragonal structure isostructural La 2 CuO4 with single CuO 2 plane. The magnetic susceptibility as well as resistance measurements indicates that the bulk superconductivity with the critical transition temperature 37 K is achieved in the crystal. 展开更多
关键词 apical oxygen effects high pressure high temperature Sr2 CuO 3+δ single crystal SUPERCONDUCTOR
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